Transactions of the Korean Society of Automotive Engineers
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v.14
no.3
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pp.178-185
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2006
This paper investigates the steady-state combustion characteristics of the Homogeneous charge compression ignition(HCCI) engine with variable valve timing(VVT) and dimethyl ether(DME) direct injection, to find out its benefits in exhaust gas emissions. HCCI combustion is an attractive way to lower carbon dioxide($CO_2$), nitrogen oxides(NOx) emission and to allow higher fuel conversion efficiency. However, HCCI engine has inherent problem of narrow operating range at high load due to high in-cylinder peak pressure and consequent noise. To overcome this problem, the control of combustion start and heat release rate is required. It is difficult to control the start of combustion because HCCI combustion phase is closely linked to chemical reaction during a compression stroke. The combination of VVT and DME direct injection was chosen as the most promising strategy to control the HCCI combustion phase in this study. Regular gasoline was injected at intake port as main fuel, while small amount of DME was also injected directly into the cylinder as an ignition promoter for the control of ignition timing. Different intake valve timings were tested for combustion phase control. Regular gasoline was tested for HCCI operation and emission characteristics with various engine conditions. With HCCI operation, ignition delay and rapid burning angle were successfully controlled by the amount of internal EGR that was determined with VVT. For best IMEP and low HC emission, DME should be injected during early compression stroke. IMEP was mainly affected by the DME injection timing, and quantities of fuel DME and gasoline. HC emission was mainly affected by both the amount of gasoline and the DME injection timing. NOx emission was lower than conventional SI engine at gasoline lean region. However, NOx emission was similar to that in the conventional SI engine at gasoline rich region. CO emission was affected by the amount of gasoline and DME.
In this study, Life Cycle Assessment(LCA) has been carried out to evaluate the environmental impacts of a metallic can. A 360 mL volume of an aluminum can bottle was used as the functional unit. The results of Life Cycle Inventory(LCI) showed that iron ore and coal were the major parts of the input materials, whereas aluminum can products, carbon dioxide, wastewater, and hazardous wastes were those of the output ones. According to LCA weighting, it was observed that the most significant impact potential was found to be global warming(49.11%) followed by abiotic resource depletion(47.72%). In the whole system, cold rolled steel coil showed the largest environmental impact potential(86%), followed by electricity(14%). Meanwhile, lubricating oil and industrial water had the minor portion of the total environmental impact potentials. It was suggested that the use of cold rolled steel and electricity should be the main source for $CO_2$, resulting in the big impact on global warming.
In this study, we investigated the effects of the number of air exchanges (NAE) on shape fruit body in two oyster mushrooms, Chunchu 2# and Suhan 2#. The suitable NAEs of Chunchu 2# were $1/10h^{-1}$ at primordial induction, $1/6h^{-1}$ at early stage of growth, $1/4h^{-1}$ at middle stage of growth, $1/4h^{-1}$ at late stage of growth and those of Suhan 2# were $1/6h^{-1}$ at primordial induction, $1/6h^{-1}$ at early stage of growth, $1/4h^{-1}$ at middle stage of growth, and $1/2h^{-1}$ at late stage of growth. In those conditions, the fruit bodies grew well. $CO_2$ concentration hardly affected the primordial formation of both mushrooms. However there were ventilation disturbances over 1500ppm. For instance, the end of pileus rolled up etc. As a result, Suhan 2# required higher ventilation compared with Chunchu 2# and the lower NAE was favorable for growth.
