• 제목/요약/키워드: Carbon decreasing rate

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Wear Resistance Characteristics of Iron System MAG Weld Overlays with Chromium and Niobium Carbide Composite (Cr 및 Nb 복합탄화물에 의한 철계 MAG용접 오버fp이의 내마모 특성)

  • 김종철;박경채
    • Journal of Welding and Joining
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    • v.20 no.3
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    • pp.54-59
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    • 2002
  • Overlays is a treatment of the surface and near-surface regions of a material to allow the surface to perform functions that are distinct from those frictions demanded far the bulk of the material. Welding, thermal spray, quenching, carburizing and nitration have been used as the surface treatment. Especially, weld overlay is a relatively thick layer of filler metal applied to a carbon or low-alloy steel base metal for the purpose of providing a wear resistant surface. In this study, weld overlay was performed by MAG welding on the base metal(SS400) with filler metal which contain composite powders($Cr_3C_2+Mn+Mo+NbC$) and solid wire(JIS-YGW11). Characteristics of hardness and wear resistance on overlays were analyzed by EDS, EPMA, XRD and microstructures. Carbide formations were $M(Cr, Fe)_7C_3$ and NbC phases. And carbide volume fraction, hardness and specific wear resistance of overlays were increased with increasing powder feed rate and decreasing wire fred rate. Hardness and wear resistance were almost proportioned to carbide volume fraction of overlay.

CHEMICAL EVOLUTION OF THE GALAXY: RADIAL PROPERTIES

  • PARK BYEONG-GON;KANG YONG HEE;LEE SEE-WOO
    • Journal of The Korean Astronomical Society
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    • v.29 no.1
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    • pp.63-73
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    • 1996
  • The previous study of chemical evolution of the Galaxy is extended to the radial properties of the Galactic disk. The present model includes radial dependency of the time-dependent bimodal IMF, radial flow of material in the disk, and the change of type I supernova explosion rate with radial distance from the disk center as model parameters and observed gas and stellar density distributions and metallicity abundance gradient as observational constraints. The results of two models in this study explain the observed gas and stellar density distributions well, with the slope of the gas density gradient in the region of 4.5 kpc$Y_1$ and -0.123dex/kpc in model $Y_2$, respectively, which fit well the observed gradient of -0.l1dex/kpc. The abundance gradient reproduced in model $Y_1$ is getting flatter with decreasing radius, while that in model $Y_2$ is getting steeper, which fits better the observed abundance gradient. This result shows the necessity of exponentially increasing type I supernova explosion rate with decreasing radius in order to explain the observed abundance gradient in the disk. The fitness of observed density distribution and star formation rate distribution justifies the reliability of time-dependent bimodal IMF as a compound quantitative chemical evolution model of the Galaxy. The temporal variations of metallicity gradients for carbon, nitrogen and oxygen are also shown.

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An Analysis on the Effects of EGR to Extend Operation Region for a HCCI Hydrogen Engine (HCCI 수소기관에서 운전영역확장을 위한 EGR 효과 분석)

  • LEE, KEONSIK;KIM, JINGU;BYUN, CHANGHEE;LEE, JONGTAI
    • Journal of Hydrogen and New Energy
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    • v.26 no.6
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    • pp.560-566
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    • 2015
  • HCCI (Homogeneous Charge Compression Ignition) hydrogen engine has relatively narrower operation range caused by knock occurrence due to the rapid pressure rising by using higher compression ratio. In this study, EGR as one of the countermeasure methods is considered to extend operation range of HCCI hydrogen engine. Also, the effects of hydrogen EGR are compared with the effects of EGR using hydrocarbon fuel. Hydrocarbon EGR is carried out by adding carbon dioxide to exhaust gas of HCCI hydrogen engine. As the results, EGR has positive effects on a HCCI hydrogen engine in reducing rate of pressure rise as same as the other engines used hydrocarbon fuels. However, the effects of hydrogen EGR are better than those of hydrocarbon EGR in decreasing minimum compression ratio and rate of pressure rise. When applying EGR to HCCI hydrogen engine by 20% rate, the rate of pressure rise decreases by 58% and it results in about 48% increase of the operation range in terms of supply energy.

A study on carbon composite fabrication using injection/compression molding and insert-over molding (사출/압축 공정과 인서트 오버몰딩을 이용한 탄소복합소재 성형에 대한 연구)

  • Jeong, Eui-Chul;Yoon, Kyung-hwan;Hong, Seok-Kwan;Lee, Sang-Yong;Lee, Sung-Hee
    • Design & Manufacturing
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    • v.14 no.4
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    • pp.11-16
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    • 2020
  • In this study, forming of carbon composite parts was performed using an injection/compression molding process. An impregnation of matrix is determined by ability of wet and flow rate between the matrix and reinforcement. The flow rate of matrix passing through the reinforcements is a function of permeability of reinforcement, a viscosity of matrix and pressure gradient on molding, and the viscosity of the matrix depends on the mold temperature, molding pressure and shear strain of matrix. Therefore, compression molding experiment was conducted using a heating mold in order to confirm the possibility of matrix impregnation. The impregnation of the matrix through the porosities between the woven yarns was confirmed by the cross-sectional SEM image of compression molded parts. An injection molding process was also performed at a short cycle time, high molding pressure and low mold temperature than those of compression experiment conditions. Deterioration of impregnation on the surface of molded parts were caused by these injection conditions and it could be the reason of decreasing the maximum tensile strength. In order to improve impregnation of matrix on the surface, injection/compression molding and insert-over molding were applied. As a result of applying injection/compression molding and insert-over molding, it was shown that the improvement of impregnation on the surface and the maximum tensile strength was increased about 2.8 times than the virgin matrix.

