• Title/Summary/Keyword: Carbon Zero

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A Comparative Study for Steam-Methane Reforming Reaction Analysis Model (수증기-메탄개질반응 해석모델의 비교연구)

  • Choi, Chong-Gun;Chung, Tae-Yong;Nam, Jin-Hyun;Shin, Dong-Hoon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.7
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    • pp.497-503
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    • 2008
  • Hydrogen is considered as a fuel of the future for its renewability and environmental compatibility. The reforming of hydrocarbon fuels is currently the most important source of hydrogen, which is expected to continue for next several decades. In this study, extensive CFD simulations on the steam-methane reforming process were conducted to study the performance of four reaction models, i.e. three Arrhenius-type models and a user-defined function (UDF) model. The accuracies of different reaction models for various operating temperatures and steam carbon ratios (SCRs) were evaluated by comparing their CFD results with zero-dimensional intrinsic model of Xu and Froment. It was found that the UDF model generally produced more accurate results than Arrhenius-type models. However, it was also shown that Arrhenius-type models could be made sufficiently accurate by choosing appropriate reaction coefficients, and thus could also be useful for the simulation of the steam-methane reforming process.

Nitrogen Removal Comparison in Porous Ceramic Media Packed-Bed Reactors by a Consecutive Nitrification and Denitrification Process

  • Han, Gee-Bong;Woo, Mi-Hee
    • Environmental Engineering Research
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    • v.16 no.4
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    • pp.231-236
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    • 2011
  • Biological nitrogen removal, using a continuous flow packed-bed reactor (CPBR) in a consecutive nitrification and denitrification process, was evaluated. An apparent decline in the nitrification efficiency coincided with the steady increase in $NH_4{^+}$-N load. Sustained nitrification efficiency was found to be higher at longer empty bed contact times (EBCTs). The relationship between the rate of alkalinity consumption and $NH_4{^+}$-N utilization ratio followed zero-order reaction kinetics. The heterotrophic denitrification rate at a carbon-tonitrogen (C/N) ratio of >4 was found to be >74%. This rate was higher by a factor of 8.5 or 8.9 for $NO_3{^-}$-N/volatile solids (VS)/day or $NO_3{^-}-N/m^3$ ceramic media/day, respectively, relative to the rates measured at a C/N ratio of 1.1. Autotrophic denitrification efficiencies were 80-90%. It corresponds to an average denitrification rate of 0.96 kg $NO_3{^-}-N/m^3$ ceramic media/day and a relevant average denitrification rate of 0.28 g $NO_3{^-}$-N/g VS/day, were also obtained. Results presented here also constitute the usability of an innovative porous sulfur ceramic media. This enhanced the dissolution rate of elemental sulfur via a higher contact surface area.

Environmental analysis of present and future fuels in 2D simple model marine gas tubines

  • El Gohary, M. Morsy
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.5 no.4
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    • pp.559-568
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    • 2013
  • Increased worldwide concerns about fossil fuel costs and effects on the environment lead many governments and scientific societies to consider the hydrogen as the fuel of the future. Many researches have been made to assess the suitability of using the hydrogen gas as fuel for internal combustion engines and gas turbines; this suitability was assessed from several viewpoints including the combustion characteristics, the fuel production and storage and also the thermodynamic cycle changes with the application of hydrogen instead of ordinary fossil fuels. This paper introduces the basic environmental differences happening when changing the fuel of a marine gas turbine from marine diesel fuel to gaseous hydrogen for the same power output. Environmentally, the hydrogen is the best when the $CO_2$ emissions are considered, zero carbon dioxide emissions can be theoretically attained. But when the $NO_x$ emissions are considered, the hydrogen is not the best based on the unit heat input. The hydrogen produces 270% more $NO_x$ than the diesel case without any control measures. This is primarily due to the increased air flow rate bringing more nitrogen into the combustion chamber and the increased combustion temperature (10% more than the diesel case). Efficient and of course expensive $NO_x$ control measures are a must to control these emissions levels.

