• Title/Summary/Keyword: Carbon dioxide (CO2)

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Quality Changes in Delaware Grapes Treated with Chitosan during Storage (키토산 처리된 델라웨어 포도의 저장 중 품질 변화)

  • Yum, Su Jin;Kang, Ji Hoon;Jung, Seung Hun;Song, Kyung Bin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.44 no.5
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    • pp.739-745
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    • 2015
  • To maintain quality of Delaware grapes during storage, grape samples were treated with 0.1% chitosan dissolved in 0.5% acetic acid, packaged with low density polyethylene film, and stored at 4 or $20^{\circ}C$ for 12 days. Chitosan treatment reduced initial populations of yeast and molds in grapes by 1.86 log CFU/g compared to that of the control. During storage, oxygen contents in packages of samples decreased, whereas carbon dioxide contents increased. In addition, regardless of storage temperature, changes in oxygen and carbon dioxide concentrations of grapes treated with chitosan were lower than those of the control. Hardness of samples decreased, and Hunter L, a, and b values were not significantly different among treatments. Regarding pH and total soluble content, grapes stored at $4^{\circ}C$ maintained pH and had greater total soluble content than those stored at $20^{\circ}C$. These results suggest that chitosan treatment and low temperature storage can be useful for maintaining microbiological safety and quality of Delaware grapes during storage.

Effects of Production of Ever-bearing Strawberries Using Cool Air from Mushroom Cultivation House (버섯재배시설의 냉공기 이용이 사계성딸기 생산성에 미치는 영향)

  • Jeoung, Yun-Kyeoung;Park, Ju-Hyen;Ha, Tae Moon;Lee, Young-Suk;Seo, Myeong-Hoon;Kim, In-Chul
    • Journal of Bio-Environment Control
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    • v.28 no.1
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    • pp.28-37
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    • 2019
  • We designed a system that can automatically collect, convey, and control cool air of $15^{\circ}C-20^{\circ}C$ containing carbon dioxide from a mushroom cultivation house to a strawberry plastic house. We recorded the temperature at various positions from July to August 2017. The average temperature of the green house during day and at night was maintained at $33^{\circ}C$ and $26^{\circ}C$, respectively. In the moveable three-tier cylindrical bed, the average temperature around root was maintained at $26^{\circ}C$ and $21^{\circ}C$ during day and at night, respectively. On the high-bench in the green house, the temperature was maintained at $32^{\circ}C$ and $30^{\circ}C$ during day and at night, respectively. The carbon dioxide concentration was maintained around 800-1,600 ppm in the mushroom cultivation system and 400-800 ppm in the strawberry plastic house. The growth characteristics of the strawberry treated with moveable three-tier cylindrical bed were significantly different from those of the untreated high-bench bed. In addition, during the summer season, moveable three-tier cylindrical bed showed more tendency to increase in normal fruit number (NFN) and to decrease in defective fruit number (DFN) compare to the high-bench bed. Therefore, the moveable three-tier cylindrical bed showed a tendency to be more than 2 times higher yields than that of the high-bench bed. It was confirmed that ever-bearing strawberry cultivars could be cultivated in green house due to the cool air supply from the mushroom cultivation system in the summer season.

$\textrm{CO}_2$ Gas Sensor Based on $\textrm{Li}_2\textrm{ZrO}_3$ System ($\textrm{Li}_2\textrm{ZrO}_3$ 계를 이용한 $\textrm{CO}_2$ 가스 센서)

  • Park, Jin-Seong;Kim, Si-Uk;Lee, Eun-Gu;Kim, Jae-Yeol;Lee, Hyeon-Gyu
    • Korean Journal of Materials Research
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    • v.9 no.9
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    • pp.896-899
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    • 1999
  • A carbon dioxide gas sensor was studied as a function of temperature and $CO_2$concentration in the Li$_2$ZrO$_3$ system. Lithium zirconate(Li$_2$ZrO$_3$) was synthesized by the heat-treatment of zirconia(ZrO$_2$)and Lithium carbonate(Li$_2$CO$_3$). The specimens were prepared both as bulk disk, 10mm in diameter and 1.0mm thickness, and thick films on an alumina substrate. Lithium zirconate readily responded to $CO_2$concentration from 0.1% to 100% in the range of 45$0^{\circ}C$ to $650^{\circ}C$. The sensitivity to $CO_2$ was dependent on the measuring temperature. Lithium zirconate(Li$_2$ZrO$_3$) decomposes into Li$_2$CO$_3$ and ZrO$_2$after the reaction with $CO_2$in the range of 45$0^{\circ}C$ to $650^{\circ}C$. Li$_2$CO$_3$ changes into Li$_2$O and $CO_2$ above $650^{\circ}C$. The material showed difficulty with reversibility and recovery. The optimum temperature for the highest sensitivity is around 55$0^{\circ}C$.

