• Title/Summary/Keyword: Carbon-free

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Hydrogen production by catalytic decomposition of methane and propane mixture over carbon black catalyst in a fluidized bed (카본블랙 촉매를 이용한 유동층 반응기에서 메탄과 프로판 혼합물의 촉매 분해에 의한 수소생산 연구)

  • Lee, Seung-Chul;Yoon, Yong-Hee;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.97-100
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    • 2007
  • A fluidized bed reactor made of quartz with 0.055 m I.D. and 1.0 m in height was employed for the thermocatalytic decomposition of methane to produce $CO_2$ - free hydrogen . The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. The methane decomposition rate with the carbon black N330 catalyst was quickly reached a quasi-steady state rate and remained for several hour. The methane and propane mixture decomposition reaction was carried out at the temperature range of 850 - 900 $^{\circ}C$, methane and propane mixture gas velocity of 1.0 $U_{mf}$ ${\sim}$ 3.0 $U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature, gas velocity on the reaction rates was investigated. The produced carbon by the methane decomposition was deposited on the surfaces of carbon catalysts and the morphology was observed by TEM image.

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Effect of Free Radical Scavenging from Green Tea Extraction using Carbon Dioxide Fluid (이산화탄소 유체를 이용한 녹차의 용매 추출물의 래디칼 소거 기능)

  • Kang Ok-Ju
    • Korean journal of food and cookery science
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    • v.21 no.6 s.90
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    • pp.936-941
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    • 2005
  • Green tea was extracted with different solvents such as hot water, varying concentrations of ethanol and carbon dioxide fluid. The carbon dioxide fluid extraction of green tea was a very effective extraction method in terms of antioxidant yield and stability. At pressure of 125kgf, antioxidant extract of green tea produced a yield 1.87 and 2.8 times higher than hot water and $95\%$ ethanol extract, respectively. Antioxidant extract of carbon dioxide fluid was also very stable during 7-day storage at 35?.

Vibration characteristics of functionally graded carbon nanotube-reinforced composite double-beams in thermal environments

  • Zhao, Jing-Lei;Chen, Xu;She, Gui-Lin;Jing, Yan;Bai, Ru-Qing;Yi, Jin;Pu, Hua-Yan;Luo, Jun
    • Steel and Composite Structures
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    • v.43 no.6
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    • pp.797-808
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    • 2022
  • This paper presents an investigation on the free vibration characteristics of functionally graded nanocomposite double-beams reinforced by single-walled carbon nanotubes (SWCNTs). The double-beams coupled by an interlayer spring, resting on the elastic foundation with a linear layer and shear layer, and is simply supported in thermal environments. The SWCNTs gradient distributed in the thickness direction of the beam forms different reinforcement patterns. The materials properties of the functionally graded carbon nanotube-reinforced composites (FG-CNTRC) are estimated by rule of mixture. The first order shear deformation theory and Euler-Lagrange variational principle are employed to derive the motion equations incorporating the thermal effects. The vibration characteristics under several patterns of reinforcement are presented and discussed. We conducted a series of studies aimed at revealing the effects of the spring stiffness, environment temperature, thickness ratios and carbon nanotube volume fraction on the nature frequency.

Vibration response of rotating carbon nanotube reinforced composites in thermal environment

  • Ozge Ozdemir;Ismail Esen;Huseyin Ural
    • Steel and Composite Structures
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    • v.47 no.1
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    • pp.1-17
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    • 2023
  • This paper deals with the free vibration behavior of rotating composite beams reinforced with carbon nanotubes (CNTs) under uniform thermal loads. The temperature-dependent beam material is assumed to be a mixture of single-walled carbon nanotubes (SWCNTs) in an isotropic matrix and five different functionally graded (FG) distributions of CNTs are considered according to the variation along the thickness, namely the UD-uniform, FG-O, FG-V, FG-Λ and FG-X distributions where FG-V and FG-Λ are unsymmetrical patterns. Considering the Timoshenko beam theory (TBT), a new finite element formulation of functionally graded carbon nanotube reinforced composite (FGCNTRC) beam is created for the first time. And the effects of several essential parameters including rotational speed, hub radius, effective material properties, slenderness ratio, boundary conditions, thermal force and moments due to temperature variation are considered in the formulation. By implementing different boundary conditions, some new results of both symmetric and non-symmetrical distribution patterns are presented in tables and figures to be used as benchmark for further validation. In addition, as an alternative advanced composite application for rotating systems exposed to thermal load, the positive effects of CNT addition in improving the dynamic performance of the system have been observed and the results are presented in several tables and figures.

Development of fluorination methodology for carbon-fluorine bond formation: nucleophilic fluorinating reagents in the mid-2000s

  • Bae, Dae Young;Lee, Eunsung
    • Journal of Radiopharmaceuticals and Molecular Probes
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    • v.3 no.2
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    • pp.129-133
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    • 2017
  • Since carbon-fluorine (C-F) bonds play a key role to improve bioavailability and lipophilicity, they have found commonly in pharmaceuticals, radiopharmaceuticals, agrochemicals, and material science. Advances on the efficient method to introduce fluorine to complex organic molecules are mainly results of development of fluorination reagents and transition metal catalysts. In this mini-review, we want to emphasize two representative nucleophilic fluorinating reagents regarding carbon-fluorine bond formation, which were developed in the mid-2000s.

