• 제목/요약/키워드: Carbon number distribution

검색결과 167건 처리시간 0.024초

Improving the Long-term Field Emission Stability of Carbon Nanotubes by Coating Co and Ni Oxide Layers

  • 최주성;이한성;이내성
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 추계학술발표대회
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    • pp.18.1-18.1
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    • 2011
  • Some applications of carbon nanotubes (CNTs) as field emitters, such as x-ray tubes and microwave amplifiers, require high current emission from a small emitter area. To emit the high current density, CNT emitters should be optimally fabricated in terms of material properties and morphological aspects including high crystallinity, aspect ratio, distribution density, height uniformity, adhesion on a substrate, low outgassing rate during electron emission in vacuum, etc. In particular, adhesion of emitters on the substrate is one of the most important parameters to be secured for high current field emission from CNTs. So, we attempted a novel approach to improve the adhesion of CNT emitters by incorporating metal oxide layers between CNT emitters. In our previous study, CNT emitters were fabricated on a metal mesh by filtrating the aqueous suspensions containing both highly crystalline thin multiwalled CNTs and thick entangled multiwalled CNTs. However, the adhesion of CNT film was not enough to produce a high emission current for an extended period of time even after adopting the metal mesh as a fixing substrate of the CNT film. While a high current was emitted, some part of the film was shown to delaminate. In order to strengthen the CNT networks, cobalt-nickel oxides were incorporated into the film. After coating the oxide layer, the CNT tips seemed to be more strongly adhered on the CNT bush. Without the oxide layer, the field emission voltage-current curve moved fast to a high voltage side as increasing the number of voltage sweeps. With the cobalt-nickel oxide incorporated, however, the curve does not move after the second voltage sweep. Such improvement of emission properties seemed to be attributed to stronger adhesion of the CNT film which was imparted by the cobalt-nickel oxide layer between CNT networks. Observed after field emission for an extended period of time, the CNT film with the oxide layer showed less damage on the surface caused by high current emission.

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앙골라분지 백악기 흑색셰일의 유기물상 (Kerogen Facies of the Cretaceous Black Shales from the Angola Basin (DSDP Site 530), South Atlantic)

  • 박영수
    • 한국해양학회지
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    • 제22권2호
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    • pp.87-104
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    • 1987
  • 앙골라분지 심해시추연구(DSDP) 정점 530에서의 중기 백악기층은 유기탄소의 함량이 풍부한 흑색셰일과 유기탄소의 함량이 빈약한 적색 및 녹색의 점토암이 주 기적으로 교호한다. 이들 흑색셰일층의 퇴적환경을 밝히기 위하여 이들 중에 함유 된 불용성퇴적 유기물(Kerogen)의 종류 및 그 분포에 관하여 분석하였다. 앙골라분 지 백악기 흑색셰 일층에 함유된 유기물의 종류는 대부분 무정형유기물(Amorphous Organic Matter)로서, 이들의 주된 기원은 부유성 해양 조류. 즉 화석화되지 않은 해양 부유성 쌍편모충류로 추정되었다. 이들 부유성 조류는 환경의 변화에 따라 주 기적으로 다량 번식하여 앙골라 심해저로 공급됨으로써 , 백악기 당시 용존산소의 농도가 현재보다 훨씬 낮고 폐쇄된 환경의 앙골라 심해저에 환원환경을 주기적으로 야기시켜 유기물의 집적을 용이하게 함으로써 흑색셰일층이 형성되었음이 추측된 다.

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NEAR-INFRARED PAH FEATURES IN GALACTIC PLANETARY NEBULAE

  • Ohsawa, R.;Onaka, O.;Sakon, I.;Mori, T. I.;Kaneda, H.;Matsuura, M.
    • 천문학논총
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    • 제32권1호
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    • pp.87-91
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    • 2017
  • Polycyclic aromatic hydrocarbons (PAHs) are considered to be carriers of the unidentified infrared bands, which are ubiquitously observed in the Universe. PAHs are mainly formed around evolved carbon-rich stars and injected into interstellar space. Planetary nebulae (PNe), a late stage of low- and intermediate stellar mass evolution, are suitable objects to investigate the formation and evolution of PAHs. The shortest PAH feature is located in $3.3{\mu}m$, which is important to examine the excitation and size distribution of PAHs. While the number of samples had been limited before, the high sensitivity of AKARI /IRC has drastically increased the number of samples. We obtained the $2-5{\mu}m$ spectra of Galactic PNe with AKARI /IRC and compiled a near-infrared spectral catalog, containing 73 PNe. We investigate the detection rate and the evolution of the PAH features. The characteristics of the catalog are illustrated and the origin of the evolution of the PAH features is discussed.

