• 제목/요약/키워드: Carbon-11

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내부 네트워크의 성능저하요인에 따른 이산화탄소 배출에 관한 연구 (A Study of Carbon Dioxide Emissions due to the Performance Degradation Factors of An Inner Network)

  • 전정훈
    • 한국통신학회논문지
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    • 제36권11B호
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    • pp.1315-1322
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    • 2011
  • 최근 지구온난화 문제는 전 세계의 매우 심각한 환경문제로 대두되고 있으며, 이를 해결하기 위한 방안으로 '그린 IT'가 이슈화되고 있다. 이러한 상황에서 네트워크는 진화와 함께 다양한 공격기술들이 나타나고 있어, 대부분의 여러 보안장치 및 시스템들을 추가 배치하고 있다. 그러나 이와 같은 네트워크 구축방법은 내부 네트워크의 성능과 보안에 큰 영향을 미치며, $CO_2$의 배출량을 증가시키고 있다. 따라서 본 논문은 내부 네트워크의 성능저하요인에 따른 $CO_2$배출을 분석하여, 향후 내부 네트워크의 성능 및 보안성 향상과 IT분야의 $CO_2$배출을 경감하기 위한 자료로 활용될 것으로 기대한다.

연성도 및 에너지 소산능력 비교에 따른 콘크리트충전 탄소섬유튜브 기둥의 성능 (Capacity of Concrete Filled Carbon Tube Columns Based on the Comparison of Ductility and Energy Dissipation Capacity)

  • 이경훈;홍원기;이영학;김희철
    • 한국지진공학회논문집
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    • 제11권1호
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    • pp.29-35
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    • 2007
  • 본 연구에서는 반복 횡하중을 받는 콘크리트충전 탄소섬유튜브기둥의 휨성능 평가실험을 수행하였다. 시험체의 단면형상은 각형과 원형이며 탄소삼유튜브의 두께 및 와인딩각도(winding angle)를 실험변수로 채택하였다. 모든 시험체는 건물의 한 층 높이와 유사한 높이를 갖는 full scale 크기로 제작되었으며 3대의 가력기(actuator)를 동시에 가동시켜 축하중과 횡하중을 가력하였다. 실험결과를 분석하여 기둥의 휨강도, 변형능력 및 에너지소산능력을 평가하였으며, 횡하중에 대한 기둥의 연성거동 또한 평가되었다.

페로브스카이트 ($La_{0.9}$$Sr_{0.1}$$CuO_3$) 전극에서 이산화탄소의 전해환원에 의한 알콜류 생성 (Carbon Dioxide Reduction to Alcoholson Perovskite-Type $La_{0.9}$$Sr_{0.1}$$CuO_3$ Electrodes)

  • 김태근;임준혁
    • 한국환경과학회지
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    • 제5권5호
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    • pp.677-682
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    • 1996
  • 페로브스카이트 ($La_{0.9}$$Sr_{0.1}$$CuO_3$) 전극을 이용하여 이산화탄소를 메탄올, 에탄올등의 알콜류와 아세트 알데히드로 전해환원하였다. 전해환원 실험은 전류밀도 100mA/c$m^2$ 그리고 환원 전위 -2 to -2.5 V vs. Ag/AgCl에서 수행하였다. 실험결과 메탄올은 11.6%, 에탄올은 15.3% 그리고 아세트알데히드는 6.2 %의 최고효율을 나타내었다. 따라서 페로브스카이트 전극은 알콜생성 면에서 기타 다른 금속전극에 비하여 매우 우수한 효과를 보여주었다.

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Preparation of Amine-epoxy Adducts(AEA)/Thin Multiwalled Carbon Nanotubes (TWCNTs) Composite Particles using Dry Processes

  • Jung, Hyun-Taek;Cho, Young-Min;Kim, Tae-Ho;Kim, Tae-Ann;Park, Min
    • Carbon letters
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    • 제11권2호
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    • pp.107-111
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    • 2010
  • We prepared the amine epoxy adducts (AEA)/thin multiwalled carbon nanotubes (TWCNTs) composite particles using nonsolvent based methods including dry mechano-chemical bonding(MCB) process and supercritical fluid (SCF) process. The resulting TWCNTs/AEA composite particles have been used as curing agents for urethane modified bispheol A type epoxy resin. The thermal, thermomechanical properties of the epoxy resins cured with TWCNTs/AEA composite particles were measured by DMA and the dispersion of CNT was characterized by SEM. Because of high degree of CNT dispersion, thermal and mechanical properties of the epoxy resin cured with TWCNTs/AEA composite particles prepared by SCF process are better than those cured with mechano-chemically prepared TWCNTs/AEA composite particles.

