• Title/Summary/Keyword: Carbon number distribution

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Assessment of the Locations for Carbon Monoxide Monitoring Stations in Daegu according to Emission Distribution (배출량 분포에 따른 대구시 일산화탄소 측정망 위치의 적절성 평가)

  • Kim, Hyo-Jeong;Jo, Wan-Kuen
    • Spatial Information Research
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    • v.20 no.2
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    • pp.25-34
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    • 2012
  • Air quality in Daegu area is lower compared to many other cities, since Daegu is a basin surrounded by mountains. Accordingly, the present study investigated the location of carbon monoxide(CO) monitoring stations for systematic CO pollution management on the basis of the CO emission distribution in Daegu area. In order to achieve this purpose, the location of CO monitoring stations, which can be used for the establishment of CO management, were assessed. Emission map in Daegu area was prepared using numerical map and Clean Air Policy Support System(CAPSS) data supplied by the M inistry of Environment. Average emissions were estimated by dividing emission sources into four subgroups(roadway, apartment, industry, and municipal incineration facility) according to legal division. The CO emission intensities were subdivided into 10, which a high number represents a high emission intensity, and the current monitoring stations were evaluated for the determination of their steps in CO emission intensities. As a result, additional installation of monitoring stations were suggested for the high CO emission areas rather than the low CO emission areas. A systematic CO management strategy would be established by the supplying various principle CO data when the CO monitoring stations are additionally installed at Kukwudong and other six sites on the basis of analyses of data obtained from 1999 to 2007.

A Study on the Status of Air and Water Pollutants Emission from Industries in Korea (전국(全國) 산업장(産業場)에서 배출(排出)되는 오염물질량(汚染物質量)에 관(關)한 연구(硏究))

  • Cha, Chul-Hwan;Jang, Chang-Supp;Kim, Hyung-Won;Sung, Young-Ja
    • Journal of Preventive Medicine and Public Health
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    • v.6 no.1
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    • pp.27-41
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    • 1973
  • In order to provide some basic data for the control of air and water pollution in Korea, the authors have estimated the amount of air and water pollutants emitted from industries which are employed over 20 employees. This study have done from July 1, 1972 to the end of March 1973. The results are as followings; 1. Total number of establishments with over 20 employees is 5,197 in Korea and the largest group establishments was the manufacturing of textiles with 1,363 establishments (26.2%). 2. By order of number of employees it was observed that there 2,800 industries with 20-59(53.9%) employees, 1,101 with 50-99 (21.2%), 571 with 100-199 (11.0%), 501 with 200-499 (9.6%) and 225 with over 500 (4.3%) respectively. 3. By order of regional distribution, it was observed that there were 2,257 industries in Seoul (43.2%) and 736 industries in Pusan(14.2%). 4. Industrial coal consumption was 596,154 M/T in 1972, but it' 11 be 315,000 M/T in 1980. Fuel consumption was 4,972,000 K1 in 1972, and estimated volume will be 19,370,000 K1 in 1980. 5. Total amounts of air polutants entitled from industries by fuel combustion were sulfur oxides 79,459 tons, carbon monoxide 33,908 tons, particulate 31,304 tons and hydrocarbon 30,280 tons in 1972 but in 1990 there will be sulfur oxides 1,010,474 tons, nitrogen oxides 204,575 tons, carbon monoxide 68,014 tons, particulate 64,820 tons and hydrocarbon 67,622 tons, respectively. 6. Annual emitted air pollutants through the working processes were sulfur oxides 91,250 tons and nitrogen oxides 32,485 tons in 1972, but sulfur oxides 118,625 tons and nitrogen oxides 42,555 tons will be present in 1980, respectively. 7. Annual emitted air pollutants by national unit area amounted to $0.77ton/km^2/year$ in 1965 and $14.7ton/km^2/year$ in 1980. 8. Total industrial wastes from all industries in Korea were estimated at 810,360 tons/day in 1972; manufacturing of chemicals and plastic products showed the highest amount of wastes at 470,000 tons/day. 9. The amounts of water pollutants due to industrial wastes were the B.O.D., 471.5 tons/day, suspended solid 331.5 tons/day, CN, 2.3 tons/day, and Cr. 3.4 tons/day in 1972, but it might be evident of a B.O.D. of 3,388 tons/day, suspended solid 2,544 tons/day, CN 20.1 tons/day, and 26.5 tone/day in 1990. 10. Total population equivalent of B.O.D. was 943,000 in 1972, and the estimated value in 1950 will be 6,780,000.

