• Title/Summary/Keyword: Carbon dioxide (CO2)

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The Study on CDM Project of Ligneous Biomass Co-fired in Coal Thermal Power Plant (석탄화력에서 목질계 바이오매스의 혼소시 CDM 사업 연구)

  • Jeong, Nam-Young;Kim, Lae-Hyun
    • Journal of Energy Engineering
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    • v.20 no.3
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    • pp.231-235
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    • 2011
  • Ligneous biomass such as wood pellet is characterized as carbon neutral which has no carbon dioxide emission ; additionally, it can be used as an alternative fuel by co-firing without additional plant reformation as well as for maintaining stability of fuel supply. We can develop CDM project while co-firing by using biomass into conventional coal fired thermal power plant with AM0085 CDM methodology, and it's possible to prove additionality as fuel cost per kWh is higher than bituminous. The study shows that the electricity by biomass can reduce green house emission by $0.6737tCO_2$ per MWh.

Sea Surface pCO2 and Its Variability in the Ulleung Basin, East Sea Constrained by a Neural Network Model (신경망 모델로 구성한 동해 울릉분지 표층 이산화탄소 분압과 변동성)

  • PARK, SOYEONA;LEE, TONGSUP;JO, YOUNG-HEON
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.21 no.1
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    • pp.1-10
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    • 2016
  • Currently available surface seawater partial pressure carbon dioxide ($pCO_2$) data sets in the East Sea are not enough to quantify statistically the carbon dioxide flux through the air-sea interface. To complement the scarcity of the $pCO_2$ measurements, we construct a neural network (NN) model based on satellite data to map $pCO_2$ for the areas, which were not observed. The NN model is constructed for the Ulleung Basin, where $pCO_2$ data are best available, to map and estimate the variability of $pCO_2$ based on in situ $pCO_2$ for the years from 2003 to 2012, and the sea surface temperature (SST) and chlorophyll data from the MODIS (Moderate-resolution Imaging Spectroradiometer) sensor of the Aqua satellite along with geographic information. The NN model was trained to achieve higher than 95% of a correlation between in situ and predicted $pCO_2$ values. The RMSE (root mean square error) of the NN model output was $19.2{\mu}atm$ and much less than the variability of in situ $pCO_2$. The variability of $pCO_2$ with respect to SST and chlorophyll shows a strong negative correlation with SST than chlorophyll. As SST decreases the variability of $pCO_2$ increases. When SST is lower than $15^{\circ}C$, $pCO_2$ variability is clearly affected by both SST and chlorophyll. In contrast when SST is higher than $15^{\circ}C$, the variability of $pCO_2$ is less sensitive to changes in SST and chlorophyll. The mean rate of the annual $pCO_2$ increase estimated by the NN model output in the Ulleung Basin is $0.8{\mu}atm\;yr^{-1}$ from 2003 to 2014. As NN model can successfully map $pCO_2$ data for the whole study area with a higher resolution and less RMSE compared to the previous studies, the NN model can be a potentially useful tool for the understanding of the carbon cycle in the East Sea, where accessibility is limited by the international affairs.

Toxicity Evaluation of the Combustion Products from Synthetic Wood as Internal Finish (건축물 내부 마감재인 합성목재별 연소가스 독성평가)

  • Kim, Jong-Buk;Lee, Si-Young
    • Fire Science and Engineering
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    • v.30 no.2
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    • pp.7-18
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    • 2016
  • This study evaluated the toxicity of the burning gas from the synthetic wood products used in housings or warehouses. The combustion products of five materials, viz. impregnated laminated board, MDF, Douglas fir plywood, core plywood, and Lauan retardant, were analyzed using SEM, FTIR and a Cone Calorimeter. For the Lauan retardant, 256,965 ppm of carbon dioxide ($CO_2$) and 1,475 ppm of sulfur dioxide ($SO_2$) were measured, which are 2.5 times and 3.6 times as high as their lethal concentrations of 100,000 ppm and 400 ppm, respectively. For the impregnated laminated board, 1,569 ppm of nitrogen dioxide ($NO_2$) was measured, which is 6 times as high as its lethal concentration of 250 ppm. For MDF, 795 ppm of ammonia ($NH_3$) was measured, which is higher than its lethal concentration of 750 ppm. As a result, most internal-finishes generated toxic combustion products at levels higher than their lethal concentrations, which underlines the importance of the selection and manufacturing of internal-finish materials.

