• Title/Summary/Keyword: Carbonized sludge

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Properties of Cement Matrix According to Carbonized Sludge Replacement Ratio (탄화슬러지 치환율에 따른 시멘트 경화체의 특성)

  • Park, Chae-Wool;Kim, Yeon-Ho;Choi, Byung-Cheol;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.143-144
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    • 2020
  • For modern people who spend 80% of the day indoors, indoor air quality is an important factor in their lives. Radon and fine dust, which are indoor air quality pollutants, cause various diseases and lung diseases, so a method is needed to reduce them. Therefore, this study intends to utilize the air pollutant adsorption properties of the carbonized sludge by using the carbonized sludge generated through drying and carbonization of the sludge. As a result of the experiment, it was shown that the concentration of radon and fine dust gradually decreased as the replacement ratio of carbonized sludge increased. The reason is that the carbonized sludge has the ability to adsorb fine dust and radon, so it is considered that it gradually decreases as the replacement ratio increases. Also, the compressive strength and flexural strength tend to decrease gradually. The reason for this is that the carbonized sludge has a number of internal voids, and as the replacement ratio increases, the internal voids increase and the strength decreases. If the refinement and strength of the carbonized sludge replacement ratio are supplemented, it is believed that it will be able to replace the existing finishing materials.

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Study on Adsorption of Pb and Cd in Water Using Carbonized Water Treatment Sludge (탄화 정수 슬러지를 이용한 수중의 납과 카드뮴 흡착에 관한 연구)

  • Kim, Younjung;Kim, Daeik;Choi, Jong-Ha;Hong, Yong Pyo;Ryoo, Keon Sang
    • Journal of the Korean Chemical Society
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    • v.61 no.5
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    • pp.238-243
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    • 2017
  • In this study, water treatment sludge carbonized with $400^{\circ}C$ was tested as an adsorbent for the removal of Pb and Cd in water. The carbonized sludge was characterized by thermo-gravimetric analysis (TGA), scanning electron microscopy (SEM), X-ray fluorescence spectrometry (XRF), and surface area analysis. Carbonized sludge exhibited much higher specific surface area and total pore volume than water treatment sludge itself. In batch-type adsorption process, carbonized sludge represented better adsorption performance for Pb than Cd, achieving 90~98% at the concentrations conducted in the experiments. Equilibrium data of adsorption were analyzed using the Freundlich and Langmuir isotherm models. It was seen that both Freundlich and Langmuir isotherms have correlation coefficient $R^2$ value larger than 0.95. The results of studies indicated that carbonized water treatment sludge by heat treatment could be used as an efficient adsorbent for the removal of Pb and Cd from water.

Recycling Technology of Sewage Sludge by Carbonization

  • Park, Sang-U;Jang, Cheol-Hyeon;Kim, Nak-Ju
    • Journal of Environmental Science International
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    • v.13 no.2
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    • pp.161-165
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    • 2004
  • This study has been conducted to develop a new recycling technology of sewage sludge using a carbonization process. The carbonizing yield, the calorific value and EC(electric conductivity) of carbonized sewage sludge had a tendency to be decreased with increase of the carbonizing temperature and time, but pH and the C/N were increased with increase the carbonizing temperature and time. The whole pore volume of carbonized sludge processed in the carbonizing furnace was /g, which was smaller than that in the electric furnace. But, the rates of mesopore and macropore were found to account for 100% therein. Rate of color and organic materials removal for dyeing wastewater were determined 70~97%, 78~83% on cotton yarn, 88~96%, 69~80% on wool wastewater and 77~89%, 77~87% on towel compared with powder activated carbon. Effect of carbonized sludge on chrysanthemum growth was investigated. Plant height and number of leaves was better mixture of carbonized sludge than comparison.

