• Title/Summary/Keyword: Carbon dioxide (CO2)

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Performance Analysis with Change in Design Parameters of $CO_2$ Heat Pump Gas Cooler ($CO_2$ 히트펌프 가스쿨러의 설계변수 변화에 따른 성능해석)

  • Chang, Young-Soo;Kim, Min-Seok
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.639-644
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    • 2006
  • The outlet temperature of gas cooler has a great effect on the efficiency of carbon dioxide heat pump system. In order to obtain a small approach temperature difference at gas cooler, near-counter flow type heat exchanger has been proposed, and larger heat transfer area is demanded. The optimum design of gas cooler involving the analysis of trade-offs between heat transfer performance and cost is desirable. In this study, the effects of geometric parameters, such as the circuit arrangement, tube diameter, transverse tube spacing, longitudinal tube spacing and the number of tube rows and fin spacing on the performance of heat transfer were investigated using the developed model. This study suggested various simulation results for optimum designs of gas cooler.

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$CO_2$ Production in Fermentation of Dongchimi (Pickled Radish Roots, Watery Radish Kimchi) (동치미의 발효중 $CO_2$ 발생특성)

  • 이동선;이영순
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.26 no.6
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    • pp.1021-1027
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    • 1997
  • $CO_2$production in fermentation of dongchimi was measured and interrelated with changes in pH and titratable acidity. The effects of salt content and temperature on $CO_2$production rate were analysed. Fermentation of dongchimi showed drastic pH decrease in early stage and subsequent levelling off around 3.9, with linearly increased acidity up to 0.3~0.4% optimum quality. $CO_2$production of dongchimi could be analysed to consist of two consecutive stages of constant rate. The first stage $CO_2$production of higher rate moved to the second stage of lower rate when acidity rose beyond 0.3%. When compared to those of 1 and 2% salt content, dongchimi of 3% salt showed lower $CO_2$production rate in the 1st stage and slower acidity change through the whole fermentation period. However, it resulted in the product of highest $CO_2$accumulation at optimal ripeness because of consistent $CO_2$production of longer 1st stage period and relatively high $CO_2$production rate in 2nd stage. $CO_2$production depended on temperature less compared to acidity change(activation energy: 57.3 and 44.3kJ/mol for $CO_2$production of 1st and 2nd stages, respectively; 79.3kJ/mol for acidity change), which means higher ratio of $CO_2$production rate relative to acidity increase at lower temperature. Slower increase in acidity at low temperature also was shown to extend the period of 1st stage $CO_2$production. Therefore, low temperature fermentation was effective in producing the high $CO_2$content dongchimi at adequate acidity, which is desirable organoleptically.

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A Study on the Hydrogenation of CO2 Using Cu/ZnO/Cr2O3/Al2O3 Catalysts (Cu/ZnO/Cr2O3/Al2O3 촉매를 이용한 이산화탄소의 수소화 연구)

  • Sim, Kyu-Sung;Han, Sang-Do;Kim, Jong-Won;Kim, Youn-Soon;Myoung, Kwang-Sik;Park, Ki Bae
    • Journal of Hydrogen and New Energy
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    • v.7 no.2
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    • pp.147-155
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    • 1996
  • The aim of this study is the development of technologies of methanol production from carbon dioxide by catalytic hydrogenation. Experiments about carbon dioxide hydrogenation by catalyst mixed with CuO, ZnO, $Cr_2O_3$ and $Al_2O_3$ were conducted to find optimum catalyst and reaction condition. Reactions were carried out at atmospheric and high pressures between 200 to $350^{\circ}C$. High yield of methanol was obtained with $Cu/ZnO/Cr_2O/Cr_2O_3/Al_2O_3$ catalyst at $250^{\circ}C$ and above 30 atmospheric pressure. There was not any increament of hydrogenation reactivity for the catalysts which was made by the addition of Pd to $Cu/ZnO/Cr_2O/Cr_2O_3/Al_2O_3$.

