• Title/Summary/Keyword: Carbon conversion

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Atomization Characteristics of Coal-Water Mixture Fuel (석탄-물 혼합연료(CWM)의 분무 특성)

  • 노남선;신대현;김광호
    • Journal of Energy Engineering
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    • v.3 no.2
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    • pp.130-150
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    • 1994
  • Coal-water mixture(CWM) fuel has attracted much attention as a substitute fuel for oil by which high economics and short-term commercialization might be realized in comparison with other coal conversion technologies. There are many factors that affect the CWM combustibility, such as the physical properties of CWM, the performance of atomizer and burner, operating conditions, capacity and load of the boiler, etc. Particularly, atomization quality is extremely critical to achieving acceptable carbon conversion efficiency of CWM fuel and maintaining the flame stability, because the coal particles in the CWM droplets burn as agglomerates. This paper presents the R&D results about the CWM atomization characteristics, including the significance of CWM atomization the R&D results about the CWM atomization characteristics, including the significance of CWM atomization quality, the atomization and combustion mechanism, the type of CWM atomizer, size and size distribution of CWM droplets and some factors that influence the atomization performance.

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Microbial Conversion of (+)-Limonene by an Enterobacter agglomerans Isolate

  • Park, Yeon-Jin;Kim, In-Cheol;Chang, Hae-Choon
    • Journal of Microbiology and Biotechnology
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    • v.13 no.4
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    • pp.636-639
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    • 2003
  • Entercbacter agglomerans 6L was isolated from citron (Citrus junos) peel by using an enrichment culture containing (+)-limonene. It was able to metabolize limonene and grew well ($A_{600}$:4.5) on limonene as a sole carbon source. E. agglomernas 6L was highly resistant to limonene toxicity, and grew to 1.0 optical density ($A_{600}$) even at 5% (v/v) of limonene in Luria-Bertani media. ${\gamma}-Valerolactone$ and cryptone were detected as the major metabolic products of limonene by E. agglomerans 6L.

Methane Reforming Using Atmospheric Plasma Source (대기압 플라즈마를 이용한 메탄 개질 반응)

  • Lee, Dae-Hoon;Kim, Kwan-Tae;Cha, Min-Suk;Song, Young-Hoon;Kim, Dong-Hyeon
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.64-68
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    • 2005
  • Methane reforming processes to obtain hydrogen were investigated experimentally by using atmospheric plasma source. Among possible reforming processes, such as a $CO_2$ reforming(dry reforming), a partial oxidation (POx), a steam reforming(SR), and a steam reforming with oxygen(SRO or auto-thermal reforming), partial oxidation and the steam reforming with oxygen were considered. We choose a rotating arc plasma as an atmospheric plasma source, since it shows the best performances in our preliminary tests in terms of a methane conversion, a hydrogen production, and a power consumption. Then, the effects of a feeding flow-rate, an electrical power input to a plasma reaction, an $O_2/C$ ratio and a steam to carbon ratio in the case of SRO on the reforming characteristics were observed systematically. As results, at a certain condition almost 100% of methane conversion was obtained and we could achieve the same hydrogen production rate by consuming a half of electrical power which was used by the best results for other researchers.

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Characteristics of a Mutant of Trehalose-producing Micrococcus luteus and Optimization of Production Conditions (Trehalose를 생산하는 Micrococcus luteus 변이주의 특성 및 생산배지의 최적화)

  • 송희상;황기철;방원기
    • Microbiology and Biotechnology Letters
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    • v.27 no.5
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    • pp.399-403
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    • 1999
  • For the production of trehalose, microorganisms capable of producing trehalose extracellularly were screened from the stock cultures in our laboratory. among them, Micrococcus luteus IFO 12708 showed the highest productivity of trehalose. For the increase of productivity, the mutant strai Hs-208 having higher trehalose production was selected with NTG(N-methyl-N'-nitrosoguanidine) mutagenesis, which led to the decrease of the specific activity of trehalose phosphorylase(3.2-fold) as compared to the wild strain. The optimum condition for the trehalose production was established as follows: 20g/l of glucose and 6g/l of tryptone were used as a sole carbon source and nitrogen source, respectively, and cultivations were carried out at 3$0^{\circ}C$ and pH 6.0. After 20hrs cultivation, addition of 20unit/ml penicillin G led to the higher conversion yield of trehalose. Under the optimum condition, 6.547g/l trehalose was produced with conversion yield of 32.7%.

