• 제목/요약/키워드: Carbon-11

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KOTRON-13 사이클로트론의 고효율C-11 가스 표적장치 (Development and optimization of C-11 gas target system in KOTRON-13 cyclotron)

  • 이홍진;이원경;박준형;문병석;이인원;채성기;이병철;김상은
    • 핵의학기술
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    • 제15권1호
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    • pp.86-89
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    • 2011
  • 최근 들어 양전자방출단층촬영(positron emission tomography, PET) 대표적인 진단검사인 FDG (2-[$^{18}F$]fluoro-2-deoxy-D-glucose)를 이용한 전신암 및 장기별 대사 검사뿐만 아니라 또 다른 양전자 방출 동위원소 탄소-11로 표지 된 다양한 방사성의약품 사용이 증가될 예정이다. 본 논문에서는 현재 국내에 설치 보급되어있는 국산 KOTRON-13 사이클로트론에 냉각 성능이 개선된 탄소-11 표적 장치를 설계, 제작하고, 다양한 생산시험을 통하여 탄소-11의 생산량 증대를 입증 하였다. 성공적으로 기존의 불소-18 타겟과 새로운 탄소-11 타겟 호환장치를 도입하였고, 실험 결과 고효율 탄소-11표적 장치가 내수성이 우수하고, 30분 조사 시 최대 2,000 mCi를 생산하였다. 본 시험결과를 통해 향후 불소-18만이 생산 가능했던 국산 KOTRON-13 사이클로트론에 효율적이고 안정적으로 탄소-11생산 시스템을 도입할 수 있음을 증빙하였다.

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Recent advances in carbon-11 chemistry

  • Lu, Yingqing;Lee, Byung Chul;Kim, Sang Eun
    • 대한방사성의약품학회지
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    • 제2권1호
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    • pp.9-16
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    • 2016
  • Carbon-11 is one of the most sensitive and desirable positron emission tomography radio-isotope, which offers the capacity to be incorporated, through a covalent bond, into biologically active molecules without altering their biological properties. Carbon-11 can be obtained from the cyclotron with two different chemical forms: $[^{11}C]CO_2$ and $[^{11}C]CH_4$. [$^{11}C$]Methyl iodide has been widely used as a highly reactive labelling precursor that can be applied to label carbon-11 with biologically active molecules via alkylation of N-, O-, or S-nucleophiles. A more recent and still challenging labeling method is transition metal mediated $^{11}C$-carbonylation. Advances in organic chemistry, radiochemistry and improved automated techniques greatly encourage researchers to develop more carbon-11 labelled radiotracers for molecular imaging studies. This mini-review will introduce a historical track of carbon-11 chemistry combining with examples and its role in near future.

방전플라즈마 소결법으로 제조된 탄소나노튜브 강화 SKD11 금형강의 분말소결 특성 (Powder Sintering Characteristics of Carbon Nanotubes Reinforced SKD11 Tool Steel Sintered by Spark Plasma Sintering)

  • 문제세;정성실;이대열;정영근;강명창;박춘달;윤국태
    • 한국분말재료학회지
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    • 제22권3호
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    • pp.157-162
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    • 2015
  • SKD11(ASTM D2) tool steel is a versatile high-carbon, high-chromium, air-hardening tool steel that is characterized by a relatively high attainable hardness and numerous, large, chromium rich alloy carbide in the microstructure. SKD11 tool steel provides an effective combination of wear resistance and toughness, tool performance, price, and a wide variety of product forms. Adding of CNTs increased the performance of mechanical properties more. 1, 3 vol.% CNTs was dispersed in SKD11 matrix by mechanical alloying. SKD11 carbon nanocomposite powder was sintered by spark plasma sintering process. FE-SEM, HR-TEM and Raman analysis were carried out SKD11 carbon nanocomposites.

탄소나노튜브 강화 SKD11 냉간금형용 하이브리드 탄소나노소결체 제조 및 특성 평가 (Fabrication and Characteristic Evaluation of Hybrid Carbon Nanotubes Reinforced SKD11 Cold Work Tool Steel)

  • 정성실;문제세;이대열;윤국태;박춘달;송재선
    • 한국분말재료학회지
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    • 제20권4호
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    • pp.291-296
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    • 2013
  • SKD11 (ASTM D2) tool steel is a versatile high-carbon, high-chromium, air-hardening tool steel that is characterized by a relatively high attainable hardness and numerous, large, chromium rich alloy carbide in the microstructure. SKD11 tool steel provides an effective combination of wear resistance and toughness, tool performance, price, and a wide variety of product forms. The CNTs was good additives to improve the mechanical properties of metal. In this study, 1, 3 vol% CNTs was dispersed in SKD11 matrix by mechanical alloying. The SKD11+ CNT hybrid nanocomposites were investigated by FE-SEM, particle size distribution, hardness and wear resistance. The CNT was well dispersed in the SKD11 matrix and the mechanical properties of the composite were improved by CNTs addition. It shows good feasibility as cold work die tool.

