• Title/Summary/Keyword: Carbon dioxide (CO2)

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The Study of KOGAS DME Process in Small and Medium Sized Gas Field Containing $CO_2$ ($CO_2$가 함유된 중소규모 가스전을 위한 KOGAS DME Process 연구)

  • Mo, Yong-Gi;Cho, Won-Jun;Song, Taek-Yong;Baek, Young-Soon
    • Journal of the Korean Institute of Gas
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    • v.14 no.4
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    • pp.51-55
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    • 2010
  • The global activities to reduce the $CO_2$ emission as a greenhouse gas have been various efforts. Under this circumstance, small and medium sized gas field containing $CO_2$ to develop as LNG is not economic feasibility. Particularly, for the separation of $CO_2$ in gas field, separation facilities should be installed to add. This is and increase in plant construction cost and separated $CO_2$ emission into the atmosphere is not the result of greenhouse gas reduction. When the uneconomic gas field apply the KOGAS DME process, the gas field containing $CO_2$ can be increase economic feasibility because of natural gas and $CO_2$ can be use to resource gas. The Tri-reformer produced syngas as H2 and CO in KOGAS DME process and the resource gases are natural gas, steam, oxygen and $CO_2$. The $CO_2$ is used as raw material gases from recover $CO_2$ in DME process. In this study, we investigated range of application of $CO_2$ in gas field.

A Numerical Study on the Extinguishing Effects of CO2 in Counterflow Diffusion Flames with the Concept of Local Application System (국소방출방식 개념의 대향류 확산화염에서 CO2 소화효과에 관한 수치해석 연구)

  • Mun, Sun-Yeo;Park, Chung-Hwa;Hwang, Cheol-Hong;Oh, Chang-Bo
    • Fire Science and Engineering
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    • v.26 no.4
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    • pp.55-62
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    • 2012
  • The suppression mechanisms of carbon dioxide ($CO_2$) as a representative fire suppression agent were revisited using a counterflow diffusion flame which could be applied the concept of a local application system. To end this, the low strain rate $CH_4$/air counterflow diffusions with $CO_2$ addition in either fuel or oxidizer stream were examined numerically using detailed-kinetic chemistry. Radiative heat loss due to radiating gas species including $CO_2$ added was considered by the optically thin model (OTM). As a result, the critical $CO_2$ volume fractions in the oxidizer stream required to extinguish the flame were in good agreement with the experimental data reported in the literature, while somewhat under-prediction was observed with $CO_2$ added in the fuel stream. The surrogate agents were adopted to estimate the quantitative contribution with changing in global strain rate ($a_g$) on the flame extinguishment among pure dilution effect, thermal effects including radiation heat loss and chemical effect due to the $CO_2$ fire suppression agent.

Effect of Alkanolamine Additives on CO2 Absorption Rate and Salt Formation of K2CO3 Aqueous Solution (알카놀아민 첨가제가 K2CO3 수용액의 이산화탄소 흡수속도와 염 석출에 미치는 영향)

  • Moon, Cheol-Ho;Jung, Taesung;Cho, Chang Sin;Kim, Jong-Nam;Rhee, Young Woo
    • Clean Technology
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    • v.20 no.2
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    • pp.146-153
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    • 2014
  • In this study, the effect of alkanolamine additives, 2-amino-2-methyl-1-propanol (AMP) and 2-amino-2-methyl-1,3-propanediol (AMPD) on $CO_2$ absorption rate of $K_2CO_3$ solution and the formation of $KHCO_3$ crystals was investigated. The normalized $CO_2$ flux and the equilibrium $CO_2$ partial pressure were measured for 5 wt% additives and 30 wt% $K_2CO_3$ mixtures using a wetted-wall column unit at $40^{\circ}C$ and $60^{\circ}C$. Both additives showed the increased $CO_2$ absorption rate and lowered the equilibrium $CO_2$ partial pressure acting as promoters. Besides, AMPD which has two hydroxyl groups enhanced the formation of $KHCO_3$ solid product separated from the $CO_2$-rich solution from the results of batch cooling crystallization experiments.