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Characteristics of Aqueous Ammonia-CO2 reaction at Regeneration Condition of High Temperature and Pressure (고압고온 재생조건에서의 암모니아수-CO2 반응특성)

  • Kim, Yun Hee;Yi, Kwang Bok;Park, Sung Youl;Ko, Chang Hyun;Park, Jong-Ho;Beum, Hee Tae;Han, Myungwan;Kim, Jong-Nam
    • Korean Chemical Engineering Research
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    • v.48 no.2
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    • pp.253-258
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    • 2010
  • In the field of the $CO_2$ absorption process using aqueous ammonia, the effects of regeneration pressure and temperature on $CO_2$ absorption performances of the aqueous ammonia were investigated. The absorbents were prepared by dissolving ammonium carbonate solid in water to grant the resulted solution 0.5 $CO_2$ loading ($mol\;CO_2/mol\;NH_3$) and various ammonia concentration (14, 20, 26 and 32 wt%). As-prepared absorbents were regenerated at high pressure and temperature (over $120^{\circ}C$ and 6 bar) before the absorption test. The absorption test was carried out by injecting the simulated gas that contains 12 vol% of $CO_2$ into a bubbling reactor. The introduction of 26 wt% of the ammonia concentration for $CO_2$ absorption test resulted in the higher absorption capacities than other experimental conditions. In particular, when the absorbents with 26 wt% of the ammonia were regenerated at $150^{\circ}C$ and 14 bar, the highest absorption capacity, $45ml\;CO_2/g$, was obtained. According to the analysis of absorbents using acid-base titration, the ammonia loss during the regeneration of the absorbents with a fixed ammonia concentration decreased as the regeneration pressure increased, while it increased as the regeneration temperature increased. In the condition of fixed regeneration pressure and temperature, as expected, the ammonia loss increased as the ammonia concentration increased. The measured $CO_2$ loadings and ammonia concentrations of absorbents were compared to the values calculated by Electrolyte NRTL model in Aspen Plus.

Biomass Production Potential of Chlorella vulgaris Under Different CO2 Concentrations and Light Intensities

  • Lee, Chang-Min;Kim, Mi-Jeong;Sanjay, Kumar;Kwag, Jung-Hoon;Ra, Chang-Six
    • Journal of Animal Science and Technology
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    • v.53 no.3
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    • pp.261-268
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    • 2011
  • The increasing demand of the crops (soybean and corn) for biofuel production has increased the focus of the animal nutritionists to look for alternative feeds, which are economic and environmental friendly. To identify microalgae as suitable candidate as an alternative feed, growth response of Chlorella vulgaris was studied under varying concentrations of carbon dioxide (0.07, 1.4, 3.0 and 5.0%) and photon densities (39.19, 72.97, 105.41, 116.22, 135.14, $175.68\;{\mu}mol/m^2/s$) by employing a photo-bioreactor. Swine wastewater was also investigated as nutritional source to economize the biomass production. Results showed that the higher biomass production was found to be at 3.0% $CO_2$ compared to other $CO_2$ concentrations. However, no difference in biomass production was found at $105.41\;{\mu}mol/m^2/s$ and above photon densities with 12 h of photoperiodicity. It was observed that C. vulgaris could easily grow in 200 times diluted swine wastewater and growth was found to be similar with that of artificial medium. Provided the conducive conditions for optimal growth, it has also the potentiality of depleting ammonia nitrogen ($NH_4$-N) and orthophosphate ($PO_4^{3-}$-P) completely from the wastewater after 3~4 days of cultivation. Thus, growing C. vulgaris would not only solve the problem of animal feed, but also help in biological $CO_2$ mitigation and wastewater treatment.