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Comparing Exhaust Gas Emission and PN in LPG and CNG Vehicle under FTP-75 and WLTC Test Mode (FTP-75, WLTC 시험 모드에서 LPG, CNG 자동차의 배출가스 및 PN 비교)

  • Jang, Jinyoung;Lee, Youngjae;Kwon, Ohseok;Kim, Jeonghwan
    • Journal of the Korean Institute of Gas
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    • v.20 no.6
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    • pp.9-15
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    • 2016
  • Liquefied petroleum gas (LPG) and compressed natural gas (CNG) are often used as fuel for vehicles because they are clean alternative gas fuels. CNG, as a low-carbon fuel, can contribute to the reduction of greenhouse gas emissions. LPG is often used as fuel for taxis because the performance is almost the same as that of gasoline but the price is lower. In the present study, the exhaust gas and the particle number (PN) of particulate matter, which is a recent environmental issue, were compared between LPG and CNG for the same vehicle. A chassis dynamometer was used to conduct the test according to the Federal Test Procedure (FTP)-75 and Worldwide harmonized Light-duty vehicle Test Procedure (WLTC) modes. The PN values of discharged particles having sizes of 5 nm or larger and 23 nm or larger were measured using two condensation particle counters (CPC). The ratio of carbon dioxide was high in the exhaust gas from the LPG vehicle; the ratio of methane was high in the exhaust gas from the CNG vehicle. The PN values of the emitted particles from the two fuels were similar. The PN values of particles having sizes of 23 nm or smaller were high in the high-speed WLTC mode.

Ultrafine Particle Events in the Ambient Atmosphere in Korea

  • Maskey, Shila;Kim, Jae-Seok;Cho, Hee-Joo;Park, Kihong
    • Asian Journal of Atmospheric Environment
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    • v.6 no.4
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    • pp.288-303
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    • 2012
  • In this study, real time measurements of particle number size distribution in urban Gwangju, coastal Taean, and industrial Yeosu in Korea were conducted in 2008 to understand the occurrence of ultrafine particle (UFP) (<100 nm) events, the variation of its concentration among different sampling sites, and UFP formation pathways. Also, to investigate seasonal and long-term variation of the UFP number concentration, data were collected for the period of 5 years (2007, 2008, 2010, 2011, and 2012) in urban Gwangju. Photochemical and combustion events were found to be responsible for the formation of UFP in the urban Gwangju site, whereas only photochemical event led to the formation of UFP in the coastal Taean site. The highest UFP concentration was found in industrial Yeosu (the average UFP number fractions were 79, 59 and 58% in Yeosu, Gwangju, and Taean, respectively), suggesting that high amount of gas pollutants (e.g., $NO_2$, $SO_2$, and volatile organic carbon (VOC)) emitted from industries and their photochemical reaction contributed for the elevated UFP concentration in the industrial Yeosu site. The UFP fraction also showed a seasonal variation with the peak value in spring (61.5, 54.5, 50.5, and 40.7% in spring, fall, summer, and winter, respectively) at urban Gwangju. Annual average UFP number concentrations in urban Gwangju were $5.53{\times}10^3\;cm^{-3}$, $4.68{\times}10^3\;cm^{-3}$, $5.32{\times}10^3\;cm^{-3}$, $3.99{\times}10^3\;cm^{-3}$, and $2.16{\times}10^3\;cm^{-3}$ in the year 2007, 2008, 2010, 2011, and 2012, respectively. Comparison of the annual average UFP number concentration with urban sites in other countries showed that the UFP concentrations of the Korean sites were lower than those in other urban cities, probably due to lower source strength in the current site. TEM/EDS analysis for the size-selected UFPs showed that the UFPs were classified into various types having different chemical species. Carbonaceous particles were observed in both combustion (soot and organics) and photochemical events (sulfate and organics). In the photochemical event, an internal mixture of organic species and ammonium sulfate/bisulfate was identified. Also, internal mixtures of aged Na-rich and organic species, aged Ca-rich particles, and doughnut shaped K-containing particles with elemental composition of a strong C with minor O, S, and K-likely to be originated from biomass burning nearby agricultural area, were observed. In addition, fly ash particles were also observed in the combustion event, not in the photochemical event.

