• KSBB Journal
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• 제16권3호
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• pp.233-236
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• 2001

Because of casehardenign effect of amorphous paclitaxel, residual solvents, methylene chloride and emthanol could not be reduced to the maximum value allowed, 600 ppm and 3,000 ppm, in accord with the guidelines issued by the International Conference on Harmonization (ICH, 1997), using rotary evaporation and successive drying in a vacuum oven. However, methylene chloride and methanol were reduced to 486 ppm and 403 ppm, respectively using supercritical $CO_2$ on purified paclitaxel. The optimum pressure and operating time were 80 bar and 30 min at fixed operating temperature ($40^{circ}C$). This approach serves as a novel application of supercritical fluid extraction to remove residual solvents from active pharmaceutical ingredients.

• Journal of Environmental Science International
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• 제29권6호
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• pp.605-612
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• 2020

To improve the initial strength and stability of lightweight-foamed concrete, which shows suitable sound absorption and insulation characteristics, the effect of CO₂-reduced cement on the properties of the concrete was investigated. Various mixing ratios were applied by substituting a certain amount of slag and Calcium Sulfo Aluminate (CSA) in CO₂-reduced Ordinary Portland Cement (OPC) and the physical properties of the samples were examined using the Korean Standard. The kiln temperatures of the CSA were 100-200℃ ; these values are lower than those of OPC and can lead to energy saving. In addition, the low limestone content reduces greenhouse gas emissions by 20 %. Adding a small amount of CSA in OPC content activates Ca-Al-H₂-based hydrates, and the initial compressive strength of the concrete is improved. As the CSA content increased, the thermal conductivity of the concrete decreased by up to 8% compared to plain concrete, thus indicating an improvement in its insulation. Therefore, the settlement stability was improved as the addition of CSA shortened the setting time.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 추계학술대회 초록집
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• pp.54.1-54.1
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• 2011

The conventional energy-production system by burning fossil fuels releases many pollutants and carbon dioxide($CO_2$) to the environment. Therefore, many countries pay attention to new and renewable energy and invest in the development of these new technologies for the future energy security. One of the most promising of these technologies is a photovoltaic system. In this study, Life Cycle Assessment(LCA) is carried out to analyse the environmental issues(e.g. global warming, abiotic resource depletion) of CdTe photovoltaic system. The spatial and temporal scope of this study was set in Korea during 2004~2005. We assumed that CdTe photovoltaic system was installed in Mokpo where the amount of solar irradiation was higher than other places in Korea. Based on the present data and some assumptions, greenhouse gas emission was 39.2g $CO_2$-eq./kWh. Therefore the electricity produced by CdTe photovoltaic system is more environmentally friendly than the conventional power generation system.

• Proceedings of the Korean Institute of Building Construction Conference
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• 한국건축시공학회 2005년도 추계 학술논문 발표대회
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• pp.101-104
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• 2005

The world's cement demand is anticipated to increase about 2.558$\%$ every year until the first half of the 21st century. To be closed the increase of cenment damand and simultaneously comply with the Kyoto Protocal, cement that gives less carbon dioxide(Co2) discharge should be urgently developed. If cement can be manufactured with industrial byproducts such as granulated blast furnace slag(GBFS), phosphogypsum(PG), and waste lime(WL) instead of clinker as its counterproposal, there would be many advantages including maximum use of these industrial byproducts for high value-added resources, conservation of natural resources and energy by omitting the use of clinker, minimized environmental pollution problems caused by Co2 discharge and reduction of the cost. So this study aims to solve the problems by manufacturing non-sintered cement.

• Journal of the Korean Solar Energy Society
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• 제30권2호
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• pp.39-45
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• 2010

Zero Emission Building is abuilding which emits virtually '0(zero)' carbon dioxide. Although simple in concept, ZEB requires totally different approach from conventional building in terms of design, engineering, construction and operation. There are few research on ZEB design process as ZEB design requires understanding and knowledge regarding energy and technology. The study aims to propose a design process of Zero Emission Building for architects. The study examined the concept of Zero Emission Building through intensive literature search. The examples of Zero Emission Buildings were investigated, and strategies and technologies applied to the buildings were analyzed. Various conventional design processes were identified and analyzed to examine the applicability to ZEB design, Finally, a new design process which effectively accommodate the requirement of Zero Emission Building was proposed.

• Transactions of the Korean Society of Automotive Engineers
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• 제14권4호
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• pp.149-156
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• 2006

This paper investigates the steady state combustion characteristics of LPG homogeneous charge compression ignition(HCCI) engine with variable valve timing(VVT) and dimethyl ether(DME) direct injection, to find out the benefits in exhaust gas emissions. VVT is one of the attractive ways to control HCCI engine. Hot internal residual gas which is controlled by VVT device, makes fuel is evaporated easily, and ignition timing is advanced. Regular gasoline and liquefied petroleum gas(LPG) were used as main fuel and dimethyl ether(DME) was used as ignition promoter in this research. Operating range and exhaust emissions were compared LPG HCCI engine with gasoline HCCI engine. Operating range of LPG HCCI engine was wider than that of gasoline HCCI engine. The start of combustion was affected by the intake valve open(IVO) timing and the ${\lambda}TOTAL$ due to the latent heat of vaporization, not like gasoline HCCI engine. At rich operation conditions, the burn duration of the LPG HCCI engine was longer than that of the gasoline HCCI engine. CAD at 20% and 90% of the mass fraction burned were also more retarded than that of the gasoline HCCI engine. And carbon dioxide(CO2) emission of LPG HCCI engine was lower than that of gasoline HCCI engine. However, carbon oxide(CO) and hydro carbon(HC) emission of LPG HCCI engine were higher than that of gasoline HCCI engine.