급수관내 염소 주입이 미생물의 증식과 부식에 미치는 영향 (The Influence of Chlorine Application on Corrosion and Bacterial Growth in Home Plumbing Systems)

  • 김태현;이윤진;임승주
    • 한국환경보건학회지
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    • 제32권5호
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    • pp.431-439
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    • 2006
  • This research was conducted using a model home plumbing system composed of copper, stainless steel, galvanized iron, carbon steel, and PVC (polyvinyl chloride) pipe. The number of bacteria present in stainless steel pipe and PVC was higher than other pipes. High turbidity and zinc release were found in galvanized iron pipe material and detected during the first 6 months. Conversely, there was a decrease in turbidity and zinc release after 6 months resulting in levels similar to other pipes. Copper concentration decreased as operation times increased. In this experiment, the number of bacteria detected in biofilm for a copper pipe continued to increase. Pipe material influenced bacterial numbers in biofilm and water. This showed that elevated chlorine could not control bacterial growth in biofilm for galvanized iron and stainless steel systems. It also suggested that the dosing of chlorine might not be available for all kinds of pipes. Therefore, another complementary method should be introduced to manage biofilm effectively in water distribution systems.

4대강 보 건설에 따른 실지렁이류(Aquatic Oligochaeta) 서식분포 특성 비교 (Comparison of the habitat distribution characteristics of Aquatic Oligochaeta according to the construction of weirs in four major rivers in South Korea)

  • 왕주현;박형준;박정호;송행섭;김호준;박연정;최준길;이황구
    • 환경생물
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    • 제37권4호
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    • pp.607-617
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    • 2019
  • 본 연구는 4대강 보 설치에 따른 실지렁이류의 분포 특성을 파악하고자 연구를 실시하였다. 현지조사는 2018년 3월부터 10월까지 총 10회 실시하였다. 조사결과 총 18종 35,390 ind. m-2 개체가 출현하였다. Limnodrilus hoffmeisteri (77.1%)이 우점종, Branchiura sowerbyi (9.5%)이 아우점종으로 분석되었다. 건중량 분석결과 총 32.418 g m-2이 계측되었으며, 각 종별 건중량과 TOC 농도와의 상관 분석 결과 실지렁이, 아가미지렁이와 TOC 농도 간 음의 상관성을 갖는 것으로 나타났다. 실지렁이류와 물리적·이화학적 요인들 간의 다변량 상관분석 결과 퇴적토 깊이, Clay 비율, Silt 비율, Cobble 비율, Pebble 비율, pH, TOC 항목과 상관성을 갖는 것으로 분석되었다(p<0.05, p<0.01). 조사지역별 실지렁이류 개체수와 퇴적토 깊이 및 Clay의 비율과 비교·분석한 결과 퇴적토의 깊이와 Clay의 비율이 높을수록 개체수가 많은 것으로 나타났다. 조사시기에 따른 실지렁이류의 개체수, TOC 비교·분석결과 3월부터 10월까지 개체수는 감소하는 경향성을 나타냈으며, TOC는 증가하는 경향성을 갖는 것으로 분석되었다.