Analysis of research trends in methane emissions from rice paddies in Korea

  • Choi, Eun-Jung;Lee, Jae-Han;Jeong, Hyun-Cheol;Kim, Su-Hun;Lim, Ji-Sun;Lee, Dong-Kyu;Oh, Taek-Keun
    • Korean Journal of Agricultural Science
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    • v.44 no.4
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    • pp.463-476
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    • 2017
  • Climate change is considered as the greatest threat to our future and descendants. The Korean government has set a target for 2030 to reduce emission of greenhouse gases (GHGs) by 37% from the business-as-usual levels which are projected to reach 851 million metric tons of $CO_2eq$ (Carbon dioxide equivalent). In Korea, GHGs emission from agriculture account for almost 3.1% of the total of anthropogenic GHGs. The GHGs emitted from agricultural land are largely classified into three types: carbon dioxide ($CO_2$), methane ($CH_4$), and nitrous oxide ($N_2O$). In Korea, rice paddies are one of the largest agricultural $CH_4$ sources. In order to analyze domestic research trends related to $CH_4$ emission from rice paddies, 93 academic publications including peer reviewed journals, books, working papers, reports, etc., published from 1995 to September 2017, were critically reviewed. The results were classified according to the research purposes. $CH_4$ characteristics and assessment were found to account for approximately 65.9% of the research trends, development of $CH_4$ emission factors for 9.5%, $CH_4$ emission reduction technology for 14.8%, and $CH_4$ emission modeling for 6.3%, etc. A number of research related to $CH_4$ emission characteristics and assessment have been studied in recent years, whereas further study on $CH_4$ emission factors are required to determine an accurate country-specific GHG emission from rice paddies. Future research should be directed toward both studies for reducing the release of $CH_4$ from rice paddies to the atmosphere and the understanding of the major controlling factors affecting $CH_4$ emission.

Microscopic Influence of Temperature on Carbonation for Marine Concrete Structure (항만콘크리트 구조물의 탄산화에 미치는 온도의 미세구조적 영향)

  • Han, Sang-Hun
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.22 no.4
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    • pp.272-278
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    • 2010
  • Some recent researches reported that high temperature rising decreases the carbonation depth of concrete, which is contrary to the previous research results. Carbonation has been known as a reaction between calcium hydroxide and carbon dioxide. But a few researches showed that the other cement hydrates as well as calcium hydroxide react with carbon dioxide. This paper investigates the influence of temperature on carbonation and the variation of $Ca(OH)_2$ and $CaCO_3$ by carbonation. In order to estimate the carbonation depth and the quantities of reactant and product of carbonation reaction, phenolphthalein testing and thermagravimetric analyzer test were conducted. The measurement of carbonation depth with temperature showed that the temperature increase from $20^{\circ}C$ to $30^{\circ}C$C in carbonation environment makes the carbonation depth larger, but the increase from $30^{\circ}C$ to $40^{\circ}C$ has a small influence on the carbonation depth. Comparing calcium hydroxide and calcium carbonate with temperature, the quantity of $CaCO_3$ of specimen carbonated at $30^{\circ}C$ is greater than that of specimen carbonated at $40^{\circ}C$ and the quantity of $Ca(OH)_2$ of specimen carbonated at $30^{\circ}C$ is similar to that of specimen carbonated at $40^{\circ}C$. This observation shows that there is the optimum temperature increasing carbonation depth and the optimum temperature is close to $30^{\circ}C$.

Effects of Various Ventilation Systems on the Carbon Dioxide Concentration and Fruiting Body Formation of King Oyster Mushroom (Pleurotus eryngii) Grown in Culture Bottles (새송이버섯 병재배에서 환기방법이 이산화탄소 농도 및 자실체형성에 미치는 영향)

  • Lee, Hyun-Uk;Ahn, Mi-Jeong;Lee, Shin-Woo;Lee, Cheol-Ho
    • Journal of Life Science
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    • v.17 no.1 s.81
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    • pp.82-90
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    • 2007
  • In an attempt to establish the appropriate ventilation device for the bottle culture of king oyster mushroom (Pleurotus eryngii), we investigated carbon dioxide concentration and fruiting body formation according to the various ventilation systems within the mushroom house. In addition to, the efficiency of air circulation and growth rate as well as the appearance of physiologically abnormal phenotypes during their growth stage were also evaluated. four different ventilation devices, parallel-pressure type, positive-pressure type, negative-pressure type, and positive- and negative-pressure type were applied in this study. The positive-and negative-pressure type showed the highest efficiency of air circulation as $CO_2$ concentration was 800 ppm and the level of air current was relatively low compared to the other types (the $CO_2$ concentration of parallel-pressure type was 1,400 ppm). Moreover, the stipe length, the cap diameter, yield, and general quality grown in positive- and negative type ventilation device were also better than in the other three devices though it took slightly longer period for harvesting (18.4 days) than the others (17.6, 17.9 and 18.3 days). The appearance of physiologically abnormal phenotypes such as fruiting body lump, soft rot, and brown rot were significantly decreased in positive-and negative type compared to other types, while the appearance rates were not much different for other symptoms of bacterial ooze, stipe limb and stipe bumpy. In summary, we propose that the optimal ventilation system for the bottle culture of king oyster mushroom is positive- and negative type, and this device is expected to increase the total quality as well as yield all year around.

