• 한국수소및신에너지학회논문집
• /
• 제33권6호
• /
• pp.715-722
• /
• 2022

Pt-Fe/carbon black nanocatalysts were prepared by spontaneous reduction reaction of Platinum(II) acetylacetonate and Iron(II) acetylacetonate in a nucleophilic solvent and they were characterized by scanning electron microscopy (SEM), energy dispersive X-ray analyzer (EDS), thermogravimetric analyzer (TGA), transmission electron microscopy (TEM), Brunauer, Emmett and Teller (BET) surface area analysis and anion exchange membrane (AEM) water electrolysis test station. The distribution of the Pt and Fe nanoparticles on carbon black was observed by TEM, and the loading weight of Pt-Fe nanocatalysts on the carbon black was measured by TGA. Elemental ratio of Fe:Pt was estimated by EDS and it was found that elemental ratio of Pt and Fe was changed in the range of 1:0 to 0:1, and the loading weight of Pt-Fe nanoparticles on the carbon black was 5.95-6.78 wt%. Specific surface area was greatly reduced because Pt-Fe nanocatalysts blocked the pores. I-V characteristics were estimated.

• Journal of Welding and Joining
• /
• 제31권6호
• /
• pp.112-118
• /
• 2013

In this study, constant loading test (CLT) was performed to evaluate the hydrogen embrittlement resistance for multipass FCA weld metals of 600MPa tensile strength grade. The microstructures of weld metal-2 having the smallest carbon equivalent (Ceq=0.37) consisted of grain boundary ferrite and widmanstatten ferrite in the acicular ferrite matrix. The weld metal-1 having the largest Ceq=0.47, showed the microstructures of grain boundary ferrite, widmanstatten ferrite and the large amount of bainite (vol.%=19%) in the acicular ferrite matrix. The weld metal-3 having the Ceq=0.41, which was composed of grain boundary ferrite, widmanstatten ferrite, and the small amount of bainite (vol.%=9%) in the acicular ferrite matrix. Hydrogen desorption spectrometry (TDS) used to analyze the amount of diffusible hydrogen and trapping site for the hydrogen pre-charged specimens electrochemically for 24 hours. With increasing the current density of hydrogen pre-charging, the released amount of diffusible hydrogen was increased. Furthermore, as increasing carbon equivalent of weld metals, the released diffusible hydrogen was increased. The main trapping sites of diffusible hydrogen for the weld metal having a low carbon equivalent (Ceq=0.37) were grain boundaries and those of weld metals having a relatively high carbon equivalent (Ceq: 0.41~0.47) were grain boundaries and dislocation. The fracture time for the hydrogen pre-charged specimens in the constant loading test was decreased as the carbon equivalent increased from 0.37 to 0.47. This result is mainly due to the increment of bainite that is vulnerable to hydrogen embrittlement.

• Steel and Composite Structures
• /
• 제22권2호
• /
• pp.277-299
• /
• 2016

In this paper, free vibration, forced vibration, resonance and stress wave propagation behavior in nanocomposite plates reinforced by wavy carbon nanotube (CNT) are studied by a mesh-free method based on first order shear deformation theory (FSDT). The plates are resting on Winkler-Pasternak elastic foundation and subjected to periodic or impact loading. The distributions of CNTs are considered functionally graded (FG) or uniform along the thickness and their mechanical properties are estimated by an extended rule of mixture. In the mesh-free analysis, moving least squares (MLS) shape functions are used for approximation of displacement field in the weak form of motion equation and the transformation method is used for imposition of essential boundary conditions. Effects of CNT distribution, volume fraction, aspect ratio and waviness, and also effects of elastic foundation coefficients, plate thickness and time depended loading are examined on the vibrational and stresses wave propagation responses of the nanocomposite plates reinforced by wavy CNT.

• 한국재료학회지
• /
• 제12권2호
• /
• pp.135-139
• /
• 2002

Carbon powders (CP) and carbon fiber (CF) were introduced info glass fiber reinforced plastics (FRP) composites to obtain fracture detection function. The composites were evaluated through the relation between a load-displacement curve and an electrical resistance change curve in three point bending test. CP containing FRP (CP-FRP) has a sensitivity of electrical resistance change at much lower load level than CF containing FRP (CF-FRP). In loading-unloading tests, CP-FRP showed a large amount of residual electrical resistance which enables the estimation of loading hysteresis.