Ha, Tae-Min;Son, Seung-Nam;Lee, Jun-Yong;Hong, Sang-Jeen
Proceedings of the Korean Vacuum Society Conference
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2012.02a
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pp.434-435
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2012
Plasma enhanced chemical vapor deposition (PECVD) silicon dioxide thin films have many applications in semiconductor manufacturing such as inter-level dielectric and gate dielectric metal oxide semiconductor field effect transistors (MOSFETs). Fundamental chemical reaction for the formation of SiO2 includes SiH4 and O2, but mixture of SiH4 and N2O is preferable because of lower hydrogen concentration in the deposited film [1]. It is also known that binding energy of N-N is higher than that of N-O, so the particle generation by molecular reaction can be reduced by reducing reactive nitrogen during the deposition process. However, nitrous oxide (N2O) gives rise to nitric oxide (NO) on reaction with oxygen atoms, which in turn reacts with ozone. NO became a greenhouse gas which is naturally occurred regulating of stratospheric ozone. In fact, it takes global warming effect about 300 times higher than carbon dioxide (CO2). Industries regard that N2O is inevitable for their device fabrication; however, it is worthwhile to develop a marginable nitrous oxide free process for university lab classes considering educational and environmental purpose. In this paper, we developed environmental friendly and material cost efficient SiO2 deposition process by substituting N2O with O2 targeting university hands-on laboratory course. Experiment was performed by two level statistical design of experiment (DOE) with three process parameters including RF power, susceptor temperature, and oxygen gas flow. Responses of interests to optimize the process were deposition rate, film uniformity, surface roughness, and electrical dielectric property. We observed some power like particle formation on wafer in some experiment, and we postulate that the thermal and electrical energy to dissociate gas molecule was relatively lower than other runs. However, we were able to find a marginable process region with less than 3% uniformity requirement in our process optimization goal. Surface roughness measured by atomic force microscopy (AFM) presented some evidence of the agglomeration of silane related particles, and the result was still satisfactory for the purpose of this research. This newly developed SiO2 deposition process is currently under verification with repeated experimental run on 4 inches wafer, and it will be adopted to Semiconductor Material and Process course offered in the Department of Electronic Engineering at Myongji University from spring semester in 2012.
Journal of the Korean Recycled Construction Resources Institute
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v.6
no.2
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pp.97-102
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2011
Amount of disposed construction materials like waste concrete is growing fast and use of the recycled aggregate for concrete has been seriously considered. But the use of the recycled aggregate is very limited because recycled aggregate has very low quality. Therefore, quality of recycled aggregate is very important in the manufacturing of recycled aggregate concrete. We have studied a series of research according to chemical processes and investigate the alkaline elimination effect of recycled aggregate and quality variation of recycled aggregate by sodium carbonate. Thereafter we have evaluated quality of recycled fine aggregate and experimented quality of this aggregate. As a results, we find that it is easy to eliminate the calcium hydroxide in recycled aggregate by sodium carbonate and the quality of recycled aggregate increase by elimination of alkaline.
Journal of the Korean Applied Science and Technology
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v.20
no.1
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pp.33-43
/
2003
$LiMn_2O_4$ catalyst for $CO_2$ decomposition was synthesized by oxidation method for 30 min at 600$^{\circ}C$ in an electric furnace under air condition using manganese(II) nitrate $(Mn(NO_3)_2{\cdot}6H_2O)$, Lithium nitrate ($LiNO_3$) and Urea $(CO(NH_2)_2)$. The synthesized catalyst was reduced by $H_2$ at various temperatures for 3 hr. The reduction degree of the reduced catalysts were measured using the TGA. And then $CO_2$ decomposition rate was measured using the reduced catalysts. Phase-transitions of the catalysts were observed after $CO_2$ decomposition reaction at an optimal decomposition temperature. As the result of X-ray powder diffraction analysis, the synthesized catalyst was confirmed that the catalyst has the spinel structure, and also confirmed that when it was reduced by $H_2$, the phase of $LiMn_2O_4$ catalyst was transformed into $Li_2MnO_3$ and $Li_{1-2{\delta}}Mn_{2-{\delta}}O_{4-3{\delta}-{\delta}'}$ of tetragonal spinel phase. After $CO_2$ decomposition reaction, it was confirmed that the peak of $LiMn_2O_4$ of spinel phase. The optimal reduction temperature of the catalyst with $H_2$ was confirmed to be 450$^{\circ}C$(maximum weight-increasing ratio 9.47%) in the case of $LiMn_2O_4$ through the TGA analysis. Decomposition rate(%) using the $LiMn_2O_4$ catalyst showed the 