• Title/Summary/Keyword: Carbon burn-out

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Properties of Activated Carbon Blacks Filled SBR Rubber Composites

  • Ao, Geyou;Hu, Quanli;Kim, Myung-Soo
    • Carbon letters
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    • v.9 no.2
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    • pp.115-120
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    • 2008
  • Rubber reinforcing carbon black N330 was treated by physical activation under $CO_2$ to different degrees of burn-off. The mechanical properties indicating the reinforcement of SBR (Styrene-Butadiene Rubber) vulcanizates filled by activated carbon blacks, such as tensile strength, modulus at 300% strain and elongation at break were determined. During $CO_2$ activation of fresh carbon blacks, the development of microporous structure caused an increase of extremely large specific surface area and the porosity turned out to be an increasing function of the degree of burn-off. The tensile strength and modulus at 300% of activated carbon blacks filled rubber composites were improved at lower loading ratios of 20 and 30 phr, but decreased drastically after 30 phr, which is considered that it might be difficult to get a fully dispersed rubber mixture at higher loading ratios for fillers having very large specific surface areas. However, the Electromagnetic Interference (EMI) shielding effectiveness of SBR rubber composites having activated carbon black at 74% yield were improved at a large extent when compared to those having raw carbon black and increased significantly as a function of increasing loading ratio.

Effect of Post-Heat Treatment on Field Emission Properties for Carbon Nanotube Cathodes (탄소나노튜브 캐소드의 전계방출 특성에 미치는 재열처리의 영향)

  • Ha, Sang-Hoon;Kwon, Na-Hyun;Song, Pung-Keun;Chang, Jiho;Cho, Young-Rae
    • Korean Journal of Metals and Materials
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    • v.48 no.2
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    • pp.180-186
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    • 2010
  • For the application of field emission display (FED), it is essential to develop a carbon nanotube (CNT) cathode with high emission current density. In this study, we developed and demonstrated a post-heat treatment (PHT) process to improve field emission properties of CNT cathodes. Since the PHT is intended to burn out organic materials covering the CNTs, the PHT was carried out by heating samples at a high temperature in an atmosphere. The PHT process is applied for samples processed by surface treatment with an adhesive tape. Compared to samples prior to the PHT, samples after the PHT at $360^{\circ}C$ showed about 17% improvement in emission current density. The major reason for the increased current density is mainly the increased aspect ratio of the CNTs because of the removal of the adhesive organic residues covering the CNTs, which were attached on the CNT surfaces during the surface treatment using the adhesive taping method.

A Study on Application of Combustion Products for Forest Fire Investigation (산불화재 감식을 위한 연소생성물의 응용에 관한 연구)

  • Park, Young-Ju;Lee, Hae-Pyeong
    • Journal of the Korean Society of Safety
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    • v.26 no.4
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    • pp.111-119
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    • 2011
  • This study was designed to provide basic data applicable to fire investigation through consideration of combustion products and propose vulnerability of combustibles through analysis of $CO_2$ emission. In order to achieve these research objectives, characteristics of combustion products such as smoke release rate of each part(raw leaves, branches and barks), $CO_2$ emission and ash production were considered targeting on 6 oak species(Quercus variabilis Blume, Quercus aliena Blume, Quercus serrata, Quercus mongolica Fisch, Quercus dentata Sapling and Quercus acutissima) using cone calorimeter and smoke density tester. As a result, it was found that raw leaves release smoke more relatively than branches and barks, when they burn, and that Quercus variabilis Blume has the highest smoke density. Also, Quercus acutissima released CO and $CO_2$ which are respectively, 6.67 times and 1.43 times more than Quercus variabilis Blume with low $CO_2$ emission. In addition, branches released CO and $CO_2$ more relatively. There was a big difference in ash production among raw leaves(3.1 g), branches(10.5 g) and barks(16.43 g). It was identified that Quercus serrata produces ashes which are nearly 9.95 times more than Quercus variabilis Blume. It demonstrates that Quercus serrata contains relatively higher minerals and that Quercus variabilis Blume can leave lots of traces like stain and carbonization, as it releases smoke a lot and it's difficult to predict visibility, when a forest fire breaks out in its community area. It is also considered that smoke particles containing oil in the air leave strain on the surface of a tree, and that CO and $CO_2$ emission increases, when crown fire to burn branches breaks out.

The Development of High Performance Flame Stability(HPFS) Tangential Coal-Fired Burner (고효율 화염 안정형 접선식 석탄 버너 개발)

  • Kim, Hyeok-Pill;Kim, Sang-Hyeun;Kim, Hyuk-Je;Song, Si-Hong
    • Journal of the Korean Society of Combustion
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    • v.11 no.2
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    • pp.1-6
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    • 2006
  • This report presents a study of the development of an advanced coal nozzle used in burners to reduce unburned carbon (UBC) in a tangential coal-fired boiler. To understand the mechanism of UBC reduction, experiments using conventional burners were carried out to evaluate the effects of air injection velocity, coal fineness and over fired air (OFA) on combustion efficiency. It was confirmed that ignition of pulverized coal particles close to the burner is helpful toward the complete burn of residual carbon in fly ash. These efforts indicated the additional results that UBC was strongly dependent on the primary air velocity and coal fineness; especially that UBC dramatically decreased when the weight fraction of pulverized coal under $75{\mu}m$ was over 85 %. New coal nozzles, modified from conventional nozzles, were prepared and tested to improve the combustion efficiency. Some of these nozzles offered relatively lower unburned carbon than those of conventional burners and are referred to as HPFS (High Performance Flame Stability) coal nozzles.