Study on the Pyrolysis Kinetics of Mixture of RDF and Carbonized Sludge with Thermogravimetric Analysis (RDF와 탄화슬러지 혼합물의 열중량 및 열동역학 특성 연구)

  • Sun, Jian Feng;Hwang, Hyeon Uk;Kim, Myung Gyun;Nzioka, Antony Mutua;Lee, Chang Soo;Kim, Young Ju
    • Journal of Environmental Science International
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    • v.25 no.2
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    • pp.281-288
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    • 2016
  • After analyzing of heating value of four kinds of RDF, the RDF-D has the highest heating value, was chosen to be mixed with carbonized sludge by different ratio. The 85%:15% ratio, which has the highest efficiency, was analyzed with thermogravimetric and pyrolysis kinetics. Applying of Kissinger method, activation energy was obtained from slope which is calculated from relation of ln(${\beta}/T^2{_m}$) and $1/T_m$. The kinetic parameters obtained from Kissinger method were 46.06 kJ/mol of RDF, 55.99 kJ/mol of carbonized sludge and 40.68 kJ/mol of mixture of RDF and carbonized sludge. The mixture of RDF and carbonized sludge has the lowest activation energy and frequency factor, during thermal decomposition reaction it has the slowest reaction rate and needs the lowest energy. Although activation energy with pyrolysis of RDF was irregularly scattered, it showed that activation energy was stabilized by co-pyrolysis of RDF and additives(Carbonized Sludge).

Study on Manufacturing Characteristics of Carbonated lightweight Aggregate using Sewage Sludge (하수슬러지를 이용한 탄화경량골재의 제조 특성 연구)

  • Yoo, Yeong-Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.6
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    • pp.743-750
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    • 2013
  • In this study, the carbonized aggregate of light weight and high mechanical strength using sewage sludge was evaluated with changing carbonation variables of temperature, detention time and feed condition. Porosity and mechanical strength was simultaneously increased according to increase of carbonization temperature unexpectedly. Carbonization detention time above 1 hour nearly affect on the porosity, but mainly on mechanical strength of the carbonized aggregate in case of clay addition. On $900^{\circ}C$, porosity and mechanical strength was increased rapidly, but above $1000^{\circ}C$, porosity began to decrease. Clay addition was very effective on increase of mechanical strength following much loss in porosity. The carbonized aggregate manufactured at $900^{\circ}C$ adding 30 % clay in sewage sludge was higher a little in porosity and 3 times in mechanical strength than those at $700^{\circ}C$ not adding clay. Consequently, in manufacturing the carbonized aggregate having simultaneously high porosity and mechanical strength, it is desirable to have operational condition of $900{\sim}1000^{\circ}C$ temperature and 1 hour time, and clay addition within 30 % for further higher mechanical strength.

Recycle Technology of Sewage Sludge by Carbonization Process

  • Park, Sang-Woo;Jang, Cheol-Hyeon;Kim, Nack-Joo
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.204-207
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    • 2003
  • This study has been conducted for the purpose to develop a new technology using the carbonization process for establishing the resources circulation system for sewage sludge and enabling the sludge amount and volume to be reduced sanitarily and safely. Besides, it is thought that the effective value of the carbonized sludge is much greater even though there is any limitation to its applicable fields or use since it is not a product that is intentionally produced like any existing materials for conventional uses.

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Adsorption Characteristics of Benzene by Carbonized Cast (탄화분변토를 이용한 Benzene의 흡착특성)

  • 김재홍;손희정;김미룡
    • Journal of environmental and Sanitary engineering
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    • v.14 no.1
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    • pp.97-102
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    • 1999
  • This study was carried out view that reuse of sludge of adsorbent for benzene in carbonized cast compare with activated carbon. Not only the carbonized cast is good than carbonized carbon in cation exchange capacity and 12 adsorption capacity, but also benzene adsorption capacity is no differences compare to activated carbon. As results, benzene adsorption capacity of carbonized cast and activated carbon are decreased as temperature increase($25~70^{\circ}C$).It is compatible in Lamgmuir model. Therefore, carbonized cast is applied general adsorbent. From experimental results and data regression, in model concerning effect of temperature, relative errors between the experimental data and those calculated by the model are within the range of 1.2~7.8%. In relative humidity effect (RH 0.25~0.50) of benzene adsorption, modified Freundlich model : $QB_{enzene}{;\}QB_{enzene},{\}_{RH=0}=1-kRH^{IN}$, relative errors between the experimental data and those calculated by the model are within are range of 0.5-5.1%. The constants k and l/n in equation were found to be 1.25, 1.89 in carbonized cast.