Effect of Interphase Modulus and Nanofiller Agglomeration on the Tensile Modulus of Graphite Nanoplatelets and Carbon Nanotube Reinforced Polypropylene Nanocomposites

  • Karevan, Mehdi;Pucha, Raghuram V.;Bhuiyan, Md.A.;Kalaitzidou, Kyriaki
    • Carbon letters
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    • 제11권4호
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    • pp.325-331
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    • 2010
  • This study investigates the effect of filler content (wt%), presence of interphase and agglomerates on the effective Young's modulus of polypropylene (PP) based nanocomposites reinforced with exfoliated graphite nanoplatelets ($xGnP^{TM}$) and carbon nanotubes (CNTs). The Young's modulus of the composites is determined using tensile testing based on ASTM D638. The reinforcement/polymer interphase is characterized in terms of width and mechanical properties using atomic force microscopy which is also used to investigate the presence and size of agglomerates. It is found that the interphase has an average width of ~30 nm and modulus in the range of 5 to 12 GPa. The Halpin-Tsai micromechanical model is modified to account for the effect of interphase and filler agglomerates and the model predictions for the effective modulus of the composites are compared to the experimental data. The presented results highlight the need of considering various experimentally observed filler characteristics such as agglomerate size and aspect ratio and presence and properties of interphase in the micromechanical models in order to develop better design tools to fabricate multifunctional polymer nanocomposites with engineered properties.

Anodic Stripping Voltammetric Detection of Arsenic(III) at Platinum-Iron(III) Nanoparticle Modified Carbon Nanotube on Glassy Carbon Electrode

  • Shin, Seung-Hyun;Hong, Hun-Gi
    • Bulletin of the Korean Chemical Society
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    • 제31권11호
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    • pp.3077-3083
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    • 2010
  • The electrochemical detection of As(III) was investigated on a platinum-iron(III) nanoparticles modified multiwalled carbon nanotube on glassy carbon electrode(nanoPt-Fe(III)/MWCNT/GCE) in 0.1 M $H_2SO_4$. The nanoPt-Fe(III)/MWCNT/GCE was prepared via continuous potential cycling in the range from -0.8 to 0.7 V (vs. Ag/AgCl), in 0.1 M KCl solution containing 0.9 mM $K_2PtCl_6$ and 0.6 mM $FeCl_3$. The Pt nanoparticles and iron oxide were co-electrodeposited into the MWCNT-Nafion composite film on GCE. The resulting electrode was examined by cyclic voltammetry (CV), scanning electron microscopy (SEM), and anodic stripping voltammetry (ASV). For the detection of As(III), the nanoPt-Fe(III)/MWCNT/GCE showed low detection limit of 10 nM (0.75 ppb) and high sensitivity of $4.76\;{\mu}A{\mu}M^{-1}$, while the World Health Organization's guideline value of arsenic for drinking water is 10 ppb. It is worth to note that the electrode presents no interference from copper ion, which is the most serious interfering species in arsenic detection.

Investigation of Narrow Pore Size Distribution on Carbon Dioxide Capture of Nanoporous Carbons

  • Meng, Long-Yue;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • 제33권11호
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    • pp.3749-3754
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    • 2012
  • Nanoporous carbons with a high specific surface area were prepared directly from thermoplastic acrylic resin as carbon precursor and MgO powder as template by carbonization over the temperature range, $500-1000^{\circ}C$. The effect of the carbonization temperature on the pore structure and $CO_2$ adsorption capacity of the obtained porous carbon was examined. The textural properties and morphology of the porous carbon materials were analyzed by $N_2/-196^{\circ}C$ and $CO_2/0^{\circ}C$ adsorption/desorption isotherms, SEM and TEM. The $CO_2$ adsorption capacity of the prepared porous carbon was measured at $25^{\circ}C$ and 1 bar and 30 bar. The specific surface area increased from 237 to $1251m^2/g$, and the total pore volumes increased from 0.242 to $0.763cm^3/g$ with increasing the carbonization temperature. The carbonization temperature acts mainly by generating large narrow micropores and mesopores with an average pore size dependent on the level of carbonization of the MgO-templated nanoporous carbons. The results showed that the MgO-templated nanoporous carbons at $900^{\circ}C$ exhibited the best $CO_2$ adsorption value of 194 mg/g at 1 bar.

탄소 단섬유가 첨가된 Cu기지 복합재료의 섬유 분율 및 배열에 따른 열적 특성 (Thermal Properties according to Content and Alignment of Carbon Fiber in Cu Matrix Composite Reinforced with Chopped Carbon Fiber)

  • 김민경;한준현
    • 한국재료학회지
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    • 제31권11호
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    • pp.626-634
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    • 2021
  • Cu matrix composites reinforced with chopped carbon fiber (CF), which is cost effective and can be well dispersed, are fabricated using electroless plating and hot pressing, and the effects of content and alignment of CF on the thermal properties of CF/Cu composites are studied. Thermal conductivity of CF/Cu composite increases with CF content in the in-plane direction, but it decreases above 10% CF; this is due to reduction of thermal diffusivity related with phonon scattering by agglomeration of CF. The coefficient of thermal expansion decreases in the in-plane direction and increases in the through-plane direction as the CF content increases. This is because the coefficient of thermal expansion of the long axis of CF is smaller than that of the Cu matrix, and the coefficient of thermal expansion of its short axis is larger than that of the Cu matrix. The thermal conductivity is greatly influenced by the agglomeration of CF in the CF/Cu composite, whereas the coefficient of thermal expansion is more influenced by the alignment of CF than the aggregation of CF.