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A Study on Anaerobic Degradation of Carbarvl (1-naphthyl-N-rnethylcarbamate) by Microorganism (저층(Sediment)에서 분리된 미생물에 의한 Carbaryl (1-naphthyl-N-methylcarbamate)의 혐기적 분해에 관한 연구)

  • 두옥주;정문호
    • Journal of Environmental Health Sciences
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    • v.16 no.2
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    • pp.75-82
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    • 1990
  • Carbaryl was degradaded to monomethylamine(MA) by bacterium. which isolated from lake sediment. Its carbaryl degradation was maximized when grown on mineral salt medium conditioning 20 $\mu$M of carbaryl as a sole carbon source at 26${\circ}$C and initial pH 7.0-9.0 Its degradation ability was minimized at initial pH 3.0 and 5.0 The percent conversions { (moles of MA in excess of control / mole of carbaryl added) $\times$ 100} for 10. 20. 40 and 80 $\mu$M of carbaryl were 18.6. 16.1. 18.1 and 11.6 respectively. It suggests that increasing amount of carbaryl added above 80 $\mu$M. the percent conversion should be decreased. The MA production by the bacterium was lineary related to the cultural time. After 7days culture. its percent conversion was 46.2. and this result suggests that a half amount of carbaryl would be hydrolyzed to MA by the bacterium within 8 days.

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A Study on characteristics of AUC Powder Prepared with the Waste AC Solution (폐 AC용액으로부터 제조된 AUC분말의 특성에 대한 연구)

  • 정경채;김태준;최종현;박진호
    • Journal of the Korean Ceramic Society
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    • v.33 no.3
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    • pp.332-338
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    • 1996
  • This study was investigated on the recycle feasibility of the waste AC(Ammonium Carbonate) solution produ-ced in a commercial AUC(Ammonium Uranyl Carbonate) conversion plant. AUC particles were produced with the AC solution which was prepared with AC solid-agent instead of ammonia and carbon-dioxide gases. As the results particles of monoclinic shapes has been obtained regardless of the pH change if the carbonate concentration is sufficient in the mother liquore. Also a lot of twinned or aggregated particles were formed in case of the increase of pH in the reaction system but not affected in the change of temperature. Consequen-tly the characteristics of the particles which converted for AUC were produced withAC solution to UO2, particles specific surface area shape sintered density and others were similar to that of the particles which were produced with gases only when the pellets are fabricated in the nuclear fuel manufacturing process So the waste AC solution which is produced in the commercial AUC conversion plant is possible to recycle.

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Characterization of Enhanced CO Oxidation Activity by Alumina Supported Platinum Catalyst

  • Jo, Myung-Chan
    • Journal of Environmental Science International
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    • v.18 no.10
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    • pp.1071-1077
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    • 2009
  • A novel pretreatment technique was applied to the conventional Pt/alumina catalyst to prepare for the highly efficient catalyst for the preferential oxidation of carbon monoxide in hydrogen-rich condition. Their performance was investigated by selective CO oxidation reaction. CO conversion with the oxygen-treated Pt/Alumina catalyst increased remarkably especially at the low temperature below $100^{\circ}C$. This result is promising for the normal operation of the proton exchange membrane fuel cell (PEMFC) without CO poisoning of the anode catalyst. XRD analysis results showed that metallic Pt peaks were not observed for the oxygen-treated catalyst. This implies that well dispersed small Pt particles exist on the catalyst. This result was continued by high resolution transmission electron microscopy (HRTEM) analysis. Consequently, it can be concluded that highly dispersed Pt nanoparticles could be prepared by the novel pretreatment technique and thus, CO conversion could be increased considerably especially at the low temperatures below $100^{\circ}C$.

