• Membrane Journal
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• v.21 no.1
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• pp.55-61
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• 2011

$BaCo_{0.7}Fe_{0.22}Nb_{0.08}O_{3-{\delta}}$ oxide was synthesized by solid state reaction method. Dense ceramic membrane was prepared using as-prepared powder by pressing and sintering at $1,200^{\circ}C$. XRD result of membrane showed single perovskite structure. Leakage and oxygen permeation test were conducted on the membrane sealed by glass ring as a sealing material. The oxygen permeation flux increased with increasing temperature and pressure difference and maximum oxygen permeation flux was $2.3mL/min{\cdot}cm^2$ at $950^{\circ}C$ with $Po_2$ = 0.63 atm of oxygen partial pressure. The oxygen permeation in the condition of air with $CO_2$ (300 ppm) as feed stream decreased as much as only maximum 2.9% in comparison with air feed stream. It indicated $BaCo_{0.7}Fe_{0.22}Nb_{0.08}O_{3-{\delta}}$ membrane is more stable than another membrane for carbon dioxide.

• Proceedings of the Korean Society of Crop Science Conference
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• 2017.06a
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• pp.45-45
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• 2017

The Indian meal moth, Plodia interpunctella, is one of the most important pests of stored food in the food processing industry worldwide. To control the Indian meal moth, methyl bromide, phosphine, high carbon dioxide, sulfuryl fluoride and plant essential oil fumigation have been considered. However, these treatments have disadvantages. For example, depleting the ozone layer, showing resistance in insect, low control efficacy or need high cost for treatment. Chlorine dioxide ($ClO_2$) is strong disinfectant and insecticide. The gas caused a malfunction in enzymes. The oxidative stress induced by $ClO_2$ gas treatment damaged to a physiological system and all life stages of P. interpunctella. The gaseous $ClO_2$ is a convincing alternative to methyl bromide for controlling P. interpunctella. The gaseous $ClO_2$ was generated by a chlorine dioxide generator (PurgoFarm Co., Ltd., Hwasung, Korea). It generated highly pure $ClO_2$ gas and the gas blown out through a vent into a test chamber. Gas entry to the chamber was automatically controlled and monitored by a PortaSene II gas leak detector (Analytical Technology, Collegeville, PA, USA). The properly prepared eggs, larvae, pupae, and adults of P. interpunctella were used in this experiment. Data were analyzed using SAS 9.4. Percentage data were statistically analyzed after arcsine-root transformation. Analysis of variance was performed using general linear model, and means were separated by the least significant difference test at P < 0.05. Fumigation is an effective management technique for controlling all stages of P. interpunctella. We found that $ClO_2$ gas treatment directly effects on egg, larvae, pupae and adults of P. interpunctella. The gas treatment with proper concentration for over a day achieved 100 % mortality in all stages of P. interpunctella and short time treatment or low concentration gas treatment results showed that the egg hatchability, pupation rate, and adult emergency rate were lowered compare with untreated control. Also, abnormal pupae or adult rate were increased. Gaseous $ClO_2$ treatment induced insecticidal reactive oxygen species (ROS), and it resulted in fatal oxidative stress in P. interpunctella. Taken together, these results showed that exposure proper concentration and time of the gas control all stages of P. interpunctella by inducing fatal oxidative stress. Further studies will be required to apply the gas treatment under real-world condition and to understanding physiological reaction in P. interpunctella caused by oxidative stress.

• Journal of Bio-Environment Control
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• v.27 no.2
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• pp.111-116
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• 2018

This study were carried out to evaluate the efficiency of using burn-type $CO_2$ generators in greenhouse for cultivation 'Seolhyang' strawberry ($Fragaria{\times}ananassa\;Duch.$) during winter season. The concentration of $CO_2$ was 200 to $600{\mu}mol{\cdot}mol^{-1}$ in the control, and 800 to $1,100{\mu}mol{\cdot}mol^{-1}$ in using burn-type $CO_2$ generator between 6 and 11 hours. At other times, it was observed that at similar concentration in the control and using burn-type $CO_2$ generator. Measured greenhouse air temperature inside the of using burn-type $CO_2$ generator was $2{\sim}3^{\circ}C$ higher than the control at 6 ~ 10 am. There was no temperature difference between treatments after 11 o'clock. Plant height, leaf length, leaf width, root diameter, fresh weight, and dry weight were not different between treatments. The marketable yield (kg/10a) of using burn-type generator were 4,131 kg, which was 519 kg higher than the control. Therefore, the total fruit yields increased 17% compared to the control.