Hydrogen Generation Characteristics of SMART System with Inherent $CO_2/H_2$ Separation ($CO_2/H_2$ 원천분리 SMART 시스템의 수소생산특성)

  • Ryu, Ho-Jung
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.4
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    • pp.382-390
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    • 2007
  • To check the feasibility of SMART(Steam Methane Advanced Reforming Technology) system, an experimental investigation was performed. A fluidized bed reactor of diameter 0.052m was operated cyclically up to 10th cycle, alternating between reforming and regeneration conditions. FCR-4 catalyst was used as the reforming catalyst and calcined limestone(domestic, from Danyang) was used as the $CO_2$ absorbent. Hydrogen concentration of 98.2% on a dry basis was reached at $650^{\circ}C$ for the first cycle. This value is much higher than $H_2$ concentration of 73.6% in the reformer of conventional SMR (steam methane reforming) condition. The hydrogen concentration decreased because the $CO_2$ capture capacity decreased as the number of cycles increased. However, the average hydrogen concentration at 10th cycle was 82.5% and this value is also higher than that of SMR. Based on these results, we could conclude that the SMART system can replace SMR system to generate pure hydrogen without HTS (high tempeature shift), LTS (low temperature shift) and $CO_2$ separation process.

The Study on the Global Emission Reduction Commitments and Environment Change After Climate Agreement (기후협정후의 배출감소와 환경변화이행에 관한 연구)

  • Kim, Kyung-Woo
    • Journal of the Korea Society of Computer and Information
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    • v.19 no.12
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    • pp.319-328
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    • 2014
  • Although most of the debate on global climate change policy has focused on quantity controls due to their political appeal, this paper argues that agreement commitment are more efficient. Scenarios show that to have a likely chance of limiting the increase in global mean temperature to two degrees Celsius, means lowering global greenhouse gas emissions by 40 to 70 percent compared with 2010 by mid-century, and to near-zero by the end of this century. Ambitious mitigation may even require removing carbon dioxide from the atmosphere. This paper emphasizes on global cooperation which is a key for preventing global warming and toward sustainable development, and fair emission reduction targets among countries are significant for achieving emission reductions.

Study on the Characterization of the Methane Stream Reforming in the High Pressure Using Reforming Catalyst (개질촉매를 이용한 고압에서 메탄 수증기 개질 특성연구)

  • 조종훈;백일현
    • Journal of Energy Engineering
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    • v.12 no.2
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    • pp.145-153
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    • 2003
  • In order to develop the carbonation process as a core technology of zero emission coal power plant, study on characterization of methane steam reforming (MSR) which is main reaction of this process was carried out. The effects of gas hourly space velocity (GHSV), steam/carbon (S/C) ratio and pressure in the MSR using reforming catalyst were investigated. The equilibrium composition of the gases produced in the MSR were obtained below GHSV 7,000 hr$\^$-1/. The operating conditions of carbonation process using hybrid reaction (MSR+CO$_2$ adsorption using CaO) were 700∼800$^{\circ}C$ and S/C ratio of 2.5∼3. The equilibrium mixture of gases composed of 75∼78% H$_2$ and 8∼9% CO$_2$ at atmospheric pressure and 60∼78% H$_2$ and 9∼l1% CO$_2$ at 1∼30 atm respectively under above operating conditions.

Local activation using traditional knowledge and ecological resources of Korean islands

  • Hong, Sun-Kee
    • Journal of Ecology and Environment
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    • v.38 no.2
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    • pp.263-269
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    • 2015
  • When we consider changes in agro-fishery systems instigated by environmental changes in islands, rise in sea levels, and natural disasters such as tsunamis, there is an urgent need to carry out initiatives to enhance life standard and conserve ecosystem in island and coastal regions. To protect the region's landscape from the effects of climate change, it is necessary to develop an integrated management system for ecosystem conservation, human settlements, and the local economy. This paper discusses the outline of a preliminary national plan for a sustainable island management system for remote (inhabited and uninhabited) islands in Korea. Two main ideas to enhance life standard are adapting to the natural environment by applying traditional knowledge and utilizing ecological resources of islands, i.e., improving the quality of life and creating added value. As a technique for improving the quality of life, the establishment of eco-villages based on energy-efficient passive houses and ecological welfare is suggested. Another technique for creating added value, the development of sea-farming islands that utilize islands' new recyclable energy is also proposed. Finally, the suggested ideas are discussed in relation to island ecotourism and carbon zero islands.

