• Title/Summary/Keyword: Cathodic

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Effects of Weld Fume on the Corrosion Protection of Epoxy Coated on Carbon Steel

  • Shon, MinYoung
    • Corrosion Science and Technology
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    • v.10 no.3
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    • pp.80-86
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    • 2011
  • Welding was widely used in shipbuilding industries as a joining method. In present study, the effects of welding fume contaminated on steel surface on corrosion protection were examined by water ballast simulation test and condensation chamber test. Pull-off adhesion test, blistering test and cathodic disbondment test were carried out to evaluate the effects of residual welding fume. Consequently, it was clearly indicated that the residual welding fume didn't affect the corrosion protection of epoxy coated on steel when surface was treated by light sweep blasting to heavy sweep blasting which was applied in this study.

Peroxidase Isozyme Pattern and Polyamine Contnts in Germinating Peas (Pisum staivum) (완두 발아시 Polyamine 함량 변화 및 Peroxidase Isozyme 양상)

  • 표병식
    • Journal of Plant Biology
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    • v.36 no.4
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    • pp.307-312
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    • 1993
  • In germinating pea, contents of enodgenous polyamine in the leaf and stem were determined, and protein content, peroxidase activity and pattern of isozymes were examined in the leaf treated with polyamines. During growth of the pea for 14 days in light condition, the polyamines in leaf and stem showed the highest level at the 5th day, and were decreased rapidly at the 7th day, kept almost constant level since then. The putrescine level was relatively higher than those of spermidine and spermine, and cadaverine was also detected. On the other hand, in the leaf treated with spermine (0.01 mM) protein content increased about 250% than that of the control, the peroxidase activity increased ore than 100% in spermine of 0.01 mM and 0.1 mM. In treating with putrescine of 0.1 mM the pattern of peroxidase isozyme appeared 4 new cathodic bands (pI 4.8, 5.6, 5.9 and 6.8) compared with the control, the clear cathodic bands (pI 5.6, 5.9, 6.4 and 6.6) were also observed in spermine of 0.1 mM. These results suggest that polyamines were important factor in the differentiation of pea at the early stage of germination.

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Cathodic Protection Test and Feasibility Study on Remote Monitering System of Concrete Structure (콘크리트내 철근의 전기방식과 리모트 모니터링 시스템의 활용에 관한 연구)

  • 권기주;서용표;이경진;이장화;민병렬;이문환
    • Magazine of the Korea Concrete Institute
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    • v.10 no.3
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    • pp.209-218
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    • 1998
  • 본 연구에서는 콘크리트내 철근의 방식성을 검토하기 위하여 실제 구조물과 유사하도록 콘크리트 대형 패널 실험체를 제작하였으며, 실험체 제작시 콘크리트 내부에 염화물을 혼입하여 음극전기방식 공법을 도입한 실험체와 공법을 도입하지 않은 실험체의 염화물에 의한 철근방식효과를 비교 분석하였다. 실험에 사용된 음극전기방식은 비소모성 티타늄 양극망을 사용한 외부전원방식이며, 최근에 국내에서도 사용실적이 늘고 있는 리모트 모니터링 시스템을 적용하여 구조물의 유지관리상 연속성 있게 콘크리트내 철근의 방식정도를 확인할 수 있는지에 대해 검토하였다.

Repair of Highway Bridge damaged by Chloride Attack in Marine Environment(2) - Application of Cathodic Protection (해양에 위치한 고속도로교량에 대한 내염보수 공법(2)-전기방식시공결과)

  • Chi, Han-Sang;Han, Bog-Kyu;Cheong, Hai-Moon;Ahn, Tae-Song;Ryu, Jong-Hyun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.786-789
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    • 2004
  • Corrosion of reinforced concrete structures in marine environment is one of the most important mechanism of deterioration. However, conventional rehabilitation techniques in tidal zone, which consist of removing delaminated areas of concrete, cleaning affected steel and patching with portland cements mortar, have proven to be ineffective for marine structures. Also, repairs are often repeated every several years. The purpose of this report is to announce appropriate repair method of highway bridge damaged by chloride attack in marine environment (application of cathodic protection) using FRP and antiwashout underwater mortar.

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The Development of the High-efficiency Rectifier on Marine Metallic Structures(II) (해양금속구조물의 전기방식을 위한 고효율 정류기 개발(II))

  • Ha, Tae-Hyun;Bae, Jeong-Hyo;Kim, Dae-Kyeong;Lee, Hyun-Goo;Choi, Sang-Bong;Jeong, Seong-Hwan
    • Proceedings of the KIEE Conference
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    • 2000.11d
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    • pp.727-728
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    • 2000
  • The Cathodic Protection system which is usually applied to marine metallic structures in domestic is Sacrificial Anode Method. In general. low efficiency rectifiers are using in the field of Cathodic Protection. These rectifiers are not only low efficiency but also manual type which is not able to control remotely. In this paper we describe the high efficiency rectifier used the high speed switching method for optimum corrosion control of marine metallic structures.