A study on Measurement and Improvement of Indoor Air Quality in Dental Clinic

  • Choi, Mi-Suk;Ji, Dong-Ha
    • Journal of the Korea Society of Computer and Information
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    • v.23 no.11
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    • pp.143-149
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    • 2018
  • The purpose of this study is to propose a management method to maintain the pleasant indoor air quality of the dental clinic by measuring and analyzing the indoor air quality of the dental clinic. The measurement was conducted in two rooms, a lobby where many residents stay in the reception room for waiting for medical treatment, and a VIP room where treatment activities are mainly performed. Measurement items are Temperature, Humidity, $CO_2$, CO, $NO_2$, $CH_2O$, VOC, $PM_{10}$ and measurement were taken on April 27, 2018. As a result of analyzing the temperature and humidity of the dental clinic, it was analyzed that the average indoor temperature was maintained at $25^{\circ}C$ and the humidity was kept at around 50%, maintaining proper indoor temperature and humidity environment. $CO_2$ was 855ppm in the VIP Room, which satisfied the maintenance standard. In the case of the lobby, it was analyzed to be 1,160ppm, which exceeded the maintenance standard and it is judged that the carbon dioxide generated by the respiration of the people staying in the lobby is the main reason. The mean concentration of formaldehyde in the VIP room was analyzed as $436{\mu}g/m^3$, exceeding the maintenance standard, and $2,100{\mu}g/m^3$ for the VOC exceeded the recommended standard. It was analyzed that the concentration was relatively higher due to the use of disinfectant and other drugs. The mean concentration of PM-10 in the lobby was analyzed as $65{\mu}g/m^3$ and it was analyzed that it satisfied the maintenance standard. To maintain a pleasant indoor air quality in a dental clinic it is necessary to minimize the effects of formaldehyde, VOC, $CO_2$ in the VIP rooms and lobby. For this purpose, the entire ventilation system and air purification system of the dental clinic should be installed. In case of the VIP room, local exhaust ventilation should be installed and workers should wear personal protective equipment.

A Study on the CO2 Removal Efficiency with Aqueous MEA and Blended Solutions in a Vortex Tube Type Absorber (Vortex Tube 형 흡수장치에서 MEA와 혼합흡수용액을 이용한 CO2 제거 효율 고찰)

  • Ryu, Woo-Jung;Han, Keun-Hee;Choi, Won-Kil;Lee, Jong-Sub;Park, So-Jin
    • Korean Chemical Engineering Research
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    • v.47 no.6
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    • pp.795-800
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    • 2009
  • In this study, the $CO_2$ removal characteristics of the Vortex tube type absorbtion apparatus were investigated to enhance the compactness of $CO_2$ absorption process and to reduce the amount of absorbing solution of the $CO_2$ separation process. The Vortex tube with the diameter of 17 mm and the length of 250mm was introduced in the experimental apparatus to treat $20Nm^3/hr$ of $CO_2$ containing flue gas. The flue gases for experiments containing 11~13 vol% of $CO_2$ were supplied from the coal-firing CFBC power plant with 12 ton/hr of steam producing capacity. The mixed solutions of 20 wt% of MEA as base solution with the adding solutions like HMDA, AMP and KOH were used as absorbents. The experiments were executed under the various conditions like the absorbing solution concentrations in the range of 20 to 50 wt%, the flow rate of $CO_2$ containing flue gases in the range of 6 to $15Nm^3/hr$ and the flow rate of absorbing solution in the range of 1.0 to 3.0 l/min. As a results, the $CO_2$ removal efficiency of mixed absorbent of 20 wt% of MEA with HMDA was remarkable. From this study, we concluded that the efficient separation of $CO_2$ from flue gases using the features of the Vortex tube type absorbing unit for gas/liquid contact and the separation of gas/liquid be possible. But more works are needed to increase the $CO_2$ removal efficiency of Vortex tube process.

Carbonation Mechanism of Hydrated Cement Paste by Supercritical Carbon Dioxide (초임계 이산화탄소에 의한 시멘트 페이스트의 중성화 반응 메커니즘)