Estimation of CO2 Emission from a Eutrophic Reservoir in Temperate Region (온대지역 부영양 저수지의 이산화탄소 배출량 산정)

  • Chung, Se-Woong;Yoo, Ji-Su;Park, Hyung-Seok;Schladow, S. Geoffrey
    • Journal of Korean Society on Water Environment
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    • v.32 no.5
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    • pp.433-441
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    • 2016
  • Many large dams have been constructed for water supply, irrigation, flood control and hydropower in Korea for the last century. Meanwhile, recent studies indicated that the artificial reservoirs impounded by these dams are major sources of carbon dioxide (CO2) to the atmosphere and relevant to global budget of green house gases. However, limited information is available on the seasonal variations of CO2 evasion from the reservoirs located in the temperate monsoon regions including Korea. The objectives of this study were to estimate daily Net Atmospheric Flux (NAF) of CO2 in Daecheong Reservoir located in Geum River basin of Korea, and analyze the influencing parameters that characterize the variation of NAF. Daily pH and alkalinity (Alk) data collected in wet year (2012) and dry year (2013) were used for estimating the NAFs in the reservoir. The dissolved inorganic carbon (DIC) was computed using the pH and Alk measurements supposing an equilibrium state among the carbonate species. The results showed seasonal variations of NAF; negative NAFs from May to October when the primary production of the reservoir increased with water temperature increase, while positive NAF for the rest of the period. Overall the reservoir acted as sources of CO2 to the atmosphere. The estimated NAFs were 2,590 and 771 mg CO2 m-2d-1 in 2012 and 2013, respectively, indicating that the NAFs vary a large extent for different hydrological years. Statistical analysis indicated that the NAFs are negatively correlated to pH, water temperature, and Chl-a concentration of the reservoir.

Preliminary Study of a New Extracorporeal Membrane Oxygenator Development When Using Pulsatile Flow

  • Lee, Sa-Ram;Lee, Kyung-Soo;Jung, Jae-Hoon;Mun, Cho-Hay;Min, Byoug-Goo
    • Journal of Biomedical Engineering Research
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    • v.28 no.3
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    • pp.387-391
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    • 2007
  • An oxygenator is a very important artificial organ and widely used for patients with lung failure or during open heart surgery. Although an oxygenator has been widely studied worldwide to enhance its efficiency, studies on oxygenators, in particular when using a pulsatile blood flow, are domestically limited. Therefore, a new oxygenator was developed in the lab and animal experimental results are described in the paper. The oxygenator is composed of polycarbonate housing and polypropylene hollow fibers. It has a total length of 400 mm and a surface area of $1.7 m^2$. The animal experiment lasted for 4 hours. The blood flow rate was set to 2 L/min and a pulsatile blood pump, T-PLS (Twin-Pulse Life Support), was used. Samples were drawn at the oxygenator's inlet and outlet. The total hemoglobin (Hb), saturation oxygen ($sO_2$), and partial oxygen pressure ($pO_2$), partial $CO_2$ pressure ($pCO_2$), and plasma bicarbonate ion concentration ($HCO_3^-$) were measured. The oxygen and carbon dioxide transfer rates were also calculated based on the experimental data in order to estimate the oxygenator's gas transfer efficiency. The oxygen and carbon dioxide transfer rates were $16.4{\pm}1.58$ and $165.7{\pm}10.96 mL/min$, respectively. The results showed a higher carbon dioxide transfer rate was achieved with the oxygenator. Also, the mean inlet and outlet blood pressures were 162.79 and 137.92 mmHg, respectively. The oxygenator has a low pressure drop between its inlet and outlet. The aim of own preliminary study was to make a new oxygenator and review its performance when applying a pulsatile blood pump thus, confirming the possibility of a new oxygenator suitable for pulsatile flow.

