• Title/Summary/Keyword: Carbon index

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Study on Chemical Stabilities with R-1234yf Refrigerant of Polyol Ester Refrigerant Oil for Electric Vehicles (전기 자동차용 폴리올 에스테르계 냉동기유의 R-1234yf 냉매와의 적합성 연구)

  • Hong, J.S.;Chung, K.W.;Kim, N.K.;Shin, J.H.;Kim, Young Woon;Lee, E.H.;Go, B.S.;Hwang, S.Y.
    • Tribology and Lubricants
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    • v.36 no.3
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    • pp.139-146
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    • 2020
  • Global warming has led to an increase in demand of eco-friendly vehicles, such as electric cars, for reducing greenhouse gas emissions, and especially, regulating carbon dioxide generation. In addition, electric vehicles are equipped with an electric drive-type hermetic scroll compressor and a refrigerant, which exhibit current and future trends of using environmentally friendly refrigerants, including R-1234yf. In this study, polyol ester-based refrigeration oils are prepared via condensation esterification of polyol and fatty acids. The oils can be combined with R-1234yf refrigerant for applications in air conditioning and cooling systems of electric vehicles. The structure of synthetic polyol esters is confirmed via 1H-NMR and FT-IR spectrum analysis, and the composition of the polyol ester is analyzed via gas chromatogram analysis. Furthermore, kinematic viscosity, viscosity index, total acid value, pour point, and color are analyzed as fundamental physical properties of the synthetic polyol esters. The compatibility and chemical stability of the synthetic polyol ester combined with the R-1234yf refrigerant are obtained via high temperature and high pressure oil-resistant refrigerant tests. The changes in the oil color and catalyst activity are observed before and after the experiment to determine whether it is suitable as a refrigerator oil.

Evaluation of Cigarette Quality by Measurement of Oxygen Free Radicals in Smoke (담배 연기 중 산소 자유 라디칼 측정에 의한 품질 평가)

  • Ji-Chang Park;Kyung-Ran Yoon;Young-Ha Rhee;Cheong Ho Lee
    • Journal of the Korean Society of Tobacco Science
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    • v.12 no.1
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    • pp.19-27
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    • 1990
  • To evaluate tobacco quality, several mathods including sensory test, or measurement of some toxic compounds such as tar, nicotine and carbon monoxide in cigarette smoke have been used. However, many detrimental effects of smoking on the physiological functions including respiratory system reported were turned out to be the action of reactive oxygen species. Therefore, the amounts of oxygen free radicals such as superoxide, hydroxyl radical, even hydrogen peroxide in the cigarette smoke are thought the very important factors. In the present study, we have determined the generation of superoxide and the content of hydrogen peroxide using superoxide dismutase and catalase in the gas and particulate phases obtained from cigarette smoke, respectively. In the aqueous extracts of total particulate materials, suproxide and hydrogen peroxide were detected, and there was an excellent correlation between oxygen tint of oxygen free radicals in cigarette smoke may be a useful index for evaluation of cigarette quality in the aspect of smoking and health.

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The applicable evaluation of biodegradable polymer coated-mulching paper for afforestation seedlings (생분해성 고분자 코팅 조림묘목용 mulching mat 원지의 적용성 평가)

  • Lee, Geum-Ja;Yoo, Yeong-Jeong;Ko, Seung-Tae;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.1
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    • pp.54-63
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    • 2010
  • Recently, as the function of largest supplier of biomass for "low carbon green growth", the necessity for systematic management of afforestation areas is emphasizing. The forestation of seedling, besides the afforestation cost itself, is required some additional follow-up management costs, like mowing and fertilizing of forestation area, and removal of bindweed. The mulching mat for afforestation seedlings is available for rooting of little seedlings as well as initial forestation expenses. Mulching technique is also used to control soil temperature and moisture by covering the surface of ground. In this study, the paper based-mulching film coated with biodegradable polymer and functional additive was specially produced using laboratory bar coater, and analyzed for its degradable behavior. Coating colors were prepared by dissolving PE (polyester) 80 % and PLA(polylactic acid) 20 % in chloroform and finally applied to handsheet prepared by preceding study conditions. Base paper and polymer-coated paper were artificially aged by 2 kinds of degradation methods, which are soil degradation by microorganism and light degradation by 257 nm UV wavelengths. Strength property, oxidation index and morphological property were evaluated by reduction rates of tensile strength, FTIR spectra ratio of carboxyl and carbonyl group and SEM micrograph. As these results, polymer coated-paper was superior to base paper in degradation behaviors, having results with lower reduction rate of strength properties.