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SiC aggregates synthesized from carbonized rice husks, paper sludge, coffee grounds, and silica powder (탄화왕겨, 제지슬러지, 커피찌거기 및 실리카 혼합물로부터 탄화규소 결정체 합성)

  • Park, Kyoung-Wook;Yun, Young-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.2
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    • pp.45-49
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    • 2019
  • Relatively fine silicon carbide (SiC) crystalline aggregates have been synthesized with the carbonized rice husks, paper sludge, coffee grounds as the carbon sources and the silica powder. The main reaction source to obtain silicon carbide (SiC) aggregates from the mixture of carbon sources and silica was inferred as the gaseous silicon monoxide (SiO) phase, being created from this mixture through the carbothermal reduction reaction. The silicon carbide (SiC) crystalline aggregates, fabricated from the carbonized rice husks and paper sludge, coffee grounds and silica ($SiO_2$) powder, were investigated by XRD patterns, FE-SEM and FE-TEM images. In these specimens, obtained from the carbonized rice husks, paper sludge and silica, XRD patterns showed rather high strong peak of (111) plane near $35^{\circ}$. The FE-TEM images and patterns of specimens, synthesized from carbonized rice husks, paper sludge, coffee grounds and silica under Ar atmosphere, showed relatively fine particles under $1{\mu}m$ and crystalline peak (110) of silicon carbide (SiC) diffraction pattern.

A Study on Drying and Carbonization of Organic Sludge from Sewage Plant and Petrochemical Industries for Energy and Resources Recovery (하수슬러지 및 석유화학산업단지 폐수슬러지의 에너지화와 재활용을 위한 건조 및 탄화에 관한 연구)

  • Jun, Kwan-Soo;Hwang, Eung-Ju;Kim, Hyung-Jin
    • Clean Technology
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    • v.15 no.3
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    • pp.154-164
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    • 2009
  • In 2007, 94% of organic wastewater sludge from industries located in Ulsan was disposed of by ocean dump. The ocean dump of organic sludge would be totally prohibited by the year of 2012. However, there is no alternative but incinerating the sludge from the industries located in Ulsan. Securing the technology for sludge treatment and on-land disposal is very important issue among the industries in the Ulsan Petrochemical Industry Complex. In this study, the material aspects of dried and carbonized sludge as a fuel were evaluated for petrochemical and sewage sludge from Ulsan. The dried and carbonized sludges from the factories producing terephthalic acid, BTX, propylene, chemical textile, etc. of which the low heat value exceeded 3,000 kcal/kg had high potential as a fuel according to the results of thermal characteristic analysis. However, the dried sludges with heat values lower than 2,100 kcal/kg and carbonized sludges, lower than 1,100 kcal/kg containing more Inorganic material from the industries producing pulp, paper, methylamine, amide, etc. had a little potential to be used as a fuel. In most cases, drying the sludge showed better results than carbonization in the aspect of thermal characteristics of sludge.

A Fundamental Study on the Application of Cast for Removal of VOCs Produced in the Oil-contaminated Soil (유류오염 토양에서 발생되는 VOCs 제거를 위한 분변토의 활용 가능성에 관한 기초연구)

  • Son, Hee-Jeong;Chun, Mi-Hee;Kim, Chul
    • Journal of Environmental Health Sciences
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    • v.33 no.5
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    • pp.456-461
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    • 2007
  • This study was carried out two point view that reuse of sludge and adsorption of benzene, toluene and o-xylene of VOCs in cast, carbonized cast and activated carbon. The cation exchange capacity of cast and carbonized cast were 59.2, 112 meq/100g, respectively. The specific surface were 560, $800m^2/g$, respectively. The average removal rates of benzene by 50g cast of 50% hydrous cast, anhydrous cast, carbonized cast, activated carbon were 15.0, 41.2, 88.2, 99.4% in 60min of retention time. The average removal efficiency of toluene by 50 g cast of 50% hydrous cast, anhydrous cast, carbonized cast, activated carbon were 12.5, 34.2, 88.2, 99.5% in 60 min of retention time. The average removal rates of o-xylene 50 g cast of 50% hydrous cast, anhydrous cast, carbonized cast, activated carbon were 8.8, 28.5, 84.8, 98.1% in 60min of retention time. The adsorption efficiency of test absorbent was in order of Activated Carbon > Carbonized Cast > Cast.