• Title/Summary/Keyword: Carbon ion

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Determination of Trace Strontium with o-Cresolphthaleoxon by Electroanalytical method (o-Cresolphthaleoxon을 이용한 스트론튬의 전기화학적 분석)

  • Choi, Won Hyung;Lee, Jin Sik;Kim, Do Hoon;Kim, Jae Soo
    • Analytical Science and Technology
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    • v.6 no.3
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    • pp.247-254
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    • 1993
  • Strontium can not be determined by conventional dc polarography method since it is very difficult to be reduced at the drop mercury electrode(DME) in aqueous solution. However the analytical sensitivity was improved by adsorptive stripping voltammetry in which electro-reduction of ligand in a complex formed between strontium and o-cresolphthaleoxone was performed. Strontium could be determined in range of $5{\sim}30{\mu}g/L$ concentration. This method was affected by coexistent alkali earth metal ions. Consequently ion exchange separation is recommended to analyze strontium in samples.

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Removal of low concentration organic matter by reverse osmosis membranes in ultrapure water production process (초순수 제조 공정에서 역삼투 막의 저농도 유기물 제거)

  • Lee, Hongju;Kim, Suhan
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.4
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    • pp.391-396
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    • 2014
  • Ultrapure water (UPW) is water containing nothing but water molecule ($H_2O$). The use of UPW is increasing in many industries such as the thermal and nuclear power plants, petrochemical plants, and semiconductor manufacturers. In order to produce UPW, several unit processes such as ion exchange, reverse osmosis (RO), ultraviolet (UV) oxidation should be efficiently arranged. In particular, RO process should remove not only ions but also low molecular weight (LMW) organic matters in UPW production system. But, the LMW organic matter removal data of RO membranes provided by manufacturers does not seem to be reasonable because they tested the removal in high concentration conditions like 1,000 ppm of isopropyl alcohol (IPA, MW=60.1). In this study, bench-scale experiments were carried out using 4-inches RO modules. IPA was used as a model LMW organic matter with low concentration conditions less than 1 ppm as total organic carbon (TOC). As a result, the IPA removal data by manufacturers turned out to be trustable because the effect of feed concentration on the IPA removal was negligble while the IPA removal efficiency became higher at higher permeate flux.

Purification and Characterization of Extracellular Poly(3-hydroxybutyrate) Depolymerase from Penicillium simplicissimum LAR13

  • Han, Jee-Sun;Kim, Mal-Nam
    • Journal of Microbiology
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    • v.40 no.1
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    • pp.20-25
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    • 2002
  • An extracellular PHB depolymerase was purified from P. simplicissimum LAR13 cultural medium by Sepharose CL-6B chromatography. When the fungus was grown in a basal salt medium with poly(3-hydroxybutyrate) (PHB) as the sole carbon source, PHB depolymerase production reached maximum at its stationary phase. The mycelial growth rate was higher at 37$^{\circ}C$ than at 30$^{\circ}C$ and even higher than at 25$^{\circ}C$, However, the enzyme production was lower at 37$^{\circ}C$ than 30$^{\circ}C$ or 25$^{\circ}C$. The isolated enzyme is composed of a single polypeptide chain with a molecular mass of about 36 kDa as determined by SDS-PAGE. The optimum conditions for the enzyme activity are pH 5.0 and 45$^{\circ}C$. The enzyme was stable for 30 min at a temperature lower than 50$^{\circ}C$, and stable at pH higher than 2.0 but it was unstable at pH 1.0.1 mM Fe$\^$2+/ reduced the enzyme activity by 56% and the enzyme was inhibited almost completely by 4 mM Fe$\^$2+/ . The enzyme was partially inhibited by phenylmethylsulfonyl fluoride and was very sensitive to diazo-DL-norleucine methyl esters dithiothreitol and mercuric ion. However, N-p - tosyl - L - Iysinechloromethyl ketone, p -hydroxymercuricbenzoate and N- acetylimidazole had no influence upon its activity.

