• Korean Journal of Agricultural and Forest Meteorology
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• v.13 no.4
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• pp.192-203
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• 2011

The CERES-Barley crop simulation model was used to assess the impacts of climate change on the potential yield of winter naked barley in Korea. Fifty six sites over the southern part of the Korean Peninsula were selected to compare the climate change impacts in various climatic conditions. Based on the A1B climate change scenarios of Korea, the present climatological normal (1971-2000) and the three future ones (2011-2040, 2041-2070, and 2071-2100) were considered in this study. The three future normals were divided by three environmental conditions with changes in: (1) temperature only, (2) carbon dioxide concentration only, and (3) both temperature and carbon dioxide concentration. The agreement between the observed and simulated outcomes was reasonable with the coefficient of determination of grain yield to be 0.78. We concluded that the CERES-Barley model was suitable for predicting climate change impacts on the potential yield of winter naked barley. The effect of the increased temperature only with the climate change scenario was negative to the potential yield of winter naked barley, which ranges from -34 to -9% for the three future normals. However, the effect of the elevated carbon dioxide concentration only on the potential yield of winter naked barley was positive, ranging from 6 to 31% for the three future normals. For the elevated conditions of both temperature and carbon dioxide concentration, the potential yields increased by 8, 15, and 13% for the 2011-2040, 2041-2070, and 2071-2100 normals, respectively.

• Polymer(Korea)
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• v.34 no.6
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• pp.507-510
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• 2010

Poly(cyclohexane carbonate) diol was synthesized by the alternating copolymerization of cyclohexene oxide and $CO_2$ over Cr based transition metal catalysts. The prepared PCCD was applied as a precursor for the preparation of waterborne polyurethane (PUD) in order to investigate an application field of carbon dioxide-based polycarbonate. The scratch resistance and thermal properties of PUDs, which was prepared with two kinds of polymeric diols (PCD and PCCD) were investigated. The scratch resistance and thermal decomposition temperature of PUD film prepared with PCCD is worse than those prepared with PCD, poly(hexamethylene carbonate) glycol. While, glass transition temperature of PUD film prepared with PCCD was higher than that prepared with PCD. It might be due to the rigid cyclohexane structure in the PCCD.

• Clean Technology
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• v.11 no.3
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• pp.147-152
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• 2005

For estblishing the best technique for the micronization of Ibuprofen using supercritical fluids, the solubility should be known. The solubility of Ibuprofen in supercritical carbon dioxide was measured by observing the cloud point. The cloud point was observed using high pressure equipment equipped a variable volume view cell between temperature of 35, 40 and $45^{\circ}C$. The solubility data was correlated by the Peng-Robinson equation of state Solute physical properties, such as critical temperature (Tc), critical pressure (Pc) and acentric factor (${\omega}$) were estimated by the some group contribution method. As pressure was increased, the solubility increased at constant temperature. The retrograde phenomenon by a solute vapor pressure and a density of solvent was observed at the pressure of around 150bar. It was found that $CO_2$ can be used as a supercritical solvent in micronization of ibuprofen by RESS.

• Applied Chemistry for Engineering
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• v.23 no.1
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• pp.47-52
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• 2012

Porous carbon nanofibers were prepared as a gas sensor electrode to study the $CO_2$ sensing property based on effects of porosity and introduced amine functional groups. Electrospun fibers were obtained by using electrospinning method with polyacrylonitrile precursor and they were treated by the thermal treatment and chemical activation. Amine functional groups were introduced by the liquid state treatment using diethylenetriamine. The specific surface area increased up to $2000m^2/g$ by the chemical activation. The Introduced amine functional group was identified using FT-IR spectroscopy. $CO_2$ gas sensing property was improved as four folds via introduced amine functional groups on the activated carbon nanofiber. In conclusion, the gas sensing property was improved based on the developed porosity by the chemical activation and the chemical attraction of $CO_2$ gas by introduced functional groups.

• Rapid Communication in Photoscience
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• v.2 no.2
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• pp.42-45
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• 2013

Natural photosynthesis utilizes solar energy to convert carbon dioxide and water to energy-rich carbohydrates. Substantial use of sunlight to meet world energy demands requires energy storage in useful fuels via chemical bonds because sunlight is intermittent. Artificial photosynthesis research focuses the fundamental natural process to design solar energy conversion systems. Nicotinamide adenine dinucleotide ($NAD^+$) and $NADP^+$ are ubiquitous as electron transporters in biological systems. Enzymatic, chemical, and electrochemical methods have been reported for NADH regeneration. As photochemical systems, visible light-driven catalytic activity of NADH regeneration was carried out using platinum nanoparticles, molecular rhodium and cobalt complexes in the presence of triethanolamine as a sacrificial electron donor. Pt nanoparticles showed photochemical NADH regeneration activity without additional visible light collector molecules, demonstrating that both photoactivating and catalytic activities exist together in Pt nanoparticles. The NADH regeneration of the Pt nanoparticle system was not interfered with the reduction of $O_2$. Molecular cobalt complexes containing dimethylglyoxime ligands also transfer their hydrides to $NAD^+$ with photoactivation of eosin Y in the presence of TEOA. In this photocatalytic reaction, the $NAD^+$ reduction process competed with a proton reduction.