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Methanol Electro-Oxidation Properties of Pt Electro-Catalysts Embedded by Porous Carbon Nanofiber Supports (다공성 탄소나노섬유 지지체에 담지된 백금촉매의 메탄올 산화 특성 연구)

  • Sin, Dong-Yo;An, Geon-Hyoung;Ahn, Hyo-Jin
    • Korean Journal of Materials Research
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    • v.25 no.3
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    • pp.113-118
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    • 2015
  • To improve the methanol electro-oxidation in direct methanol fuel cells(DMFCs), Pt electrocatalysts embedded on porous carbon nanofibers(CNFs) were synthesized by electrospinning followed by a reduction method. To fabricate the porous CNFs, we prepared three types of porous CNFs using three different amount of a styrene-co-acrylonitrile(SAN) polymer: 0.2 wt%, 0.5 wt%, and 1 wt%, respectively. A SAN polymer, which provides vacant spaces in porous CNFs, was decomposed and burn out during the carbonization. The structure and morphology of the samples were examined using field emission scanning electron microscopy and transmission electron microscopy and their surface area were measured using the Brunauer-Emmett-Teller(BET). The crystallinities and chemical compositions of the samples were examined using X-ray diffraction and X-ray photoelectron spectroscopy. The electrochemical properties on the methanol electro-oxidation were characterized using cyclic voltammetry and chronoamperometry. Pt electrocatalysts embedded on porous CNFs containing 0.5 wt% SAN polymer exhibited the improved methanol oxidation and electrocatalytic stability compared to Pt/conventional CNFs and commercial Pt/C(40 wt% Pt on Vulcan carbon, E-TEK).

A Study on the Mechanical Properties of the Friction Welding with Solid Shaft of SM45C (SM45C 중실축의 마찰용접 기계적 특성에 관한 연구)

  • Koo, Keon Seop
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.21 no.6
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    • pp.932-937
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    • 2012
  • In the presented study, SM45C carbon steel parts were joined by friction welding. The welding process was carried out under optimized conditions using statistical approach. The study of SM45C is conducted with various combinations of process parameters. Parameter optimization, microstructure and mechanical property correlation are the major contribution of the study. The welded joints were produced by varying spindle revolution speed, friction pressure, upset pressure and burn-off length. Tension tests were applied to welded parts to obtain the strength of the joints. Fracturs properties were additionally obtained experimentally under fluctuated tensile loads. Microstructures using microphotographs were examined in the weld interface and weld region and heat affected zone and base metal and flash zone of welded parts. Finally, Hardness variations in welding zone and base metal were also obtained. Through these tests, the optimum conditions of parameters for ${\phi}20$ SM45C in friction welding were obtained when the friction spindle revolution was 1,950 rpm, the friction pressures was 30 MPs, upset pressures was 50 MPs.

Effect of Using Burn-type CO2 Generators When Cultivation Strawberry in a Greenhouse (딸기재배 시 연소식 탄산가스 발생기 이용 효과 구명)

  • Lee, Jae Han;Lee, Jung Sup;Park, Kyoung Sub;Kwon, Joon Kook;Kim, Jin Hyun;Lee, Dong Soo;Yeo, Kyung Hwan
    • Journal of Bio-Environment Control
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    • v.27 no.2
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    • pp.111-116
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    • 2018
  • This study were carried out to evaluate the efficiency of using burn-type $CO_2$ generators in greenhouse for cultivation 'Seolhyang' strawberry ($Fragaria{\times}ananassa\;Duch.$) during winter season. The concentration of $CO_2$ was 200 to $600{\mu}mol{\cdot}mol^{-1}$ in the control, and 800 to $1,100{\mu}mol{\cdot}mol^{-1}$ in using burn-type $CO_2$ generator between 6 and 11 hours. At other times, it was observed that at similar concentration in the control and using burn-type $CO_2$ generator. Measured greenhouse air temperature inside the of using burn-type $CO_2$ generator was $2{\sim}3^{\circ}C$ higher than the control at 6 ~ 10 am. There was no temperature difference between treatments after 11 o'clock. Plant height, leaf length, leaf width, root diameter, fresh weight, and dry weight were not different between treatments. The marketable yield (kg/10a) of using burn-type generator were 4,131 kg, which was 519 kg higher than the control. Therefore, the total fruit yields increased 17% compared to the control.