Chromate Removal from Wastewater using Micellar Enhanced Ultrafiltration and Activated Carbon Fibre Processes; Validation of Experiment with Mathematical Equations

  • Bade, Rabindra;Lee, Seung-Hwan
    • Environmental Engineering Research
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    • v.13 no.2
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    • pp.98-104
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    • 2008
  • In this study, chromate and cetylperidinium chloride (CPC) removal from artificial wastewater was monitored by using micellar enhanced ultrafiltration (MEUF) and activated carbon fibre (ACF) adsorption hybrid processes. For the efficient chromate removal, molar concentration of the CPC should be five times that of chromate and it should be at least one critical micelle concentration (CMC). The MEUF was found to be effective in the chromate removal while ACF in the CPC adsorption to produce chromate and CPC free effluents. The chromate and CPC removal was 99.8% from MEUF-ACF process. Effluent chromate concentration was exponentially correlated with molar ratio of CPC to chromate and pH.

Dynamic Mechanical Properties of the Symmetric Laminated high Strength Carbon Fiber Epoxy Composite Thin Beams (대칭 적층한 얇은 고강도 탄소섬유 에폭시 복합재 보의 기계적 동특성)

  • 정광섭;이대길;곽윤근
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.8
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    • pp.2123-2138
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    • 1994
  • A study on the dynamic mechanical properties of the high strength carbon fiber epoxy composite beam was carried out. The macromechanical model was used for the theoretical analysis of the symmetric laminated composite beam. The anisotropic plate theory and Bernoulli-Euler beam theory were used to predict the effective flexural elastic modulus and the specific damping capacity of laminated composite beam. The free flexural vibration and torsional vibration tests were carried out to determine the specific damping capacities of the unidirectional laminated composite beam. The vibration tests were performed in a vacuum chamber with laser vibrometer system and electromagnetic hammer to obtain accurate experimental data. From the computational and experimental results, it was found that the theoretical values with the macromechanical analysis and the experimental data of symmetric laminated composite beam were in good agreement.

SWCNT/Nafion Composite Development for Improvement of Mechanical Properties of IPMC (IPMC의 기계적 특성향상을 위한 SWCNT/Nafion 복합체 개발)

  • Kwon, Hui-June;Lee, Heon-Sang;Lee, Jung-Hwa;Jun, Chan-Bong;Kang, Jung-Ho
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.10 no.1
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    • pp.47-53
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    • 2011
  • From recent research, it has revealed that Electroacitve polymer(EAP) has a physical limitation. Carbon nanotube(CNT) is known as the promising material which has excellent electro-mechanical characteristics and is mostly defect-free. It is expected that a successful synthesis of CNT and Nafion known as a primary material for IPMC would make a great improvement on its electro-mechanic feature. In this paper, we suggest the method of synthesis of CNT with Nafion which improves electro-mechanical characteristic. Using mechanical dispersion with Nafion and Isopropyl Alcohol(IPA), we disperse Single-walled carbon nanotubes(SWCNT). For a uniformly layer of CNT, we used a spray gun on a hot plate by a simplified method. In the result, we fabricated a disperse SWCNT/Nafion composite uniformly.

Effects of Alloy Additions and Annealing Parameters on Microstructure in Cold-Rolled Ultra Low Carbon Steels (극저탄소 냉연강판에서 합금원소 및 어닐링조건이 미세조직에 미치는 영향)

  • Jeong, Woo Chang
    • Journal of the Korean Society for Heat Treatment
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    • v.17 no.2
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    • pp.78-86
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    • 2004
  • Effects of the annealing parameters on the formation of ferrites transformed at low temperatures were studied in cold-rolled ultra low carbon steels with niobium and/or chromium. Niobium and chromium were found to be effective in the formation of the low temperature transformation ferrites. The low temperature transformation ferrites more easily formed when both higher annealing temperature and longer annealing time, allowing substitutional alloying elements to distribute between phases, are in combination with faster cooling rate. It was found from EBSD study that the additions of niobium or chromium resulted in the increase in the numbers of high angle grain boundaries and the decrease in those of the low angle grain boundaries in the microstructures. Both granular bainitic ferrite and bainitic ferrite were characterized by the not clearly etched grain boundaries in light microscopy because of the low angle grain boundaries.

Molecular Dynamics Simulation of Friction and Wear Behavior Between Carbon and Copper (탄소와 구리의 마찰 및 마모에 관한 분자 동역학 시뮬레이션)

  • Kim Kwang-Seop;Kang Ji-Hoon;Kim Kyung-Woong
    • Tribology and Lubricants
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    • v.20 no.2
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    • pp.102-108
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    • 2004
  • In this paper, friction and wear behaviors between monocrystalline, defect-free copper and carbon on the atomic scale are investigated by using 2-dimensional molecular dynamics simulation. It is assumed that all interatomic forces are given by Morse potential. The deformation of carbon is assumed to be neglected and vacuum condition is also assumed. Average friction and normal forces for various surface conditions, various scratch speeds and scratch depths are obtained from simulations. Changes of wear behaviors for various scratch speeds and surface conditions are investigated by observing snapshots in scratch process. The effects of surface conditions, scratch speeds, and scratch depths on the friction force, normal force, and friction coefficient are also investigated.