Study of FAME components and total contents on Micro-algal Biodiesel derived from Dunaliella tertiolecta (Dunaliella tertiolecta를 이용한 미세조류 유래 바이오디젤의 FAME 성분 특성 연구)

  • Lee, Don-Min;Min, Kuyung-Il;Yim, Eui-Soon;Ha, Jong-Han;Lee, Choul-Gyun;Lee, Bong-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.2
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    • pp.320-328
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    • 2014
  • Biodiesel has very similar physical properties (density, kinematic viscosity) and has even higher cetane number compare with conventional diesel. There are no necessity to change or modify the infra-structure & engine system. It is known that fatty acid methyl ester (FAME) is oxygen-contained components increasing the combustibility, biodegradability and reduced the exhaust harmful gas. These things made the biodiesel more popular as an alternative diesel fuel. But biodiesel's sources are controversial issues about $CO_2$ reduction effect at this time because those mainly come from edible plants such as soy, palm, rapeseed already spent lot of $CO_2$ to cultivate. Whereas micro-algae is focused because they are inedible and has rapid growth rates & high carbon-dioxide adsorption rate per area. In this study, we analyze the each FAME components using $GC{\times}GC$-TOFMS in stead of GC-FID and verify the previous total FAME contents method's applicability through the micro algal biodiesel derived from Dunaliella tertiolecta.

Microbial Communities of Activated Sludge in an Anaerobic/Aerobic Sequencing Batch Reactor using Slot Hybridization (Slot Hybridization을 이용한 연속 회분식 반응기내 미생물 분포 조사)

  • Jeon, Che Ok;Shin, Kum-Joo;Lee, Dae Sung;Suh, Pann-Ghill;Park, Jong Moon
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.5
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    • pp.939-947
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    • 2000
  • Enhanced biological phosphorus removal (EBPR) was performed in an anaerobic/aerobic sequencing batch reactor (SBR). Influent was a synthetic wastewater based on acetate as a carbon source. The sludge age and hydraulic retention time were kept at 10 days and 16 hrs, respectively, Phosphate release during the anaerobic period and phosphate uptake in aerobic period were increased gradually with time. and after about 200 days, steady-state operation could be achieved with complete removal of influent phosphate. Number distribution of microbial community in the sludge performing EBPR was investigated during the steady state operation. 17 rRNA targeted oligonucleotide probes were designed and slot hybridization technique was used to determine the number distribution of each microorganism. In the acetate fed SBR, rRNA belonging to the beta subclass of proteobacteria was the most dominant in total rRNA and rRNA matching to CTE probe was the second, rRNAs of Acinetobacter, Aeromonas and Pseudomonas, which are usually thought as phosphorus accumulating organisms in EBPR processes, constituted less than 10% of total rRNA. From this community analysis, it was inferred that microorganisms belong to the beta subclass of proteobacteia (BET) and CTE such as Rhodocyclus group were important in biological phosphorus removal. Therefore, the role of Acinetobacter, Aeromonas and Pseudomonas in the EBPR might have been overestimated.

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Hydrogenation of Polycyclic Aromatic Hydrocarbons Over Pt/Kieselguhr Catalysts in a Trickle Bed Reactor (Trickle Bed Reactor에서 Pt/Kieselguhr 촉매를 이용한 다환방향족 탄화수소 수소화 반응)