• Korean Chemical Engineering Research
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• v.50 no.2
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• pp.348-352
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• 2012

Amine volatility occurring on the $CO_2$ capture process may result in significant economic losses and environmental impact. In this study, using an volatility measurement apparatus, we measured a amine volatility of various amines including MEA(Monoethanolamine), MDEA(N-Methyldiethanolamine), Pz(Piperazine), AMP(2-Amino-2-methyl-1-propanol), 2-MP(2-Methylpiperazine), DGA(Diglycolamine). For the quantitative analysis of volatility, we analyzed the effects of temperature and $CO_2$ loading using an gas chromatography analysis. The result shows that the amine volatility was increased by increasing Henry's constant(MDEA$-CH_3$)(for AMP).

• Journal of the Korean Society for Marine Environment & Energy
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• v.11 no.3
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• pp.160-163
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• 2008

$CO_2$ ocean sequestration is being considered as a way to earn a frame of time to change other industrial life pattern to overcome the global warming crisis. The method is to dilute the captured $CO_2$ into ocean by ejecting the liquefied $CO_2$ through nozzles. The main issue of such method is the effectiveness and safety, and in both problems the rising speed of those LCO2 droplet is the key parameter. In this paper, the rising speed of LCO2 droplets is numerically studied including the effect of the surfactant which can be residing along the density interface of the droplets. A front tracking method with a simple surface tension model is developed and the rising speed of the droplets is carefully investigated with varying the various parameters. It is demonstrated that the variable surface tension can change the deformation of the droplet, the flow near the interface, and the rising speed.

• Journal of the Korean Society for Railway
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• v.10 no.6
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• pp.723-729
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• 2007

The Ministry of Environment established a guide line in December 2006, "Indoor Air Quality Management guidelines in Public Facilities." As the items of the guideline, $CO_2$ (Carbon dioxide) and PM10 (particulate matter) is shown to Level 1 and 2. Therefore trains and subways are included. There are a lot of tunnels by the lay of mountains on KTX (Korean Train Express) service. HVAC (Heating Ventilating and Air-conditioning)-pressurization equipment on KTX is various functioning flaps blocking outside pressure waves. At that time, the fresh air is blocked by flap operation and the air is circulated by return air. In this study, we measured the time series of $CO_2$ and PM10 concentrations in the KTX passenger cabin during the train service of Gyongbu line (Seoul-Busan) and Honan line (Yongsan-Mokpo) from July 2006. Also, analyzed the air quality by operation of KTX HVAC-pressurization equipment in tunnel passing point. As a result, PM10 concentration was totally lower than the regulation values. However, $CO_2$ was highly correlated with several tunnels, such as Oksan-Otan, Godeung-Hyudae and Gaechak-Iijik tunnel. but, the indoor air quality of KTX train have been proved satisfy the recommendation the Ministry of Environment guidelines.

• Membrane Journal
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• v.27 no.6
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• pp.499-505
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• 2017

The increasing number of natural disasters resulting from anthropogenic greenhouse gas emissions has prompted the development of a gas separation membrane. Carbon dioxide ($CO_2$) is the main cause of global warming. Organic polymeric membranes with inherent flexibility are good candidates for use in gas separation membranes and poly(dimethyl siloxane)(PDMS) specifically is a promising material due to its inherently high $CO_2$ diffusivity. In addition, poly(vinyl pyrrolidine)(PVP) is a polymer with high $CO_2$ solubility that could be incorporated into a gas separation membrane. In this study, poly(dimethyl siloxane)-poly(vinyl pyrrolidine)(PDMS-PVP) comb copolymers with different compositions were synthesized under mild conditions via a simple one step free radical polymerization. The copolymerization of PDMS and PVP was characterized by FTIR. The morphology and thermal behavior of the produced polymers were characterized by transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). Composite membranes composed of PDMS-PVP on a microporous polysulfone substrate layer were prepared and their $CO_2$ separation properties were subsequently studied. The $CO_2$ permeance and $CO_2/N_2$ selectivity through the PDMS-PVP composite membrane reached 140.6 GPU and 12.0, respectively.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.9
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• pp.196-205
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• 2016

