• Korean Journal of Environmental Agriculture
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• v.29 no.4
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• pp.362-366
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• 2010

Carbon isotope ratio ($^{13}C/^{12}C$, expressed as ${\delta}^{13}C$) of tree ring can be proxy of atmospheric $CO_2$ concentration ([$CO_2$]) due to the inter-correlation between atmospheric [$CO_2$], ${\delta}^{13}C$ of atmospheric $CO_2$, and ${\delta}^{13}C$ of plant tissue that assimilates atmospheric $CO_2$. This study was conducted to investigate if ${\delta}^{13}C$ of tree ring of Pinus densiflora in polluted area may show a lower value than that in unpolluted area and to explore the possibility of reconstructing atmospheric [$CO_2$] using its relationship with ${\delta}^{13}C$ of tree ring. During the period between 1999 and 2005, ${\delta}^{13}C$ of tree annual ring tended to decrease over time, and the ${\delta}^{13}C$ in polluted area (-27.2‰ in 2009 to -28.3‰ in 2005) was significantly (P<0.001) lower than that (-26.0‰ in 1999 to -27.1‰ in 2005) in unpolluted area. This reflects a greater emission of $CO_2$ depleted in $^{13}C$ in the polluted area. Atmospheric [$CO_2$] was significantly (P<0.01) correlated with ${\delta}^{13}C$ of tree ring in a linear fashion. Using the linear regression equation, atmospheric [$CO_2$] in the polluted area was estimated to range from 392.3 ppm in 1999 to 410.9 ppm in 2005, and these values were consistently higher than the national atmospheric [$CO_2$] monitored at the Anmyoundo meteorological station (from 370.7 ppm in 1999 to 387.2 ppm in 2005). Our study suggested that it is possible to reconstruct atmospheric [$CO_2$] in a certain area using the relationship between tree ring ${\delta}^{13}C$ and atmospheric [$CO_2$].

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• v.2 no.2
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• pp.109-114
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• 1998

The induction of crassulacean acid metabolism(CAM) characterized by day/night acid fluctuation was investigated in leaves from 10 days exposure to elevated $CO_2$ concentration(1,000 ${\mu}L\;L^{-1}CO_2).$ For Pereskia aculeata, have $C_3-like$ gas exchange pattern in well watered condition and shift into CAM-like in water stress, showed a more typical CAM-like diurnal acid fluctuation. Whereas the massive diurnal fluctuation of acidity in typical CAM of Kalanchoe rosea was declined. The effect of short-term exposure to various concentrations of $CO_2$ on titratable acidity in P. aculeata and K. rosea was also investigated. To investigate the response of various $CO_2$ concentrations, four different $CO_2$ levels(350, 700, 1,000 and 1,500 ${\mu}L\;L^{-1})$ were imposed for 24hr and measured the titratable acidity at 06:00, when the acidity was maximum, and 14:00, when the acidity was minimum. The accumulation of acid in P. aculeata was enhanced markedly by higher concentration of $CO_2,$ while the level of acidity in f rosea did not highly respond to $CO_2.$ A notable difference between P. aculeata and K. rosea was the response of de-acidification to a higher concentration of $CO_2$ Increasing with $CO_2,$ the degree of do-acidification of P. auleata was increased while that of K. rosea was depressed.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.43 no.6
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• pp.679-686
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• 2010