Formation of Isotropic Carbon Matrix in Carbon/Carbon Composites Derived from Pitch

  • Ahn, Chong-Jin;Park, In-Seo;Joo, Hyeok-Jong
    • Carbon letters
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    • 제11권4호
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    • pp.304-310
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    • 2010
  • To manufacture a carbon/carbon composite the coal tar pitch was used as the matrix precursor and the PAN (polyacrylonitrile)-based carbon fiber was used as the reinforcing material to weave 3-directional preform. For pressure carbonization HIP equipment was used to produce a maximum temperature of $1000^{\circ}C$ and a maximum pressure of 100 MPa. The carbonization was induced by altering the dwell temperature between $250^{\circ}C$ and $420^{\circ}C$, which is an ideal temperature for the moderate growth of the mesophase nucleus that forms within the molten pitch during the pressure carbonization process. The application of high pressure during the carbonization process inhibits the mesophase growth and leads to the formation of spherical carbon particles that are approximately 30 nm in size. Most particles were spherical, but some particles were irregularly shaped. The spread of the carbon particles was larger on the surface of the carbon fiber than in the interior of the matrix pocket.

A Review on Thermal Conductivity of Polymer Composites Using Carbon-Based Fillers : Carbon Nanotubes and Carbon Fibers

  • Hong, Jin-Ho;Park, Dong-Wha;Shim, Sang-Eun
    • Carbon letters
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    • 제11권4호
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    • pp.347-356
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    • 2010
  • Recently, the use of thermal conductive polymeric composites is growing up, where the polymers filled with the thermally conductive fillers effectively dissipate heat generated from electronic components. Therefore, the management of heat is directly related to the lifetime of electronic devices. For the purpose of the improvement of thermal conductivity of composites, fillers with excellent thermally conductive behavior are commonly used. Thermally conductive particles filled polymer composites have advantages due to their easy processibility, low cost, and durability to the corrosion. Especially, carbon-based 1-dimensional nanomaterials such as carbon nanotube (CNT) and carbon nanofiber (CNF) have gained much attention for their excellent thermal conductivity, corrosion resistance and low thermal expansion coefficient than the metals. This paper aims to review the research trends in the improvement of thermal conductivity of the carbon-based materials filled polymer composites.

활성탄의 pH에 따른 Ammonia, Hydrogen Sulfide 및 Methylmercaptan 흡착 특성 (Adsorption Characteristics of Ammonia, Hydrogen Sulfide and Methylmercaptan on Activated Carbons with Different pH)

  • 김정열;신창호;서문원;김종열;김영호;이근회
    • 한국연초학회지
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    • 제19권1호
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    • pp.46-50
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    • 1997
  • The pH of coconut based activated carbon was changed by treating with NaOH and HNO3 and we have calculated the adsorption amounts of ammonia, hydrogen sulfide and methylmercaptan on the activated carbons using the break-through time which was obtained from break-through curve experiments. As a result of this study, the adsorption amounts of ammonia Has on the activated carbons were 2,6 mg/g, 17.2 mg/g and 31.6 mg/g with the pH 11, pH 7 and pH 3, respectively. These results indicated that the adsorption ability of ammonia on activated carbon was increased with decreasing the pH of activated carbon. Otherwise, in the cases of the adsorption experiment of hydrogen sulfide and methylmercaptan on the activated carbons with different pH. the activated carbon with pH 11 showed higher adsorption capacity than the activated carbons with pH 7 and pH 3. The adsorption amounts of hydrogen sulfide and methylmercaptan were 39.9 mg/g and 178 mg/g with pH 11, respectively. Finally, we analyzed the amount of ammonia delivered from 88 Lights cigarette made of triple filter which contained the activated carbon. The amount of ammonia delivered to smoke from the filter cigarette containing the activated carbon with pH 3 was 45.1${\mu}g$/cig. This value was lower 23.8 % than that from the activated carbon with the pH 11.

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탄소섬유 물리적 특성 향상을 위한 스퍼터링 탄소박막의 특성에 대한 연구 (Characteristics of Sputtering Carbon Films for the Improvement of Physical Properties in Carbon Fiber)

  • 박철민;박용섭;김재문
    • 한국전기전자재료학회논문지
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    • 제28권11호
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    • pp.694-697
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    • 2015
  • We investigated the characterizations of carbon films fabricated by dual magnetron sputtering under various RF powers for the improvement of physical properties in carbon fiber (CF). All sputtered carbon films exhibited amorphous structure, regardless of RF powers, resulting in uniform and smooth surfaces. The hardness and elastic modulus are increased with the increase of RF power, and the adhesion and friction properties of carbon films were improved with the increase of RF power. In the results, The increase of RF power in the sputtering method improved tribological properties of the carbon films, and these attributes can be expected to improve the physical properties of the carbon fiber reinforcement plastics.