• Title/Summary/Keyword: Cathode Power

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ZnO-free Inverted Polymer Solar Cells Based on New Viologen Derivative as a Cathode Buffer Layer (ZnO를 대체 가능한 새로운 Viologen 유도체가 적용된 역구조 고분자 태양전지)

  • Kim, Youn Hwan;Kim, Dong Geun;Kim, Joo Hyun
    • Applied Chemistry for Engineering
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    • v.27 no.5
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    • pp.512-515
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    • 2016
  • A new viologen derivative namely 1,1'-bis(3,4-dihydroxybutyl)-[4,4'-bipyridine]-1,1'-diium bromide (V-Pr-2OH) was synthesized and applied as a cathode buffer layer to inverted polymer solar cells (PSCs) based on the blend of PTB7 : $PC_{71}BM$. PSCs with the structure of ITO/V-Pr-2OH/PTB7 : $PC_{71}BM/MoO_3/Ag$ as the cathode buffer layer showed the power conversion efficiency (PCE) up to 7.28%, which is comparable to that of the PSCs with the structure of ITO/ZnO/PTB7 : $PC_{71}BM/MoO_3/Ag$ (7.44%) in the absence of V-Pr-2OH. This study demonstrates that a highly efficient PSCs without any high temperature heat treatment can be obtained.

Preparation and Electrochemical Performance of Electrode Supported La0.75Sr0.25Ga0.8Mg0.16Fe0.04O3-δ Solid Oxide Fuel Cells

  • Yu, Ji-Haeng;Park, Sang-Woon;Woo, Sang-Kuk
    • Journal of the Korean Ceramic Society
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    • v.48 no.5
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    • pp.479-484
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    • 2011
  • In this paper, investigations of thick film $La_{0.75}Sr_{0.25}Ga_{0.8}Mg_{0.16}Fe_{0.04}O_{3-{\delta}}$ (LSGMF) cells fabricated via spin coating on either NiO-YSZ anode or $La_{0.7}Sr_{0.3}Ga_{0.6}Fe_{0.4}O_3$ (LSGF) cathode substrates are presented. A La-doped $CeO_2$ (LDC) layer is inserted between NiO-YSZ and LSGMF in order to prevent reactions from occurring during co-firing. For the LSGF cathode-supported cell, no interlayer was required because the components of the cathode are the same as those of LSGMF with the exception of Mg. An LSGMF electrolyte slurry was deposited homogeneously on the porous supports via spin coating. The current-voltage characteristics of the anode and cathode supported LSGMF cells at temperatures between $700^{\circ}C$ and $850^{\circ}C$ are described. The LSGF cathode supported cell demonstrates a theoretical OCV and a power density of ~420 mW $cm^2$ at $800^{\circ}C$, whereas the NiO-YSZ anode supported cell with the LDC interlayer demonstrates a maximum power density of ~350 mW $cm^2$ at $800^{\circ}C$, which decreased more rapidly than the cathode supported cell despite the presence of the LDC interlayer. Potential causes of the degradation at temperatures over $700^{\circ}C$ are also discussed.

Development of HVPS of the X-Band TWTA for Military Transportable Satellite Communications (군위성통신 차량용단말 X-대역 TWTA용 HVPS 개발)

  • Park, Jae-Don;Jang, Jeen-Sang;Dong, Moon-Ho
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.30 no.12A
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    • pp.1168-1173
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    • 2005
  • The HVPS of the TWTA for military satellite communications is developed and tested. With 380 V input DC voltage, the HVPS provides -10.95 kV for Cathode, -4.27 kV for Collectorl and -6.57 kV for Collector2 of the TWT that generates 600 W X-band output signal power. The total output power of the HVPS is about 1.6 kW. The voltage ripples of Cathode, Collectorl and Collector2 are 6 V, 12 V and 6 V, respectively, which are only $0.055\%,\;0.281\%$ and $0.091\%$ compared to the absolute output voltages.