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Corrosion Rate of Buried Pipeline by Induced Alternating Current (교류가 유도되는 매설배관에서의 교류 부식속도 측정에 관한 연구)

  • Song H. S.;Kim Y. G.;Lee S. M.;Kho Y. T.;Park Y. S.
    • 한국가스학회:학술대회논문집
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    • 2001.10a
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    • pp.45-57
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    • 2001
  • An alternating current (AC) corrosion using coupon has been studied. Coupons were applied in terms of AC voltage from high value to low value through the survey of AC voltages on buried gas transmission pipeline over the country. Parameters such as AC current density of coupon, AC voltage, cathodic protection potential, soil resistivity and frequency were monitored continually. Corrosion induced by AC was observed even under cathodically protected condition that met cathodic protection criterion(: below -850mv vs. CSE). Corrosion rate was affected mainly not by AC voltage but by both of frequency and AC current density. An experimental corrosion rate relationship could be obtained statistically, in which AC corrosion rate increased linearly with effective AC current density and its slope was 0.619.

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The effect of inhibitors affecting to corrosion behaviors and hydrogen embrittlement behaviors due to over-propection of a 4340 steel in 3% NaCl solution (3% NaCl용액중에 있어서 4340강의 부식거동과 과방식에 의한 수소포화거동에 미치는 인히비타의 영향)

  • 문경만;백태실;이상태
    • Journal of Advanced Marine Engineering and Technology
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    • v.13 no.4
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    • pp.54-62
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    • 1989
  • When some kinds of inhibitors, i.e. $1{\times}10{-3}mol/l$ arsenic trioxide, 0.2 mol/l 2-mercaptoethanol, 0.2mol/l thiourea were added to 3% NaCl solution, there were some considererable effects to decrease corrosion current density in natural potential condition and the effect fo solution temperature increasing corrosion rate was smaller than that of no addition to 3% NaCl solution. However the susceptibility of hydrogen embrittlement due to over-protection in case of cathodic protection was much greater than that of no addition, especially was the greatest in case of addition of 2-mercaptoethanol. Therefore adding inhibitors for anti-corrosion effect, it is suggested that selection of the optimum protection potential is important from the view point of prevention against hydrogen embrittlement due to over-protection in case of cathodic protection.

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Redox Reaction on Polarization Curve Variations of Polymer with Enzymes

  • Park, Chil-Nam
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.3
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    • pp.165-171
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    • 2000
  • Experiments were carried out to measure variations in the oxidation potential and current density using the polarization curves of polycarbonate. The results were then examined to identify the influences affecting the oxidation potential related to various conditions, such as temperature, pH, and oxydase(citrate and lipase). The lines representing the active anodic and cathodic dissolution shifted only slightly in the potential direction relative to temperature, pH, and the effect of the enzyme. The Tafel slope for the anodic and cathodic dissolution was determined such that the reversibility polarization was indicated as being effected by various conditions. The slope of the polarization curves describing the active-to-passive transition region shifted noticeably in their direction. Also, by varying the conditions, the optimum conditions for the most ready transform were identified, including temperature, pH, oxidation rate, and resistance of oxidation potential. The critical oxidation sensitivity(I(sub)r/I(sub)f) of the anodic current density peak and maximum passive current density was also determined, which is used in measuring the critical corrosion sensitivity of a polycarbonate.

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Study on the Corrosion Charactristics and its Corrosion Protection of Steel Fishing Banks (강제어촌의 부식특성과 그 방식에 관한 연구)

  • Lim, Uh-Joh;Lee, Jong-Rark
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.28 no.2
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    • pp.216-227
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    • 1992
  • The corrosion rate, behavior of corrosion fatigue and characteristic of cathodic protection for SB41 were investigated by corrosion and corrosion control tests in seawater at laboratory and coast. The main result obtained are as the following; 1) The corrosion rate of base metal (BM) is about 28-37 mg/dm super(2) day in seawater of coast. 2) The correlation between the stress intensity factor range $\Delta$K and crack propagation rate da/dN for weldment follows paris' rule in seawater : da/dN=C($\Delta$K) super(m) where m is the slope of the correlation, and is 2.02 for BM and 1.75 for heat affected zone (HAZ) respectively. 3) The corrosion sensitivity of HAZ is more sensitive than that of BM under the low region of $\Delta$K. 4) With increase of bared surace area of cathode, cathodic protection potential is increased sharply.

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Effects of the GaAs Semiconductor Particles on Electrophysical Phenomena at the Pt Electrode Interfaces (Pt 전극 계면의 전기물리적 현상에 관한 GaAs 반도체 입자효과)

  • Jang Ho Chun
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.31A no.2
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    • pp.67-74
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    • 1994
  • Effects of the GaAs semiconductor particles on electrophysical phenomena at the Pt electrode/10S0-3TM KCl aqueous electrolyte interfaces have been studied using voltammetric time based and electrochemical impedance techniques. The anodic decomposition effect f the GaAs semiconductor particles on electrophysical phenomena was significantly observed during the positive potential scan (0 to 1.0 V vs. SCE). On the other hand, the cathodic decomposition effect of the GaAs semiconductor particles was negligible during thenegative potential scan (0 to -1.0 V vs. SCE). The GaAs semiconductor particles act as current activators or mediators during the anodic process and act as charge screens during the cathodic process. The electrolyte resistance and related impedance was increased due to the presence of the GaAs semiconductor particles. The anodic decomposition effect of the GaAs semiconductor particles can directly be applied to activate the hydrogen evolution.

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