• Title/Summary/Keyword: Carbon block

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The Effect of Fluorination on Wettability between Cokes and Binder Pitch for Carbon Block with High Density (고밀도 탄소블럭 제조를 위한 코크스와 바인더피치의 젖음성에 미치는 불소화의 영향)

  • Kim, Kyung Hoon;An, Donghae;Kim, Ji Wook;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.29 no.6
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    • pp.677-681
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    • 2018
  • In this study, the carbon block was prepared using the fluorinated coke and binder pitch by molding compression to increase its density. After fluorination, it is confirmed that the fluorine element on the coke surface was introduced up to 24.14 at% using XPS analysis. The wettability between the fluorinated coke and binder pitch was evaluated according to the reaction temperature. From the result of contact-angle tests, it can be found that the wettability was improved up to 64.7% as more fluorine atoms were introduced on the surface of cokes. Also, the density of the carbon block with the highest amount of fluorine increased with 6.8% compared to that of using the carbon block prepared by the untreated cokes.

Conductive Carbon Block filled Composite(I): The Effect of Carbon Block on the Conductivity (전도성 카본블랙이 충전된 도전성 고분자 복합재료(I): 카본블랙이 전기전도성에 미치는 영향)

  • Kim, Jin-Kuk
    • Elastomers and Composites
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    • v.33 no.5
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    • pp.355-362
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    • 1998
  • The purpose of this paper is to develop a rational engineering conductive carbon filled composite through understanding of the effect of conductive carbon black. Polycabonate(PC), Acrylonitrile Butadiene Styrene copolymer(ABS) and PC/ABS resin were used as matrix of the conductive polymer composites. From the experimental results, PC filled with the fiber shaped carbon black showed a possibility to be a rational engineering conductive composite.

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Performance Evaluation of Eco-friendly Permeable Block Using Basalt Waste Rock (현무암 폐석을 이용한 친환경 투수블록의 성능평가)

  • Sang-Soo Lee;Hyeong-Soon Kwon;Jae-Hwan Kim
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.299-306
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    • 2023
  • Environmental pollution problems are occurring due to the negative treatment of basalt waste in Jeju Island. This study identifies the characteristics of permeable block with basalt with physical and chemical adsorption mechanisms and examines their applicability and functionality as building materials. This experiment is basic data for evaluating the functionality of the permeable block by analyzing flexural strength, compressive strength, permeability coefficient, carbon dioxide, and fine dust adsorption rate by producing a permeable block using a basalt waste rock. As the basalt waste stone replacement rate increased, the flexural strength and compressive strength tended to decrease, and as the replacement rate increased, the water permeability coefficient, absorption rate, carbon dioxide, and fine dust adsorption rate tended to increase. Therefore, it is judged that the permeable block using the basalt waste rock is superior to the existing permeable block.

Does CO2 and Its Possible Determinants are Playing Their Role in the Environmental Degradation in Turkey. Environment Kuznets Curve Does Exist in Turkey.

  • RAHMAN, Zia Ur
    • Journal of Wellbeing Management and Applied Psychology
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    • v.2 no.2
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    • pp.19-37
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    • 2019
  • Over the last few decades, the atmospheric carbon dioxide emission has been amplified to a great extent in Turkey. This amplification may cause global warming, climate change and environmental degradation in Turkey. Consequently, ecological condition and human life may suffer in the near future from these indicated threats. Therefore, an attempt was made to test the relationship among a number of expected factors and carbon dioxide emissions in the case of Turkey. The study covers the time series data over the period of 1970-2017. We employed the modern econometric techniques such as Johansen co-integration, ARDL bound testing approach and the block exogeneity. The results of the Johansen co-integration test show that there is a significant long-run relationship between carbon dioxide emissions and expected factors. The long-run elasticities of the ARDL model show that a 1% increase in the GDP per capita, electric consumption, fiscal development and trade openness will increase carbon dioxide emissions by 0.14, 0.52, 0.09 and 0.20% respectively. Further, our findings reveal that the environmental Kuznets curve (EKC) hypothesis and inverted U-shaped relationship between carbon dioxide emission and economic growth prevails. Therefore, the EKC hypothesis is valid and prevailing in the Turkish economy. The diagnostic test results show that the parameters of the ARDL model are credible, sTable and reliable in the current form. Finally, Block exogeneity analysis displays that all the expected factors are contributing significantly to carbon dioxide emissions in the Turkish economy.

A study on elemental mercury adsorption behaviors of nanoporous carbons with carbon dioxide activation

  • Bae, Kyong-Min;Park, Soo-Jin
    • Carbon letters
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    • v.15 no.4
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    • pp.295-298
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    • 2014
  • In this work, nanoporous carbons (NPCs) were prepared by the self-assembly of polymeric carbon precursors and block copolymer template in the presence of tetraethyl orthosilicate and colloidal silica. The NPCs' pore structures and total pore volumes were analyzed by reference to $N_2$/77 K adsorption isotherms. The porosity and elemental mercury adsorption of NPCs were increased by activation with carbon dioxide. It could be resulted that elemental mercury adsorption ability of NPCs depended on their specific surface area and micropore fraction.