  • Park, Jeong-Won;Kim, Ji-Hyun;Lee, Min-Hee;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.5
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    • pp.403-412
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    • 2018
  • Recently, needs for utilization of recycled aggregate have been increasing. However, its utilization has been limited due to its high alkalinity, which mostly came from the unremoved cement paste particles that were attached at the surface of recycled aggregate. Various efforts has been made to reduce its alkalinity by using $CO_2$, but currently available methods that uses $CO_2$ generate the problem with pH recovery. Considering the fact that supercritical $CO_2$ ($scCO_2$) can provide more rapid carbonation of cement paste than by normal $CO_2$, $scCO_2$ was utilized in this work. The reaction between $scCO_2$ and hydrated cement paste has been systematically evaluated. According to the results, it was found that powder type showed higher carbonation compared to that of cube specimens. It seems the carbonation by $scCO_2$ has occurred only at the surface of the specimen, and therefore still showed some amount of $Ca(OH)_2$ calcium aluminates after reaction with $scCO_2$. With powder type specimen, all $Ca(OH)_2$ was converted into $CaCO_3$. Moreover, additional calcium that came from both calcium aluminate hydrates and calcium silicate hydrates reacted with $scCO_2$ to form $CaCO_3$. After carbonation with $scCO_2$, the powder type specimen did not show pH recovery, but cube specimens did show due to the presence of portlandite.

Analysis of Patent Trends on the CCUS Technologies (특허 정보 분석을 통한 CCUS 연구개발 동향 분석)

  • Kim, Jung-min;Kim, Seong-Yong;Bae, Junhee;Shinn, Young-Jae;Ahn, Eunyoung;Lee, Jae-Wook
    • Economic and Environmental Geology
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    • v.53 no.4
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    • pp.491-504
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    • 2020
  • Given the continued climate change and global warming, various technologies for greenhouse gas reduction were discussed worldwide as all 195 countries participated in the Paris Agreement on the reduction of greenhouse gases. The agreement was adopted at the 21st Conference of Parties to the UNFCCC (COP21), which was held in Paris, France, in December 2015, and it revealed that reducing CO2 is the most efficient method of greenhouse gas reduction. Accordingly, carbon capture/utilization/storage (CCUS) technology has been noted as a means of making practical contributions to CO2 reduction, and research and development (R&D) activities in many countries are active in the field of CCUS technology. Therefore, this study aims to provide a basis for CCUS R&D and strategic support measures by analyzing patent trends in technologies related to CCUS. The patent analysis collected a total of 10,137 patents in the United States, Korea, Japan, Europe, and China; the number of patents in the United States was the highest according to patent analysis by country. According to an analysis by technology, capture-related technology was high at 60%, but given the recent increase in technology related to utilization, technology demonstration, R&D, and policy support should be continued.

Experimental Study on the Geochemical and Mineralogical Alterations in a Supercritical CO2-Groundwater-Zeolite Sample Reaction System (초임계 이산화탄소-지하수-제올라이트 시료 반응계에서의 지화학적 및 광물학적 변화에 관한 실험적 연구)

  • Park, Eundoo;Wang, Sookyun;Lee, Minhee
    • Economic and Environmental Geology
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    • v.47 no.4
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    • pp.421-430
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    • 2014
  • In this study, a series of autoclave experiments were conducted in order to investigate the geochemical and mineralogical effects of carbon dioxide on deep subsurface environments. High pressure and temperature conditions of $50^{\circ}C$ and 100 bar, which are representative environments for geological $CO_2$ sequestration, were created in stainless-steel autoclaves for simulating the interactions in the $scCO_2$-groundwater-mineral reaction system. Zeolite, a widespread mineral in Pohang Basin where many researches have been focused as a candidate for geological $CO_2$ sequestration, and groundwater sampled from an 800 m depth aquifer were applied in the experiments. Geochemical and mineralogical alterations after 30 days of $scCO_2$-groundwater-zeolite sample reactions were quantitatively examined by XRD, XRF, and ICP-OES investigations. The results suggested that dissolution of zeolite sample was enhanced under the acidic condition induced by dissolution of $scCO_2$. As the cation concentrations released from zeolite sample increase, $H^+$ in groundwater was consumed and pH increases up to 10.35 after 10 days of reaction. While cation concentrations showed increasing trends in groundwater due to dissolution of the zeolite sample, Si concentrations decreased due to precipitation of amorphous silicate, and Ca concentrations decreased due to cation exchange and re-precipitation of calcite. Through the reaction experiments, it was observed that introduction of $CO_2$ could make alterations in dissolution characteristics of minerals, chemical compositions and properties of groundwater, and mineral compositions of aquifer materials. Results also showed that geochemical reactions such as cation exchange or dissolution/precipitation of minerals could play an important role to affect physical and chemical characteristics of geologic formations and groundwater.