Fabrication of Porous Ceramics for Microorganism Carrier by Hydrothermal Reaction (수열반응을 이용한 미생물 담체용 다공성 세라믹스의 제조)

  • 양성구;정승화;강종봉
    • Journal of the Korean Ceramic Society
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    • v.40 no.12
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    • pp.1213-1219
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    • 2003
  • Porous ceramics for microoganism carriers were prepared with amorphous alumina and pore formers by hydrothermal reaction, burn-out and wash-out method. Activated carbon with average size of 67,222, and 405 $\mu\textrm{m}$, organic polymer and inorganic salt were used as pore formers. Specimens were hydrothermally treated at 200$^{\circ}C$ for 24 h, heat-treated at 650$^{\circ}C$ for 5 h, and washed out at 80$^{\circ}C$ for 48 h. The formation of crystalline phase, porosity, pore size distribution and compressive strength were measured. The specimen with activated carbon was transformed to boehmite phase, but organic polymer and inorganic salt inhibited the aquohydroxoy complex gel and crystalline formation. The porous ceramics for microoganism carriers using activated carbon as a pore formers was successfully prepared, which is composed of ${\gamma}$-alumina phase with porosity of above 70 vol% and the compressive strength of 40 kgf/$\textrm{cm}^2$.

Combustion Characteristics of Imported Bituminous & Subbituminous Coal in a Pilot Scale Test Facility (발전용 역청탄 및 아역청탄의 파일롯 연소특성 평가)

  • Kim, Hyunhee;Park, Hoyoung;Lim, Hyunsoo;Baek, Sehyun;Kim, Taehyung;Kim, Youngju;Gong, Jiseon;Lee, Jeongeun
    • Journal of Energy Engineering
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    • v.23 no.4
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    • pp.207-214
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    • 2014
  • With the depletion of high grade coal, it is indispensable to be used co-combustion of low rank coal with bituminous coal in pulverized coal-fired power plants. This study describes the detailed measurements of combustion characteristics of bituminous and subbituminous coal in a 0.7MWth pilot-scale test facility. This experimental works include the measurement of gas temperature, gas concentrations along with the reactor axial and radial distance at the condition of excess air ratio of 1.2. The solid sampling was carried out and analyzed with the combustion of bituminous coal. The main reaction zone of coal flame in a reactor was formed about 1 m from the swirl burner, and at downstream, the fully developed temperature and species distribution was observed. The sampled particles of bituminous coal in a reactor revealed the complete carbon burn-out was achieved just after an main combustion zone.

Micro-Spot Atmospheric Pressure Plasma Production for the Biomedical Applications

  • Hirata, T.;Tsutsui, C.;Yokoi, Y.;Sakatani, Y.;Mori, A.;Horii, A.;Yamamoto, T.;Taguchi, A.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.44-45
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    • 2010
  • We are currently conducting studies on culturing and biocompatibility assessment of various cells such as neural stem cells and induced pluripotent stem cells(IPS cells) on carbon nanotube (CNT), on nerve regeneration electrodes, and on silicon wafers with a focus on developing nerve integrated CNT based bio devices for interfacing with living organisms, in order to develop brain-machine interfaces (BMI). In addition, we are carried out the chemical modification of carbon nanotube (mainly SWCNTs)-based bio-nanosensors by the plasma ion irradiation (plasma activation) method, and provide a characteristic evaluation of a bio-nanosensor using bovine serum albumin (BSA)/anti-BSA binding and oligonucleotide hybridization. On the other hand, the researches in the case of "novel plasma" have been widely conducted in the fields of chemistry, solid physics, and nanomaterial science. From the above-mentioned background, we are conducting basic experiments on direct irradiation of body tissues and cells using a micro-spot atmospheric pressure plasma source. The device is a coaxial structure having a tungsten wire installed inside a glass capillary, and a grounded ring electrode wrapped on the outside. The conditions of plasma generation are as follows: applied voltage: 5-9 kV, frequency: 1-3 kHz, helium (He) gas flow: 1-1.5 L/min, and plasma irradiation time: 1-300 sec. The experiment was conducted by preparing a culture medium containing mouse fibroblasts (NIH3T3) on a culture dish. A culture dish irradiated with plasma was introduced into a $CO_2$-incubator. The small animals used in the experiment involving plasma irradiation into living tissue were rat, rabbit, and pick and are deeply anesthetized with the gas anesthesia. According to the dependency of cell numbers against the plasma irradiation time, when only He gas was flowed, the growth of cells was inhibited as the floatation of cells caused by gas agitation inside the culture was promoted. On the other hand, there was no floatation of cells and healthy growth was observed when plasma was irradiated. Furthermore, in an experiment testing the effects of plasma irradiation on rats that were artificially given burn wounds, no evidence of electric shock injuries was found in the irradiated areas. In fact, the observed evidence of healing and improvements of the burn wounds suggested the presence of healing effects due to the growth factors in the tissues. Therefore, it appears that the interaction due to ion/radicalcollisions causes a substantial effect on the proliferation of growth factors such as epidermal growth factor (EGF), nerve growth factor (NGF), and transforming growth factor (TGF) that are present in the cells.

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