The exhaust gas discharged by cars not only threatens the health of the human body, but also contributes to global warming, due to the resulting increase in the concentrations of ozone, fine dust and carbon dioxide. Therefore, the government has steadily implemented careful inspection systems for exhaust emissions, in order to efficiently regulate the exhaust gas of cars. Studies on reducing the exhaust emissions of automobiles have been conducted in various fields, including ones designed to reduce the generation of HC, NOx, and $CO_2$ in the exhaust emission of vehicles. However, there have been insufficient studies on the reduction of the exhaust emission for old diesel vehicles. To develop careful inspection systems for the exhaust emissions of old diesel vehicles, studies on the reduction of the exhaust emissions and improvement of power are necessary by cleaning the carbon sediment in both the intake manifold and injector. Therefore, in this study, we analyzed and compared the amounts of gas emitted when simultaneously cleaning or not cleaning the intake manifold and injector of diesel automobiles with mileages over 80,000 km and operating periods over 5 years. The experimental results showed that in the case where the intake manifold and injector were simultaneously cleaned, there was a decline of 75.2% in the gas emission compared to the cases where only the manifold or injector is cleaned. Also, it was found that simultaneously cleansing the intake manifold and injector enabled the exhaust standard to be satisfied for less than 30% within 8.5 sec.

• The Journal of the Petrological Society of Korea
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• v.2 no.2
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• pp.95-103
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• 1993

The geology of the talc ore deposits in the Chungju area consists of the Kyemyeongsan Formation, the Munjuri Formation, the Daehyangsan Quartzite, the Hyangsanni Dolomite, and the basic rocks of the Ogcheon belt. The talc ore occurs in the Hyangsanni Dolomite near the Daehyangsan Quartzite The mineral assemblages in the Hyangsanni Dolomite are \circled1calcite-tremolite-talc-quartz, \circled2calcite-talc-quartz, \circled3tremolite-calcite-dolomite, and \circled4calcite-dolomite-phlogopite-chlorite. Talc has almost the ideal composition($X_{Mg}$=Mg/(Fe+Mg)=0.98). Talc was formed in siliceous dolomite by the medium-pressure type regional metamorphism. The evidences for contact metamorphism and/or hydrothermal reaction are not clear. The metamorphic grade of the Hyangsanni Dolomite and its adjacent pelitic or basic rocks near the deposits corresponds to epidote-amphibolite facies or greenschist facies based on the, mineral assemblages of \circled1hornblendebiotite-muscovite-epidote-quartz \circled2biotite-chlorite-quartz, and \circled3hornblende-actinolite-plagioclasequartz. The formation of the talc deposits were caused by the following reactions due to greenschist facies metamorphism of siliceous-dolomitic rocks in the Hyansanni Dolomite. (I) 3 dolomite+4 quartz+$H_2O$= talc+ 3 calcite +3 $CO_2$; (11) 3 tremolite+ 2 $H_2O$+ 6 $CO_2$= 5 talc+ 6 calcite + 4 quartz. The minimum temperature of the talc-tremolite-quartz assemblage is about $434^{\circ}C$ from calcite thermometry and the carbon dioxide mole fraction in metamorphic fulid($X_{$CO_2$}$) is about 0.1 at assumed pressure, 3 kbar.

• Clean Technology
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• v.12 no.2
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• pp.87-94
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• 2006

The reduction of $SO_2$ to elemental sulfur by CO over a series of iron niobate with nominal Nb/Fe atomic ratios of 1/0, 10/1, 5/1, 1/1, 1/5, 1/10 and 0/1 was studied with a flow fixed-bed reactor. Strong synergistic phenomena in catalytic activity and selectivity were observed for the iron niobate catalysts, and the best catalytic performance was observed for the catalyst with Fe/Nb atomic ratio of 1/1. The active phase of the activated iron niobate catalysts was identified to be $FeS_2$ using XRD and XPS. Selective reduction of $SO_2$ by CO was followed by the COS intermediate mechanism.