광주지역 PM2.5 입자 수용성 성분의 화학적 특성조사 (Chemical Characteristics of Water Soluble Components in Fine Particulate Matter at a Gwangju area)

  • 박승식;조성용;김승재
    • Korean Chemical Engineering Research
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    • 제48권1호
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    • pp.20-26
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    • 2010
  • 수용성 유기 및 무기성분은 대기 에어로졸 입자의 중요한 구성성분들이며 간접적으로 기후에 영향을 미치는 구름응결핵으로 작용한다. 유기 및 원소탄소(organic and elemental carbon, OC 및 EC) 및 수용성 유기탄소(water soluble OC, WSOC) 및 이온성분농도를 조사하기 위하여 광주지역에서 24시간 기준의 미세입자($PM_{2.5}$)를 측정하였다. 측정기간 중 $PM_{2.5}$ 수용성 분율의 주요성분인 WSOC, $NO_3^-$, $SO_4^{2-}$$NH_4^+$의 평균농도는 각각 2.11, 5.73, 3.51 및 $3.31{\mu}g/m^3$ 이었으며, $PM_{2.5}$ 농도의 12.0(2.9~23.9%), 21.0(12.9~37.6%), 11.6(2.5~25.9%), 및 11.7%(3.8~18.6%)를 차지하였다. 총 수용성 성분(유기+무기) 중 WSOC 화합물이 차지하는 분율은 평균 17.6%(5.4~35.9%)이었다. EC 추적자 기법을 이용해 평가한 2차 OC 및 WSOC 농도는 각각 평균적으로 0.78 및 $0.34{\mu}g/m^3$이었으며, 전체 OC 및 WSOC 중의 평균 17.9%(범위: 0~44.4%) 및 평균 11.2%(범위: 0~51.4%)를 차지하였다. 광주지역 겨울철에 측정한 $SO_4^{2-}$ 입자는 국지적인 기상산화반응보다는 장거리 이동 또는 수용액 변환과정에 의한 영향, 구름 내 변환과정 등이 황산염 입자 생성에 중요하게 작용했을 것으로 판단한다.

지역 및 고도별 산불로부터 온실가스 배출량 분석 연구 (A Study on Analysis of Greenhouse Gas Emissions from Forest Fires Depending on Region and Altitude)

  • 박영주;이해평
    • 한국안전학회지
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    • 제27권3호
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    • pp.182-188
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    • 2012
  • In this study we analyzed carbon emissions of leaves of a Pinus densiflora which is vulnerable to a forest fire using the cone calorimeter in order to analyze greenhouse gas emissions from forest fires depending on region and altitude. Fuels were collected from 9 regions[Hongcheon(Gangwon-do), Chungsong(Gyeongbuk-do), Yanhpyeong (Gyeonggi-do), Jecheon(Chungchongbuk-do), Gongju(Chungcheongnam-do), Wuju(Jeollabuk-do), Youngam(Jeollanam-do), Busan and Jeju-do)] and 9 altitudes(80 m, 450 m, 900 m, 1000 m, 1100 m, 1200 m, 1300 m, 1400 m and 1500 m) and then, carbon dioxide and carbon monoxide emissions contained in a weight of 50 g of fuel were analyzed. According to the results, there were differences in carbon emissions by regional groups, as the average carbon dioxide and carbon monoxide emissions in 9 regions were nearly 43.5929 g to 52.8868 g, and 0.8842 g to 3.6422 g, respectively. Busan and Jecheon had relatively higher carbon dioxide emissions and especially, Busan had 1.23 times higher carbon dioxide emissions than Jeju-do. Also, Gongju, Chungcheongnamo Province and Busan had relatively higher carbon monoxide emissions and especially, Gongju and Pusan had relatively higher carbon monoxide emissions and especially, Gongju had 4.12 higher carbon monoxide emissions than Hongcheon. In addition, there were differences in carbon emissions too depending on altitude, since carbon dioxide and carbon monoxide emissions in 9 altitudes were respectively, 40.7015 g to 68.9297 g and 1.3923 g to 12.2918 g. At the altitude of 80m, carbon dioxide and carbon monoxide emissions were respectively, 68.9297 g and 12.2918 g, and at the altitude of 450m, carbon dioxide and carbon monoxide emissions were respectively, 65.5115 g and 11.2497 g. These results show that pine trees at the lower altitude discharge relatively more carbon. It is considered that this analysis on carbon emissions depending on region and altitude can be effectively used for predicting greenhouse gas emissions and establishing statistical data from forest fires in each region and altitude.