• Applied Chemistry for Engineering
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• v.21 no.1
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• pp.24-28
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• 2010

Since the reaction of mineral fixation proceeds with a very slow rate, the pretreatment method to increases the rate of carbonation reaction should be required. To increase the reactivity of serpentine with $CO_{2}$, two pretreatment methods are performed in this study. The heat treatment is done at $630^{\circ}C$. A heat-treated serpentine shows that the strength of -OH has a lower peak in FT-IR spectrum. Chemical pretreatment is the method of leaching of magnesium from serpentine using sulfuric acid at $75^{\circ}C$ for 1 h. Because the protonation of the oxygen atoms polarizes and weakens the Mg-O-Si bond, the removal of magnesium atoms from the crystal lattice was facilitated. After performing the pre-treatment of serpentine, $CO_{2}$ fixation experiments are performed with treated serpentine in the batch reactor. Heat-treated serpentine is converted into 43% magnesite conversion, whereas untreated serpentine has 27% of magnesite conversion. Although the results of the heat-pretreatment are encouraging, this method is prohibited due to excessive energy consumption. Furthermore chemical pretreatment serpentine routes have been proposed in an effort to avoid the cost prohibitive heat pretreatment, in which the carbonation reaction was conducted at 45 atm and $25^{\circ}C$. Chemical-treated serpentine, in particularly is corresponded to a conversion of 42% of magnesite compared to 24% for the un-treated serpentine.

• Geophysics and Geophysical Exploration
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• v.8 no.4
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• pp.280-286
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• 2005

Geological sequestration of carbon dioxide ($CO_2$) is one of the most effective strategies far long-term removal of greenhouse gas from atmosphere. This paper reviews three projects for the $CO_2$ sequestration in geological formation. A unique $CO_2$ injection into a marine aquifer has been successfully monitored with repeated surface seismic measurements in the North Sea Sleipner West field. The seismic images reveal the extent and internal shape of the $CO_2$ bubble. Massive miscible $CO_2$ has been injected into a complex fractured carbonate reservoir at the Weyburn oil filed. High-resolution time-lapse P-wave data were successfully obtained to map the features of $CO_2$ movements within the two thin zones of different lithology. From the time-lapse crosswell EM imaging at the Lost Hills oil field in central California, U.S.A., the replacement of brine with $CO_2$ has been confirmed through a decrease of conductivity. The conductivity image was successfully compared with induction logs observed in the two wells.

• Korean Chemical Engineering Research
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• v.43 no.4
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• pp.537-541
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• 2005

A bubbling fluidized bed reactor was used to study $CO_2$ capture from flue gas using a sodium-based dry regenerable sorbent, sorbA which was manufactured by Korea Electric Power Research Institute. A dry sorbent, sorbA, consists of $Na_2CO_3$ for absorption and supporters for mechanical strength. $CO_2$ capture was effective in the lower temperature range of $50-70^{\circ}C$, while regeneration occurred in the range of $120-300^{\circ}C$. To increase initial $CO_2$ removal, some amount of steam was absorbed in the sorbents before injecting simulated flue gas. It was possible to remove most $CO_2$ for 1-2 minutes at $50^{\circ}C$ and residence time of 2 seconds with steam pretreatment. Little or no reduction in initial reaction rate and capture capacity was observed in multicycle tests. The carbonated and regenerated sorbent samples were analyzed by NMR to confirm the extent of reaction. The results obtained in this study can be used as basic data for the scale-up design and operation of the $CO_2$ capture process with two fluidized bed reactors.

• Journal of Environmental Health Sciences
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• v.21 no.4
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• pp.1-9
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• 1995

This study was carried to investigate the biodegradability of phenol in the wastewater with the two sludge blanket-packed bed reactor in series. Each reactor had a dimension of 0.09 m i.d. and 1.5 m height and consisted of two regions. The lower region was a sludge blanket of 0.5 m height and the upper region was a packed-bed of 1 m height. The packed bed region was charged with ceramic raschig rings of 10 mm i.d., 15 mm o.d. and 20 mm length. The reactors were operated at 35$\circ$C and the hydraulic retention time(HRT) was maintained 24 hours. The synthetic wastewater composed of glucose and phenol as major components was fed into the reactor in a continuous mode with incereasing phenol concentration. In addition, the nutrient trace metals($Na^+, Mg^{2+}, Ca^{2+}, PO_4^{3-}, NH_4^+, Co^{2+}, Fe^{2+}$ etc.) were added for growing anaerobes. The phenol concentration of the effluent, the overall gas production, the composition of product gas, the efficiency of COD reduction and the duration of acclimation period were measured to determine the performance of the anaerobic wastewater treatment system as the phenol concentration of the influent was increased from 600 to 2400 mg//l. Successfully stable biodegradation of phenol could be achieved with the anaerobic treatment system from 600 to 1, 800 mg/l of the influent phenol concentration. The upper level of influent phenol loading was high enough to meet most of the practical requirement. The duration of acclimation increased with the phenol loading. At steady state of the influent phenol concentration of 1800 mg/l, the treatment performance indicated the phenol reduction efficiency of 99%, the COD reduction efficiency of 99% and the gas production rate of 37 l/day. At the influent phenol concentration of 2400 mg/l, however, the operation of the treatment system was noted unstable. While the concentration of methane in biogas decreased with increasing the influent phenol loading, the carbon dioxide was increased. However, the concentration of hydrogen was varied negligibly. The concentration of methane was high enough to be used as a fuel. As a result, it is suggested that anaerobic phenol wastewater treament was economical in the sense of energy recovery and wastewater treatment.