A Study on the Effect of Coal Properties on the Electrochemical Reactions in the Direct Carbon Fuel Cell System (석탄 물성에 따른 직접탄소 연료전지의 전기화학 반응 특성 연구)

  • Ahn, Seong-Yool;Eom, Seong-Yong;Rhie, Young-Hoon;Moon, Cheor-Eon;Sung, Yon-Mo;Choi, Gyung-Min;Kim, Duck-Jool
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.10
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    • pp.1033-1041
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    • 2012
  • Performance evaluation of a direct carbon fuel cell (DCFC) was conducted according to coals and a graphite particle. Several fuel properties such as thermal reactivity, textural structure, gas adsorption characteristic, and functional groups on the surface of fuels were investigated and their effects on electrochemistry were discussed. The strong carbon structure inside of fuels led the rapid potential decreasing in high current density region, because it caused small surface area and low pore volume. The functional groups on the surface were related to the low current density region. The maximum current density and power density of fuels were affected by the total carbon content in fuels. The effect of operating conditions such as stirring rate and operating temperature was investigated in this study.

Effect of Herb Distillate on Hepatic Xanthine Oxidase Activity and Serum Lipid Profiles in Carbon Tetrachloride-Administered Rats

  • Park, Bum-Ho;Lee, Sang-Il;Kim, Soon-Dong
    • Preventive Nutrition and Food Science
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    • v.12 no.1
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    • pp.16-22
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    • 2007
  • In order to evaluate the hepatoprotective effect of an herb distillate, ie., a mixture of 28 traditional Korean herbs, germanium, tormarine and Gijangsoo (Gijang water), $CCl_4$ was intraperitoneally administered to rats before or after supplementation of the diluted herb distillate (HD) for 2 weeks. Then hepatic xanthine oxidase activity and serum lipid profiles were determined. The experimental groups had higher feed intake than the normal control (NC), but had lower weight gain. Water intake and the amount of feces were not significantly different, but urine was excreted in lower amounts in all the experimental groups compared to the NC. Liver weights in the HD-supplemented groups were lower than that of the distilled water-supplemented groups (DW-groups) after $CCl_4$-administration. Serum ALT activities in all the experimental groups were higher than that of the NC-group. However, the increasing activity of serum ALT in the HD-supplemented groups (HD-groups) was lower than that of the DW-groups. Total serum and LDL-cholesterol levels were higher in all the $CCl_4$-administered groups than in the NC-groups, and serum HDL-cholesterol levels were lower in all the experimental groups compared with the NC-groups. Meanwhile, the increasing rate of total serum and LDL-cholesterol levels and the decreasing rate of HDL-cholesterol in the HD-groups were lower than that of the DW-groups. But, levels of serum TG were similar among all the experimental groups. The activities of hepatic xanthine oxidase (XOD) type O of the $CCl_4$-administered rats showed a significant increase in and an increasing rate of XOD in the HD-groups, which was lower than that of the DW-groups. On the other hand, GST activities in all the experimental groups were significantly decreased, and the decreasing rate was lower in the HD-groups than in the DW-groups. The hepatic contents of GSH and LPO in all the rats were not changed by $CCl_4$ administration. These results suggest that the decreased liver damage in the HD-supplemented groups was due to the inhibition of XOD-type O activity by constituents of HD, as well as by a prevention/inhibition of serum lipid profile changes in $CCl_4$-treated rats. However, further detailed studies are needed to support this hypothesis.

Competitive Adsorption for Binary Mixture of 4-Nitrophenol and Phenol on RSTA using GAC (GAC를 이용한 RSTA에서 Phenol과 4-Nitrophenol의 이성분계 경쟁흡착)

  • Lee, Seung-Mok;Kim, Dae-Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.723-731
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    • 2000
  • In recent years, the amount and number of synthetic organic compounds(SOCs) discharged from various industries has been increasing. Granular activated carbon(GAC) adsorption is one of the best available technology to remove SOCs from water supplies and wastewater. In this paper competitive adsorption for binary mixture of 4-nitrophenol and phenol on reverse stratified tapered adsorber(RSTA) using GAC was studied. Two isotherm experiments were conducted, one for phenol and the other for 4-nitrophenol. The phenol data of binary mixture isotherm were not fitted to Freundlich isotherm. The competitive adsorption increased significantly with decreasing carbon dose and increasing adsorbate concentration. The RSTA was found to provide an increase in breakthrough time when decreasing flow rate, increasing angle and injection layers. The performance enhancement provided by RSTA can be exploited in separation and in the purification of fluids.