Thermochemical Sulfate Reduction Simulation Experiments on the Formation and Distribution of Organic Sulfur Compounds in the Tuha Crude Oil

  • Yue, Changtao;Li, Shuyuan;Song, He
    • Bulletin of the Korean Chemical Society
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    • 제35권7호
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    • pp.2057-2064
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    • 2014
  • Thermochemical sulfate reduction (TSR) was conducted in autoclave on the system of crude oil and $MgSO_4$ at different temperatures. Gas chromatography pulsed flame photometric detector (GC-PFPD) was used to detected the composition of organic sulfur compounds in oil phase products. The results of the analysis indicate that with increased temperature, the contents of organic sulfur compounds with high molecular weight and thermal stability, such as benzothiophenes and dibenzothiophenes, gradually became dominated. In order to gain greater insight into the formation and distribution of organic sulphur compounds from TSR, positive ion electrospray Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) was used in detecting the detailed elemental composition and distribution of them. The mass spectra showed that the mass range of sulfur compounds was 200-550 Da. Four sulfur class species, $S_1$, $N_1S_1$, $O_1S_1$ and $O_2S_1$, were assigned in the positive-ion spectrum. Among the identified sulfur compounds, the $S_1$ class species was dominant. The most abundant $S_1$ class species increase associated with the DBE value and carbon number increasing which also indicates the evolution of organic sulfur compounds in TSR is from the labile series to the stable one. In pure blank pyrolysis experiments with crude oil cracking without TSR, different composition and distribution of organic sulfur compounds in oil phase products were seen from mass spectra in order to evaluate their pyrolysis behaviors without $MgSO_4$. FT-IR and XRD were used in analyzing the products of solid phases. Two distinct crystallographic phases MgO and $MgSO_4$ are found to coexist in the products which demonstrated the transformation of inorganic sulfur compounds into organosulfur compounds exist in TSR.

엔진오일 내 연료성분 정량분석 (Quantitative Analysis of Fuel in Engine Oil)

  • 임영관;김지연;나용규;김종렬
    • 공업화학
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    • 제28권6호
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    • pp.714-719
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    • 2017
  • 연료가 혼합된 엔진오일은 차량의 문제(엔진마모, 화재, 급발진 등)를 초래하여, 운전자의 안전을 위협할 수 있다. 본 연구에서는 연료가 혼합된 엔진오일의 다양한 성능을 분석하였다. 분석결과, 연료혼합 엔진오일은 인화점, 유동점, 밀도, 동점도, 저온 겉보기점도가 낮아졌다. 사구법 내마모성능시험에서는 연료가 혼합된 엔진오일이 열악한 윤활성으로 마모흔(wear scar)이 증가하였다. 또한 우리 연구팀은 ASTM D2887 방법을 적용한 고온모사증류시험(SIMDIST, simulated distillation)을 통해 엔진오일 내 연료성분을 분석하였다. SIMDIST 분석결과 연료는 엔진오일보다 짧은 머무름시간을 보였으며, 엔진오일 내 연료성분의 정량분석이 가능하였다. 이 SIMDIST 분석방법을 통해 기존 많은 분석장비, 시료양, 분석시간이 필요한 물성분석법을 대신하여 엔진오일 내 연료 오염여부 및 정도를 효과적으로 판단할 수 있을 것이다.

용매 추출법에 의한 분해경유중의 방향족 분리 -추출상중의 방향족의 역수출- (Separation of Aromatics in Light Cycle Oil by Solvent Extraction - Re-extraction of Aromatics in Extract Phase -)

  • 김수진;김덕현
    • 공업화학
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    • 제8권6호
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    • pp.967-972
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    • 1997
  • 접촉분해경유(LCO)와 dimethylsulfoxide(DMSO)수용액의 평형추출로부터 얻어진 추출상을 원료로 사용한 역추출에 의해 추출상중의 방향족의 회수를 검토했다. 역추출 용매의 선정을 위해, Benzene, Toluene, m-Xylene(mX), n-Hexane(Hx)과 n-Octane(Ot)을 용매로 사용하여 추출상-용매간의 분배평형을 측정한 결과, 추출상중의 방향족의 회수면에서 Hx이 가장 적절한 용매이었다. 또, Hx을 용매로 사용하여 평형 역추출을 행해 방향족의 회수에 대한 조작인자의 영향을 검토했다. 방향족에 대한 분배계수는 용매/원료(추출상) 질량비(S/F)(S/F를 변화시켜 얻어진 추잔상 혹은 추출상중의 질량분율)에 관계없이 일정했으나 수율은 S/F가 증가함에 따라 증가했다. 조작온도는 방향족의 분배계수와 수율에 영향을 미치지 못했다. 나프탈렌류 성분(탄소수:10~12)간에는 탄소수가 많을수록 분배계수 및 수율이 컸다. 또한, 회분 교반조를 사용하여 역추출을 행해 방향족 성분의 물질이동 속도를 측정했다.