67%. The crystal structure of the synthesized $LiMn_2O_4$ observed with a scanning electron microscope(SEM) shows cubic form. After reduction, $LiMn_2O_4$ catalyst became condensed each other to form interface. It was confirmed that after $CO_2$ decomposition, crystal structure of $LiMn_2O_4$ catalyst showed that its particle grew up more than that of reduction. Phase-transition by reduction and $CO_2$ decomposition ; $Li_2MnO_3$ and $Li_{1-2{\delta}}Mn_{2-{\delta}}O_{4-3{\delta}-{\delta}'}$ of tetragonal spinel phase at the first time of $CO_2$ decomposition appear like the same as the above contents. Phase-transition at $2{\sim}5$ time ; $Li_2MnO_3$ and $Li_{1-2{\delta}}Mn_{2-{\delta}}O_{4-3{\delta}-{\delta}'}$ of tetragonal spinel phase by reduction and $LiMn_2O_4$ of spinel phase after $CO_2$ decomposition appear like the same as the first time case. The result of the TGA analysis by catalyst reduction ; The first time, weight of reduced catalyst increased by 9.47%, for 2${\sim}$5 times, weight of reduced catalyst increased by average 2.3% But, in any time, there is little difference in the decomposition ratio of $CO_2$. That is to say, at the first time, it showed 67% in $CO_2$ decomposition rate and after 5 times reaction of $CO_2$ decomposition, it showed 67% nearly the same as the first time.
Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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v.7
no.1
/
pp.1-7
/
2009
This study has been focused on determining the chemical composition of $^{14}C$ - in terms of both organic and inorganic $^{14}C$ contents - in reactor coolant from 3 different PWR's reactor type. The purpose was to evaluate the characteristic of $^{14}C$ that can serve as a basis for reliable estimation of the environmental release at domestic PWR sites. $^{14}C$ is the most important nuclide in the inventory, since it contributes one of the main dose contributors in future release scenarios. The reason for this is its high mobility in the environment, biological availability and long half-life(5730yr). More recent studies - where a more detailed investigation of organic $^{14}C$ species believed to be formed in the coolant under reducing conditions have been made - show that the organic compounds not only are limited to hydrocarbons and CO. Possible organic compounds formed including formaldehyde, formic acid and acetic acid, etc. Under oxidizing conditions shows the oxidized carbon forms, possibly mainly carbon dioxide and bicarbonate forms. Measurements of organic and inorganic $^{14}C$ in various water systems were also performed. The $^{14}C$ inventory in the reactor water was found to be 3.1 GBq/kg in PWR of which less than 10% was in inorganic form. Generally, the $^{14}C$ activity in the water was divided equally between the gas- and water- phase. Even though organic $^{14}C$ compound shows that dominant species during the reactor operation, But during the releasing of $^{14}C$ from the plant stack, chemical forms of $^{14}C$ shows the different composition due to the operation conditions such as temperature, pH, volume control tank venting and shut down chemistry.
Park, Sin-Ae;Kim, Min-Gi;Yoo, Mung-Hwa;Oh, Myung-Min;Son, Ki-Cheol
Horticultural Science & Technology
/
v.28
no.5
/
pp.864-870
/
2010
This study was conducted to determine the effects of foliage plants on reducing indoor carbon dioxide ($CO_2$). Five foliage plants such as $Hedera$$helix$ L., $Ficus$$benjamina$ L., $Pachira$$aquatica$, $Chamaedorea$$elegans$, and $Ficus$$elastica$ were selected and cultivated in two different growth medium (peatmoss and hydroball). Each plant was placed in an airtight chamber and then treated with the combinations of two different $CO_2$ concentrations (500 or 1,000 ppm) and two different light intensities (50 or $200{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$). The change of $CO_2$ concentration (ppm) in the airtight chamber during day and night was measured and then converted into the photosynthetic rate (${\mu}mol\;CO_2{\cdot}m^{-2}{\cdot}s^{-1}$). As the results, each foliage plant reduced $CO_2$ level in the airtight chamber for one hour by photosynthesis. $Pachira$$aquatica$ and $Ficus$$elastica$ absorbed $CO_2$ more effectively compared to the other plants. The plants exposed to higher $CO_2$ concentration (1,000 ppm) and higher light intensity ($200{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$) showed more effective $CO_2$ elimination rate and photosynthetic rate. The plants that have wide leaves and big leaf areas such as $Pachira$$aquatica$, $Hedera$$helix$ L.,and $Ficus$$elastica$ showed higher photosynthetic rate than the other plants that have smaller leaves. Released $CO_2$ concentration by respiration of the plants during the night was very low compared to the absorbed $CO_2$ concentration by photosynthesis during the day. There was no significant difference between peatmoss and hydroball medium on reducing $CO_2$ concentration and increasing photosynthetic rate. In conclusion, this study suggested that foliage plants can effectively eliminate indoor $CO_2$. Optimum environmental control in relation to photosyntheis and usage of right indoor foliage plants having lots of leaves and showing active photosynthesis even under low light intensity like indoor light condition would be required to increase the elimination capacity of indoor $CO_2$.
