• Journal of the Korean Society for Precision Engineering
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• v.29 no.3
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• pp.261-265
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• 2012

In this study, glassy carbon was ground for lens core of glass mold press. Ultraprecision grinding process was applied for machining of core surfaces. During the process, brittle crack occurred because of hard-brittleness of glassy carbon. Author investigated optimized grinding conditions from the viewpoint of ductile mode grinding. Geometrical undeformed chip thickness was adopted for critical chip thickness that enables crack free surface. Machined cores are utilized for biaspheric glass lens fabrication and surfaces of lens were compared for verification of ground surface.

• YAKHAK HOEJI
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• v.39 no.5
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• pp.516-520
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• 1995

The anti-dansyl antibodies were specifically labeled with stable isotope by growing hybridoma cells in serum-free medium. Assignments of the observed carbonyl carbon resonances have been determined by using $^{13}C-{15}N$ double labeling method in order to assign the Leu resonances. However, when the identical dipeptide appears more than twice in the polypeptide sequences, we applied the proteolytic fragments in the fragment-specific method. Carboxypep-tidase B-treated antibody has also been used to assign the Lys-447 in C terminal amino acid. These unambiguously assigned carbonyl carbon resonances in antibodies are thought to be useful in elucidating not only the structure of antibodies but also the structure-function relationship in the antibody by $^{13}C$ neuclear magnetic resonance spectroscopy.

• Advances in materials Research
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• v.7 no.3
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• pp.163-174
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• 2018

This article studies the free and forced vibrations of the carbon nanotubes CNTs embedded in an elastic medium including thermal and dynamic load effects based on nonlocal Euler-Bernoulli beam. A Winkler type elastic foundation is employed to model the interaction of carbon nanotube and the surrounding elastic medium. Influence of all parameters such as nonlocal small-scale effects, high temperature change, Winkler modulus parameter, vibration mode and aspect ratio of short carbon nanotubes on the vibration frequency are analyzed and discussed. The non-local Euler-Bernoulli beam model predicts lower resonance frequencies. The research work reveals the significance of the small-scale coefficient, the vibrational mode number, the elastic medium and the temperature change on the non-dimensional natural frequency.

• Journal of Korean Society of Water Science and Technology
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• v.26 no.6
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• pp.143-152
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• 2018

The process parameters of ethyl violet from aqueous solution by activated carbon adsorption were carried out as a function of pH, temperature, contact time, initial concentration and temperature. The adsorption equilibrium data can be described well by the Langmuir and Freundlich isotherm models. Base on Langmuir constant ($R_L=0.0343{\sim}0.0523$) and Freundlich constant (1/n=0.1633~0.1974), This process could be employed as effective treatment for adsorption of ethyl violet. The kinetic experimental results showed that the adsorption process can be well described with the pseudo second order model. Based on the positive enthalpy (6.505 kJ/mol), the adsorption of ethyl violet onto granular activated carbon is endothermic. The negative Gibbs free energy (-1.169~-1.681 kJ/mol) obtained indicates that the adsorption process is spontaneous and physisorption.

• Steel and Composite Structures
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• v.26 no.4
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• pp.513-531
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• 2018

In this article, static, buckling and free vibration analyses of a sinusoidal micro composite beam reinforced by single-walled carbon nanotubes (SWCNTs) with considering temperature-dependent material properties embedded in an elastic medium in the presence of magnetic field under transverse uniform load are presented. This system is used at micro or sub micro scales to enhance the stiffness of micro composite structures such as bar, beam, plate and shell. In the present work, the size dependent effects based on surface stress effect and modified strain gradient theory (MSGT) are considered. The generalized rule of mixture is employed to predict temperature-dependent mechanical and thermal properties of micro composite beam. Then, the governing equations of motions are derived using Hamilton's principle and energy method. Numerical results are presented to investigate the influences of material length scale parameters, elastic foundation, composite fiber angle, magnetic intensity, temperature changes and carbon nanotubes volume fraction on the bending, buckling and free vibration behaviors of micro composite beam. There is a good agreement between the obtained results by this research and the literature results. The obtained results of this study demonstrate that the magnetic intensity, temperature changes, and two parameters elastic foundations have important effects on micro composite stiffness, while the magnetic field has greater effects on the bending, buckling and free vibration responses of micro composite beams. Moreover, it is shown that the effects of surface layers are important, and observed that the changes of carbon nanotubes volume fraction, beam length-to-thickness ratio and material length scale parameter have noticeable effects on the maximum deflection, critical buckling load and natural frequencies of micro composite beams.

