• Composites Research
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• v.36 no.6
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• pp.408-415
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• 2023

The formation of bonding configurations such as pyridinic-N, pyrrolic-N, and graphitic-N by nitrogen doping plays a crucial role in imparting distinct physical properties to carbon nanomaterials. In this study, we propose a simple and cost-effective approach to regulate nitrogen dopant configurations in carbon nanotubes (CNTs) by mixing melamine as a dopant source. We employed three distinct mechanical mixing techniques, namely magnetic stirring, bath sonication and tip sonication. The higher the ratio of melamine to CNT, the higher the ratio of Pyrrolic-N, and when mixed through stirring, the highest ratio of Pyridinic-N was shown. The facile method proposed in this study, which can easily form various types of nitrogen dopants in carbon nanotubes, is expected to facilitate the application of nitrogen-doped carbon nanomaterials.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2004.10a
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• pp.15-18
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• 2004

Nondestructive damage sensing and mechanical properties for thermal treated carbon nanotube(CNT) and nanofiber(CNF)/epoxy composites were investigated using electro-micromechanical technique. Carbon black (CB) was used only for the comparison. Electro-micromechanical techniques were applied to obtain the fiber damage and stress transferring effect of carbon nanocomposites with their contents. Thermal treatment and temperature affected on apparent modulus and electrical properties on nanocomposites due to enhanced inherent properties of each CNMs. Coefficient of variation (COV) of volumetric electrical resistance can be used to obtain the dispersion degree indirectly for various CNMs. Dispersion and surface modification are very important parameters to obtain improved mechanical and electrical properties of CNMs for multifunctional applications. Further optimized functionalization and dispersion conditions will be investigated for the following work continuously.

• 한국정보디스플레이학회:학술대회논문집
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• 2007.08a
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• pp.782-785
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• 2007

We studied the effect of current-aging on field emission from carbon nanotubes field emitter arrays (CNT-FEAs) selectively patterned by the resist-assistan tpatterning(RAP) process. After sustaining the electric field when starting emission current density $(J_s)$ is $0.1\;mA/cm^2$ during 40 hrs, it was observed that the field emission property and uniformity were remarkably improved due to the elimination of oxygen atom and thus the reconstruction of carbon bonding at the tip of CNTs during field emission.

• Steel and Composite Structures
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• v.29 no.5
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• pp.569-578
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• 2018

This paper aims to investigate the transient vibration behavior of functionally graded carbon nanotube (FG-CNT) reinforced nanocomposite plate resting on Pasternak foundation under pulse excitation. The plate is considered to be composed of matrix material and multi-walled carbon nanotubes (MWCNTs) with distribution as per the functional grading concept. The functionally graded distribution patterns in nanocomposite plate are explained more appropriately with the layer-wise variation of carbon nanotubes weight fraction in the thickness coordinate. The layers are stacked up in such a way that it yields uniform and three other types of distribution patterns. The effective material properties of each layer in nanocomposite plate are obtained by modified Halpin-Tsai model and rule of mixtures. The governing equations of an illustrative case of simply-supported nanocomposite plate resting on the Pasternak foundation are derived from third order shear deformation theory and Navier's solution technique. A converge transient response of nanocompiste plate under uniformly distributed load with triangular pulse is obtained by varying number of layer in thickness direction. The validity and accuracy of the present model is also checked by comparing the results with those available in literature for isotropic case. Then, numerical examples are presented to highlight the effects of distribution patterns, foundation stiffness, carbon nanotube parameters and plate aspect ratio on the central deflection response. The results are extended with the consideration of proportional damping in the system and found that nanocomposite plate with distribution III have minimum settling time as compared to the other distributions.

• Structural Engineering and Mechanics
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• v.70 no.6
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• pp.737-750
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• 2019

This paper investigates the static and dynamic behaviors of imperfect single walled carbon nanotube (SWCNT) modeled as a beam structure by using energy-equivalent model (EEM), for the first time. Based on EEM Young's modulus and Poisson's ratio for zigzag (n, 0), and armchair (n, n) carbon nanotubes (CNTs) are presented as functions of orientation and force constants. Nonlinear Euler-Bernoulli assumptions are proposed considering mid-plane stretching to exhibit a large deformation and a small strain. To simulate the interaction of CNTs with the surrounding elastic medium, nonlinear elastic foundation with cubic nonlinearity and shearing layer are employed. The equation governed the motion of curved CNTs is a nonlinear integropartial-differential equation. It is derived in terms of only the lateral displacement. The nonlinear integro-differential equation that governs the buckling of CNT is numerically solved using the differential integral quadrature method (DIQM) and Newton's method. The linear vibration problem around the static configurations is discretized using DIQM and then is solved as a linear eigenvalue problem. Numerical results are depicted to illustrate the influence of chirality angle and imperfection amplitude on static response, buckling load and dynamic behaviors of armchair and zigzag CNTs. Both, clamped-clamped (C-C) and simply supported (SS-SS) boundary conditions are examined. This model is helpful especially in mechanical design of NEMS manufactured from CNTs.

