• Title/Summary/Keyword: Cathodic

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Field emission property of the nitrogen doped diamond-like carbon film prepared by filtered cathodic vacuum arc technique (진공아크방전으로 제작된 다이아몬드상 탄소 박막의 질소 도우핑에 따른 전계 방출 특성)

  • Choi, M.S.;Kim, Y.S.;Lee, H.S.;Park, J.S.;Jeon, D.;Kim, J.K.
    • Proceedings of the KIEE Conference
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    • 1997.11a
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    • pp.273-275
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    • 1997
  • We fabricated the conventional silicon tips coated with a diamond-like carbon (DLC) film. The DLC films are prepared by the filtered cathodic vacuum arc (FCVA) technique. With increasing nitrogen content in DLC film, the work function($\phi$) and the turn-on voltage decrease and the emission current increases. This phenomenon is due to the fact that the Fermi-level moves to the conduction band by increasing nitrogen doping concentration. We have tested on the stability of the DLC film coated silicon tip during 2 hours at 500V.

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A study on the corrosion fatigue and cathodic protection of the welded zone between high tensile strength steel and general strength steel used for the shipbuilding (조선용 고장력강재와 보통강도강재간의 용접부위의 부식피로와 전기방식에 관한 연구)

  • 전대희;김원녕;이의호
    • Journal of Advanced Marine Engineering and Technology
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    • v.8 no.2
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    • pp.39-50
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    • 1984
  • The plane bending corrosion fatigue test was performed on the welded zone between SM58 steel plate and SM41 steel plate jointed with submerged arc welding in the air and in the natural sea water with various conditions. The main results obtained from the test are summarized as follows: 1) The welded zone of the steel plates has the lowest impact strength and the highest electrode potential, but the hardness was mediate of SM58 base and SM41 base. 2) The cathodic protection of the welded zone was also effective for the plane bending corrosion fatigue, and the optimum protection potential of the welded zone was -1,000 mV SCE. 3) The corrosion fatigue strength under the various stress conditions of the steel plate could be estimated and also the require safety factors on the design could be obtained from the plane bending fatigue limit diagram.

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Numerical Analysis of Cathodic Protection Effect by Sacrificial Anode Attached to Condenser of Power Plant (희생양극법에 의한 발전소 복수기의 음극방식효과에 대한 수치해석)

  • Kim, Jang-Sun;Bae, Byeong-Hong;Kim, Ui-Hyeon;Lee, Chung-Geun;Kim, Jong-Yeong
    • Korean Journal of Materials Research
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    • v.5 no.7
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    • pp.842-849
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    • 1995
  • The effect of cathodic protection by the sacrificial anode attached to condenser waterbox of power plant was investigated using numerical analysis. The condenser is consisted of various materials. So in case of no protection, the serious galvanic corrosion between waterbox and tubesheet was observed. If sacrificial anodes were attached to the wall of waterbox or the area corroded galvanically, the large protection effect was showed. To demonstrate the validity of numerical analysis results, model test was executed. The numerical solution was consistent with the experimental vague well.

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The Development of Remote Corrosion Monitoring and Control System for Oil Tank by using the High Efficiency CP Rectifier (고효율 전기 방식용 정류기를 이용한 유류탱크의 원 방식 제어 시스템 개발)

  • Bae, Jeong-Hyo;Ha, Tae-Hyun;Lee, Hyun-Goo;Kim, Dae-Kyeong
    • Proceedings of the KIEE Conference
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    • 2002.11d
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    • pp.249-252
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    • 2002
  • Recently, the advanced countries are using the corrosion monitoring system in a chemical plant and an oil tank in order to protect the corrosion because it leads to a big accident, pollution of soil. and lose of money Generally. the owners of the facilities adopt CP(Cathodic Protection) systems to protect the corrosion also. However, a CP system for oil tank was not considered in Korea Moreover they didn't adopted a corrosion monitoring system. In this paper, we have been developed not only the remote automatic corrosion monitoring but also the remote corrosion control system using the high efficiency CP rectifier. This results should be used to operate the CP system effectively and economically. And also it will be possible to extend the expectation life of the Oil tanks.

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A Study on the Standardization of Performance Test Method for CP Rectifier in Korea (국내 전기방식용 정류기의 성능평가 시험 방법에 대한 표준화 연구)

  • Bae, Jeong-Hyo;Ha, Tae-Hyun;Lee, Hyun-Goo;Kim, Dae-Kyeong;Lee, Ji-In
    • Proceedings of the KIEE Conference
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    • 2002.11d
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    • pp.253-256
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    • 2002
  • Generally, the owners of the facilities adopt CP(Cathodic Protection) Systems to protect the corrosion accidents previously. The developed countries have secured the standard of CP systems through the various researches and consolidation of the rules. So in the first stage. I had been studied the international standards; JSCE, NACE Standard, ASTM, DNV, Australian Standard etc. and standardized the CP systems about items performance. specifications and so on. In this thesis, I have been studying the results of standardization of performance test methods of CP rectifier to apply in Korea.