Atomic Layer Deposition of Al2O3 Thin Films Using Dimethyl Aluminum sec-Butoxide and H2O Molecules

  • Jang, Byeonghyeon;Kim, Soo-Hyun
    • Korean Journal of Materials Research
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    • v.26 no.8
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    • pp.430-437
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    • 2016
  • Aluminum oxide ($Al_2O_3$) thin films were grown by atomic layer deposition (ALD) using a new Al metalorganic precursor, dimethyl aluminum sec-butoxide ($C_{12}H_{30}Al_2O_2$), and water vapor ($H_2O$) as the reactant at deposition temperatures ranging from 150 to $300^{\circ}C$. The ALD process showed typical self-limited film growth with precursor and reactant pulsing time at $250^{\circ}C$; the growth rate was 0.095 nm/cycle, with no incubation cycle. This is relatively lower and more controllable than the growth rate in the typical $ALD-Al_2O_3$ process, which uses trimethyl aluminum (TMA) and shows a growth rate of 0.11 nm/cycle. The as-deposited $ALD-Al_2O_3$ film was amorphous; X-ray diffraction and transmission electron microscopy confirmed that its amorphous state was maintained even after annealing at $1000^{\circ}C$. The refractive index of the $ALD-Al_2O_3$ films ranged from 1.45 to 1.67; these values were dependent on the deposition temperature. X-ray photoelectron spectroscopy showed that the $ALD-Al_2O_3$ films deposited at $250^{\circ}C$ were stoichiometric, with no carbon impurity. The step coverage of the $ALD-Al_2O_3$ film was perfect, at approximately 100%, at the dual trench structure, with an aspect ratio of approximately 6.3 (top opening size of 40 nm). With capacitance-voltage measurements of the $Al/ALD-Al_2O_3/p-Si$ structure, the dielectric constant of the $ALD-Al_2O_3$ films deposited at $250^{\circ}C$ was determined to be ~8.1, with a leakage current density on the order of $10^{-8}A/cm^2$ at 1 V.

Estimation of Decomposition Capacity for Organic Matter in Tidal Flat Sediments at Saemankeum Area (새만금지역 하구갯벌의 유기물 분해능력 평가)

  • Jong-Gu Kim;Sun-Jae You
    • Journal of Environmental Science International
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    • v.10 no.5
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    • pp.315-321
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    • 2001
  • This study was conducted to estimate the decomposition capacity for organic matter by microbe of tidal flat sediments (Hajae, Dongjin and Mankyung). The decomposition rate constants (K') have been determined by Thomas slope method and compared with the values of each tidal flats. The decomposition rates of organic matter by microbe were initially very slow, but at the end of 12 hours, very sharply increased. The values of decomposition rate constant for Dongjin, Mankyung and Hajae tidal flat sediment were 1.364$day^{-1}$/, 1.080d$day^{-1}$ and 0.735$day^{-1}$, respectively. The decomposition rate constant of Dongjin tidal flat sediment which affected by livestock wastewater was higher than others. The decomposition quantity (mg/g/day) of organic matter by microbe of tidal flat sediments was 0.4mg/g/day for Dongjin, 0.36mg/g/day for Mankyung and 0.36mg/g/day for Hajae. The average of decomposition quantity was 0.37mg/g/day. To calculate purification capacity (kg/ha) of organic matter by microbe, we applied to two assumption ; 1) biological action by microbe is occur within 0.1cm under surface 2) specific gravity of sediment are 2.5g/$\textrm{cm}^2$. The purification capacity of organic matter by microbe of tidal flat sediment was calculated to 9.25kg/ha. The relationships between decomposition rate constant (K') and ignition loss (I. L), chemical oxygen demand by sediment (CO $D_{sed}$), total carbon(TC), silt and clay as index of organic matter were a high positive($R^2$=0.97~1.00).