• Computers and Concrete
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• v.26 no.3
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• pp.213-226
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• 2020

The present study covenants with the static and free vibration behavior of nanocomposite sandwich plates reinforced by carbon nanotubes resting on Pasternak elastic foundation. Uniformly distributed (UD-CNT) and functionally graded (FG-CNT) distributions of aligned carbon nanotube are considered for two types of sandwich plates such as, the face sheet reinforced and homogeneous core and the homogeneous face sheet and reinforced core. Based on the first shear deformation theory (FSDT), the Hamilton's principle is employed to derive the mathematical models. The obtained solutions are numerically validated by comparison with some available cases in the literature. The elastic foundation model is assumed as one parameter Winkler - Pasternak foundation. A parametric study is conducted to study the effects of aspect ratios, foundation parameters, carbon nanotube volume fraction, types of reinforcement, core-to-face sheet thickness ratio and types of loads acting on the bending and free vibration analyses. It is explicitly shown that the (FG-CNT) face sheet reinforced sandwich plate has a high resistance against deflections compared to other types of reinforcement. It is also revealed that the reduction in the dimensionless natural frequency is most pronounced in core reinforced sandwich plate.

• Korean Journal of Materials Research
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• v.25 no.12
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• pp.672-677
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• 2015

Co-embedded graphitic porous carbon nanofibers(Co-GPCNFs) are synthesized by using an electrospinning method. Their morphological, structural, electrochemical, and photovoltaic properties are investigated. To obtain the optimum condition of Co-GPCNFs for dye-sensitized solar cells(DSSCs), the amount of cobalt precursor in an electrospinning solutuion are controlled to be 0 wt%(conventional CNFs), 1 wt%(sample A), and 3 wt%(sample B). Among them, sample B exhibited a high degree of graphitization and porous structure compared to conventional CNFs and sample A, which result in the performance improvement of DSSCs. Therefore, sample B showed a high current density(JSC, $12.88mA/cm^2$) and excellent power conversion efficiency(PCE, 5.33 %) than those of conventional CNFs($12.00mA/cm^2$, 3.78 %). This result can be explained by combined effects of the increased contact area between the electrode and elecytolyte caused by improved porosity and the increased conductivity caused by the formation of a high degree of graphitization. Thus, the Co-GPCNFs may be used as a promising alternative of Pt-free counter electrode in DSSCs.

• Composites Research
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• v.35 no.6
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• pp.412-418
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• 2022

Flame-retardant vinyl ester (VE) resin films were developed from the mixtures of brominated and non-brominated epoxy resins via esterification with methacrylic acid without reactive diluents. The films were used to fabricate carbon fiber (CF) prepregs via a hot melt impregnation process. The viscosity of VE resins suitable for film production was optimized by mixing low-viscosity bisphenol-A and high-viscosity brominated bisphenol-A epoxy precursors. Increasing the bromine content of the cured VE resin further increased the limited oxygen index (LOI) (39%), storage modulus (2.4 GPa) at 25℃ and residual carbonization (16.1%) values compared to non-brominated VE. Manual layup of as-prepared VE prepregs with subsequent curing led to the successful fabrication of CF-reinforced composites with high tensile and flexural strength. The results from the study hold high promise for a styrene-free, environmentally friendly VE composite process in the future.

• Transactions of Materials Processing
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• v.12 no.8
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• pp.744-749
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• 2003

The effect of tempering temperatures on microstructures and mechanical properties was studied in a low carbon steel. The disappearance of continuous yielding and the formation of an extended region in engineering stress-strain curves at tempering temperatures ranging from 673 to 873K was caused by the reduction of mobile dislocations during tempering and dynamic recovery during tensile deformation. In addition, the occurrence of discontinuous yielding in the sample treated at the tempering temperatures above 923K was attributed to the formation of new strain-free polygonal ferrite grain.

• Bulletin of the Korean Chemical Society
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• v.34 no.9
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• pp.2753-2759
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• 2013

The aim of the present study is to explore the possibility of utilizing fly ash and loess, as alternative to activated carbon, for the adsorption of diazinon in water. Batch adsorption experiment was performed to evaluate the influences of various factors like initial concentration, contact time and temperature on the adsorption of diazinon. The adsorption data shows that fly ash is not effective for the adsorption of diazinon. The equilibrium data for both activated carbon and loess were fitted well to the Freundlich isotherm model. The pseudo-second-order kinetic model appeared to be the better-fitting model because it has higher $R^2$ compared to the pseudo-first-order kinetic model. The thermodynamic parameters such as free energy (${\Delta}G$), the enthalpy (${\Delta}H$) and the entropy (${\Delta}S$) were calculated. Contrary to loess, the ${\Delta}G$ values of activated carbon were negative at the studied temperatures. It indicates that the adsorption of diazinon by activated carbon is a favorable and spontaneous process. The positive ${\Delta}H$ values of activated carbon and loess suggest that the diazinon adsorption process is endothermic in nature. In addition, the positive ${\Delta}S$ values show that increased randomness occurs at the solid/solution surface during the adsorption of diazinon.