• Clean Technology
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• v.13 no.2
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• pp.99-103
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• 2007

Pt/Nafion self-humidifying membranes for Polymer Electrolyte Membrane Fuel Cell (PEMFC) were synthesized via a supercritical-impregnation method. The Nafion 112 membranes were impregnated with Pt(II) acetylacetonate from a supercritical carbon dioxide ($scCO_2$) solution at $80^{\circ}C$ and 19.8 MPa. After the impregnation, the Pt-impregnated Nafion membrane was converted Pt deposited Nafion(Pt/Nafion) membrane by reducing agent, sodium borohydride ($NaBH_4$) under $50^{\circ}C$ and 2 hours. The prepared Pt/Nafion membranes were investigated by SEM, EDS and EPMA. The performance of the Pt/Nafion membranes was examined in PEMFC as a self-humidifying membrane. The cell performance of the Pt/Nafion membrane at $65^{\circ}C$ is better than that of Nafion 112.

• Proceedings of the KSR Conference
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• 2011.10a
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• pp.1309-1314
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• 2011

People spend approximately 80 ~ 90 % of their time in various kinds of indoor spaces. And, in metropolitan area, most people spend more than 1 hour in public transportation everyday. For this reason, people's interest in the indoor air quality is drastically increasing. Among various indoor air pollutants, $CO_2$ is one of the most severe environmental concerns. Ventilation is commonly used to keep low $CO_2$ concentration in the passenger cabin. However, ventilation may worse the indoor air quality problem in case of subway because the tunnel is seriously polluted by particulate matters. In this study, an alternative way to remove $CO_2$ was suggested. The adsorption of $CO_2$ by $CO_2$ adsorbent was studied. Zeolite modified with base was prepared, and $CO_2$ removal performance was tested in $4m^3$ and $24m^3$ environmental chambers. It was found that $CO_2$ adsorbent could effectively remove $CO_2$ in the chambers.

• Proceedings of the SAREK Conference
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• 2009.06a
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• pp.1312-1316
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• 2009

Growing interest in $CO_2$ capturing from industrial processes and storage in underground formations is emerging from commitments in reducing $CO_2$ emissions manifested in the Kyoto Protocol. In this paper, $CO_2$ liquefaction system is treated in focus of liquefaction efficiency & production rate. Presently $CO_2$ is transported in ships or trucks at a pressure of 14-20 bar. Considering this, the liquefaction pressures of 20, 15, 6.5 bar are selected. Compressor work and cooling capacity are calculated and compared. In order to investigate the effect of intercooling, the compressed gas after compressor work is cooled by ambient air or seawater. In case of applying the intercooling to the system, consuming energy can be saved larger than 20%. In the lower liquefaction pressure, the more $CO_2$ can be obtained due to higher density. In the liquefaction pressure of 6.5 bar, its $CO_2$ production is about 35% higher than that of the system with the liquefaction pressure, 20 bar.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.3181-3188
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• 2008

The supercritical $CO_2$ Brayton cycle energy conversion system is presented as a promising alternative to the present Rankine cycle. The principal advantage of the S-$CO_2$ gas is a good efficiency at a modest temperature and a compact size of its components. The S-$CO_2$ Brayton cycle coupled to a SFR also excludes the possibilities of a SWR (Sodium-Water Reaction) which is a major safety-related event, so that the safety of a SFR can be improved. KAERI is conducting a feasibility study for the supercritical carbon dioxide (S-$CO_2$) Brayton cycle power conversion system coupled to KALIMER(Korea Advanced LIquid MEtal Reactor). The purpose of this research is to develop S-$CO_2$ Brayton cycle energy conversion systems and evaluate their performance when they are coupled to advanced nuclear reactor concepts of the type under investigation in the Generation IV Nuclear Energy Systems. This paper contains the research overview of the S-$CO_2$ Brayton cycle coupled to KALIMER-600 as an alternative energy conversion system.

• Advances in Computational Design
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• v.8 no.4
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• pp.295-307
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• 2023

This paper presents an optimization of the reinforced concrete ribbed slab in terms of minimum CO₂ emissions and an economic justification of the final optimal design. The design variables are six geometry variables including the slab thickness, the ribs spacing, the rib width at the lower and toper end, the depth of the rib and the bar diameter of the reinforcement, and the seventh variable defines the concrete strength. The objective function is considered to be the minimum amount of carbon dioxide gas (CO₂) emission and at the same time, the optimal design is economical. Seven significant design constraints of American Concrete Institute's Standard were considered. A robust metaheuristic optimization method called improved dolphin echolocation and ant colony optimization (IDEACO) has been used to obtain the best possible answer. At optimal design, the three most important sources of CO₂ emissions include concrete, steel reinforcement, and formwork that the contribution of them are 63.72, 32.17, and 4.11 percent respectively. Formwork, concrete, steel reinforcement, and CO₂ are the four most important sources of cost with contributions of 67.56, 19.49, 12.44, and 0.51 percent respectively. Results obtained by IDEACO show that cost and CO₂ emissions are closely related, so the presented method is a practical solution that was able to reduce the cost and CO₂ emissions simultaneously.