• Composites Research
• /
• 제12권3호
• /
• pp.75-83
• /
• 1999

Carbon/Phenolic 및 silica/phenolic 내열 복합재료의 강화재의 종류와 적층방향에 따른 비열, 열확산 계수, 열전도도를 분석하였다. Carbon/Phenolic 및 silica/phenolic 복합재료의 비열은 시차 주사 열량법을 이용하여 측정하였으며, 열확산계수는 레이저 섬광법을 이용하여 laminar와 평행방향과 laminar와 직교방향으로 측정하였다. Carbon/Phenolic 및 silica/phenolic 복합재료의 열확산계수는 온도가 증가함에 따라 감소하였다. Carbon/Phenolic 및 silica/phenolic 복합재료의 열전도도를 밀도, 열확산계수 및 비열을 이용하여 계산하였다. 열전도도는 온도가 증가함에 따라 증가하였으며, carbon/Phenolic의 경우 laminar와 평행방향의 열전도도가 laminar와 직교방향의 열전도도보다 2배 높은 이방성을 나타내었으며 이는 carbon 섬유의 열전도도 이방성 때문으로 해석되었다. 이차원 섬유강화 복합재료의 열전도도를 기지와 강화재의 열전도도와 부피분율을 이용하여 해석하였다. Carbon/Phenolic 및 silica/phenolic 복합재료의 열전도도를 적층방향에 따라 강화재와 기지의 열전도도를 이용하여 해석하여 carbon 섬유와 silica 섬유의 열전도도를 계산하였다. 계산된 섬유의 열전도도와 기지의 열전도도로부터 섬유의 부피분율에 따른 복합재료의 상온열전도도를 예측할 수 있었다.

• Fibers and Polymers
• /
• 제5권1호
• /
• pp.31-38
• /
• 2004

In the present paper, a variety of fiber reinforcements, for instance, stabilized OXI-PAN fibers, quasi-carbon fibers, commercial carbon fibers, and their woven fabric forms, have been utilized to fabricate pseudo-unidirectional (pseudo-UD) and 2-directional (2D) phenolic matrix composites using a compression molding method. Prior to fabricating quasi-carbon fiber/phenolic (QC/P) composites, stabilized OXI-PAN fibers and fabrics were heat-treated under low temperature carbonization processes to prepare quasi-carbon fibers and fabrics. The thermal conductivity and thermal expansion/contraction behavior of QC/P composites have been investigated and compared with those of carbon fiber/phenolic (C/P) and stabilized fiber/phenolic composites. Also, the chemical compositions of the fibers used have been characterized. The results suggest that use of proper quasi-carbonization process may control effectively not only the chemical compositions of resulting quasi-carbon fibers but also the thermal conductivity and thermal expansion behavior of quasi-carbon fibers/phenolic composites in the intermediate range between stabilized PAN fiber- and carbon fiber-reinforced phenolic composites.

• 한국복합재료학회:학술대회논문집
• /
• 한국복합재료학회 1999년도 추계학술발표대회 논문집
• /
• pp.160-163
• /
• 1999

The mechanical properties and failure behaviour of carbon/phenolic composites were inverstigated by tension and compression. Carbon/phenolic composites were fabricated by infiltration of matrix into 8 harness satin woven fabric of PAN-based carbon fibers. The tensile and compressive tests were performed at 25℃ under air atmosphere and, at 400℃ and 700℃ under N₂ atmosphere. The tensile strengths of carbon/phenolic composites in with-laminar/0° warp direction were about 10 times higher than those in with-laminar/45° warp direction, which was analyzed due to a change of fracture mode from fiber pull-out by shear to tensile fracture of fibers. The fracture of carbon/phenolic composites in with-laminar/45° direction was analyzed due to delamination by buckling. Tensile and compressive strength of carbon/phenolic composites decreased to about 50% at 400℃, and to about 10% at 700℃ compared to that at room temperature. The main reason for the decrease of tensile or compressive strength with increasing temperature was analyzed due to a reduction of bond strength between fibers and matrix resulting from thermal degradation of phenolic resin.

• 한국복합재료학회:학술대회논문집
• /
• 한국복합재료학회 2002년도 추계학술발표대회 논문집
• /
• pp.29-32
• /
• 2002

The mechanical and thermal properties of spun carbon fabric/continuous carbon fabric interplay hybrid composite materials have been studied. The properties of the hybrid composites are compared with those of the continuous carbon fabric/phenolic composites and spun carbon fabric /phenolic composites. Through hybridization, tensile strength and flexural strength of hybrid composites were increased by about 17%, and 10%, respectively compared with spun carbon composites. The thermal conductivity of the hybrid composite is lower approximately 4~6% along the direction parallel to the laminar plane than that of the continuous carbon/phenolic composite.

