• Bulletin of the Korean Chemical Society
• /
• v.32 no.3
• /
• pp.939-942
• /
• 2011

Conductive carbon films were prepared at room temperature by unbalanced magnetron sputtering (UBMS) on silicon substrates using argon (Ar) gas, and the effects of post-annealing temperature on the structural, tribological, and electrical properties of carbon films were investigated. Films were annealed at temperatures ranging from $400^{\circ}C$ to $700^{\circ}C$ in increments of $100^{\circ}C$ using a rapid thermal annealing method by vacuum furnace in vacuum ambient. The increase of annealing temperature contributed to the increase of the ordering and formation of aromatic rings in the carbon film. Consequently, with increasing annealing temperature the tribological properties of sputtered carbon films are deteriorated while the resistivity of carbon films significantly decreased from $4.5{\times}10^{-3}$ to $1.0{\times}10^{-6}\;{\Omega}-cm$ and carrier concentration as well as mobility increased, respectively. This behavior can be explained by the increase of sp2 bonding fraction and ordering $sp^2$ clusters in the carbon networks caused by increasing annealing temperature.

• Journal of Surface Science and Engineering
• /
• v.33 no.2
• /
• pp.69-76
• /
• 2000

The rf plasma chemical vapor deposition is a common method employed for diamond or amorphous carbon deposition. Diamond possesses the strongest bonding, as exemplified by a number of unique properties-extraordinary hardness, high thermal conductivity, and a high melting tempera tore. Therefore, it is very important to investigate the synthesis of semiconducting diamond and its use as semiconductor devices. An inductively coupled rf plasma CVD system for producing amorphous carbon films were developed. Uniform temperature and concentration profiles are requisites for the deposition of high quality large-area films. The system consists of rf matching network, deposition chamber, pumping lines for gas system. Gas mixtures with methane, and hydrogen have been used and Si (100) wafers used as a substrate. Amorphous carbon films were deposited with methane concentration of 1.5% at the process pressure of S torr~20 torr, and process temperature of about $750^{\circ}C$. The nucleation and growth of the amorphous carbon films have been characterized by several methods such as SEM and XRD.

• The Korean Journal of Ceramics
• /
• v.3 no.2
• /
• pp.96-100
• /
• 1997

Hydrogenated amorphous carbon films were deposited on silicon substrates by using an RF PECVD. The hydrogen/methane ratio was varied from 50% to 88% to study the effect of hytdrogen in the film on the tribological properties. The friction and wear behaviors of the deposited films were investigated by ball-on-disk type wear tester. FT-IR spectra were used to characterize the structure of the films. Tribological properties of carbon films were correlated with their structure such as ratio of "polymer-like" stretching type and that of sp2 bonding. The result showed that the annealing caused a decrease in the amount of wear of contacted $Si_3N_4$ balls and a increase in the coefficient of friction. Possible explanation for annealing effect was discussed by the hydrogen desorption.esorption.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 1995.11a
• /
• pp.198-201
• /
• 1995

Carbons are the materials which are known to be usable at highest temperature in existing materials and are being increased their mechanical Properties to 2000$^{\circ}C$. They have many advantageous characteristics such as electrical and thereat conductivity. But, inspire of their properties, this materials have covalant bonding that strong1y link their atoms. the covalant bondings are too strong to occur atomic diffusions or shirinkages during the sintering. because of this sintering mechanism, carbon materials must be produced by using some binders. To obtain a good carton material, it is important that the function of binders. And to obtain a good binder, it reqired the additive which can improve the properties of the binder, so called curing agent. In this study, we make a curing agent that can improve the properties of binders to evaluate the yield of carbon from binders and to shirink the substrate. and compared the carbon materials treated with the binder containing the curing agent to that treated with common binder.

• Carbon letters
• /
• v.13 no.3
• /
• pp.187-189
• /
• 2012

This study investigates the flexural properties of multi-walled carbon nanotube (MWCNT) reinforced basalt/epoxy composites under conditions with and without moisture absorption. The basalt/CNT/epoxy composites were fabricated using 1 wt% silanized MWCNTs and kept in seawater for over 4 months. The flexural properties of the moisture absorbed specimens were evaluated and compared with those of dry specimens. The flexural properties of basalt/CNT/epoxy composites were found to decrease with moisture absorption. The flexural strength and modulus of moisture absorbed specimens were 22% and 16% lower, respectively, than those of the dry specimen. Scanning electron microscope examination of the fracture surfaces revealed that the decreases of flexural properties in the moisture absorbed specimen were due to the weakening of interfacial bonding from swelling of the epoxy matrix.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1997.10a
• /
• pp.450-455
• /
• 1997

