• Current Optics and Photonics
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• v.1 no.3
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• pp.203-206
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• 2017

We report a passive Q-switching of an all-fiber erbium-doped fiber laser delivering high pulse energy by using a high quality single-walled carbon nanotube saturable absorber (SWCNT-SA). A side-polished fiber coated with the SWCNT is employed as an in-line SA for evanescent wave interaction between the incident light and the SWCNT. This lateral interaction scheme enables a stable Q-switched fiber laser that generates high pulse energy. The central wavelength of the Q-switched pulse laser was measured as 1560 nm. A repetition rate frequency of the Q-switched laser is controlled from 78 kHz to 190 kHz by adjusting the applied pump power from 124 mW to 790 mW. The variation of pulse energy from 51 nJ to 270 nJ is also observed as increasing the pump power. The pulse energy of 270 nJ achieved at maximum pump power is 3 times larger than those reported in Q-switched all-fiber lasers using a SWCNT-SA. The tunable behaviors in pulse duration, pulse repetition rate, and pulse energy as a function of pump power are reported, and are well matched with theoretical expectation.

• Journal of the Korean Society for Nondestructive Testing
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• v.30 no.5
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• pp.411-422
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• 2010

Self-sensing on micro-failure, dispersion degree and relating properties, of carbon nanotube(CNT)/epoxy composites, were investigated using wettability, electro-micromechanical technique with acoustic emission(AE). Specimens were prepared from neat epoxy as well as composites with untreated and acid-treated CNT. Degree of dispersion was evaluated comparatively by measuring volumetric electrical resistivity and its standard deviation. Apparent modulus containing the stress transfer was higher for acid-treated CNT composite than for the untreated case. Applied cyclic loading responded well for a single carbon fiber/CNT-epoxy composite by the change in contact resistivity. The interfacial shear strength between a single carbon fiber and CNT-epoxy, determined in a fiber pullout test, was lower than that between a single carbon fiber and neat epoxy. Regarding on micro-damage sensing using electrical resistivity measurement with AE, the stepwise increment in electrical resistivity was observed for a single carbon fiber/CNT -epoxy composite. On the other hand, electrical resistivity increased infinitely right after the first carbon fiber breaks for a single carbon fiber/neat epoxy composite. The occurrence of AE events of added CNT composites was much higher than the neat epoxy case, due to micro failure at the interfaces by added CNTs.

• Carbon letters
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• v.27
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• pp.12-17
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• 2018

We fabricated a Li-S battery with post-treated carbon nanotube (CNT) films which offered better support for sulfur, and investigated the effect of the surface properties and pore structure of the post-treated CNT films on Li-S battery performance. Post-treatments, i.e., acid treatment, unzip process and cetyltrimethylammonium bromide (CTAB) treatment, effectively modified the surface properties and pore structure of the CNT film. The modified pore structure impacted the ability of the CNT films to accommodate the catholyte, resulting in an increase in initial discharge capacity.

• Journal of the Semiconductor & Display Technology
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• v.10 no.1
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• pp.107-111
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• 2011

Polypropylene(PP)/carbon fiber(CF)/multi-walled carbon nanotube(MWCNT) nanocomposites along with various CF and MWCNT contents were prepared in a Twin screw extruder. Electrical, mechanical property and morphology were investigated with a variation of CF and MWCNT contents. From the surface resistance of PP/CF/MWCNT composites, MWCNT can increase the conductivity of composites compared with PP/CF composites without MWCNT. It is suggested that MWCNT and CF can make the conductive network in the polymer matrix. Flexural modulus and Izod impact strength of the PP/CF/MWCNT composites were improved with the increase of CF contents. Morphology showed that length of CF in polymer matrix was shortened by torque during melt mixing with MWCNT. As a result of this phenomenon, the impact strength of composites was somewhat decreased.

• Composites Research
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• v.37 no.3
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• pp.197-203
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• 2024

Mechanical, electrical and thermal properties of polymer composites can be improved simultaneously by incorporating carbon fibers (CFs), which are beneficial for improving the mechanical properties, and multi-walled carbon nanotubes (MWCNTs), which are advantageous for improving the conductive properties. In this study, MWCNTs were incorporated into carbon long fiber thermoplastic (CLFT), which has excellent mass production processability and excellent mechanical properties, to control electrical and thermal properties. The mechanical and electrical properties of the prepared composites were most significantly influenced by the amount of filler incorporated. On the other hand, the thermal properties were improved due to the formation of a filler network interconnected by the incorporation of MWCNTs. By adjusting the filler amount, filler composition, and filler network structure of MWCNT-incorporated CLFT, the mechanical, electrical, and thermal properties could be controlled.