• 한국소성가공학회:학술대회논문집
• /
• 한국소성가공학회 2005년도 춘계학술대회 논문집
• /
• pp.313-316
• /
• 2005

In the present study, Bauschinger effect was investigated for the micro-alloying forging steel which has been developed for about 30 years ago to save energy consumption by eliminating the heat treatment processes in the forging industry. The micro-alloying steels used fur cold forging industry mainly aim to replace the usual carbon steel. With the conventional carbon steels, all the deformation history can be eliminated after the final heat treatment(quenching and tempering). In the case of micro-alloying forging steels, however, the prior deformation history should be taken into consideration to meet the mechanical property requirement since the microstructure of micro-alloying steels might exhibit the Bauschinger effect, which was not needed to consider in the case of conventional carbon steel having quenching and tempering treatment. In the present study, the reverse loading tests were carried out to determine the Bauschinger effect of micro-alloying steel which composed of ferrite and cementite phases.

• 한국해양공학회지
• /
• 제26권5호
• /
• pp.5-10
• /
• 2012

In this study, carbon steel (A53) is used as the material for the pipes in a marine plant and ship industry. Welds are necessary to join the carbon steel, and the effect of this welding on the properties of the carbon steel has been studied by many researchers. In this study, the dynamic behavior of welded carbon steel was studied using an acoustic emission (AE) technique, which is a nondestructive test. There are numerous AE parameters that can be used to analyze the damage behavior of carbon steel by external loading. The AE parameters of energy, cumulative count, amplitude, and AE event were used, and each parameter was differentiated according to the degree of damage to the carbon steel. The energy showed a high level at the elastic range of the load curve, while the amplitude had the highest value at the hardening region. The cumulative count showed a growth tendency similar to the loading curve. In addition, an ultrasonic technique and hardness test were applied to evaluate the mechanical properties according to the base zone, HAZ region, and weld zone of the weld specimen. The velocity and attenuation ratio showed little change between zones, and an evaluation of the ultrasonic waves on each zone of the specimen was found to be a useful method to clarify the mechanical properties of the carbon steel.

• 한국환경과학회지
• /
• 제13권9호
• /
• pp.779-878
• /
• 2004

This study was conducted to analyze the operating conditions of predenitrification process to improve the treatment efficiency in low organic loading sewage plant in use today, and to investigate the treatment efficiency of pilot plant added night soil as well as the nitrogen removal characteristics of pilot plant added carbon sources. In the operation under the condition of $BOD_{5}$ sludge load 0.03-0.28kg $BOD_{5}$/kg VSS/d and oxic ammoniac nitrogen sludge load 0.02-0.24 $kgNH_{4}^{+}$-N/kg MLVSS/d, nitrification efficiency is higher than 95%. In order to achieve 70% nitrogen removal at the T-N sludge loading 0.06kg T-N/kg VSSㆍd and the SRT 6～11 days, optimum operating factors were revealed to $CODc_{r}$/T-N ratio 9, recycle ratio 2.6, and denitrification volume ratio 0.33. At this time, denitrification capacity was approximately 0.09 kg $NO_{3}^{-}$-N/kg $CODc_{r}$; specific nitrification rate was 3.4mg $NH_{4}^{+}$-N/g MLVSS/hr; and specific denitrification rate was 4.8mg $NO_{3}^{-}$-N/g MLVSS/hr.

• 한국구조물진단유지관리공학회 논문집
• /
• 제10권1호
• /
• pp.183-189
• /
• 2006

RC 구조물에 대하여 FRP로 보수 보강 작업시, 주변 온도에 따른 일정기간의 양생을 필요로 하며 또한 양생과정 중 외부의 진동원으로부터 유해한 작용을 받는 것을 피하는 것이 바람직하다. 따라서 본 연구에서는 탄소섬유쉬트(CFS)로 보강되는 RC구조물에 대하여, CFS양생과정 중 작용하는 반복하중이 보강성능에 미치는 영향을 일련의 보 실험을 통하여 분석하였다. 실험결과 CFS 1겹 보강의 경우에는 CFS부착 후 24시간, 2겹 보강의 경우에는 12시간동안 외부로부터의 반복하중을 차단하는 것이 필요한 것으로 판단되었다.

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 2007년도 춘계학술대회 논문집
• /
• pp.665-666
• /
• 2007

• 도시과학
• /
• 제7권1호
• /
• pp.5-9
• /
• 2018

The nickel-titanium shape memory alloy (SMA), referred to as Nitinol, exhibits a superelastic effect that can be restored to its original shape even if a significant amount of deformation is applied at room temperature, without any additional heat treatment after removal of the load. Owing to these unique material characteristics, it has widely used as displacement control devices for seismic retrofitting in civil engineering fields as well as medical, electrical, electronic and mechanical fields. Contrary to ordinarty carbon steel, superelastic SMAs are very resistant to fatigue, and have force-displacement properties depending on loading speed. The change for the mechanical properties of superelastic SMAs are experimentally inviestigated in this study when loading cycle numbers and loading speeds are different. In addition, the standardized force-displacement properties of such superelastic SMAs are proposed with an aim to efficiently design the seismic retrofitting devices made of these materials.