On the background levels of $CO_2$ observed at Tae-ahn Peninsula in Korea during 1990-1992 (한국의 태안반도에서 관측된 이산화탄소의 배경농도에 관한 연구)

  • 이근준;정용승
    • Journal of Korean Society for Atmospheric Environment
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    • v.9 no.1
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    • pp.61-68
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    • 1993
  • Since November 1990, the observations of carbon dioxide$(CO_2)$ levels have been carried out at Tae-ahn Peninsula(TAP) in Korea. Analysis on atmospheric data obtained in the period from November 1990 to August 1992 is carried out and the results are included in this study. It is observed that variations of monthly average level on $CO_2$ are in the range of 315.72 $\sim$ 365.37ppm(amplitude 17.65ppm). The seasonal variation is large with a maximum occurring in March-April and with a minimum in July-August. A comparison of TAP data is made with data obtained at Ryori in Japan for 1991. The annual average value of TAP is 1.79ppm higher than that of Ryori. It is also found that in summer the minimum level of $CO_2$ at TAP is almost same as the $CO_2$ level occurring at Quinghai Province in China and at Ulaan Uul in Mongolia. Albeit, a maximum concentration of $CO_2$ at TAP is slightly higher than that of the same gas observed at other sites in spring. We interpret that TAP is generally under the influence of airflows coming from China. According to analysis of trajectories and airflows, we find the high values of $CO_2$ when an air flow is originated mainly from China and when an airflow is both of local(Korea) and of China origins. In contrast, when an airflow of maritime origin arrives, a low value of the atmospheric constituent is observed at TAP.

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Novel Sorption Enhanced Reaction Process for Direct Production of Fuel-Cell Grade $H_2$ from Synthesis Gas (합성가스로부터 연료전지급 수소의 직접 생산을 위한 흡착분리 반응 동시 공정)

  • Lee, Ki-Bong;Jeon, Sang-Goo;Na, Jeong-Geol;Ryu, Ho-Jung
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.745-748
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    • 2009
  • 수소는 지구상에 풍부하게 존재하는 원소로 최근 수소경제시대에 대한 기대와 함께 청정 에너지 carrier로 주목받고 있다. 본 연구에서는 고순도 수소 생산을 위해 water gas shift (WGS) 반응과 $CO_2$의 분리를 하나의 unit operation의 형태로 수행하는 신개념의 thermal swing sorption enhanced reaction (TSSER) 공정의 타당성을 테스트하는데 목적을 두고 있다. Le Chatelier 원리를 기본으로 하는 흡착분리 동시 반응 (sorption enhanced reaction, SER)에서는 수소생산 반응의 열역학적 한계를 극복할 수 있고 정반응의 속도를 증대시킬 수 있다. 본 연구에서는 $K_2CO_3$가 첨가된 hydrotalcite에 대한 고온에서의 $CO_2$ 화학흡착 평형 및 거동 데이터를 실험을 통하여 측정하였다. 또한 WGS 상용촉매와 화학 흡착제를 이용하여 흡착분리 동시 반응을 실험과 수치해석 시뮬레이션으로 수행하였고, 연구결과로부터 연료전지에 사용할 수 있는 고순도의 수소 (~10 ppm CO)를 직접 생산할 수 있으며, 동시에 고압상태의 $CO_2$를 고순도로 포집할 수 있음을 확인할 수 있었다. 고압, 고순도의 $CO_2$ 포집은 이후 $CO_2$ 저장에 용이하게 이용되어 온실가스 저감에 기여할 수 있을 것으로 기대된다.