The effect of Ganoderma lucidum extract on Saccharomyces cerevisiae growth and physiology has been investigated. S. cerevisiae was inoculated in Henneberg solution medium into which 0, 0.1, 0.5 or 1.0% extracts of G. lucidum were added respectively and it was fermented at $30^{\circ}C$ for 5 days, respectively. Cell number of S. cerevisiae has increased according to the concentration as in order of distilled water(Dw) extracts 1.0% added>ethanol(Et) extracts 1.0% added>Dw extracts 0.5% added>Et extracts 0.5% added>Dw extracts 0.1% added>Et extracts 0.1% added group compared to control group(extracts 0% added) and in Dw extracts 1.0% added group the number has increased than those of control group after the fermentation of 72 hours. Weights of dried yeast cell have increased in each treated group than those of control group and it increased about 1.7 times in each Dw 1.0%, Et 1.0% group than those of control group after fermentation of 120 hours. The more the extracts of G. lucidum was added, the more alcohol levels increased during fermentation. The rate of carbon dioxide production per G. lucidum extract medium was faster than those of control group as G. lucidum extract was increasingly added.
Jo, Woo-Sik;Lee, Sung-Hak;Park, Woo-Ram;Shin, Seung-Ho;Park, Chang-Min;Oh, Ji-Hyun;Park, Who-Won
Journal of Mushroom
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v.15
no.4
/
pp.264-268
/
2017
In the 21st century, information and communication technology (ICT) worldwide presents a new vision for agriculture. Time and place, as well as the high-tech industry, to overcome barriers to the fusion of the so-called "smart agriculture," are changing the agricultural landscape. Core container production in precision agriculture for mushroom cultivation, optimal temperature, humidity, irradiation, self-regulation of factors such as carbon dioxide, and environment for mushroom cultivation were adopted. Lentinula edodes (shiitake) is an edible mushroom native to East Asia, cultivated and consumed in many Asian countries. It is considered to be medicinal in certain practices of traditional medicine. We used different controlled light sources (Blue-Red-White-combined LED, blue LED, red LED, and fluorescent light) with different LED radiation intensities (1.5, 10.5, and $20.5{\mu}mol/m^2s$ for LEDs) to compare growth and development. Mushrooms were treated with light in a 12-hour-on/12-hour-off cycle, and maintained in a controlled room at $19{\sim}21^{\circ}C$, with 80~90% humidity, and an atmospheric $CO_2$ concentration of 1,000 ppm for 30 days. Growth and development differed with the LED source color and LED radiation intensity. Growth and development were the highest at $10.5{\mu}mol/m^2s$ of blue LED light. After harvesting the fruit bodies, we measured their weight and length, thickness of pileus and stipe, chromaticity, and hardness. The $10.5{\mu}mol/m^2s$ blue-LED-irradiated group showed the best harvest results with an average individual weight of 39.82 g and length of 64.03 mm, pileus thickness of 30.85 mm and pileus length of 43.22 mm, and stipe thickness of 16.96 mm with fine chromaticity and hardness. These results showed that blue LED light at $10.5{\mu}mol/m^2s$ s exerted the best effect on the growth and development of L. edodes (shiitake) mushroom in the ICT-system container-type environment.
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