• Clean Technology
• /
• v.19 no.1
• /
• pp.59-64
• /
• 2013

Pt/carbon Electrode catalysts for PEMFC were synthesized using colloidal method. PSA (platinum sulfite acid) was used as a Pt precursor and CPA (chloroplatinic acid) was also used to replace relatively expensive PSA. Electrode catalysts prepared using PSA showed Pt particle size less than 3.5 nm and Pt yield higher than 90% in 10~40 wt% Pt loading. Electrode catalysts prepared using CPA also showed Pt particle size less than 4.4 nm and Pt yield higher than 80% in 10~40 wt% Pt loading. The MEA (membrane electrode assembly) using 20 wt% Pt/VXC72 showed equivalent I-V curve comparing with commercial electrode catalyst in single cell test.

• Structural Engineering and Mechanics
• /
• v.53 no.3
• /
• pp.497-517
• /
• 2015

In this study, nonlocal nonlinear buckling analysis of embedded polymeric temperature-dependent microplates resting on an elastic matrix as orthotropic temperature-dependent elastomeric medium is investigated. The microplate is reinforced by single-walled carbon nanotubes (SWCNTs) in which the equivalent material properties nanocomposite are estimated based on the rule of mixture. For the carbon-nanotube reinforced composite (CNTRC) plate, both cases of uniform distribution (UD) and functionally graded (FG) distribution patterns of SWCNT reinforcements are considered. The small size effects of microplate are considered based on Eringen's nonlocal theory. Based on orthotropic Mindlin plate theory along with von K$\acute{a}$rm$\acute{a}$n geometric nonlinearity and Hamilton's principle, the governing equations are derived. Generalized differential quadrature method (GDQM) is applied for obtaining the buckling load of system. The effects of different parameters such as nonlocal parameters, volume fractions of SWCNTs, distribution type of SWCNTs in polymer, elastomeric medium, aspect ratio, boundary condition, orientation of foundation orthtotropy direction and temperature are considered on the nonlinear buckling of the microplate. Results indicate that CNT distribution close to top and bottom are more efficient than those distributed nearby the mid-plane for increasing the buckling load.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.26 no.7
• /
• pp.1357-1365
• /
• 2002

A robot hand is used to transport the glass substrate in TFT-LCD manufacturing process. Carbon/epoxy composite is one of the best materials for this kind of robot hand application, due to their lightweight, high stiffness, and good damping characteristics. Major requirement of the robot hand is given as allowable deflection under weight loading of glass substrate and robot hand itself. In this thesis, a carbon/epoxy robot hand was analyzed using finite element method and beam theory to determine the deflection of the hand under the loading that is equivalent to actual weight. Because natural frequency is one of the major interests in robot hand design for TFT-LCD manufacturing process, modal analysis is also conducted using finite element method and beam theory. A robot hand was manufactured, and actual deflection and natural frequency were measured to verify the analysis results and compliance to requirement. The test results showed good agreement with analysis results.

• Advanced Composite Materials
• /
• v.16 no.1
• /
• pp.1-10
• /
• 2007

Composite materials consisting of crushed carbon fiber reinforced plastics (CFRP) pieces and acrylonitrile-butadiene-styrene (ABS) resin were prepared by an injection mold method to solve the problem of recycling of CFRP. The electrical properties, such as electrical resistivity, alternating current impedance and electromagnetic interference (EMI) shielding effect, were measured for the composites. The electrical resistivity of the composites showed a percolation type of conduction behavior and no difference between parallel and perpendicular to the injection direction was observed for CFRP content higher than the critical value. Measurement of alternating current impedance revealed that the conduction mechanism is attributed to the direct conductive paths generated by distributed carbon fibers; however, strong frequency dependence of the impedance was observed for the CFRP content near the critical one. The frequency dependence of the impedance is caused by the inter-fiber connection and can be expressed as a simple equivalent circuit. The absorption component of shielding effect (SE) was smaller than the expected value estimated from its resistivity. The decline of SE is thought to be caused by the decrease in effective thickness due to fiber orientation.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.12 no.1
• /
• pp.77-83
• /
• 2013

This paper presents the feasibility on the application of composite coil spring, which has great interest in the automobile industry. In order to obtain much lighter weight of the composite spring, it will be necessary to optimize the design variables such as fiber angles and diameter of coil, etc. First of all, mechanical properties were measured to consider the effects of FVR and ply angles for carbon fiber composite material. And the shear modulus with respect to ply angles were derived based on twisting angles calculated by torsional beam model. Next we determined the design parameters of composite coil spring, which has equivalent spring rate to the steel coil spring. In order to assess the proposed method, finite element model of the composite spring was developed and analysed to obtain the spring constant. The results showed that static spring rate of the composite spring was in a good agreement with that of steel spring.