Feedback Control using Dual O2 Sensors for Improving the Conversion Efficiency of a Three-way Catalyst in a Heavy-duty CNG Engine (CNG 대형엔진에서 이중 O2 센서를 활용한 피드백 제어를 통한 삼원촉매 정화효율 향상)

  • Yoon, Sungjun;Lee, Junsun;Park, Hyunwook;Lee, Yonggyu;Kim, Changup;Oh, Seungmook
    • Journal of ILASS-Korea
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    • v.24 no.4
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    • pp.163-170
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    • 2019
  • In this study, feedback logic using dual O2 sensor values were developed to increase the purification capability of a three-way catalyst (TWC) in a compressed natural gas (CNG) engine. A heavy-duty inline 6-cylinder engine was used and the CNG was supplied to the engine through a mixer. This study consists of two main parts, namely, the proportional integral (PI) control with a front O2 sensor and the feedback control with dual O2 sensors. In the PI control experiment, effects of various parameters, such as P gain, I gain, and lean delay, on the TWC capability were identified. Based on the results of the PI control experiment, the feedback logic using dual O2 sensor values were developed. In both cases, the nitrogen oxides (NOX) emissions were nearly zero. However, the carbon monoxide (CO) emissions were reduced significant in the feedback logic with dual O2 sensors than in the PI control with the front O2 sensor.

Vibration Analysis of the Large Substrate Handling Robot (8.5G 솔라셀 평판 핸들링 로봇의 진동 제어)

  • Park, Dong Il;Park, Cheolhoon;Park, Chanhun;Kim, Doohyung
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.25 no.6
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    • pp.498-503
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    • 2016
  • Many types of robot systems are used in the mass production line of thin film solar cells and flat panel displays. There are some issues such as the deflection and the vibration of the end-effector because robots handle large and heavy substrates at high speed. Heavy payload and high speed cause much vibration because the end-effector (fork) is made of carbon fiber reinforced polymer because of its light weightiness and sufficient stiffness. This study performs a dynamic simulation of an 8.5G solar cell substrate handling robot, including rigid and flexible bodies and a vibration controller. The fifth polynomial trajectory and the zero vibration derivative input shaping algorithm are applied. The vibration reduction is also proved in the experiments.

Study for the Design of Zero-carbon City through the Application of Renewable Energies (신재생에너지 적용기술이 저탄소녹색도시건설에 미치는 영향연구)

  • Park, Young-Gyu;Kim, Jeong-In;Kim, Kap-Chul
    • New & Renewable Energy
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    • v.6 no.4
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    • pp.15-29
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    • 2010
  • In order to make the best choice for $CO_2$ abatement using renewable energy technologies, it is important to be able to adapt these technologies on the basis of their sustainability, which may include a variety of environmental indicators. This study examined the comparative sustainability of renewable technologies in terms of their life cycle $CO_2$ emissions and embodied energy, using life cycle analysis. The models developed were based on case studies of bioenergy pilot plant in P city of Kyungki province. Final results were total emission of $CO_2$ in Pocheonsi is 670,041 $tCO_2$, around 500,877 $tCO_2$ for electricity and for heat generation, and 169,164 $tCO_2$ for transportation. When used $1,984\;m^3$/day of waste (pig manure etc.) and operated CHP with wood chips of 144,664 ton/year, the $CO_2$ emission in P city was left as is an emission of 449,274 $tCO_2$ and an abatement of $CO_2$ in this region was increased by 32.9%.