• 청정기술
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• 제14권1호
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• pp.1-6
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• 2008

초임계이산화탄소를 이용하여 세라믹 사출성형체로부터 파라핀왁스를 제거하였다. 파라핀왁스는 세라믹사출성형 공정에서 바인더로 사용되는 물질이다. 파라핀왁스 제거의 최적조건을 찾기 위해 온도, 압력, 이산화탄소의 유량에 대한 영향을 조사하였다. 온도는 328.15 - 348.15 K, 압력은 15 - 30 MPa 범위에서 조절하였으며, 이산화탄소의 유속을 변화시켜가면서 파라핀왁스의 제거율을 측정하였다. 파라핀왁스의 제거율은 압력의 증가에 비례하였다. 온도는 파라핀왁스의 녹는점인 329.15K 이상일 때 파라핀왁스의 제거가 효과적이었고, 더 높은 온도에서는 더 이상의 효과가 없었다. 이산화탄소의 유량 증가에 따라 파라핀 제거율이 향상되었지만 어느 양 이상이 되면 더 이상 효과가 없었다. 파라핀왁스를 보다 더 효과적으로 제거하기 위해 프로판을 공용매로 사용하였다. 초임계이산화탄소에 프로판을 첨가했을 경우 제거율이 향상되었으며, 사출성형체의 구조나 모양에 어떠한 변화도 없이 파라핀왁스를 완전하게 제거할 수 있었다.

• Korean Chemical Engineering Research
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• 제54권5호
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• pp.606-611
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• 2016

Carbon dioxide injection is a widely known method of enhanced oil recovery (EOR). It is critical for the $CO_2$ EOR that the injected $CO_2$ to reach a condition fully miscible with oil. To reach the miscible point, a certain level of pressure is required, which is known as minimum miscibility pressure (MMP). In this study, a MMP prediction method using a process simulator is proposed. To validate the results of the simulation, those are compared to a slim tube experiment and several empirical correlations of previous literatures. Aspen HYSYS is utilized as the process simulator to create a model of $CO_2$/crude oil encounter. The results of the study show that the process simulator model is capable of predicting MMP and comparable to other published methods.

• 한국자동차공학회논문집
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• 제16권3호
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• pp.87-93
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• 2008

The $CO_2$ air conditioning system installed in fuel cell vehicles could be used either for stack cooling or for cabin cooling, and thus was used for the stack cooling when additional stack heat release was required over a fixed radiator capacity for high power generation. This study investigated the performance of the stack cooling system using $CO_2$ air conditioner at various operating conditions. Also, the heat releasing effectiveness and mutual interference were analyzed for the stack cooling system using an air conditioner and compared with the conventional radiator cooling system with/without cabin cooling. The heat release of the stack cooling system with the aid of $CO_2$ air conditioner increased up to 36% more than that of the conventional radiator cooling system with cabin cooling. Furthermore, the heat release of the stack cooling system using $CO_2$ air conditioner increased more by 7% than that of the conventional radiator cooling system without cabin cooling.

• Fisheries and Aquatic Sciences
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• 제17권1호
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• pp.59-65
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• 2014

We measured the reductions in size and solubility of mackerel muscle that was freeze-dried, deoiled by supercritical carbon dioxide (SC-$CO_2$), or roasted. The percent size reduction and solubility were high in SC-$CO_2$-treated muscle compared with freeze-dried and roasted muscle. We used oil-free residues to test for heavy metals and determine microbial safety. The SC-$CO_2$, hexane, and ethanol were used to separate oil from muscle. The concentrations of cadmium (Cd) in all treated muscles were less than the values reported in the literature, as were the concentrations of lead in SC-$CO_2$- and hexane- treated muscle. In contrast, concentrations of arsenic and mercury in muscles were greater than the reported values regardless of treatment. Zinc and iron, which are beneficial for health, were found in high levels after all treatments of muscle tissue. After 6 months of storage at different temperatures, SC-$CO_2$-and ethanol-treated muscle showed few bacterial colonies, and none were found after 4 months of storage at $-20^{\circ}C$. These results will be useful to food-processing industries for maintaining high-quality, safe mackerel muscle.

• 설비공학논문집
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• 제23권7호
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• pp.505-512
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• 2011

Recently, many researchers have analyzed the performance of the transcritical $CO_2$ refrigeration cycle in order to identify opportunities to improve the system energy efficiency. The reduction of the expansion process losses is one of the key issues to improve the efficiency of the transcritical $CO_2$ refrigeration cycle. In this study, the analytical study on the performance characteristics of $CO_2$ cycle with an ejector carried out with a variation of outdoor temperature, gascooler inlet air velocity, evaporator inlet air velocity, and evaporator inlet air temperature. As a result, the system performance could be improved over 85% by using an ejector for various operating condition because of the reduction of compressor work. Moreover, the cooling capacity increased about 18% for variable outdoor condition. Therefore, the high performance of an ejector system could be maintained for wide operating conditions and system reliability could be improved compared to that of a basic system.