Type conversion of single walled carbon nanotube field effect transistor using stable n-type dopants

  • Yun, Jang-Yeol;Ha, Jeong-Suk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.268-268
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    • 2010
  • 단일벽 탄소 나노튜브(SWCNT)는 그 뛰어난 전기적, 물리적 특성 때문에 반도체 공정에 있어서 중요한 p-type 채널 물질로 꼽히고 있다. 본 연구에서는 SWCNT를 성장하여 이를 이용한 전계효과 트랜지스터를 제작하고 또한, 부분적인 폴리머의 코팅으로 타입을 변화하는 연구를 보이고자 한다. Ferritin용액을 DI-water에 2000배 희석하여 SiO2 기판 위에 뿌린 뒤 Methanol을 이용하여 기판 표면에 촉매가 붙어있게 한다. 이 기판을 $900^{\circ}C$로 가열하여 유기물질을 제거한 뒤 화학 기상 증착(Chemical Vapor Deposition)방법으로 SWCNT를 성장하게 된다. 이렇게 성장된 SWCNT는 촉매의 농도에 비례하는 밀도를 가지게 되며 이 위에 전극을 증착하고 back-gate를 설치하여 FET를 제작한다. 메탈릭한 SWCNT는 breakdown 공정을 통하여 제거한 뒤, 전자 농도가 높은 NADH를 전체적으로 코팅을 한다. NADH는 기존의 다른 폴리머(polyethyleneimine: PEI)에 비교하여 코팅 후 전자 제공 효과가 크며 그 성질의 재현성이 높고 공기 중에서 안정성을 유지하는 능력이 있다. 이러한 NADH의 코팅으로 n-type으로의 SWCNT FET를 제작하였으며 type conversion 현상을 이용하면 국부적인 NADH의 코팅으로 homojunction-diode의 제작 등 다양한 소자의 제작에 적용될 것으로 예상한다.

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Synthesis of Nanostructured TiC/Co Composite Powder by the Spray Thermal Conversion Process

  • Lee, Gil-Geun;Ha, Gook-Hyun;Kim, Byoung-Kee
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.418-419
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    • 2006
  • In the present, the focus is on the synthesis of nanostructured TiC/Co composite powder by the spray thermal conversion process using titanium dioxide powder has an average particle size of 50 nm and cobalt nitrate as raw materials. The titanium-cobalt-oxygen based oxide powder prepared by the combination of the spray drying and desalting methods. The titanium-cobalt-oxygen based oxide powder carbothermally reduced by the solid carbon. The synthesized TiC-15wt.%Co composite powder at 1473K for 2 hours had an average particle size of 150 nm.

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Assessment of the influence of coal combustion model and turbulent mixing rate in CFD of a 500 MWe tangential-firing boiler (500 MWe급 접선 연소 보일러 해석시 난류 혼합 속도 및 석탄 연소 모델의 영향 평가)

  • Yang, Joo-Hyang;Kang, Kie-Seop;Ryu, Changkook
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.69-72
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    • 2015
  • Computational fluid dynamics (CFD) modeling of large-scale coal-fired boilers requires a complicated set of flow, heat transfer and combustion process models based on different degrees of simplification. This study investigates the influence of coal devolatilization, char conversion and turbulent gas reaction models in CFD for a tangential-firing boiler at 500MWe capacity. Devolatilization model is found out not significant on the overall results, when the kinetic rates and the composition of volatiles were varied. In contrast, the turbulence mixing rate influenced significantly on the gas reaction rates, temperature, and heat transfer rate on the wall. The influence of char conversion by the unreacted core shrinking model (UCSM) and the 1st-order global rate model was not significant, but the unburned carbon concentration was predicted in details by the UCSM. Overall, the effects of the selected models were found similar with previous study for a wall-firing boiler.

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