Synthesis or photocatalytic Ni-doped nanocomposite $TiO_2$ by mechanical alloying and heat treatment (기계적 합금화법과 열처리를 통한 Ni이 도핑 된 광촉매 $TiO_2$ 나노 복합상 제조)

  • Park, Ha-Sung;Kim, Dong-Hyun;Jho, Jae-Han;Kim, Sun-Jae;Lee, Kyung-Sub
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.11a
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    • pp.667-672
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    • 2005
  • In order to effectively utilize visible light in the photocatalytic reaction, nanaocomposite of Ni doped $TiO_2$ and $NiTiO_3$ powders were synthesized by mechanical alloying and heat treatment. About 5.4 wt% of $NiTiO_3$ with particle size less than 15nm was uniformly formed in the Ni-doped rutile $TiO_2$ matrix. The UV/VIS-DRS and PL investigation showed that the nanocompasite $TiO_2$ powders had a longer absorpt ion wavelength (600$\sim$650nm, 2.0$\sim$1.9eV) than that of Ni-doped $TiO_2$ or rutile $TiO_2$ powder. The carbon decomposition of 4-CP by the nanocompasite $TiO_2$ powders were higher than other $TiO_2$ (P-25).

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Studies on the New Antimetabolites Produced by Microorganisms (미생물이 생산하는 새로운 대사길항물질에 관한 연구)

  • 박부길
    • Microbiology and Biotechnology Letters
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    • v.6 no.4
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    • pp.187-196
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    • 1978
  • Antimetabolite N-2292 substance, an antagonist of L-aspartic acid and L-glutamic acid was isolated from the fermentation broth of Streptomyces. Taxonomical study on the producing strain made it a related species of Streptomyces albulus judged by cultural characteristics and carbon utilization. N-2292 substance was isolated as amorphous white powder with melting point at 185$^{\circ}C$. From the physicochemical characteristics of the substance, it was peptide like substance. It was active against Gram positive and Gram negative bacteria but negative against yeast and mold in its biological properties. It was reversed by L-Asp and L-Glu on the synthetic medium.

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Studies on Production of Alkaloid by Plant Cell Culture of Corydalis remota (세포 현탁배양에 의한 현호색 알칼로이드의 생산)

  • Chang, Jung-In;Chi, Hyung-Joon;Shin, Seung-Won
    • Korean Journal of Pharmacognosy
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    • v.27 no.4
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    • pp.289-294
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    • 1996
  • In previous paper, we described the induced callus of Corydalis remota contains a significant amount of alkaloids. This study describes an optimal condition to maximize alkaloid production. The suspension cultures maintained alkaloid production ability after fifth subculture and a small amount of alkaloid seemed to be released out of cells. The yields of alkaloid by cultured cells was varied depending on the concentrations of NAA, carbon sources and phosphate ion and depending on the vitamin combinations and concentrations. Biosynthetic precursor and an elicitor treatment also affected the total alkaloid yield of the cultures. The optimal conditions for alkaloid production were as follows: 1) MS basal salt containing 30 g/l of glucose, 1.0 mg/l of NAA, and vitamins of LS medium should be used. 2) The culture should be treated with tyrosine 20 mg/l, and yeast extract 1.5 ml/l after the culture reached a stationary phase of growth. Five alkaloids were isolated from the cultures and they were characterized. The spectral data unambiguously revealed that the isolated compounds were dihydrosanguinarine, protopine. tetrahydropalmatine, allocyptopine and ambinine, respectively.