• Journal of Sensor Science and Technology
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• v.30 no.6
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• pp.357-363
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• 2021

We developed a chemiresistive anion sensor using highly conductive carbon nanotube fibers (CNTFs) functionalized with anion receptors. Mechanically robust CNTFs were prepared via wet-spinning utilizing the nematic liquid crystal properties of CNTs in chlorosulfonic acid (CSA). For anion detection, polymeric receptors composed of dual-hydrogen bond donors, including thiourea 1, squaramide 2, and croconamide 3, were prepared and bonded non-covalently on the surface of the CNTFs. The binding affinities of the anion receptors were studied using UV-vis titrations. The results revealed that squaramide 2 exhibited the highest binding affinity toward AcO^-, followed by thiourea 1 and croconamide 3. This trend was consistent with the chemiresistive sensing responses toward AcO^- using functional CNTFs. Selective anion sensing properties were observed that CNTFs functionalized with squaramide 2 exhibited a response of 1.08% toward 33.33 mM AcO^-, while negligible responses (<0.1%) were observed for other anions such as Cl^-, Br^-, and NO₃^-. The improved response was attributed to the internal charge transfer of dual-hydrogen bond donors owing to the deprotonation of the receptor upon the addition of AcO^-.

• Carbon letters
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• v.27
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• pp.98-107
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• 2018

Free-standing electrodes of CuO nanorods in carbon nanotubes (CNTs) are developed by synthesizing porous CuO nanorods throughout CNT webs. The electrochemical performance of the free-standing electrodes is evaluated for their use in flexible lithium ion batteries (LIBs). The electrodes comprising CuO@CNT nanocomposites (NCs) were characterized by charge-discharge testing, cyclic voltammetry, and impedance measurement. These structures are capable of accommodating a high number of lithium ions as well as increasing stability; thus, an increase of capacity in long-term cycling and a good rate capability is achieved. We demonstrate a simple process of fabricating free-standing electrodes of CuO@CNT NCs that can be utilized in flexible LIBs with high performance in terms of capacity and cycling stability.

• Proceedings of the Korean Fiber Society Conference
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• 2003.10a
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• pp.29-30
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• 2003

Several forms of nanonetworked carbon materials were synthesized by high pressure and high temperature treatments of fullerene C$\_$60/ and single-walled carbon nanotube bundles. Structural properties (e.g. thermal expansion coefficients and compressibilities) of the synthesized materials were investigated by XRD measurements using synchrotron X-ray. Their formation mechanisms are also discussed.

• Computers and Concrete
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• v.22 no.6
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• pp.501-514
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• 2018

The paper presents the thermo-mechanically induced non-linear response of multiwall carbon nanotube reinforced laminated composite beam (MWCNTRCB) supported by elastic foundation using higher order shear deformation theory and von-Karman non-linear kinematics. The elastic properties of MWCNT reinforced composites are evaluated using Halpin-Tsai model by considering MWCNT reinforced polymer matrix as new matrix by dispersing in it and then reinforced with E-glass fiber in an orthotropic manner. The laminated beam is supported by Pasternak elastic foundation with Winkler cubic nonlinearity. A generalized static analysis is formulated using finite element method (FEM) through principle of minimum potential energy approach.

• Polymer(Korea)
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• v.30 no.1
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• pp.90-94
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• 2006

An electrospinning process was used to fabricate poly(methyl methacrylate) (PMMA) nanofibers embedding multi-walled carbon nanotubes(MWNTs). SEM images showed that the nanofiber surface and structural morphology depended on solvent types (dimethyl formamide, chlor-form and toluene) and carbon nanotube contents (0.5 and $3.0\;wt\%$). Nano-fiber alignments could be controlled by adjusting the electrodes configuration at collector sites. Relationship between carbon nanotube and PMMA nanofiber was studied with radius of gyration of polymer chain and carbon nanotube sizes. As the carbon nanotube content ratio increased, the number of bead increased.