• Title/Summary/Keyword: Carbon coated

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Preparation of Carbon-Coated $TiO_2$ at Different Heat Treatment Temperatures and Their Photoactivity

  • Chen, Ming-Liang;Bae, Jang-Soon;Oh, Won-Chun
    • Carbon letters
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    • v.7 no.4
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    • pp.259-265
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    • 2006
  • Carbon-coated $TiO_2$ was prepared by $CCl_4$ solvent mixing method with the different heat treated temperatures (HTTs). Since the carbon layers derived from pitch on the $TiO_2$ particles were porous, the carbon-coated $TiO_2$ sample series showed a good adsorptivity. The values of BET surface areas measured were shown independently on the HTTs. The surface states by SEM present to the characterization of porous texture on the carbon-coated $TiO_2$ sample and carbon distributions on the surfaces. From XRD data, PT700 and PT750 were shown the X-ray diffraction patterns of the anatase $TiO_2$, but PT800 and PT850 were kept anatase-type structure even after heating at $800^{\circ}C$, though small amount of the rutile-type structure appears. The results of EDX microanalyses were observed for each sample show the spectra corresponding to almost all samples similar to C, O and Ti elements with an increase of HTTs. Finally, the excellent photoactivity of carbon-coated $TiO_2$ (especially, PT700 and PT750) could be attributed to the homogeneous coated carbon on the external surface and the structural anatase phase.

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Adsorption of Organic Chemical by Coconut Activated Carbon treated with Zinc Salt (아연염으로 표면처리한 활성탄에 의한 수중 유기화합물의 흡착)

  • 김영규;한진수
    • Journal of environmental and Sanitary engineering
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    • v.10 no.1
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    • pp.132-141
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    • 1995
  • The objectives of this study was to find the effect of zinc salt treated with coconut activated carbon and the effect of humic substance. The bottle- Point technique was used in determining the Freundlich isotherm equation. The adsorptive capacity of granular activated carbon was reduced when humic substance are present. Coconut activated carbon was coated with 0.0001 N zinc chloride decreased the BET surface area but increased the adsorptive capacity more than coconut activated carbon not coated with zinc chloride. The adsorptive capacity of TCE in coconut activated carbon coated with higher concentration of zinc chloride was reduced but increased in the solution containing humic substance when the coconut activated carbon was coated with 0.01 N- zinc chloride. The zinc salt coated with coconut activated carbon did not Increase the adsorptive velocity of coconut activated carbon.

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Oxidation Resistant SiC Coating for carbon/carbon Composites

  • Joo, Hyeok-Jong;Lee, Nam-Joo;Oh, In-Seok
    • Carbon letters
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    • v.4 no.1
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    • pp.24-30
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    • 2003
  • In this study, densified 4D carbon/carbon composites were made from carbon fiber and coal tar pitch through the process of pressure impregnation and carbonization and then followed by carbonization and graphitization. To improve the oxidative resistance of the prepared carbon/carbon composites, the surface of carbon/carbon composites was coated on SiC by the pack cementation method. The SiC coated layer was created by depending on the constitution of pack powder, and reaction time of pack-cementation. The morpology of crystalline and texture of these SiC coated carbon/carbon composites were investigated by XRD, SEM/EDS observation. So the coating mechanism of pack-cementation process was proposed. The oxidative res istance were observed through the air oxidation test, and then the optimal condition of pack cementation was found by them. Besides, the oxidative mechanism of SiC formed was proposed through the observation of SiC coated surface, which was undergone by oxidation test.

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Electrochemical Properties and Structural Analysis of Carbon-Coated Silicon Anode for Lithium Secondary Batteries

  • Kim, Hyung-Sun;Chung, Kyung-Yoon;Cho, Byung-Won
    • Journal of the Korean Electrochemical Society
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    • v.11 no.1
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    • pp.37-41
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    • 2008
  • The effects of carbon-coated silicon anode on the electrochemical properties and structural change were investigated. The carbon-coated silicon powders have been prepared by thermal decomposition under argon/10wt% propylene mixed gas flow at $700^{\circ}C$. The surface and crystal structure of the synthesized materials were examined by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and Raman spectroscopy. Lithium cells with electrodes made from the uncoated and the carbon coated silicon anode were assembled and tested. The carbon-coated silicon particles merged together well after the insertion/extraction of lithium ions, and showed a relatively low irreversible capacity compared with the uncoated silicon particle.

Electrochemical Performance of Carbon Coated LiMn2O4 Nanoparticles using a New Carbon Source

  • Park, Jin Seo;Park, Yong Joon
    • Journal of Electrochemical Science and Technology
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    • v.7 no.2
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    • pp.139-145
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    • 2016
  • The electrochemical performance of carbon-coated LiMn2O4 nanoparticles was reported. The polydopamine layer was introduced as a new organic carbon source. The carbon layer was homogeneously coated onto the surface of the LiMn2O4 nanoparticles because the polymerization process from the dopamine solution (in a buffer solution, pH 8.5) easily and uniformly formed a polydopamine layer. The phase integrity of LiMn2O4 deteriorated during the carbon-coating process due to oxygen loss, although the main structure was maintained. The carbon-coated sample led to improved rate capability because of the effect of the conductive carbon layer. Moreover, the carbon coating also enhanced the cyclic performance. This indicates that the carbon layer may suppress unwanted side reactions with the electrolytes and compensate for the low electronic conductivity of the pristine LiMn2O4.