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The Design and Electrical Characteristics of 50kW Energy Storage System Using Hybrid Supercapacitor (하이브리드 슈퍼커패시터를 이용한 50kW급 에너지 저장 장치 설계 및 전기적 특성)

  • Mang, Ju-Cheul;Cho, Moon-Taek;Yoon, Jung-Rag
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.7
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    • pp.854-859
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    • 2018
  • This paper describes the characteristics of a hybrid supercapacitor module for power quality stabilization. Hybrid supercapacitor is an promising energy storage device that positioned between conventional EDLC and Li-ion battery. A cylindrical 7500F hybrid supercapacitor ($60{\times}138mm$) was assembled by using the $Li_4Ti_5O_{12}$ electrode as an anode and activated carbon as a cathode. Considering the ESR and efficiency has been designed to module with 41.6F 480V design results in 180 series combination. In order to determine the characteristics of the hybrid supercapacitor module for power system, hybrid supercapacitor cells were connected in series with active balancing circuit. As a result of measuring the 50kw UPS, it was discharged at the current of 104A~143A during the discharge in the voltage range of 350V~480V, and the compensation time at discharge was measured to be about 30s. These results can be used to stabilization of power quality by applying hybrid supercapacitor module.

Altered Langmuir Adsorption Isotherm under the Consideration of the Displacement of Water Molecules with Adsorbate Ion at the Surface of Adsorbent (흡착제(吸着劑) 표면(表面)에서의 흡착질(吸着質)과 물분자(分子)의 치환(置換)을 고려(考慮)한 수정(修正) Langmuir 등온흡착식(等溫吸着式))

  • Kim, Dong-Su
    • Resources Recycling
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    • v.15 no.3 s.71
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    • pp.81-86
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    • 2006
  • Altered Langmuir adsorption isotherm has been suggested for adsorption reactions occurring in aqueous environment based upon the concept of the steric displacement between adsorbates and water molecules at the surface of adsorbent. For the adsorption of $Cd^{2+}$ on activated carbon, the suggested adsorption isotherm was shown to be more well applied to the experimental results compared with the classical Langmuir adsorption isotherm. Based on this, regarding the adsorption system which following the Langmuir model more precise design and controllable operation of the process were considered to be attainable when the adsorption process is analyzed employing the altered adsorption isotherm.

A study of detector size effect using Monte Carlo simulation

  • Park, Kwang-Yl;Yi, Byong-Yong;Vahc, Young W.
    • Proceedings of the Korean Society of Medical Physics Conference
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    • 2004.11a
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    • pp.36-38
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    • 2004
  • The detector size effect due to the spatial response of defectors is one critical source of inaccuracy in clinical dosimetry and has been a subject of numerous studies. Conventionally, the detector response kernel contains all of the influence that the detector size has on the measured beam profile. Various analytic models for this kernel have been proposed and studied in theoretical and experimental works. Here, we use a method to determine detector response kernel simply by using Monte Carlo simulation and convolution theory. Based on this numerical method and DOSIMETER, an EGS4 Monte Carlo code, the detector response for a Farmer type ion chamber embedded in water phantom is obtained. There exists characteristic difference in the simulated chamber readings between one with carbon graphite wall and the other with Acrylic wail. Using the obtained response and the convolution theory, we are planning to derive the detector response kernel numerically and remove detector size effect from measurements for 6MV, 10${\times}$l0cm2 and 0.5${\times}$10 cm2 photon beam.

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A Study on the Friction and Wear Characteristics of C-N Coated Spur Gear (C-N 코팅 스퍼기어의 마찰${\cdot}$마모 특성에 관한 연구)

  • Lu Long;Lyu Sung-ki
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.41-46
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    • 2004
  • This study deals with the friction and wear characteristics of C-N coated spur gear. The PSII apparatus was built and a SCM415 test piece and test gear with steel substrate was treated with carbon nitrogen by this apparatus. The composition and structure of the surface layer were analyzed and compared with that of PVD coated TiN layer. It was found that both of friction coefficients of C-N coating and TiN coaling decreased with increasing load, however, C-N coating showed relatively lower friction coefficient than that of TiN coating. We was investigated the effect of C-N coating on hardness, friction and wear. The TiN coated gear showed more serious friction phenomena than that of C-N coated gear. It was considered that coating of TiN, which was conducted at a vacuum chamber at about $500^{\circ}C$ results in a tempering of base material that causes microstructure change, which in turn resulted in decreasing of hardness. The C-N coated gear and pinion had higher wear resistance that of TiN coated gear and pinion. C-N coating significantly improved the friction and wear resistance of the gear.

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