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Stacking Sequence Design of Fiber-Metal Laminate Composites for Maximum Strength (강도를 고려한 섬유-금속 적층 복합재료의 최적설계)

  • 남현욱;박지훈;황운봉;김광수;한경섭
    • Composites Research
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    • v.12 no.4
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    • pp.42-54
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    • 1999
  • FMLC(Fiber-Metal Laminate Composites) is a new structural material combining thin metal laminate with adhesive fiber prepreg, it nearly include all the advantage of metallic materials, for example: good plasticity, impact resistance, processibility, light weight and excellent fatigue properties. This research studied the optimum design of the FMLC subject to various loading conditions using genetic algorithm. The finite element method based on the shear deformation theory was used for the analysis of FMLC. Tasi-Hill failure criterion and Miser yield criterion were taken as fitness functions of the fiber prepreg and the metal laminate, respectively. The design variables were fiber orientation angles. In genetic algorithm, the tournament selection and the uniform crossover method were used. The elitist model was also used to be effective evolution strategy and the creeping random search method was adopted in order to approach a solution with high accuracy. Optimization results were given for various loading conditions and compared with CFRP(Carbon Fiber Reinforced Plastic). The results show that the FMLC is more excellent than the CFRP in point and uniform loading conditions and it is more stable to unexpected loading because the deviation of failure index is smaller than that of CFRP.

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Effects of Air Pollution on Public and Private Health Expenditures in Iran: A Time Series Study (1972-2014)

  • Raeissi, Pouran;Harati-Khalilabad, Touraj;Rezapour, Aziz;Hashemi, Seyed Yaser;Mousavi, Abdoreza;Khodabakhshzadeh, Saeed
    • Journal of Preventive Medicine and Public Health
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    • v.51 no.3
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    • pp.140-147
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    • 2018
  • Objectives: Environmental pollution is a negative consequence of the development process, and many countries are grappling with this phenomenon. As a developing country, Iran is not exempt from this rule, and Iran pays huge expenditures for the consequences of pollution. The aim of this study was to analyze the long- and short-run impact of air pollution, along with other health indicators, on private and public health expenditures. Methods: This study was an applied and developmental study. Autoregressive distributed lag estimating models were used for the period of 1972 to 2014. In order to determine the co-integration between health expenditures and the infant mortality rate, fertility rate, per capita income, and pollution, we used the Wald test in Microfit version 4.1. We then used Eviews version 8 to evaluate the stationarity of the variables and to estimate the long- and short-run relationships. Results: Long-run air pollution had a positive and significant effect on health expenditures, so that a 1.00% increase in the index of carbon dioxide led to an increase of 3.32% and 1.16% in public and private health expenditures, respectively. Air pollution also had a greater impact on health expenditures in the long term than in the short term. Conclusions: The findings of this study indicate that among the factors affecting health expenditures, environmental quality and contaminants played the most important role. Therefore, in order to reduce the financial burden of health expenditures in Iran, it is essential to reduce air pollution by enacting and implementing laws that protect the environment.