To investigate the contribution of macroalgae to biogeochemical nutrients and carbon cycles, we measured the uptake rates of nutrients and $CO_2$ by Undaria pinnatifida using an incubation method in an acrylic chamber. From January to March 2010, U. pinnatifida was sampled at Ilkwang, a well-known area of macroalgae culture in Korea. The initial and final concentrations of nutrients, dissolved oxygen, total alkalinity, and pH of the chamber water were measured, and production/uptake rates were calculated using concentration changes, chamber volume, and incubation time. The production rate of dissolved oxygen by U. pinnatifida (n = 32) was about $5.4{\pm}4.0\;{\mu}mol\;g_{fw}^{-1\;}h^{-1}$. The uptake rate of total dissolved inorganic carbon (TDIC), calculated by total alkalinity and pH, was $7.9{\pm}6.5\;{\mu}mol\;g_{fw}^{-1}\;h^{-1}$. Nutrients uptake averaged $141.7{\pm}119.2$ nmol N $g_{fw}^{-1}\;h^{-1}$ and $15.0{\pm}9.1$ nmol P $g_{fw}^{-1}\;h^{-1}$. A positive linear correlation ($r^2$ = 9.6) existed between the production rate of dissolved oxygen and the uptake rate of total dissolved inorganic carbon, suggesting that these two factors serve as good indicators of U. pinnatifida photosynthesis. The relationships between fresh weight and uptake rates of nutrients and $CO_2$ suggested that younger specimens (<~50 g fresh weight) are much more efficient at nutrients and $CO_2$ uptake than are specimens >50 g. The amount of carbon uptake by the total biomass of U. pinnatifida in Korea during the year of 2008 was about 0.001-0.002% of global ocean carbon uptake. Thus, more research should be focused on macroalgae-based biogeochemical cycles to evaluate the roles and contributions of macroalgae to the global carbon cycle.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.6
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• pp.1179-1186
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• 2012

For better understanding of carbon cycle dynamics of an agro-ecosystem, an accurate assessment of seasonal and daily $CO_2$ flux is essential to understand the relationship between various environmental factors and crop productivity. We developed the automatic sliding canopy chamber (ASCC) system that measured continuous net ecosystem productivity (NEP) over whole growing season under the natural meteorological rhythm. The ASCC was composed of two main parts which were sliding part for measuring NEP, and automatic opening and closing chamber (AOCC) for measuring soil respiration (SR) on the soil surface. The ASCC was developed by using open flow method for measuring soil $CO_2$ efflux. The disturbance of natural meteorological condition was minimized by opening the base frames. In the field test with barley (Hordeum vulgare L.), NEP was calculated at $140mg\;CO_2\;m^{-2}h^{-1}$ on a clear day using continuous data and eliminated the possibility of overestimate about 16% using one hour data during the day time. Unlike other small scale chamber system, installation on cropping-field made it possible to take any modifications which might be caused by natural environmental condition.

• Journal of the Korean Chemical Society
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• v.53 no.6
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• pp.635-639
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• 2009

Experimental work was carried out to study the combustion kinetics of the Indian coal-char in the varying mixture of carbon dioxide-oxygen ($CO_2-O_2$). The coal sample was pulverized and sieved to less than 58 microns and charred using volatile furnace by passing the nitrogen gas. The experiments were carried out using the Thermo Gravimetric Analyzer (TGA-50) at CPRI, Bangalore, different proportions of ($CO_2-O_2$) gas was allowed in to the TGA-50 (80-20, 60-40, 40-60, 20-80) mole basis were used to study the combustion kinetics of coal Isothermally, kinetic parameters like Activation energy (E) and the pre-exponential factors (A) are calculated using the unification approach and modified Arrhenius equation.

• Journal of the Korea Organic Resources Recycling Association
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• v.20 no.2
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• pp.15-19
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• 2012

Wood wastes could be renewable resources by recycling as particleboard manufacturing or energy production. Particle board is the most common item of wood waste recycling and energy production from wood wastes has highlighted for energy recovery to reduce greenhouse gas generation in recent years. The aim of this study was to evaluate the environmental benefits of the processes for particle board manufacturing and energy production. The functional unit was one ton of wood wastes and the environmental impact was analyzed by life cycle assessment methodology. The result was that 112kg of carbon dioxide equivalent was produced from particle board manufacturing process and 382kg of carbon dioxide equivalent was produced from combined heat and power generation process. The concept of temporary biomass carbon storage was to applied to this study.