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Prediction of carbon dioxide emissions based on principal component analysis with regularized extreme learning machine: The case of China

  • Sun, Wei;Sun, Jingyi
    • Environmental Engineering Research
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    • v.22 no.3
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    • pp.302-311
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    • 2017
  • Nowadays, with the burgeoning development of economy, $CO_2$ emissions increase rapidly in China. It has become a common concern to seek effective methods to forecast $CO_2$ emissions and put forward the targeted reduction measures. This paper proposes a novel hybrid model combined principal component analysis (PCA) with regularized extreme learning machine (RELM) to make $CO_2$ emissions prediction based on the data from 1978 to 2014 in China. First eleven variables are selected on the basis of Pearson coefficient test. Partial autocorrelation function (PACF) is utilized to determine the lag phases of historical $CO_2$ emissions so as to improve the rationality of input selection. Then PCA is employed to reduce the dimensionality of the influential factors. Finally RELM is applied to forecast $CO_2$ emissions. According to the modeling results, the proposed model outperforms a single RELM model, extreme learning machine (ELM), back propagation neural network (BPNN), GM(1,1) and Logistic model in terms of errors. Moreover, it can be clearly seen that ELM-based approaches save more computing time than BPNN. Therefore the developed model is a promising technique in terms of forecasting accuracy and computing efficiency for $CO_2$ emission prediction.

Study on Conceptual Design of Pressure Vessel to Transport CNG and CO2 (CNG 및 CO2 겸용 수송을 위한 압력용기 개념 설계에 대한 연구)

  • Kim, Young-Hun
    • Journal of Ocean Engineering and Technology
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    • v.27 no.1
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    • pp.51-58
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    • 2013
  • Recently, there has been an increase in the demand for natural gas as a source of clean energy, which has increased the demand for LNG carriers. However, LNG carriers require a capital investment to obtain equipment for the regasification process, which prevents fires and explosions. Thus, on account of NIMBY, a CNG carrier is suggested that eliminates the need for regasification equipment. Meanwhile, carbon dioxide emissions are more and more regulated by international conventions such as the Kyoto Protocol. Because of this, $CO_2$ carriers have also received international attention as a methodology to transport and store $CO_2$ cargoes. Several vessels or tanks to transport and store $CO_2$ gas have been studied in various countries. This paper proposes a conceptual design for a 20ft container shaped tank to effectively transport small cargoes of $CO_2$ and CNG. The proposed pressure vessel or tank will be carried by a conventional containership or special cargo ship. The influences of the design parameters for proposed pressure vessel or tank. Including the materials, scantlings, and shape of the pressure vessel, are studied theoretically and computationally.

Model for Estimating CO2 Concentration in Package Headspace of Microbiologically Perishable Food

  • Lee, Dong-Sun;Kim, Hwan-Ki;An, Duck-Soon;Yam, Kit L.
    • Preventive Nutrition and Food Science
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    • v.16 no.4
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    • pp.364-369
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    • 2011
  • Levels of carbon dioxide gas, a metabolite of microbial growth, have been reported to parallel the onset of microbial spoilage and may be used as a convenient index for a packaged food's shelf life. This study aimed to establish a kinetic model of $CO_2$ production from perishable food for the potential use for shelf life control in the food supply chain. Aerobic bacterial count and package $CO_2$ concentration were measured during the storage of seasoned pork meat at four temperatures (0, 5, 10 and $15^{\circ}C$), and their interrelationship was investigated to establish a mathematical model. The microbial growth at constant temperature was described by using model of Baranyi and Roberts. $CO_2$ production from the stored food could be explained by taking care of its yield and maintenance factors linked to the microbial growth. By establishing the temperature dependence of the microbial growth and $CO_2$ yield factor, $CO_2$ partial pressure or concentration in package headspace could be estimated to a limited extent, which is helpful for controlling the shelf life under constant and dynamic temperature conditions. Application and efficacy of the model needs to be improved with further refinement in the model.