A Latch-Up Immunized Lateral Trench IGBT with $p^{+}$ Diverter Structure for Smart Power IC (스마트 파워 IC를 위한 $p^{+}$ Diverter 구조의 횡형 트랜치 IGBT)

  • 문승현;강이구;성만영;김상식
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.7
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    • pp.546-550
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    • 2001
  • A new Lateral Trench Insulated Gate Bipolar Transistor(LTIGBT) with p$^{+}$ diverter was proposed to improve the characteristics of the conventional LTIGBT. The forward blocking voltage of the proposed LTIGBT with p$^{+}$ diverter was about 140V. That of the conventional LTIGBT of the same size was 105V. Because the p$^{+}$ diverter region of the proposed device was enclosed trench oxide layer, he electric field moved toward trench-oxide layer, and punch through breakdown of LTIGBT with p$^{+}$ diverter was occurred, lately. Therefore, the p$^{+}$ diverter of the proposed LTIGBT didn't relate to breakdown voltage in a different way the conventional LTIGBT. The Latch-up current densities of the conventional LTIGBT and proposed LTIGBT were 540A/$\textrm{cm}^2$, and 1453A/$\textrm{cm}^2$, respectively. The enhanced latch-up capability of the proposed LTIGBT was obtained through holes in the current directly reaching the cathode via the p$^{+}$ divert region and p$^{+}$ cathode layer beneath n$^{+}$ cathode layer./ cathode layer.

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Structure evolution of Pt doped amorphous $V_{2}O_{5}$ cathode film for thin film battery (Pt이 도핑된 박막 전지용 비정질 산화바나듐 박막의 구조적 변화)

  • 김한기;전은정;옥영우;성태연;조원일;윤영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.889-892
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    • 2000
  • We have investigated the Pt doping effect on structural and electrochemical properties of amorphous vanadium oxide film, grown by radio frequency magnetron sputtering. Room temperature charge-discharge measurements based on a half-cell with a constant current clearly indicated that the Pt doping could improve the cyclibility of V$_2$O$_{5}$ cathode film. Using glancing angle x-ray diffraction (GXRD) and high resolution transmission electron microscopy (HRTEM) analysis, we found that the Pt doping with l0W r.f. power induce more random amorphous structure than undoped V$_2$O$_{5}$ film. As the r.f. power of Pt increases, large amount of Pt incorporates into amorphous V$_2$O$_{5}$ and makes PtOx microcrystalline phase in amorphous matrix. This result suggests that the semicondcuting PtOx microcrystalline phase in amorphous matrix lead to a drastically faded cyclibility of 50W Pt doped V$_2$O$_{5}$ cathode film. Possible explanations are given to describe the Pt doping effect on cyclibility of vanadium oxide cathode film.de film.

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Theoretical Modeling of the Internal Power Flow and Absorption Loss of the Air Mode Based on the Proposed Poynting Vector Analysis in Top-emitting Organic Light-emitting Diodes

  • Kim, Jiyong;Kim, Jungho;Kim, Kyoung-Youm
    • Journal of the Korean Physical Society
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    • v.73 no.11
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    • pp.1663-1674
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    • 2018
  • We propose the Poynting vector analysis of the air mode in a top-emitting organic light-emitting diode (OLED) by combining the transfer matrix method and dipole source term. The spatial profiles of the time-averaged optical power flow of the air mode are calculated inside and outside the multilayer structure of the OLED with respect to the thickness of the semi-transparent top cathode and capping layer (CPL). We elucidate how the micro-cavity effect controlled by the thickness variation of the semi-transparent top cathode or CPL affects the internal optical power and absorption loss inside the OLED multilayer and the external optical power coupled into the air. When the calculated absorption loss and external power obtained by the proposed Poynting vector and currently-used point dipole models are compared, two calculation results are identical, which demonstrates the validity of the two models.

An SOFC Cathode Composed of LaNi0.6Fe0.4O3 and Ce(Ln)O2 (Ln=Sm, Gd, Pr)

  • Chiba, Reiichi;Komatsu, Takeshi;Orui, Himeko;Taguchi, Hiroaki;Nazawa, Kazuhiko;Arai, Hajime
    • Journal of the Korean Ceramic Society
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    • v.45 no.12
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    • pp.766-771
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    • 2008
  • We fabricated single cells with a cathode consisting of a $LaNi_{0.6}Fe_{0.4}O_3-Ce_{0.8}Sm_{0.2}O_{1.9}$ composite (LNF-S20DC composite) active layer and an LNF current collecting layer on a ${0.89ZrO_2}-{0.10Sc_2}{O_3}-0.01{Al_2}{O_3}$ electrolyte sheet. The cathode layers were prepared by the screen-printing method. The cathode properties of these cells were measured by the AC impedance method at $800^{\circ}C$. The cathodes with the ceria-LNF composite active layer exhibited high power performance prior to current loading. We investigated the influence of the mixture ratio of LNF and S20DC on the cathodes properties. The Sm in the ceria particles of the composite cathode was substituted with other rare-earth elements. Cathodes with Pr and Gd co-doped ceria in the active layer provided the better performance than those with Sm- or Gd-doped ceria.

