• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2022년도 가을 학술논문 발표대회
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• pp.75-76
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• 2022

In the event of a fire in the lower space, a high temperature of 1000℃ or more and an explosive fire may occur due to the closed structural features and combustible materials. On the other hand, more than 90% of oyster shells are made of CaCO₃, and when heated to about 700℃ or higher, CaO and CO₂ is generated due to decarboxylation reaction. In this study, we try to infer the amount generated by CO₂ changing the weight of mortar using oyster shells as fine aggregates after heating. in conclusion It is considered that the smaller the particle, the greater the decarboxylation reaction and the greater the weight change.

• 한국환경과학회지
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• 제20권7호
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• pp.873-879
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• 2011

Adsorption experiment of carbon dioxide was performed on MCM41 silica impregnated with two kinds of EDA(ethylenediamine) and MEA(monoethanolamine). The prepared adsorbents were characterized by BET surface area, X-ray diffraction and FT-IR. The $CO_2$ capture study was investigated in a U type packed column with GC/TCD. The results of XRD for MCM-41 and amine-impregnated MCM41 showed typical the hexagonal pore system. BET results showed the MCM 41 impregnated amine to have a surface area of 141 $m^2/g$ to 595 $m^2/g$ and FT-IR revealed a N-H functional group at about 1400$cm^{-1}$ to 1600$cm^{-1}$. The $CO_2$ adsorption capacity on EDA and MEA was as follow: MCM41-EDA30 > MCM41 -EDA40 >MCM41-EDA20 >MCM-EDA10 and MCM41-MEA40 >MCM41-MEA30 > MCM41-MEA20> MCM41-MEA10. The MCM41-EDA30 showed the highest adsorption capacity due to physical adsorption and chemical adsorption by amino-group content. The results suggest that mesoporous media with EDA is effective adsorbent for $CO_2$ capture from flue gases.

• 대한원격탐사학회지
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• 제29권6호
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• pp.657-662
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• 2013

The comparison between $CO_2$ volume mixing ratios observed by GOSAT and TCCON from September 2009 through November 2012 was performed at Tsukuba and Saga, two downwind sites in East Asia. The temporal trends of $CO_2$ values obtained from GOSAT show good agreement with those observed by TCCON at these two by the TCCON, showing a coefficient of determination ($R^2$) of 0.65. The regression slop we obtained was 0.92, showing a small bias of GOSAT $CO_2$ values compared to those observed by TCCON. However, we found the higher correlation in fall and winter than that in spring and summer. The $CO_2$ volume mixing ratios observ sites. The $CO_2$ volume mixing ratios observed by GOSAT are also in good agreement with those measured ed by GOSAT are in good agreement with those measured by the TCCON at those two sites in fall and winter, showing a coefficient of determination ($R^2$) of 0.66 where as the correlation of determination obtained between GOSAT and TCCON was only 0.27 in spring and summer.

• 한국환경과학회지
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• 제25권3호
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• pp.385-393
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• 2016

Oxidative and thermal degradation of alkanolamines for a promising $CO_2$ capture technology of absorption might cause decrease in $CO_2$ capture efficiency and formation of hazardous byproducts. In this study, characteristics of a representative absorbent of monoehtanolamine (MEA) were examined for a long term operation using a laboratory scale absorption system. An $CO_2$ absorption system with ID 56 mm and absorption zone height 100 cm was developed for the characterization. Absorption solution of 30 wt% MEA was circulated at 100 mL/min to treat air with 15% $CO_2$ and 1 ppm NO at 10 L/min. Temperatures of absorber and stripper were maintained at $40^{\circ}C$ and $120^{\circ}C$, respectively. For the course of 5 weeks continuous operation, MEA concentration was decreased approximately by 70% and $CO_2$ removal efficiency was dropped from 95% to 65%. Ionic byproducts of $NH_4{^+}$, $NO_2{^-}$, and $NO_3{^-}$ were accumulated up to 48 g/mL, 0.2 g/mL, and 1.5 g/mL, respectively, tracking the variation of MEA concentration. Formation of various organic byproducts were also observed.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2005년도 후기학술대회논문집
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• pp.240-241
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• 2005

The experiments were conducted without oil in a closed refrigerant loop which was driven by a magnetic gear pump. The main components of the refrigerant loop are a receiver, a variable-speed pump, a mass flow meter, a pre-heater and evaporator(test section). The test section was made of a horizontal stainless steel tube with the inner diameter of 4.57 mm, and length of 4 m. The experiments were conducted at mass flux of 200 to 700 kg/$m^2s$, saturation temperature of 0$^{circ}C$ to 20$^{circ}C$, and heat flux of 10 to 30 kW/$m^2$. The test results showed the evaporation heat transfer of $CO_2$ has great effect on more nucleate boiling than convective boiling. The evaporation heat transfer coefficients of $CO_2$ are highly dependent on the vapor quality, heat flux and saturation temperature. In comparison with test results and existing correlations, correlations failed to predict the evaporation heat transfer coefficient of $CO_2$, therefore, it is necessary to develop reliable and accurate predictions determining the evaporation heat transfer coefficient of $CO_2$ in a horizontal tube.