In recent years the research and development about the new material proceeds rapidly and actively in building industry. We are concerned with high-strength concrete as a new material. As the building structure becomes bigger, higher and more specialized, so does the demand of material and member with high strength for building expands greatly. In the future, we will quite need to research repair and rehabilitation to make high strength concrete structural building for our safe. So, I did an study on carbon fiber sheet rehabilitation(CFSR) of reinforced high strength concrete beams. The carbon fiber reinforced plastic(CFRP) bonding method is widely used for reinforcing the existing concrete structure among the various methods. The test results indicate that CFS is very effective for strengthening the damaged beams and controlling deflections of the repaired beams. When carbon fiber sheet rehabilitation of reinforced high strength concrete beams happened diagonal crack, the increase in the number of CFS layer didn't effect the increase in strength of beams. Also, by changing the CFS stick position gave diversified ultimate load in CFSR beams.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2004.04b
• /
• pp.60-63
• /
• 2004

Recently, carbon nanotubes(CNTs) have been demonstrated to possess remarkable mechanical and electronic properties, in particular, for field emission applications. Its high aspect ratio and extremely small diameter, hollowness, together with high mechanical strength and high chemical stability, are advantages for use in field emitter. In this paper, we demonstrate electrical discharge properties from carbon nanotube cathode electrodes to use as an emitter electrode of vacuum gauges. Vertically aligned $2{\times}2mm^2$ CNT arrays on the silicon substrate were synthesized by the thermal CVD method on Fe catalytic metal, and a glass patterning by the sand blast method and the silicon/glass anodic bonding processes were applied to make samples with 2 electrodes. The field emission was examined under the vacuum range of $10^{-3}$ Torr.

• Carbon letters
• /
• v.1 no.2
• /
• pp.87-90
• /
• 2000

Porous carbon from charcoal filled polypropylene composites were prepared and their mechanical properties were evaluated. In preparing the composites, crosslinking agent (sodium benzonate) were used in order to improve the bonding force between matrix and fillers. In this study, the effects of charcoal powder and sodium benzonate concentration on the mechanical properties and interface phenomena on the composites were evaluated. The mechanical properties of composites increased progressively with the decrease of filler loading. In the case of addition of the crosslinking agent into the composite, the mechanical properties were increased and showed maximum value at the 3 wt% concentration of sodium benzonate. According to the result of the TGA, the weight loss of composite according to crosslinking agent was not observed and initial thermal degradation temperature of composite reinforced charcoal was located at $390^{\circ}C$.

• Proceedings of the KSR Conference
• /
• 2009.05a
• /
• pp.574-580
• /
• 2009

This study is investigate the bending behavior of real size RC beams strengthened with carbon fiber sheets. For experimental study, 1 control beam and 8 strengthened beams of real size(4 NU-beams and 4 U-beams) are tested and compared. NU-beam has not a V-shaped band and V-beam has a V-shaped band. The variables of experiment are composed of the number of carbon fiber sheets, the existence of U-shaped band, and four point loading, etc. The experimental results showed that the strengthening system with U-shaped band controls the premature debonding and provides a more ductile failure mode than the strengthening system without V-shaped band. It can be found from the load-deflection curves that as the number of fiber sheets is increased, the maximum strength and the flexural rigidity is increased. For the strengthening method with carbon fiber sheets of the real size RC beams, it is required the finding a solution to the bonding problem.

• Journal of the Korean Chemical Society
• /
• v.61 no.1
• /
• pp.7-11
• /
• 2017

The extended $H{\ddot{u}}ckel$ method is employed to analyze the interaction of carbon monoxide with the TiC(001) surfaces, both perfect and containing carbon vacancies. CO exhibits a similar ${\sigma}$-donation interaction for both $Ti_{25}C_{25}$ and $Ti_{25}C_{23}$ clusters, as deduced from the fact that the populations of the CO $5{\sigma}$ orbital are identical upon adsorption, but it bonds more strongly with the $Ti_{25}C_{23}$ than with the $Ti_{25}C_{25}$ because the metal d electron density in $Ti_{25}C_{23}$ provides ${\pi}$ back-bonding interactions with CO that are absent in $Ti_{25}C_{25}$. This work suggests that a difference in reactivity toward CO of stoichiometric TiC and TiC with carbon defects is connected with the occupancy of $2{\pi}^*$ orbitals that leads to a significant weakening of the C-O bond.