• 한국석유지질학회지
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• 제13권1호
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• pp.24-29
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• 2007

본 연구의 주요 목적은 대한해협 대륙붕 이토대 지역의 천부 공기층 가스의 기원을 규명하는데 있다. 채취한 시료의 공기층 가스 분석 결과에 의하면 천부 공기층 가스의 대부분은 메탄으로 구성되어 있으며, 메탄 내 탄소 및 수소 동위원소 값은 각각 $-93.4%o{\sim}-70.9%o{\sim}\;-228%o{\sim}-199%o$ 가진다. 이러한 분석결과는 천부 공기층 가스 내 메탄가스가 열기원(thermogenic) 가스보다는 이산화탄소 환원작용($CO_2$ reduction)에 의한 생물 기원(biogenic) 가스임을 지시한다. 또한 메탄과 이산화탄소의 탄소 동위원소비 차는 54.4에서 72.2의 범위를 가지고 있으며, 이러한 결과 역시 전기한 결과를 뒷받침하는 또 다른 증거이다.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.418-419
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• 2006

In the present, the focus is on the synthesis of nanostructured TiC/Co composite powder by the spray thermal conversion process using titanium dioxide powder has an average particle size of 50 nm and cobalt nitrate as raw materials. The titanium-cobalt-oxygen based oxide powder prepared by the combination of the spray drying and desalting methods. The titanium-cobalt-oxygen based oxide powder carbothermally reduced by the solid carbon. The synthesized TiC-15wt.%Co composite powder at 1473K for 2 hours had an average particle size of 150 nm.

• 한국대기환경학회지
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• 제3권2호
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• pp.27-32
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• 1987

大氣汚染의 疫學的 硏究의 일부로서 미국내 휴스턴시의 家庭을 對象으로 5가지 主要硏究物質($SO_2$, $NO_2$, CO, $O_3$)에 대한 室內外 濃度를 調査하였다. 室內濃度는 침실, 부엌, 거실에서 調査하였고 室外濃度와 比較하였다. 그 結果 오존을 除外한 각 汚染物質에서 부엌과 거실의 濃度는 室外濃度 보다 높았다. 또한 $NO_2$와 $O_3$를 除外한 각 汚染物質의 室內外 濃度比는 1.8 ~ 2.7을 나타냈다. 특히 家庭 內에서 汚染物質의 室內濃度는 家庭의 住宅構造, 居住者의 吸煙狀況 등에 影響을 받는 것으로 시사되었다.

• 한국농림기상학회:학술대회논문집
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• 한국농림기상학회 2013년도 추계 학술발표논문집
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• pp.30-31
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• 2013

Land use and land cover change (LULCC) due to human activities directly affects natural systems and contributes to changes in carbon exchange and climate through a range of feedbacks. How land use and land cover changes affect carbon exchanges can be assessed using multiyear measurement data from micrometeorological flux towers. The objective of the research is to assess the impact of land use and land cover change on carbon exchange in a heterogeneous cropland area. The heterogeneous cropland area in Haenam, South Korea is also subjected to a land conversion due to rural development. Therefore, the impact of the change in land utilization in this area on carbon exchange should be assessed to monitor the cycle of energy, water, and carbon dioxide between this key agricultural ecosystem and the atmosphere. We are currently conducting the research based on 10 years flux measurement data from Haenam Koflux site and examining the LULCC patterns in the same temporal scale to evaluate whether the LULCC in the surrounding site and the resulting heterogeneity (or diversity) have a significant impact on carbon exchange. Haenam cropland is located near the southwestern coast of the Korean Peninsula with land cover types consisting of scattered rice paddies and various croplands (seasonally cultivated crops). The LULCC will be identified and quantified using remote sensing satellite data and then analyzing the relationships between LULCC and flux footprint of $CO_2$ from tower flux measurement. We plan to calculate annual flux footprint climatology map from 2003 to 2012 from the 10 years flux observation database. Eventually, these results will be used to quantify how the system's effective performance and reserve capacity contribute to moving the system towards more sustainable configuration. Broader significance of this research is to understand the co-evolution of the Haenam agricultural ecosystem and its societal counterpart which are assumed to be self-organizing hierarchical open systems.

• 생물환경조절학회지
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• 제2권1호
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• pp.27-36
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• 1993

Carbon dioxide enrichment for greenhouse crops has generally been a standard commercial practice for many years. Vegetable crops such as tomato, cucumber, and lettuce respond positively to the $CO_2$ enrichment. But improper $CO_2$ enrichment leads to physiological damage and economical loss. This study was carried out to develop a $CO_2$ concentration control algorithm considering growth stage and efficiency. The measurand was $CO_2$ consumption rate and top fresh weight that represents growth stage. The weight of top fresh lettuce as a whole in the tray was measured through a non-destructive method. The demand in $CO_2$ concentration according to growth stage was investigated. The results are summarized as follows. 1. The $CO_2$ consumption rate could be measured within the error of $\pm$ 15.4mg$CO_2$/hr in the range of $CO_2$ concentration of 500-1500ppm. 2. The weight of top fresh lettuce could be measured within the error $\pm$ 4.3g in the range of 0-1400g. 3. The $CO_2$ control model developed could determine an economical $CO_2$ supply rate considering $CO_2$ consumption rate and leakage rate. 4. The $CO_2$ control algorithm based on the control model was composed of feedforward control for maintaining a stable $CO_2$ concentration level, and feedback control with $CO_2$ consumption rate and top fresh weight for adapting to the change in $CO_2$ demand by growth stage. 5. For the performance test with the developed control algorithm on lettuce the decrease in $CO_2$ supply rate was obtained without a significant decrease in top fresh weight.