• Journal of the Korean Society for Marine Environment & Energy
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• v.8 no.4
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• pp.203-212
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• 2005

Anthropogenic emissions of greenhouse gases, particularly carbon dioxide($CO_2$) which arises mainly as wastes from the fossil fuel burning processes, are causing global warming. The effects of global warming become increasingly felt all over the world including sea level rise and extreme weather. The more direct consequences of the elevated atmospheric $CO_2$ on the ocean is the acidification of the surface ocean which brings a far reaching adverse impact on the life at sea and probably on the whole ecosystem of the planet. Improvement in energy efficiency and use of alternative energy sources are being made to reduce $CO_2$ emissions. However, a rapid transition to alternatives seems unachievable within a few decades due to the constraints on the associated technology and socio-economic factors in the world, since fossil fuels make up approximately 85% of the world's commercial energy demands. It has now been recognized that capture and geological sequestration of $CO_2$ could significantly reduce its emissions from fossil fuel utilization and therefore provides the means to rapidly achieve large reductions in $CO_2$ emissions(excerpts from London Convention, LC/SG 28, 2005). In Korea, well-developed sedimentary basins are spread over the vast continental shelf and slope regions, whereas, the land is densely populated and limited in area. Consequently, the offshore area is preferred to the land for the sites for geological sequestration. The utilization of the offshore area, however, may be subject to international agreements including London Convention. In this paper, the recent trends in technologies and regulations for $CO_2$ capture and geological sequestration are described to encourage its applications in Korea.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.3
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• pp.255-263
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• 2013

Carbon dioxide reduction technologies using photosynthetic microorganism were suggested to overcome environmental destruction caused by $CO_2$ in flue gases from power plant and other industries. However, there are many toxic constituents in flue gas including CO, NOx, SOx. Continuous and Excessive supply of these noxious gases to cells will leads to inhibition of microalgal growth along with partial cell death. In this study, we tested the noxious effect of SOx and NOx on the pH and microalgal growth under photoautotrophic culture in three microalgae of Neochloris oleoabundans, Chlorella vulgaris and Haematococcus pluvialis. As a result, SOx concentration more than 50 ppm led to the rapid reduction of pH, thereby inhibiting of the growth in Neochloris oleoabundans and Chlorella vulgaris. NOx concentration more the 100 ppm reduced the exponential growth of N. oleoabundans and C. vulgaris. And H. pluvialis exhibited low sensitivity to SOx and NOx. Consequently, the three microalgae of N. oleabundas, C. vulagaris and H. pluvialis showed the normal vegetative growth in 25 ppm of NOx and SOx. Above all, H. pluvialis was useful for the $CO_2$ sequestration of the flue gas including high concentrations of NOx and SOx.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.122.1-122.1
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• 2011

The motivation for this work was the potential of hydrophobic amino acids such as glycine, L-alanine, and L-valine to be applied as thermodynamic hydrate inhibitors (THIs). To confirm their capabilities in inhibiting the formation of gas hydrates, three-phase (liquid-hydrate-vapor) equilibrium conditions for carbon dioxide hydrate formation in the presence of 0.1 to 3.0 mol% amino acid solutions were determined in the range of 273.05 to 281.45 K and 14.1 to 35.2 bar. From quantitative analyses, the inhibiting effects of the amino acids (on a mole concentration basis) decreased in the following order: L-valine > L-alanine > glycine. The application of amino acids as THIs has several potential advantages over conventional methods. First, the environmentally friendly nature of amino acids as compared to conventional inhibitors means that damage to ecological systems and the environment could be minimized. Second, the loss of amino acids in recovery process would be considerably reduced because amino acids are non-volatile. Third, amino acids have great potential as a model system in which to investigate the inhibition mechanism on the molecular level, since the structure and chemical properties of amino acids are well understood.

• Corrosion Science and Technology
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• v.19 no.2
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• pp.66-74
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• 2020

In this paper, the author's team has carried out a comparative experimental study on the corrosion characteristics of Q235 steel commonly used in large-scale storage tanks under the specific bottom water environment found with Russian and Daqing crude oil. It was found that there is a certain degree of uniform or local corrosion on the tank floor depending on the kind of bottom water. The bottom water corrosion of Daqing crude oil is a uniform corrosion caused by carbon dioxide. While the Russian crude oil bottom water corrosion is clearly local corrosion caused by co-corrosion of carbon dioxide and hydrogen sulfide, here the corrosion rate is obviously higher than that caused by Daqing crude oil. There are two modes of storage tank inspection and maintenance that have been currently adopted by Chinese refining and chemical enterprises: a regular inspection mode and a API581-2016 risk-based detection mode. These modes have been effectively combined to form an intelligent tank inspection and maintenance mode, software tools to support this intelligent inspection and maintenance management have been developed.