Effect of Unidirectional Carbon Fiber Sheet Manufacturing Process Using Coated Glass Fiber and Carbon Fiber on Concrete Reinforcement (유리섬유 코팅사와 탄소섬유를 이용한 일방향 탄소섬유시트 제조공정이 콘크리트 보강에 미치는 영향)

  • Kwon, Jieun;Kwon, Sunmin;Chae, Seehyeon;Jeong, Yedam;Kim, Jongwon
    • Textile Coloration and Finishing
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    • v.34 no.3
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    • pp.185-196
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    • 2022
  • In this study, carbon fiber and coated glass fiber are applied to warp and weft fiber in order to reduce the amount of carbon fiber used in carbon fiber fabrics, which are often used for reinforcement of building structures. A low-cost thermoplastic resin was coated on glass fibers to prepare a shape-stabilizing glass fiber. A unidirectional carbon fiber sheet was manufactured using the prepared coated glass fiber and carbon fiber. In order to identify whether it can be used for reinforcing architectural and civil structures, it was attached to a concrete specimen and its mechanical properties were analyzed. The optimum manufacturing conditions for the coated glass fiber were 0.3 mm in diameter of the coating nozzle, the coating temperature was 190 ℃, and the coating speed was 0.3 m/s. 14 mm was optimal for the weft spacing of the coated glass fiber. The flexural strength of the concrete reinforced with the manufactured unidirectional carbon fiber sheet was slightly lower than that of the concrete reinforced with carbon fiber fabric, but it was confirmed that the reinforcement effect was better when the amount of carbon fiber was considered.

Preparation of Anode Material for Lithium Secondary Battery using Pitch-coated Graphite Residue Compounds

  • Ko, Young-Shin;Oh, Won-Chun
    • Carbon letters
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    • v.8 no.3
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    • pp.207-213
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    • 2007
  • The properties and electrochemical characteristics of anode material using pitch-coated graphite residue compounds by heat-treatment at $600^{\circ}C$ for 1 hour were investigated. The distance of layers of pitch-coated graphite residual compounds was 3.3539 ${\AA}$, which was as same as that of graphite. Its electrochemical and charge discharge characteristics were tested according to different four types of carbon material, natural graphite, pitch-coated graphite, amorphous graphite and pitch-coated graphite residual compounds, respectively. So it was shown the best charge-discharge characteristics in all of the samples. For the electrochemical and charge-discharge characteristics, although pitch-coated graphite residual compounds had different carbon contents 70% and 80%, these two samples were shown good electrochemical and charge-discharge characteristics.

The study on the influence of surface cleanness and water soluble salt on corrosion protection of epoxy resin coated carbon steel

  • Shon, MinYoung
    • Corrosion Science and Technology
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    • v.13 no.5
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    • pp.163-169
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    • 2014
  • The corrosion resistance of epoxy-coated carbon steel was evaluated. The carbon steel surface was subjected to different treatment methods such as steel grit blasting and power tool treatment as well as contamination of water soluble salt. To study the effect of the surface treatments and contamination, the topology of the treated surface was observed by confocal microscopy and a pull-off adhesion test was conducted. The corrosion resistance of the epoxy-coated carbon steel was further examined by electrochemical impedance spectroscopy (EIS) combined with immersion test of 3.5 wt% of NaCl solution. Consequently, the surface contamination by sodium chloride with $16mg/m^2$, $48mg/m^2$ and $96mg/m^2$ didn't affect the adhesion strength for current epoxy coated carbon steel and blister and rust were not observed on the surface of epoxy coating contaminated by various concentration of sodium chloride after 20 weeks of immersion in 3.5 wt% NaCl aqueous solutions. In addition, the results of EIS test showed that the epoxy-coated carbon steel treated with steel grit blasting and power tool showed similar corrosion protection performance and surface cleanness such as Sa 3 and Sa 2.5 didn't affect the corrosion protectiveness of epoxy coated carbon steel.

Preparation and characteristics of conducting polymer-coated multiwalled carbon nanotubes for a gas sensor

  • Jang, Woo-Kyung;Yun, Ju-Mi;Kim, Hyung-Il;Lee, Young-Seak
    • Carbon letters
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    • v.12 no.3
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    • pp.162-166
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    • 2011
  • Conducting polymer-coated multiwalled carbon nanotubes (MWCNTs) were prepared by template polymerization in order to enhance their gas sensitivity. This investigation of the conducting polymer phases that formed on the surface of the MWCNTs is based on field-emission scanning electron microscopy images. The thermal stability of the conducting polymer-coated MWCNTs was significantly improved by the high thermal stability of MWCNTs. The synergistic effects of the conducting polymer-coated MWCNTs improve the gas-sensing properties. MWCNTs coated with polyaniline uniformly show outstanding improvement in gas sensitivity to $NH_3$ due to the synergistic combination of efficient adsorption of $NH_3$ gas and variation in the conduction of electrons.

Effects of Carbon-coated SiC Whiskers on the Mechanical Properties of SiC Whisker Reinforced Silicon Nitride Ceramic Composite (SiC 휘스커 강화 질화규소 복합재료의 기계작 성질에 미치는 카본 코팅 SiC 휘스커의 영향)

  • 배인경;이영규;조원승;최상욱;장병국;임실묵
    • Journal of the Korean Ceramic Society
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    • v.36 no.10
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    • pp.1007-1015
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    • 1999
  • The Si3N4 composites reinforced with carbon-coated SiC whiskers were fabricated by hot-pressing at 180$0^{\circ}C$ for 2 hours to examine the effects of carbon-coated whiskers on the mechanical properties of SiC whisker reinforced Si3N4 composites. The flexural strength of the Si3N4 composites and Si3N4 monolith respectively. The weak interfacial bond between carbon-coated SiC whiskers and Si3N4 matrix which enhances the crack deflection and whisker pull-out could contribute to the improvement of mechanical properties of the composites.

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