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Alteration of Gas Exchange in Rice Leaves Infected with Magnaporthe grisea

  • Yun, Sung-Chul;Kim, Pan-Gi;Park, Eun-Woo
    • The Plant Pathology Journal
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    • v.16 no.5
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    • pp.257-263
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    • 2000
  • Infection with rice blast fungus (Magnaporthe grisea) significantly reduced foliar net photosynthesis (A) of rice cultivars: Ilpoom, Hwasung, and Choochung in greenhouse experiments. By measuring the amount of diseased leaf area with a computer image analysis system, the relation between disease severity (DS) and net photosynthetic rate was curvilinearly correlated (r=0.679). Diseased leaves with 35% blast symptom can be predicted to have a 50% reduction of photosynthesis. The disease severity was linearly correlated (r=0.478) with total chlorophyll (chlorophyll a and chlorophyll b) per unit leaf area(TC). Light use efficiency was reduced by the fungal infection according to the light response curves. However, dark respiration (Rd) did not change after the fungal infection (p=0.526). Since the percent of reduction in photosynthesis greatly exceeded the percent of leaf area covered by blast lesions, loss of photosynthetic tissue on an area basis could not by itself account for the reduced photosynthesis. Quantitative photosynthetic reduction can be partially explained by decreasing TC, but cannot be explained by decreasing Rd. By photosynthesis (A)-internal CO$_2$ concentration (C$_i$ curve analysis, it was suggested that the fungal infection reduced ribulose-1,5-bisphosphate carboxylase/oxygenase (Rubisco) activity, ribulose-1,5-bisphosphate (RuBP) regeneration, and inorganic phosphate regeneration. Thus, the reduction of photosynthesis by blast infection was associated with decreased TC and biochemical capacity, which comprises all carbon metabolism after CO$_2$ enters through the stomata.

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The Effects of Cure System on Vulcanization Reaction Constant and Physical Properties of Rubber Compounds (가황시스템 변화가 배합고무의 가황반응속도 및 물리적 특성에 미치는 영향)

  • Lee, Seag;Park, Nam Cook
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.419-426
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    • 1999
  • In this study, the reaction rate constant, activation energy, total crosslinking density, elastic constant, cure properties ($t_5,\;t_{90}$), modulus, and abrasion resistance of rubber compounds were investigated as a function of cure temperatures, cure systems and reinforcing filler loadings. Reaction rate constants showed strong dependence on thc carbon black loading, cure temperature and cure system, and increased sharply with increasing the reaction temperatures. The lowest activation energy was obtained in the efficient cure (EC) system which corresponds to the high level of sulfur to accelerator ratio, and the activation energy was decreased with decreasing the carbon black loadings. The change of carbon black loadings directly affects the modulus and abrasion resistance, but the change of cure system showed various effects on the rubber compounds. Increased carbon black loadings showed the high modulus, improved abrasion resistance and short scorch time but decrease in crosslinking density and elastic constant. Higher crosslinking density and elastic constant were shown in the EC cure system regardless of carbon black loadings, but scorch timc ($t_5$) was not affected by the change of the ratio of sulfur to accelerator. Rapid optimum cure time ($t_{90}$) were showen in the EC cure system. Also, the equivalent cure curve coefficient of rubber compound was 0.96 for conventional cure (CC) system, and 0.94 for semi-efficient cure (SEC) and EC system regardless carbon black loadings. As regarding the abrasion resistance, wear volume showed the logarithmic increase for the loaded weight.

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Improvement of Out-of-Plane Impact Damage Resistance of CFRP Due to Through-the-Thickness Stitching

  • Yoshimura, Akinori;Nakao, Tomoaki;Takeda, Nobuo
    • Advanced Composite Materials
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    • v.18 no.2
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    • pp.121-134
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    • 2009
  • The present study investigated, both experimentally and numerically, the improvement of low-velocity impact damage resistance of carbon fiber reinforced plastic (CFRP) laminates due to through-the-thickness stitching. First, we conducted drop-weight impact tests for stitched and unstitched laminates. The results of damage inspection confirmed that stitching did improve the impact damage resistance, and revealed that the improvement effect became greater as the impact energy increased. Moreover, the stitching affected the through-the-thickness damage distribution. Next, we performed FEM analysis and calculated the energy release rate of the delamination crack using the virtual crack closure technique (VCCT). The numerical results revealed that the stitching affected the through-the-thickness damage distribution because the stitch threads had a marked effect on decreasing both the modes I and II energy release rate around the bottom of the laminate. Comparison of the results for models that contained delaminations of various sizes revealed that the energy release rate became lower as delamination size increased; therefore the stitching improved the impact resistance more effectively when the impact energy was higher.