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Fungal Clusters and Their Uniqueness in Geographically Segregated Wetlands: A Step Forward to Marsh Conservation for a Wealth of Future Fungal Resources

  • Park, Jong Myong;Hong, Ji Won;Lee, Woong;Lee, Byoung-Hee;You, Young-Hyun
    • Mycobiology
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    • 제48권5호
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    • pp.351-363
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    • 2020
  • Here, we investigated fungal microbiota in the understory root layer of representative well-conserved geographically segregated natural wetlands in the Korean Peninsula. We obtained 574,143 quality fungal sequences in total from soil samples in three wetlands, which were classified into 563 operational taxonomic units (OTU), 5 phyla, 84 genera. Soil texture, total nitrogen, organic carbon, pH, and electrical conductivity of soil were variable between geographical sites. We found significant differences in fungal phyla distribution and ratio, as well as genera variation and richness between the wetlands. Diversity was greater in the Jangdo islands wetland than in the other sites (Chao richness/Shannon/Simpson's for wetland of the Jangdo islands: 283/6.45/0.97 > wetland of the Mt. Gariwang primeval forest: 169/1.17/0.22 > wetland of the Hanbando geology: 145/4.85/0.91), and this variance corresponded to the confirmed number of fungal genera or OTUs (wetlands of Jangdo islands: 42/283> of Mt. Gariwang primeval forest: 32/169> of the Hanbando geology: 25/145). To assess the uniqueness of the understory root layer fungus taxa, we analyzed fungal genera distribution. We found that the percentage of fungal genera common to two or three wetland sites was relatively low at 32.3%, while fungal genera unique to each wetland site was 67.7% of the total number of identified fungal species. The Jangdo island wetland had higher fungal diversity than did the other sites and showed the highest level of uniqueness among fungal genera (Is. Jangdo wetland: 34.5% > wetland of Mt. Gariwang primeval forest: 28.6% > wetland of the Hanbando geology: 16.7%).

확률분포를 이용한 취성재료 특성의 탄소섬유보강폴리머 인장물성평가 및 보정 (Evaluation and Modification of Tensile Properties of Carbon Fiber Reinforced Polymer(CFRP) as Brittle Material with Probability Distribution)

  • 김윤곤
    • 한국구조물진단유지관리공학회 논문집
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    • 제23권3호
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    • pp.17-24
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    • 2019
  • 탄소섬유보강폴리머(CFRP)는 경량이며, 성형성 및 작업성이 뛰어나 보수보강재료로서 널리 사용되고 있다. 하지만, 연성재료인 철근과는 달리 CFRP는 취성재료이므로, 철근에서 사용되는 전통적인 설계접근 방법을 적용하는 것은 부적합하다. 연성재료인 철근은 항복이후 요소사이의 응력재분배가 이뤄져 복합요소의 거동은 평균화된다. 따라서 복합요소의 응력 평균은 단위요소의 평균과 같고, 표준편차는 더 작아진다. 따라서 연성재료의 설계값은 증가시킬 수 있으나, 안전측, 실무적 접근에서 고정값을 사용한다. 반면 취성재료의 경우, 응력재분배를 기대하기 어려워 복합요소의 거동은 더 약한 요소에 의해 결정된다. 이에 복합요소의 응력의 평균값과 표준편차는 감소한다. 따라서 취성재료의 설계값은 요소수가 증가할수록 감소한다. 이 논문에서는 취성재료에서 정규분포를 가지는 단위요소가 요소 결합에 따라 와이블 분포를 가지게 됨을 증명하고, 이를 반영하여 하중이 작용하는 면적에 따른 물성치의 보정식을 제안하였다.