• 설비공학논문집
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• 제16권12호
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• pp.1134-1139
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• 2004

The evaporative heat transfer coefficient of $CO_2$ (R-744) in a horizontal tube was investigated experimentally. The experiments were conducted without oil in a closed refrigerant loop which was driven by a magnetic gear pump. The main components of the refrigerant loop are a receiver, a variable-speed pump, a mass flow meter, a pre-heater and evaporator (test section). The test section consists of a smooth, horizontal stainless steel tube of inner diameter of 7.75 mm. The experiments were conducted at mass flux of 200 to 500 kg/m$^2$s, saturation temperature of -5 to 5$^{\circ}C$, and heat flux of 10 to 40kW/m$^2$. The test results showed the heat transfer of $CO_2$ has a greater effect on nucleate boiling more than convective boiling. Mass flux of $CO_2$ does not affect nucleate boiling too much, and the effect of mass flux on evaporative heat transfer of $CO_2$ is much smaller than that of refrigerant R-22 and R-134a. In comparison with test results and existing correlations, correlations failed to predict the evaporative heat transfer coefficient of $CO_2$, therefore, it is necessary to develope reliable and accurate predictions determining the evaporative heat transfer coefficient of $CO_2$ in a horizontal tube.

• Bulletin of the Korean Chemical Society
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• 제31권4호
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• pp.829-834
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• 2010

Ligand variation was carried out on a cobalt(III) complex of Salen-type ligand comprised of 1,2-cyclohexenediamine and salicylaldehyde bearing a methyl substituent on 3-position and -[$CMe(CH_2CH_2CH_2N^+Bu_3)_2$] on 5-position, which is a highly active catalyst for $CO_2$/propylene oxide copolymerization. Replacement of the methyl substituent with bulky isopropyl group resulted in alteration of the binding mode, consequently lowering turnover frequency significantly. Replacement with an ethyl group preserved binding mode and activity. Replacement of the tributylammonium unit with trihexylammonium or trioctylammonium, or replacement of 1,2-cyclohexenediamino unit with -$NC(Me)_2CH_2N$- decreased activity, even though the binding mode was unaltered.

• Korean Chemical Engineering Research
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• 제57권5호
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• pp.589-595
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• 2019

"파리 협정"을 통해 출범된 신기후체제에 따라 세계 각국에서 온실가스를 감축하기 위한 정책과 연구가 수행되고 있으며, 우리나라에서도 온실가스 감축을 위한 대책 마련이 시급한 실정이다. IEA 보고서에 따르면 에너지 부분의 $CO_2$ 배출량이 전체 배출량의 2/3에 해당하기 때문에 온실가스 감축을 위해서는 단기적으로는 화석연료 사용을 대체할 수 있는 신재생에너의 생산과 적용 기술 개발과 에너지효율개선 기술 도입이 최선이며, 장기적인 관점에서는 온실가스를 포집하고 활용하는 온실가스 포집 및 활용(CCUS, Carbon Capture Utilization and Storage) 기술 개발이 필수적이다. CCUS 기술은 온실가스를 직접적으로 감축시키는 기술로 활발하게 연구되고 있는 기술이다. 본 논문에서는 다양한 CCUS 기술 개요 및 연구 현황과 향후 전망에 대해서 살펴보았다.

• 한국화재소방학회논문지
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• 제24권5호
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• pp.128-135
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• 2010

본 연구에서는 구획화재로부터 발생되는 화학종의 특성을 파악하기 위해서 혼합분율분석을 수행하였다. 메탄, 헵탄 그리고 톨루엔과 같은 탄화수소 연료들을 사용한 화재 실험이 ISO 9705 표준 화재실에서 수행되었으며 상층부의 두 지점에서 가스종 농도와 그을음(soot) 분율 등을 측정하였다. 미연탄화수소(UHC), 일산화탄소(CO), 이산화탄소($CO_2$), 산소($O_2$) 그리고 그을음 등의 측정된 화학종에 대한 질량분율을 혼합분율의 함수로 나타내었고, 탄화수소 연료의 이상적인 반응식에 기초한 상태 관계식과 비교 분석하였다. 혼합분율 분석은 다양한 화재 조건 및 측정 위치에서 얻은 수많은 측정데이터를 하나의 일관된 파라미터, 즉 혼합분율의 항으로 분류할 수 있게 하였다. 해석 결과를 통해 혼합분율 계산에 그을음을 고려하는 것이, 특히 헵탄이나 톨루엔과 같이 그을음 발생이 큰 연료의 경우 분석의 정확성을 향상시킴을 확인하였다.

• 청정기술
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• 제20권2호
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• pp.179-188
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• 2014

본 연구에서는 고정탑 반응기(높이 30 cm, 내경 1 cm)에 서로 다른 4종류의 제올라이트(zeolite) 시료를 충전하여, 탈착압력이 $CO_2$ 흡착파과 및 탈착파과 거동에 미치는 영향을 연구하였다. 흡착제로는 상용물질인 제올라이트 3A, 4A, 5A, 13X 펠렛(pellet)을 사용하였다. 연속조작(cyclic operation)실험은 흡착-탈착 순으로 5회 반복하여 실험하였으며, 흡착 및 탈착 시간은 각각 80분이었다. 탈착압력이 연속조작거동에 미치는 영향을 살펴보기 위해 탈착 압력(혹은 재생 압력)을 진공(0 bar)에서 3 bar까지 변경하며 실험을 진행하였다. 흡착압력(3 bar), 온도(293 K), 농도($CO_2:N_2=10:90$vol%)와 유량(400 ccm) 조건은 고정하였다. 파과시간(breakthrough time), 포화시간(saturation time), 재생시간(regeneration time), 흡착량 그리고 탑 내 온도변화 등을 측정하였다. 상기 변수 실험을 통하여 연소 후 $CO_2$ 포집에 적합한 흡착제 및 운전조건을 찾고자 하였다.