Fabrication of High Permeable Nanoporous Carbon-SiO$_2$ Membranes Derived from Siloxane-containing Polyimides

  • Kim, Youn Kook;Han, Sang Hoon;Park, Ho Bum;Lee, Young Moo
    • Korean Membrane Journal
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    • v.6 no.1
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    • pp.16-23
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    • 2004
  • The silica containing carbon (C-SiO$_2$) membranes were fabricated using poly(imide siloxane) (PIS) having -CO- swivel group. The characteristics of porous C-SiO$_2$ structures prepared by the pyrolysis of poly(imide siloxane) were related with the micro-phase separation between the imide block and the siloxane block. Furthermore, the nitrogen adsorption isotherms of the CMS and the C-SiO$_2$ membranes were investigated to define the characteristics of porous structures. The C-SiO$_2$ membranes derived from PIS showed the type IV isotherm and possessed the hysteresis loop, which was associated with the mesoporous carbon structures, while the CMS membranes derived from PI showed the type I isotherm. For the molecular sieving probe, the C-SiO$_2$ membranes pyrolyzed at 550, 600, and 700$^{\circ}C$ showed the O$_2$ permeability of 924, 1076, and 367 Barrer (1 ${\times}$ 10$\^$-10/㎤(STP)cm/$\textrm{cm}^2$$.$s$.$cmHg) and O$_2$/N$_2$ selectivity of 9, 8, and 12.

Effect of β-Resin of Petroleum-based Binder Pitch on Density of Carbon Block (석유계 바인더 피치의 β-resin이 탄소블럭의 밀도에 미치는 영향)

  • Kim, Kyung Hoon;Lee, Sangmin;An, Donghae;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.28 no.4
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    • pp.432-436
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    • 2017
  • Carbon blocks were prepared by compression molding process using the mixture of isotropic cokes and binder pitches, which were reformed with different ${\beta}$-resin contents from pyrolysis fuel oil. Physical and chemical properties and also thermal behavior of binder pitches were investigated through elemental analysis, FT-IR and thermogravimetric analysis, respectively. The adhesion of binder pitches to isotropic coke particles was evaluated from SEM images of the fracture surface of carbon blocks. From these results, it is shown that the adhesion between the cokes and binder was enhanced by increasing the ${\beta}$-resin content of binder pitches. The density of the carbon block after carbonization also increased from 1.325 to $1.383g/cm^3$ by increasing the ${\beta}$-resin content of binder pitches from 1.4 to 20.1%.

Low energy and area efficient quaternary multiplier with carbon nanotube field effect transistors

  • Rahmati, Saeed;Farshidi, Ebrahim;Ganji, Jabbar
    • ETRI Journal
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    • v.43 no.4
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    • pp.717-727
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    • 2021
  • In this study, new multiplier and adder method designs with multiplexers are proposed. The designs are based on quaternary logic and a carbon nanotube field-effect transistor (CNTFET). The design utilizes 4 × 4 multiplier blocks. Applying specific rotational functions and unary operators to the quaternary logic reduced the power delay produced (PDP) circuit by 54% and 17.5% in the CNTFETs used in the adder block and by 98.4% and 43.62% in the transistors in the multiplier block, respectively. The proposed 4 × 4 multiplier also reduced the occupied area by 66.05% and increased the speed circuit by 55.59%. The proposed designs are simulated using HSPICE software and 32 nm technology in the Stanford Compact SPICE model for CNTFETs. The simulated results display a significant improvement in the fabrication, average power consumption, speed, and PDP compared to the current bestperforming techniques in the literature. The proposed operators and circuits are evaluated under various operating conditions, and the results demonstrate the stability of the proposed circuits.

Flexural Behaviors of 4D Carbon/carbon Composites with the Preform Architectures

  • Lee, Ki-Woong;Park, Jong-Min;Joo, Hyeok-Jong
    • Carbon letters
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    • v.9 no.1
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    • pp.28-34
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    • 2008
  • Multidirectional reinforcement is aimed primarily at overcoming interlaminar weakness, hence a major interest lies in the mechanical properties of multidirectional carbon/carbon composites. Mechanical properties depend on the type of carbon fiber, the size of the fiber bundle, the spacing of the bundles, the angles of the bundles relative to the axes of the block, and matrix formation. In the present studies, PAN based carbon fiber preforms manufactured different size of unit cell have been prepared. Densification of these used high pressure infiltration and carbonization technique with coal tar pitch as matrix precursor was carried out. Scanning electron microscopy has been used to study the fracture behavior of composites. The size of unit cell of the preforms has considerably affected on the flexural properties as well as microstructure of the carbon/carbon composites.