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Enhanced Charge Transfer Through Polypyrrole Electropolymerized on Poly(acrylonitrile-co-butadiene)/Pt Electrodes

  • Chae, Won-Seok;Moon, Jung-Nim;Kim, Kang-Jin
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.603-610
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    • 1995
  • The charge transfer rate in polypyrrole(PPy) electropolymerized within poly(acrylonitrile-co-butadiene)(PAB) was compared with that in PPy deposited Pt electrodes by using cyclic voltammetry, chronoamperometry, and chronopotentiometry in acetonitrile. For both electrodes anodic and cathodic peak currents were proportional to scan rates below 100 mV/sec, but to square root of scan rates beyond 200 mV/sec. The apparent diffusion coefficient of $ClO{_4}^-$ in the PPy/PAB composite is estimated to be 1.6 times larger than that in PPy. The PPy films composited within PAB layer showed higher anodic and cathodic currents and possessed faster charging-discharging process and larger capacity.

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Corrosion protection behavior of AZ31 magnesium alloy with cathodic electrophoretic coating pretreated by cerium based conversion coatings at various pH

  • Fazal, Basit Raza;Phuong, Nguyen Van;Moon, Sungmo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.268-268
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    • 2015
  • The corrosion protection behavior of AZ31 magnesium alloy (Mg alloy) with cathodic electrophoretic coating (E-coating) pretreated by cerium-based conversion coatings at various pH was investigated in this study. Cerium-based conversion coatings (CeCCs) were deposited on AZ31 Mg alloy by immersion treatment in the nitrate-based cerium salt solution. The morphology and composition of the CeCCs were analyzed using scanning electron microscopy and energy dispersive X-ray spectroscopy. The corrosion properties of the AZ31 Mg alloy pretreated with cerium coating and subsequently E-coated were studied during salt-spray testing. The surface morphologies of the E-coated Mg alloy were examined in detail after different testing times using digital photography. It was found that the protective properties of the E-coating on AZ31 Mg alloy generated are heavily dependent upon the CeCC factors such as treatment time, coating thickness and pH of the solution.

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Effects of organic additives in cyanide zinc electroplating Bath(Part 2) (시안화아연 도금욕에 있어서 유기화합물 첨가제의 영향 (제 2 보))

  • Lee, Ju-Seong;Park, Jung-Il
    • Journal of the Korean institute of surface engineering
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    • v.12 no.3
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    • pp.174-179
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    • 1979
  • The effects of brightness, electrochemical behaviour on the organic additives, such as aldehydes, polymers, amines and condensed product obtained from epichlorohydrin and nicotinamide, in cyanide zinc electrolplating bath have been studied by controlled potential electrolyser. The results were summerized as follows: (1) It was found that the addition of only one compound of these organic compounds in the bath was unsuitable but mixture of anisaldehyde or monoethanolamine and condensed product as suitable as brightener. (2) The cathodic polarization curve of polymers or aldehydes in cyanide zinc electroplating bath was almost the same but the cathodic polarization curve of condensed product remarkable shifted to noble potential more than non-additive curve.

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Corrosion Rate of Buried Pipeline by Alternating Current

  • Song, H.S.;Kim, Y.G.;Lee, S.M.;Kho, Y.T.;Park, Y.S.
    • Corrosion Science and Technology
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    • v.4 no.1
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    • pp.1-7
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    • 2005
  • An alternating current (AC) corrosion on buried pipeline has been studied using coupon and ER probe. Coupons and ER probes were applied to the sites from high value of AC voltage to low value based on the survey of AC voltages on buried gas transmission pipeline over the country. Parameters such as AC current density of coupon, AC voltage, cathodic protection potential, soil resistivity and frequency were monitored continually. Corrosion induced by AC was observed even under cathodically protected condition that met cathodic protection criterion (; below -850 mV vs. CSE). Corrosion rate was affected mainly not by AC voltage but by both of frequency and AC current density. An experimental corrosion rate relation could be obtained according to effective AC current density, in which AC corrosion rate increased linearly with effective AC current density, and its slope was 0.619 in coupon method and 0.885 in ER probes.

Thickness Distributions of Metal Nitride Films Manufactured by Cathodic Vacuum Arc Deposition (음극진공아크에 의해 제조된 금속질화물 박막의 두께 분포)

  • Gwon, O-Jin;Kim, Mi-Seon;Lee, Jeong-Seok
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.103.2-103.2
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    • 2016
  • 금속질화물 박막은 대표적인 고경도, 고내열성 박막이다. 박막의 두께는 기계적물성과 밀접한 상관관계가 있으며, 두께의 관리와 제어는 매우 중요하다. 3조 2배열의 증발원을 이용하여 Cathodic vacuum arc deposition(CVAD)법으로써 금속질화물 박막을 제조하였으며, 평균 두께 $4.38{\mu}m$, 표준편차 ${\pm}11.5%$ 박막들을 제조할 수 있었다. 증발원과 증발원 사이의 중첩이 되는 지점에 장착된 시편보다 각각의 증발원에서 평행한 위치에 장착된 시편에 코팅된 박막이 두꺼웠다.

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