• Carbon letters
• /
• 제17권1호
• /
• pp.33-38
• /
• 2016

In the present study, exfoliated graphite nanoplatelets (xGnP) with different particle sizes were coated onto polyacrylonitrile-based carbon fibers by a direct coating method. The flexural properties, interlaminar shear strength, and the morphology of the xGnP-coated carbon fiber/phenolic matrix composites were investigated in terms of their longitudinal flexural strength and modulus, interlaminar shear strength, and by optical and scanning electron microscopic observations. The results were compared with a phenolic matrix composite counterpart prepared without xGnP. The flexural properties and interlaminar shear strength of the xGnP-coated carbon fiber/phenolic matrix composites were found to be higher than those of the uncoated composite. The flexural and interlaminar shear strengths were affected by the particle size of the xGnP, while the particle size had no significant effect on the flexural modulus. It seems that the interfacial contacts between the xGnP-coated carbon fibers and the phenolic matrix play a role in enhancing the flexural strength as well as the interlaminar shear strength of the composites.

• 한국항공우주학회지
• /
• 제49권5호
• /
• pp.355-363
• /
• 2021

리오셀계 탄소/페놀릭 복합재료의 항공우주용 내열 부품 적용 가능성을 확인하기 위하여 내열성능 평가 및 열 해석을 수행하였다. 탄소/페놀릭의 열반응 평가는 내열성능평가모터(Thermal Protection Evaluation Motor, TPEM)로 수행되었다. 본 논문에서는 열 해석을 위해 유체의 경계층 해석을 고려한 경계층 적분 코드와 삭마 및 열분해를 고려한 MSC-Marc 2018 코드를 사용하였다. 추진기관의 압력 곡선, 연소 시험 후 절개된 목삽입재 시편을 통하여 삭마 및 단열성능을 분석하였고, 리오셀계 탄소/페놀릭 복합재료의 열반응은 레이온계 탄소/페놀릭 재료와 유사하였다. 연소시험을 통한 결과를 바탕으로 국산 리오셀계 탄소/페놀릭의 항공우주용 내열 부품으로의 적용 가능성을 확인하였다.

• 한국복합재료학회:학술대회논문집
• /
• 한국복합재료학회 2002년도 추계학술발표대회 논문집
• /
• pp.48-51
• /
• 2002

This paper predicted the thermal conductivity of spun carbon/phenolic composites by the thermal resistance method. This method uses the analogy between the diffusion of heat and electrical charge. To verify the theoretical predictions, the thermal conductivity of spun carbon/phenolic composites was examined experimentally. The reported thermal conductivities of graphite/epoxy composite of a eight harness satin laminate was used of the comparison with the prediction values of the model and it was noticed that a good agreement has been found.

• Composites Research
• /
• 제33권6호
• /
• pp.329-335
• /
• 2020

본 연구에서는 각각에 다른 연화점을 갖는 석유계 피치의 열 유변학적 특성을 연구하였으며, 이를 함침용 페놀수지에 석유계 피치를 첨가하여 B-stage 형태의 페놀수지/석유계 피치 혼합물을 제조하였다. 그 결과, 연화점이 다른 석유계 피치는 QI의 함량이 증가할수록 피치의 유동성이 감소하였고, 고체의 점탄성 특성을 나타내었다. 또한, 다른 연화점을 갖는 석유계 피치를 페놀수지에 첨가함으로써, 페놀수지의 경화거동과 열 유변학적 특성에 미치는 영향에 대해 고찰하였을 때, 다른 연화점의 석유계 피치를 첨가함에 따라 페놀수지의 경화속도 및 경화거동을 조절할 수 있었으며, 이 중 P-Pitch 2가 첨가된 페놀수지 혼합물의 경우 동일한 경화 온도조건에서 다른 혼합물에 비해 유동성이 높은 것을 확인할 수 있었다.

• 한국복합재료학회:학술대회논문집
• /
• 한국복합재료학회 2003년도 춘계학술발표대회 논문집
• /
• pp.50-52
• /
• 2003

본 연구에서는 비교계측법을 이용하여 탄소/페놀릭 주자직 복합재료에 대한 열전도도를 계측하였다.

• Carbon letters
• /
• 제1권3_4호
• /
• pp.154-157
• /
• 2001

Composite adsorbents were prepared by mixing water plant sludge with phenolic resin having the ratio of 1 : 1, 1 : 2, and 1 : 3 respectively, curing from $100^{\circ}C$ to $170^{\circ}C$ under $N_2$ atmosphere, and then activating with $N_2$ at $700^{\circ}C$. Thermal property, specific surface area and morphology of the composite adsorbents as well as their precursors were measured by TGA, BET and SEM respectively. Removal efficiency of the composite adsorbents to ${NH_4}^+$ and TOC was compared with those of commercial zeolite and activated carbon. The adsorbents presented very promising TOC removal efficiency of 98%, which was identical level to that of commercial activated carbon while they displayed removal efficiency, only 32%, of ${NH_4}^+$. Therefore, this composite adsorbent considered as the alternative material of commercial activated carbon, used as an expensive removal agent of organic substances and THM in water treatment plant and it also suggested a possibility of practical application in other processes.