The Study of Indoor Air Quality at Schools in Chung-Nam Area (충남 지역 학교의 실내공기질에 관한 연구)

  • Cho, Tae-Jin;Choi, Han-Seam;Jeon, Young-Taek;Lee, Che-Won;Lee, Jong-Dae;Jou, Hye-Mee;Son, Bu-Soon
    • Journal of Environmental Science International
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    • v.17 no.5
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    • pp.501-507
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    • 2008
  • The concentrations of HCHO(formaldehyde), $PM_{10}$(particulate matter), $CO_2$(carbon dioxide) and TBC(total bacteria counter) distribution in schools(Chung-Nam Area) were examined, and the results were compared with the recommended criterion of the administration law of indoor air. The subjects were an elementary school, a middle school and a high school in Chung-Nam area, and the concentration of TBC was examined by Single Stage Air Cascade Sampler, which applied the inertia collision catching method of 28.29L/min(flux) during 5 months from March, 2007 to July, 2007. The instrument(LD-3B, SIBATA Company)was used to examine $PM_{10}$, by a light scattering method and a light transmission method. The instrument(Airboxx(KD Engineering) was used to examine $CO_2$. The instrument(Z300XP(Environmental sensor)was used to examine HCHO. The result indicated that the $PM_{10}$ average concentrations of the surveyed classrooms were $49{\mu}g/m^3$ in Spring and $59{\mu}g/m^3$ in Summer. The $CO_2$ average concentration of the surveyed schools were 576 ppm in the classroom and 527 ppm in the stateroom. The average concentration of TBC were $729CFU/m^3$ in an elementary school, $401CFU/m^3$ in a middle school, $381CFU/m^3$ in a high school. The HCHO average concentration of the surveyed schools were 0.03 ppm in the classroom, 0.02 ppm in the stateroom.

Performance Evaluation of a $CO_2$ Heat Pump System for Fuel Cell Vehicles (연료전지 자동차용 이산화탄소 열펌프 시스템의 성능평가)

  • Kim, Sung-Chul;Park, Jong-Chul;Kim, Min-Soo;Won, Jong-Phil
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.1
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    • pp.37-44
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    • 2008
  • The global warming potential (GWP) of $CO_2$ refrigerant is 1/1300 times lower than that of R134a. Furthermore, the size and weight of the automotive heat pump system can decrease because $CO_2$ operates at high pressure with significantly higher discharge temperature and larger temperature change. The presented $CO_2$ heat pump system was designed for both cooling and heating in fuel cell vehicles. In this study, the performance characteristics of the heat pump system were analyzed for heating, and results for performance were provided for operating conditions when using recovered heat from the stack coolant. The performance of the heat pump system with heater core was compared with that of the conventional heating system with heater core and that of the heat pump system without heater core, and thus the heat pump system with heater core showed the best performance among the selected heating systems. On the other hand, the heating performance of two different types of coolant/air heat pump systems with heater core was compared each other at various coolant inlet temperatures. Furthermore, to use exhausted thermal energy through the radiator, experiments were carried out by changing the arrangement of a radiator and an outdoor evaporator, and quantified the heating effectiveness.

Influence of Discharge Voltage-Current Characteristics on CO2 Reforming of Methane using an Elongated Arc Reactor (신장 아크 반응기를 이용한 메탄 CO2 개질반응에서 방전 전압-전류특성의 영향)

  • Kim, Kwan-Tae;Hwang, Na-Kyung;Lee, Jae-Ok;Lee, Dae-Hoon;Hur, Min;Song, Young-Hoon
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.6
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    • pp.683-689
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    • 2010
  • Reforming of methane with carbon dioxide has been carried out using a bipolar pulse driven elongated arc reactor operating at atmospheric pressure and non-equilibrium regime. This plasma reactor is driven by two kinds of power supply, characterized by different voltage-current characteristics under the same operating power and frequency. Varying the $CO_2/CH_4$ ratio and the discharge power, the conversion rate, yield, and reforming efficiency for the two power supplies are investigated in conjunction with the static and dynamic behaviors of voltage and current. It is found that not only the values of voltage and current but also their shapes give an influence on the reforming performances. Finally, a better electrical operation regime for the efficient plasma reforming is proposed based on the relationship between the voltage-current characteristics and the reforming performance.

A dynamic analysis on minute particles' detachment mechanism in a cryogenic $CO_2$ cleaning process (극저온 $CO_2$ 세정과정 시 미세오염물의 탈착 메커니즘 연구)

  • Seok, Jong-Won;Lee, Seong-Hoon;Kim, Pil-Kee;Lee, Ju-Hong
    • Journal of the Semiconductor & Display Technology
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    • v.7 no.4
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    • pp.29-33
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    • 2008
  • Rapid increase of integrity for recent semiconductor industry highly demands the development of removal technology of contaminated particles in the scale of a few microns or even smaller. It is known that the surface cleaning technology using $CO_2$ snow has its own merits of high efficiency. However, the detailed removal mechanism of particles using this technology is not yet fully understood due to the lack of sophisticated research endeavors. The detachment mechanism of particles from the substrates is known to be belonged in four types; rebounding, sliding, rolling and lifting. In this study, a modeling effort is performed to explain the detachment mechanism of a contaminant particle due to the rebounding caused by the vertical collision of the $CO_2$ snow. The Hertz and Johnson-Kendall-Roberts(JKR) theories are employed to describe the contact, adhesion and deformation mechanisms of the particles on a substrate. Numerical simulations are followed for several representative cases, which provide the perspective views on the dynamic characteristics of the particles as functions of the material properties and the initial inter-particle collision velocity.

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