  • Seung Kyo, Oh;Seohyeon, Oh;Gi Bo, Han;Byunghun, Jeong;Jong-Ki, Jeon
    • Clean Technology
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    • v.28 no.4
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    • pp.331-338
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    • 2022
  • The objective of this study is to prepare bead-type and pellet-type Pt (1 wt%)/Kieselguhr catalysts as hydrogenation catalysts for the polycyclic aromatic hydrocarbons (PAHs) included in pyrolysis fuel oil (PFO). The optimal reaction temperature to maximize the yield of saturated cyclic hydrocarbons during the PFO-cut hydrogenation reaction in a trickle bed reactor was determined to be 250 ℃. A hydrogen/PFO-cut flow rate ratio of 1800 was found to maximize 1-ring saturated cyclic compounds. The yield of saturated cyclic compound increased as the space velocity (LHSV) of PFO-cut decreased. The difference in hydrogenation reaction performance between the pellet catalyst and the bead catalyst was negligible. However, the catalyst impregnated by Pt after molding the Kieselguhr support (AI catalyst) showed higher hydrogenation activity than the catalyst molded after Pt impregnation on the Kieselguhr powder (BI catalyst), which was a common phenomenon in both the pellet catalysts and bead catalysts. This may be due to a higher number of active sites over the AI catalyst compared to the BI catalyst. It was confirmed that the pellet catalyst prepared by the AI method had the best reaction activity of the prepared catalysts in this study. The majority of the PFO-cut hydrogenation products were cyclic hydrocarbons ranging from C8 to C15, and C11 cyclic hydrocarbons had the highest distribution. It was confirmed that both a cracking reaction and hydrogenation occurred, which shifted the carbon number distribution towards light hydrocarbons.

Development of Casting Furnace for Directional Solidification Ingot (잉곳의 방향성 응고를 위한 주조 로 개발)

  • Ju, Jin-Young;Lee, Seung-Jun;Baek, Ha-Ni;Oh, Hun;Cho, Hyun-Seob;Lee, Choong-Hun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.2
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    • pp.808-816
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    • 2012
  • This paper is the study for the directional solidification of the ingot through the thermal analysis simulation and structural change of casting furnace. With the results of thermal analysis simulation, the silicon as a whole has reached the melting temperature as the retention time 80 min. The best cooling conditions showed at the upper cooling temperature $1,400^{\circ}C$ and cooling time 60min. The fabricated wafers showed the superior etching result at the grain boundary than that of existing commercial wafers. The FTIR measurements of oxygen and carbon impurities were not in the critical value for solar conversion efficiency. The NAA analysis of metal impurities were also detected the total number of 18 different metals, but the concentration distribution showed no significant positional deviations in the same position from the top to the bottom.

The Passenger Evacuation Simulation Using Fluent and EXODUS (Fluent와 EXODUS를 이용한 승객피난 시뮬레이션)

  • Jang, Yong-Jun;Lee, Chang-Hyun;Park, Won-Hee;Jung, Woo-Sung
    • Journal of the Korean Society for Railway
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    • v.11 no.1
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    • pp.95-100
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    • 2008
  • The simulation analysis of fire-driven flow and passenger evacuation in Daegu subway station, Chung-Ang, have been performed. The first location of outbreak of fire is inside passenger car in the third basement in Chung-Aug station, The smoke flow in the second and third basement has been analyzed using FLUENT 6.2. The CO (carbon monoxide) and temperature distribution in the train units and station platform have been obtained and transferred to input data for evacuation simulation. The highest temperature in the train units was 1500k. For the simulation of passenger evacuation, EXODUS has been used for whole basements (level 1${\sim}$level 3) in the station. Total number of people was assumed to be one thousand and 640 were placed inside train and 360 were placed outside train. In evacuation simulation, an average of 135 passengers were killed and an average time to evacuate takes 10min 19sec. The main evacuation routes used by passengers were investigated and the cause of death was identified by evacuation simulation.

A Study on the Implementation of Microscopic Traffic Simulation Model by Using GIS (GIS를 이용한 미시적 수준의 교통모형 구현에 관한 연구)

  • Kim, Byeongsun
    • Spatial Information Research
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    • v.23 no.4
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    • pp.79-89
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    • 2015
  • This study aims to design and implement a traffic model that can simulate the traffic behavior on the microscopic level by using the GIS. In the design of the model, the vehicle in the simulation environment recognizes the GIS road centerline data as road network data reflecting number of lanes, speed limit and so on. In addition, the behavior model was designed by dividing functions into the environmental perception model, time headway distribution model, car following model, and lane changing model. The implemented model was applied to Jahamun-road of Jongno-gu district to verify the accuracy of the model. As a result, the simulation results on the Jahamun-road had no great error compared with the actual observation data. In the aspect of usability of model, it is judged that this model will be able to effectively contribute to analysis of amount of carbon emission by traffic, evaluation of traffic flow, plans for location of urban infrastructure and so on.