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Studies of Pretreatment Mehtods for Additional Reduction of Sewage Sludge (최종 하수처리장 슬러지의 추가감량을 위한 슬러지 전처리 연구)

  • Kim, Seogku;Kim, Jahyun;Lim, Junhyuk;Lee, Jeakun;Lee, Taeyoon
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.10
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    • pp.15-21
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    • 2014
  • In this study, biochemical methane potential test was conducted to estimate ultimate methane and carbon dioxide yield for anaerobic digestion and pretreatment with sewage sludge cake. Two of 0.2 % TS of sewage sludge cakes were treated with 5M NaOH or sonication of 0.51 W/mL during 30 min respectively. Another sample was treated simultaneously with NaOH and sonication in same condition. Then, initial soluble COD increased from 33.1 mg/L to 494 mg/L. After BMP test, methane production ranged from 3.12 and 84.2 mL $CH_4$ per g of Volatile Solid (VS) and 9.2 and 13.5 mL $CO_2$ per g of Volatile Solid (VS) for carbon dioxide. In other tests, injection of nutrient media or sludge supernatant produced 73.1 and 73.8 mL $CH_4$ per g of Volatile Solid (VS) and 11.2 and 13.6 mL $CO_2$ per g of Volatile Solid (VS) respectively. When BMP test finished, 62 % of initial volatile solids decreased to 33.8~45.4 %. Simultaneous pretreatment increased soluble COD, reduction rate of volatile solids and digestion efficiency than those for alkaline and ultrasonic pretreatment.

Development of Building System for Achieving an Optimal Growth Environment in a Vertical Smart Farm (수직형 스마트 팜의 적정 생육환경 조성을 위한 건축 시스템 개발 - 수직형 스마트 팜에 최적화된 내부 공기 균일성 향상에 대한 연구 -)

  • Kim, Handon;Lee, Jeonga;Choi, Seun;Jang, Hyounseung;Kim, Jimin
    • Korean Journal of Construction Engineering and Management
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    • v.22 no.4
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    • pp.3-10
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    • 2021
  • According to the IPCC, humans are influencing the climate system. Such changes in the climate system can cause problems in the supply of food ingredients in the agricultural field by changing the existing growing environment. To solve this problem, vertical farms can be a good alternative for a stable supply of food ingredients. Although the vertical smart farm pays close attention to maintaining and managing the growing environment of crops, it is difficult to uniformly implement temperature, humidity, illumination, oxygen, and carbon dioxide concentrations in the building space. As a result of conducting computational fluid dynamics analysis to ensure air uniformity, a remarkable result is that it is advantageous to continuously spray suitable carbon dioxide CO2 concentrations for a long period of time for air uniformity in a vertical smart farm. Through this result, it is possible to efficiently plan a growing environment system optimized for a vertical smart farm. Based on this study, if efficient crops are produced by creating an optimized growing environment for vertical smart farms, it will be able to contribute to the development of the agricultural field.

Study on Forestry-Based Carbon Offset Programs (산림을 이용한 탄소상쇄 프로그램의 해외 사례 고찰)

  • Lee, Seung-Eun
    • Journal of Climate Change Research
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    • v.1 no.2
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    • pp.97-107
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    • 2010
  • A forest project for the sequestration of carbon dioxide helps to reduce the concerntration of greenhouse gas in atmosphere and provides various co-benefits. A lot of forestry-based carbon offset programs have been developing for the purpose of CSR(Corporate Social Responsibility), voluntary GHG emission reduction, and regulatory context etc. in worldwide. We studied major characteristics - project type and criteria, additionality, credits, permanence, carbon accounting and monitoring, co-benefit - of advanced forest carbon offset programs. Also, we tried to comprehend the direction and basic elements to design a domestic program.

Conceptual Design of 100 MWe Oxy-coal Power Plant-Youngdong Project (100 MWe 순산소 석탄연소 발전시스템의 개념설계-영동 프로젝트)

  • Choi, Sangmin
    • Journal of the Korean Society of Combustion
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    • v.17 no.3
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    • pp.30-45
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    • 2012
  • An existing unit of power plant is considered to refurbish it for possible application of carbon capture and storage(CCS). Conceptual design of the plant includes basic considerations on the national and international situation of energy use, environmental concerns, required budget, and time schedule as well as the engineering concept of the plant. While major equipment of the recently upgraded power plant is going to be reused, a new boiler for air-oxy fired dual mode operation is to be designed. Cryogenic air separation unit is considered for optimized capacity, and combustion system accommodates flue gas recirculation with multiple cleaning and humidity removal units. The flue gas is purified for carbon dioxide separation and treatment. This paper presents the background of the project, participants, and industrial background. Proposed concept of the plant operation is discussed for the possible considerations on the engineering designs.