• Asian-Australasian Journal of Animal Sciences
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• v.25 no.6
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• pp.812-817
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• 2012

Nitrate can serve as a terminal electron acceptor in place of carbon dioxide and inhibit methane emission in the rumen and nitrate reducing bacteria might help enhance the reduction of nitrate/nitrite, which depends on the type of feed offered to animals. In this study the effects of three levels of sodium nitrate (0, 5, 10 mM) on fermentation of three diets varying in their wheat straw to concentrate ratio (700:300, low concentrate, LC; 500:500, medium concentrate, MC and 300:700, high concentrate, HC diet) were investigated in vitro using buffalo rumen liquor as inoculum. Nitrate reducing bacteria, isolated from the rumen of buffalo were tested as a probiotic to study if it could help in enhancing methane inhibition in vitro. Inclusion of sodium nitrate at 5 or 10 mM reduced (p<0.01) methane production (9.56, 7.93 vs. 21.76 ml/g DM; 12.20, 10.42 vs. 25.76 ml/g DM; 15.49, 12.33 vs. 26.86 ml/g DM) in LC, MC and HC diets, respectively. Inclusion of nitrate at both 5 and 10 mM also reduced (p<0.01) gas production in all the diets, but in vitro true digestibility (IVTD) of feed reduced (p<0.05) only in LC and MC diets. In the medium at 10 mM sodium nitrate level, there was 0.76 to 1.18 mM of residual nitrate and nitrite (p<0.01) also accumulated. In an attempt to eliminate residual nitrate and nitrite in the medium, the nitrate reducing bacteria were isolated from buffalo adapted to nitrate feeding and introduced individually (3 ml containing 1.2 to $2.3{\times}10^6$ cfu/ml) into in vitro incubations containing the MC diet with 10 mM sodium nitrate. Addition of live culture of NRBB 57 resulted in complete removal of nitrate and nitrite from the medium with a further reduction in methane and no effect on IVTD compared to the control treatments containing nitrate with autoclaved cultures or nitrate without any culture. The data revealed that nitrate reducing bacteria can be used as probiotic to prevent the accumulation of nitrite when sodium nitrate is used to reduce in vitro methane emissions.

• Journal of the Korea Organic Resources Recycling Association
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• v.27 no.4
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• pp.25-33
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• 2019

Operating characteristics of a 30 L microbial electrolysis cell (MEC) for producing biogas from sewage sludge was studied. During the 32-day inoculation period, carbon dioxide concentration decreased and methane concentration increased with operating time, and the overall methane content of biogas was 69.1% with a production rate of 171.6 mL CH₄/L·d. In fed-batch experiments for 6 operating cycles, CH₄ concentration of 66.5~77.2% was obtained at a production rate of 184.9~372.9 mL CH₄/L·d, COD, TS and VS removal efficiency ranged from 28.2 to 42.1%, 20.7 to 37.5% and 18.5 to 36.9%, respectively. The MEC system was observed to be stabilized as operating cycles were repeated after inoculation. In the last operating cycle, 5221 mL/L of methane was produced with CH₄ yield of 316.7 L CH₄/kg COD_rem, and the energy recovery was 73%.

• Horticultural Science & Technology
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• v.28 no.5
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• pp.902-911
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• 2010

Oriental melon ($Cucumis$ $melo$ var. $makuwa$) is a popular and high-value market fruit cultivated in Korea. Consumers are becoming increasingly interested in oriental melon as a healthy diet over the past few years. However, the melons have relatively high quality loss because the fruit are mainly produced for a limited period of time in the summer season. Lack of the proper postharvest treatments and high temperature exposure at harvest or during distribution are the most critical environmental factors limiting postharvest life of fruit. This review focuses on the overview of current research studies for postharvest treatment and functional packaging technology of oriental melon in Korea. Major physiological problems of the harvest fruit include the ripening process in quality changes of the produce such as loss of weight, firmness, flavor, and decay during the storage periods. Low temperature at 7 to $10^{\circ}C$ with high relative humidity of 90 to 95% is the suitable environmental condition used to maintain the quality of fresh oriental melon. Controlled atmosphere (CA) storage or modified atmosphere (MA) packaging can be used as supplemental treatments to extend postharvest-life. For oriental melon, an optimum CA is currently recommended to be 2-3% oxygen and 5-10% carbon dioxide atmosphere. Precooling, pretreatments of ethylene action and functional packaging system can be applied to oriental melon after harvest in order to extend storage life. Major active packaging technologies are concerned with a selectively gas permeable film related to respiration of produce and the packaging applications of ethylene removal, antimicrobial, and antifogging substances to keep the effective freshness of fruit.