• Microbiology and Biotechnology Letters
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• 제9권3호
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• pp.123-128
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• 1981

The effects of the crude saponin extracted from ginseng leaves on carbon dioxide evolution, alcohol fermentation, and cell production by Saccharomyces cerevisiae were investigated. The results were summarized as follows : 1) In the process of fermentation, $CO_2$ evolution by yeast was faster in the order of 3%, 1.5%, 0.7%, 5%, 7%, 0.3% than in control in concentration of the crude saponin extracts. 2) In the course of fermentation, the content of alcohol increased in the order of 0%, 0.3%, 7%, 1.5%, 3%, 5%. Among all these concentration, the production of alcohol was remarkably much in 5% and 3%. 3) In the process of fermentation, pH in the low content (0-0.7%) of the crude saponin extracts was gradually decreased as tine goes by and in the high content (1.5-7%) dropped suddenly between 24 hrs. and 48 hrs., and after 48 hrs., increased. 4) Dried yeast cell weight increased more in all the above concentration than control (0%) and among these it increased visibly in 3%.

• Korean Chemical Engineering Research
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• 제48권6호
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• pp.763-767
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• 2010

High-pressure phase behavior for the binary mixture of 1-propanol with supercritical $CO_2$ has been measured by means of a high-pressure phase equilibrium apparatus equipped with a variable-volume view cell. The equilibrium loci of the pressure - composition and pressure - temperature were obtained for the binary mixture of 1-propanol + $CO_2$ system at 305.15 K, 313.15 K, 323.15 K and 333.15 K, and from 2 MPa to 11 MPa. The critical temperature of the mixture increased with the temperature. The pressure-composition line for the binary mixture of $CO_2$-1-propanol system showed a typical type-II phase behavior. The experimental P-x envelopes were correlated by using the Peng-Robinson equation of state in a satisfactory manner to obtain the parameters with $k_{ij}=0.116$ and ${\eta}_{ij}=-0.065$.

• Transactions of the Korean Society of Mechanical Engineers B
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• 제32권8호
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• pp.612-620
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• 2008

New alternative refrigerants have been developed due to the ozone layer depletion and global warming. For this reason, carbon dioxide is believed to be a promising refrigerant for use in air conditioners and heat pumps. Evaporative heat transfer characteristics and pressure drop of $CO_2$ with outer diameter of 5 mm in inclined ($45^{\circ}$) smooth and micro-fin tubes have been investigated by the experiments with respect to several test conditions such as mass fluxes, heat fluxes, evaporation temperatures in this study. The inclined ($45^{\circ}$) smooth and micro-fin tubes with length of 1.44 m were installed to measure the evaporative heat transfer coefficients of $CO_2$ and heat was supplied to the refrigerant by direct heating method where the test tube was uniformly heated by electricity. The tests were conducted at mass fluxes from 212 to $656\;kg/m^2s$, heat fluxes from 15 to $60\;kW/m^2$ and evaporation temperatures from -10 to $20^{\circ}C$. The heat transfer coefficients of $CO_2$ are slightly increased with increasing mass flux, and the heat transfer characteristics in the inclined ($45^{\circ}$) tubes are enhanced about $5{\sim}10%$ compared with those in horizontal or vertical tubes.

• Horticultural Science & Technology
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• 제33권5호
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• pp.675-686
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• 2015

Asparagus (Asparagus officinalis L.) needs proper post-harvest treatment to prolong its storage life. This study investigated the effect of 1-methylcyclopropene (1-MCP) on the quality and storage life of asparagus. Fresh-harvested asparagus was treated with 1-MCP ($1mg{\cdot}L^{-1}$), CEPA($10mg{\cdot}L^{-1}$), and 1-MCP($1mg{\cdot}L^{-1}$) + CEPA($10mg{\cdot}L^{-1}$) and compared with an untreated control. The carbon dioxide ($CO_2$) production, ethylene production, and morphological characteristics of the preserved asparagus were observed. The flow-system and the static-type measurement methods for ethylene and $CO_2$ production (respiration rate) were used. Weight loss, respiration rate, degree of freshness, and ethylene production were monitored during storage at $7^{\circ}C$. The results further showed that CEPA (2-chloroethylphosphonic acid) treatment had greater effects on $CO_2$ and ethylene production than using the 1-MCP process. The asparagus treated with CEPA or 1-MCP + CEPA had significantly increased the ethylene production rate compared to the control or using only 1-MCP during storage. There were no evident changes in the respiration rate of asparagus under 1-MCP treatment as compared with the control. Using the flow-system, slight differences in the rates of $CO_2$ and ethylene production were noted as compared to using the static type. Findings showed that in using the flow-system, asparagus manifested clearer results as compared with the static type. Weight loss in asparagus was significantly lower in control and 1-MCP treated samples than in those treated with CEPA. Likewise, the $CO_2$ and ethylene production of the CEPA treated samples significantly increased. The 1-MCP treatment reduced the effects of CEPA on weight loss, soluble solids content, and osmolality. The effect was not observed with exogenous ethylene as CEPA treatment had no visible effect as compared to the untreated group. Thus, 1-MCP treatment of asparagus could slightly reduce damage to the quality of asparagus during its distribution where ethylene gas is produced. Therefore, this study suggests that 1-MCP treatment can reduce the damage induced by ethylene gas on asparagus in poor distribution environments.