Characteristics of Chemical Composition in Carbonaceous Aerosol of PM2.5 Collected at Smoke from Coal Combustion (석탄 연소 시 발생되는 PM2.5 내 탄소 에어로졸의 화학 조성 연구)

  • Chang, Yu Woon;Joo, Hung Soo;Park, Ki Hong;Lee, Ji Yi
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.3
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    • pp.265-276
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    • 2017
  • The $PM_{2.5}$ samples were obtained from coal combustion with the four different combustion temperatures (550, 700, 900 and $1100^{\circ}C$) to understand chemical composition in carbonaceous aerosol. OC concentration was the highest when the combustion temperature was $550^{\circ}C$, while, the highest concentration for EC was shown at $700^{\circ}C$ of the coal combustion temperature. However, OC concentrations were very low and EC was not detected when the temperature was over $900^{\circ}C$. It indicates complete combustion was achieved when the combustion temperature was over $900^{\circ}C$. For six groups of organic compounds, n-alkanes and n-alkanoic acids were predominant at all of the combustion temperature in smoke of coal combustion, while, PAHs was only detected at $550^{\circ}C$. The diagnostic ratios of PAHs calculated in this study were 0.59 for Fluoranthene/(Fluoranthene+Pyrene), reflecting the characteristics of coal combustion. The Carbon number Preference Index (CPI) values of n-alkanes which ranged from 0.9 to 1.3 also showed the characteristics of coal combustion.

Measurements of 50 Non-polar Organic Compounds Including Polycyclic Aromatic Hydrocarbons, n-Alkanes and Phthalate Esters in Fine Particulate Matter (PM2.5) in an Industrial Area of Chiba Prefecture, Japan

  • Ichikawa, Yujiro;Watanabe, Takehisa;Horimoto, Yasuhide;Ishii, Katsumi;Naito, Suekazu
    • Asian Journal of Atmospheric Environment
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    • v.12 no.3
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    • pp.274-288
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    • 2018
  • Quantitative data of 50 non-polar organic compounds constituting $PM_{2.5}$ were continuously collected and analyzed from June 2016 to October 2017 (approximately 17 months) at Ichihara, one of the largest industrial areas in Japan. Target non-polar organic compounds including 21 species of polycyclic aromatic hydrocarbons (PAHs), 24 species of n-alkanes and 5 species of phthalate esters(PAEs) were simultaneously measured by gas chromatography/mass spectrometry. Basically, the average concentrations of the total PAHs, n-alkanes and PAEs in each season remained nearly level, and seasonal variations were little throughout the study period. These results suggest that the emission sources, which are not influenced by the seasons, are the dominant inputs for the target organic compounds. Diagnostic ratios of PAHs, assessment of n-alkane homologue distributions, carbon preference index, and the contribution of wax n-alkanes from plants were used to estimate source apportionments. These results indicate that anthropogenic sources were the main contributor for most PAHs and n-alkanes throughout the study period. The concentrations of PAEs selected in this study were low because emission amounts of these chemicals were little within the source areas of the sampling site. To our knowledge, this study is the first attempt to simultaneously measure a high number of non-polar organic compounds in $PM_{2.5}$ collected from the ambient air of Japan, and the resultant data will provide valuable data and information for environmental researchers.

Studies on the Lactose Fermenting Yeast from Nuruk Starter (누룩 스타터의 유당발효 효모에 관한 연구)

  • Park, Sang-Kyo;Kang, Mi-Young;Kim, Dong-Shin
    • Korean Journal of Food Science and Technology
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    • v.22 no.2
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    • pp.129-133
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    • 1990
  • The strain of Nuruk yeat No. 15 (NY-15) which ferments lactose in milk was Isolated from Nuruk and identified as Saccharomyces marxianus according to the API 20C profile index. The lactose hydrolysing ability of NY-15 was similar to that Saccharomyces fragilis ATCC 8583 which has ${\beta}-galactosidase$ activity. Its optimum growth temperature, pH and time for the production of maximum enzyme activity showed $28^{\circ}C$, 4.5 and 28hr, respectively. Galactose as well as sucrose as carbon sources, and urea as nitrogen source Increased the production of enzyme. In order to test the production of alcohol, NY-15 was inoculated in whey medium and whey medium added with sugar. In the former, NY-15 produced 2% alcohol and in the latter, it showed 12% alcohol production. The optimal medium pH for lactose hydrolysis of NY-15 is 4.5, whereas that of Saccharomyces fragilis ATCC 8583 is 3.5

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