• Korean Journal of Weed Science
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• v.7 no.1
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• pp.12-18
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• 1987

Seed dormancy and germination responses to light and gases were determined for Echinochloa colona (L.) Link. E. colons seeds did not require a period of after-ripening for breaking dormancy. Water movement occurred readily across the seed coat. Repeated cycles of hydration and dehydration reduced viability and thence germination. Water imbibition for 24 h increased seed moisture by 21%; seeds returned to their original weight after drying at room temperature for 13 h. Removal of seed-coats increased germination in the dark. Light stimulated germination. Germination at a daylight intensity of 51.9 $Wm^{-2}$ or less was significantly reduced. Germination of seeds which were exposed to light for 1 h each day was significantly less than that of seeds exposed for longer than 2 h a day. Seeds subjected to blue light had delayed and decreased germination compared to seeds exposed to red light. Ethylene or carbon dioxide exogenenously added in the presence of light stimulated germination. The addition of the two gases together had a synergistic effect. In the dark, however, the two gases did not increase germination.

• Resources Recycling
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• v.5 no.3
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• pp.65-72
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• 1996

Colloidal calcium wrbonate(diametcr 0.02-0 09 m~wja s developed to maintain the mamenl of pnriide formatio~>w ~lhoutsurlace trealment. The control factors of particle size and optimum condiliuna for compound fam*tition has not bccn studiedyet. This shldy war aimed at developing a method fur compounding colloidal calcium carbonfcte to cnl~hol cubic calciumcarbonate, and then compounding the b-o types oI precipitated calcium wrbonatc under optimum wndilrans Calc~umhydroxide was calcinated at 1, lWC far two hours, md then hydrated for 30 minutes at t i i O rprn and ambiznt temperahlle.Two-liter suspension was subjected to the contact with carbon dioxide at l5"C, 600 ipxn and C0= injection in the rate of 1 Umin Two types of dcium carbonate(cuhic calcium carbonatc(0 24.9 pm) md collnidd calcium mhnnate (0.02-0 09 pm))were compounded by "wing the concentrations of calcium oxide and ihe suspension were compounded. It was found that theoptimum concentrations of each suspensions were 5 wt % and 2.5 \I*.% respectively. ' h c key control factor af thc parlicle slzcdislribution was the concenkation al the suspension. The size of compounded particles was measured by a Zcla S k r 'fieaverage particle size of the cubic calcium carbonate aas 223.4 nm(0.223 pm), and that of thc colloidal a~lciumc arbonate was93.6 nm (0.093 km). Ihe particle sizc was evenly cantlolled on a stdblc basis in an H, O reaction system.asis in an H, O reaction system.

• Journal of Chest Surgery
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• v.29 no.12
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• pp.1299-1305
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• 1996

The rat thoracic aorta was harvested to determine whether either hyperkalemla or hypothermia impairs the endothelium-dependent re axation of the vascular smooth muscle. Isolated thoracic aorta segments were studied in five groups(n=10 in each group). In group I(control), the isolated aortic seglnents were suspended in organ bath without any intervention. In group ll(endotheilum removAl). the endothelium of the aortic segment was removed by gentle rubbing of the intimal surface with a pair of forceps. In group III(457), IV(4mST), and V(3757), the aortic segments were exposed for 45minutes to 4$^{\circ}C$ St. Thomas hospital cardioplegic solution(57 : NaCl, 144.3; KCI, 19.6, MgCl:, 15.7 : CaCl, 2.2 mmol/L).4$^{\circ}C$ modified St. Thomas hospital cardioplegic solution(NaCl, 144.3 : KCI. 140.0 : MgCl:, 15.7; CaCl:. 2.2 mmol/L). and 37$^{\circ}C$ 57, before suspending in the organ bath, respectively. Then, aorta segments were suspended in organ baths(physiologic salt solution, 37$^{\circ}C$, 95% oxygen and 5% carbon dioxide) for Isometric tension recording. The vasodilatation to acetylcholine (10-2 to 10-2mol/L) was not impaired in control, 457, 4mST, nd 3757 groups. The vasodilatation to acetylcholine was impaired in endothelium removal group. The vasodilatation to sodium nitroprusslde (10-2 to 10-2 mol/L) was not impaired in all groups. In conclusion, both hyperkalemia and hypothermia do not alter irreversibly the function of the rondothelium of the thoracic aorta of the rat.