The adsorption characteristics of carbon dioxide by Impregnated Activated Carbon using potassium Hydroxide (KOH 첨착활성탄소의 $CO_2$ 흡착 특성)

  • 박영태;김정덕;손부순;임계규
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.384-388
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    • 2000
  • 일반적으로 흡착분리공정 기술개발은 대략 3단계의 과정을 거치게 되는데 흡착제의 선정, 흡착탑의 거동해석, 연속공정 구성 및 운전으로 이루어진다. 이중 흡착제의 선정은 대상 혼합물에 어떤 흡착제를 사용하여 효율적인 분리 결과를 얻을 수 있는가를 결정하는 기초단계이면서도 가장 중요한 과정이다. 이를 위해 여러 흡착제에 대한 흡착평형량과 이로부터 얻어지는 선택도, 흡착열, 그리고 흡착질과 흡착제 사이의 물질전달저항과 흡착제의 기공 분포도, 기공부피, 기공율, 비표면적, 충전 밀도(Bulk Density), 파쇄 강도 및 마모저항 등과 같은 물리적 특성을 종합적으로 비교 검토하여 흡착제를 선택하여야 한다. (중략)

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Microwave-enhanced gasification of sewage sludge waste

  • Chun, Young Nam;Song, Hee Gaen
    • Environmental Engineering Research
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    • v.24 no.4
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    • pp.591-599
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    • 2019
  • To convert sewage sludge to energy, drying-gasification characteristics during microwave heating were studied. During the gasification of carbon dioxide, the main products were gas, followed by char, and tar in terms of the amount. The main components of the producer gas were carbon monoxide and hydrogen including a small amount of methane and light hydrocarbons. They showed a sufficient heating value as a fuel. The generated tar is gravimetric tar, which is total tar. As light tars, benzene (light aromatic tar) was a major light tar. Naphthalene, anthracene, and pyrene (light polycyclic aromatic hydrocarbon tars) were also generated, but in relatively small amounts. Ammonia and hydrogen cyanide (precursor for NOx) were generated from thermal decomposition of tar containing protein and nitrogen in sewage sludge. In the case of sludge char, its average pore diameter was small, but specific area, pore volume, and adsorption amounts were relatively large, resulting in superior adsorption characteristics.

DEVELOPMENT OF THE DUAL COUNTING AND INTERNAL DOSE ASSESSMENT METHOD FOR CARBON-14 AT NUCLEAR POWER PLANTS

  • Kim, Hee-Geun;Kong, Tae-Young;Han, Sang-Jun;Lee, Goung-Jin
    • Journal of Radiation Protection and Research
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    • v.34 no.2
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    • pp.55-64
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    • 2009
  • In a pressurized heavy water reactor (PHWR), radiation workers who have access to radiation controlled areas submit their urine samples to health physicists periodically; internal radiation exposure is evaluated by the monitoring of these urine samples. Internal radiation exposure at PHWRs accounts for approximately 20 $\sim$ 40% of total radiation exposure; most internal radiation exposure is attributed to tritium. Carbon-14 is not a dominant nuclide in the radiation exposure of workers, but it is one potential nuclide to be necessarily monitored. Carbon-14 is a low energy beta emitter and passes relatively easily into the body of workers by inhalation because its dominant chemical form is radioactive carbon dioxide ($^{14}CO_2$). Most inhaled carbon-14 is rapidly exhaled from the worker's body, but a small amount of carbon-14 remains inside the body and is excreted by urine. In this study, a method for dual analysis of tritium and carbon-14 in urine samples of workers at nuclear power plants is developed and a method for internal dose assessment using its excretion rate result is established. As a result of the developed dual analysis of tritium and carbon-14 in urine samples of radiation workers who entered the high radiation field area at a PHWR, it was found that internal exposure to carbon-14 is unlikely to occur. In addition, through the urine counting results of radiation workers who participated in the open process of steam generators, it was found that the likelihood of internal exposure to either tritium or carbon-14 is extremely low at pressurized water reactors (PWRs).