• Advances in nano research
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• v.16 no.5
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• pp.445-458
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• 2024

The objective of this paper is to present free vibration and static stability analyses of rotating composite beams reinforced with carbon nanotubes (CNTs) under uniform thermal loads. Beam structural equations and CNT-reinforced composite (CNTRC) beam formulations are derived based on Timoshenko beam theory (TBT). The temperature-dependent properties of the beam material, such as the elastic modulus, shear modulus, and material density, are assumed to vary over the thickness according to the rule of mixture. The beam material is modeled as a mixture of single-walled carbon nanotubes (SWCNTs) in an isotropic matrix. The SWCNTs are aligned and distributed in the isotropic matrix with different patterns of reinforcement, namely the UD (uniform), FG-O, FG-V, FG- Λ and FG-X distributions, where FG-V and FG- Λ are asymmetric patterns. Numerical examples are presented to illustrate the effects of several essential parameters, including the rotational speed, hub radius, effective material properties, slenderness ratio, boundary conditions, thermal force, and moments due to temperature variation. To the best of the authors' knowledge, this study represents the first attempt at the finite element modeling of rotating CNTRC Timoshenko beams under a thermal environment. The results are presented in tables and figures for both symmetric and asymmetric distribution patterns, and can be used as benchmarks for further validation.

• Composites Research
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• v.29 no.6
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• pp.336-341
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• 2016

This paper conducted the study on the electromagnetic and mechanical applicability of CNT-coated glass fiber for wind blades. Large-size wind blade has the serious pending problems to meet the target, such as interfering radar signals, increasing weights, and increasing repair costs. In this paper, we are suggesting the CNT-coated glass fiber in order to overcome these problems. First, the CNTs were strongly coated on the surfaces of glass fiber by suggested coating process, and the CNT-coated glass fiber/epoxy composites were fabricated by Va-RTM process. We designed and fabricated a radar absorbing structure using the CNT-coated glass fiber, which showed over 90% radar absorbing performance between 8.3 and 12.1 GHz frequency. In addition, we confirmed the improvement of mechanical properties on the strength and modulus of tensile, compressive, and in-plane shear.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.19 no.8
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• pp.891-898
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• 2008

In this paper, we have studied on the possibilities of the biomaterial detection using single-walled carbon nanotube (SWNT) based on interdigital capacitors. For the four different configurations, such as interdigital capacitor, SWNT in the $5\;{\mu}m$ gap interdigital capacitor, biotinlated SWNT, and biotin and sreptavidin immobilization cases, the resonant frequency has been measured as 10.02 GHz, 11.02 GHz, 10.82 GHz, and 10.22 GHz, respectively. Assuming that the resonant frequency reflects the capacitance changes due to binding of two-different permittivity biomaterials, we have suggested an equivalent circuit model based on measured results, confirming the capacitance changes. For biotinlated SWNT and biotin-streptavidin immobilization cases, the capacitances are $C_b=0.55\;pF$ and $C_s=0.95\;pF$. In this work, we experimentally demonstrated that the specific biomaterial binding causes the capacitance change and therefore this gives rise to resonant frequency. In conclusion, we confirmed the sufficient possibility as CNT biosensor because an analyte biomaterial(streptavidin) binding arouses a considerable resonant frequency change.

• Carbon letters
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• v.10 no.4
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• pp.320-324
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• 2009

We investigated the effect of diameter and content of carbon nanotubes (CNTs) on the physical properties of styrenebutadiene rubber (SBR)/CNTs nanocomposites. CNTs-reinforced SBR nanocomposites were prepared by the melt mixing process. CNTs with different diameters were synthesized by the chemical vapor deposition method (CVD). In this work, the mechanical property and other physical properties of SBR/CNTS nanocomposites were discussed as a function of the content and diameter of CNTs.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.37 no.2
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• pp.153-160
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• 2013

An orthotropic magneto-rheological rubber composite (MRRC) based on a general-purpose rubber can be manufactured by using an electromagnetic device during the curing processes of rubber mixtures. The magnetic transmissivity of MRRCs increases with the iron particle (IP) content, and that of aligned MRRCs with a 2-T magnetic field is 1.8 to 2 times higher as compared to that of randomly dispersed MRRCs. The effect of a 2-T magnetic field on carbon nanotube (CNT) reinforced MRRC has been identified clearly, and the magnetic transmissivity is found to be 3.7%. The compressive stress of MRRC (IP 90 + CNT 5, 2 T alignment) under a magnetic field of 0.49 T is 2.1 times higher as compared to that of the matrix. The MR effect of MRRC increases with the IP content, and that of aligned MRRC with the IP 90 and 2 T magnetic field is 20.4%. It is confirmed that the magnetic field when making the specimen and when performing the compression test greatly impacts the compression characteristics.