Power Density Enhancement of Anion-Exchange Membrane-Installed Microbial Fuel Cell Under Bicarbonate-Buffered Cathode Condition

  • Piao, Jingmei;An, Junyeong;Ha, Phuc Thi;Kim, Taeyoung;Jang, Jae Kyung;Moon3, Hyunsoo;Chang, In Seop
    • Journal of Microbiology and Biotechnology
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    • v.23 no.1
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    • pp.36-39
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    • 2013
  • We introduce a high-performance microbial fuel cell (MFC) that was operated using a 0.1M bicarbonate buffer as the cathodic electrolyte. The MFC had a 136.42 $mW/m^2$ maximum power density under continuous feeding of 5 mM acetate as fuel. Results of the electrode potential measurements showed that the cathode potential of the bicarbonate-buffered condition was higher than the phosphate-buffered condition, although the phosphate condition had less interfacial resistance between the membrane and electrolyte. Therefore, we posit here that the increased power of the bicarbonate-buffered MFC may be caused by the higher cathode potential rather than by the interfacial membrane-electrolyte resistance.

Prevention of Power Overshoot and Reduction of Cathodic Overpotential by Increasing Cathode Flow Rate in Microbial Fuel Cells used Stainless Steel Scrubber Electrode (스테인리스강 수세미 전극을 사용한 미생물연료전지의 전력 오버슈트 예방과 환원조 유속 증가에 의한 환원전극 과전압 감소)

  • Kim, Taeyoung;Kang, Sukwon;Chang, In Seop;Kim, Hyun Woo;Sung, Je Hoon;Paek, Yee;Kim, Young Hwa;Jang, Jae Kyung
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.10
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    • pp.591-598
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    • 2017
  • Power overshoot phenomenon was observed in microbial fuel cells (MFCs) used non-catalyzed graphite felt as cathode. Voltage loss in MFCs was mainly caused by cathode potential loss. Cheap stainless steel scrubber, which has high conductivity, and Pt/C coated graphite felt as cathode were used for overcoming power overshoot and reducing the cathode potential loss in MFCs. The MFCs used stainless steel scrubber showed no power overshoot even slow catholyte flow rate and produced 29% enhanced maximum current density ($23.9A/m^3$) than MFCs used non-catalyzed graphite felt while the power overshoot phenomenon was existed in Pt/C coated MFCs. Increasing catholyte flow rate resulted in disappearing power overshoot of MFCs used non-catalyzed graphite felt. In addition, maximum power density and current density of both MFCs used non-catalyzed graphite felt and stainless steel scrubber increased by 2-3.5 times. Cathode potential losses in all region of activation loss, ohmic loss, and mass transport loss were reduced according to increase of catholyte flow rate. Therefore, stainless steel scrubber has advantages that are economical materials as electrode and prevents power overshoot, leading to enhance electricity generation. In addition, increasing catholyte flux is one of great solution when power overshoot caused by cathodic overpotential is observed in MFCs.

Measurement of Ar Temperature of Hollow Cathode Discharge Plasma

  • Lee, Jun-Hoi;Shin, Jae-Soo;Lee, Sung-Jik;Lee, Min-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.4
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    • pp.381-385
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    • 2005
  • The plasma temperature of Ar gas in hollow cathode discharge were measured. This is done by measuring the line profile of the 1s/sub 8/-2p/sub 8/ transition in Ar, using a single-frequency diode laser. Low power diode lasers have been successfully used for investigation of the line profiles of Ar transitions in hollow cathode discharges. It turns out that the plasma temperature of Ar is 640∼783 K in the discharge current range at 7∼10 mA.