• Carbon letters
• /
• v.15 no.1
• /
• pp.38-44
• /
• 2014

This paper reports the effect of adding reduced graphene oxide (RGO) as a conductive material to the composition of an electrode for capacitive deionization (CDI), a process to remove salt from water using ionic adsorption and desorption driven by external applied voltage. RGO can be synthesized in an inexpensive way by the reduction and exfoliation of GO, and removing the oxygen-containing groups and recovering a conjugated structure. GO powder can be obtained from the modification of Hummers method and reduced into RGO using a thermal method. The physical and electrochemical characteristics of RGO material were evaluated and its desalination performance was tested with a CDI unit cell with a potentiostat and conductivity meter, by varying the applied voltage and feed rate of the salt solution. The performance of RGO was compared to graphite as a conductive material in a CDI electrode. The result showed RGO can increase the capacitance, reduce the equivalent series resistance, and improve the electrosorption capacity of CDI electrode.

• International Journal of Naval Architecture and Ocean Engineering
• /
• v.5 no.3
• /
• pp.376-391
• /
• 2013

Brackets in ships and offshore structures are added structures that can endure stress concentrations. In this study, a concurrent engineering solution was proposed, and a high strength low carbon cast steel alloy applicable to offshore structures was designed and developed. The yield strength and ultimate tensile strength of the designed steel were 480 and 600 MPa, respectively. The carbon equivalent of the steel was 0.446 with a weld crack susceptibility index of 0.219. The optimal structural design of the brackets for offshore structures was evaluated using ANSYS commercial software. The possibility of replacing an assembly of conventional built-up brackets with a single casting bulb bracket was verified. The casting process was simulated using MAGMAsoft commercial software, and a casting fabrication process was designed. For the proposed bulb bracket, it was possible to reduce the size and weight by approximately 30% and 50%, respectively, compared to the conventional type of bracket.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.29 no.11 s.242
• /
• pp.1551-1559
• /
• 2005

This paper explains manufacturing process and experimental studies on a composite carbody of Korean tilting train. The composite carbody with length of 23m was manufactured as a sandwich structure composed of a 40mm-thick aluminium honeycomb core and 5mm-thick woven fabric carbon/epoxy face. In order to evaluate structural behavior and safety of the composite carbody, the static load tests such as vertical load, end compressive load, torsional load and 3-point support load tests have been conducted. These tests were performed under Japanese Industrial Standard (JIS) 17105 standard. From the tests, maximum deflection was 12.3mm and equivalent bending stiffness of the carbody was 0.81$\times$10$^{14}$ kgf$\cdot$mm$^{2}$ Maximum stress of the composite body was lower than 12.2$\%$ of strength of the carbon/epoxy. Therefore, the composite body satisfied the Japanese Industrial Standard.

• Proceedings of the Safety Management and Science Conference
• /
• 2004.05a
• /
• pp.247-257
• /
• 2004

Electrodes were fabricated based on activated carbon powder BP-20, conducting agent such as Super P, vapor grown carbon fiber (VGCF) and acetylene black (AB), and the mixed binders of flexible poly(vinylidenefluoridehexafluoropropylene) [P(VdF-co-HFP)] and cross linking dispersion agent of polyvinylpyrrolidone (PVP) to increase mechanical strength. According to impedance measurement of the electrode with the addition of conducting agent, we found that it was possible to charge rapidly by the fast steady-state current convergence due to low equivalent series resistance (AC-ESR, fast charge transfer rate at interface between electrode and electrolyte and low RC time constant. The self-discharge of unit cell showed that diffusion process was controlled by the ion concentration difference of initial electrolyte due to the characteristics of Electric Double Layer Capacitor (EDLC) charged by ion adsorption in the beginning, but this by current leakage through the double-layer at the electrode/electrolyte interface had a minor effect and voltages of curves were remained constant regardless of electrode material. We found that the 2.3V/230F grade EDLC would be applied to industrial safety usage such as uninterrupted power supply (UPS) because of the constant DC-ESR by IR drop regardless of discharge current.

• International Journal of High-Rise Buildings
• /
• v.6 no.4
• /
• pp.327-332
• /
• 2017

This paper discusses several topics associated with the densification caused by supertall buildings and their impact on city systems. The paper covers five key areas where a supertall tower creates a concentration of needs and effects. First, the paper comments on population shifts towards the city and how they affect carbon footprint, utilities infrastructure and transport. The effect of single- and mixed-use towers is discussed in the context of population density. The second section brings the issues of transit, accessibility and master planning into focus. The use and criticality of public transport, cycling and walking is described. Servicing and deliveries using freight consolidation and shared systems is also discussed along with their contribution to the culture of sustainable travel. In the third section the paper reflects on supertall buildings' below-ground utilities and drainage provision, particularly the challenges faced in established city infrastructures. The utilities issues associated with supertall concentration (in land-use terms) compared to equivalent low-rise distribution is also commented on in the context of surface water runoff. In the fourth section, the topic of supertall sustainability is discussed and how city systems need to respond to create desirable and affordable space for occupiers. The changing need for vertical communities, 'stacked neighbourhoods' and the notion of a micro-city is described. Finally, the paper considers the energy consumption and resilience of supertall buildings in the context of basic geometry, façade design, climate and mixed-use benefits as they impact city systems.