• 분석과학
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• 제19권5호
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• pp.376-382
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• 2006

In this work, pitch/activated carbon/$TiO_2$ composite were prepared by $CCl_4$ solvent method with different mixing ratios. The BET surface area of pitch/activated carbon/$TiO_2$ composite has a significantly increase with increasing activated carbon content in pitch/activated carbon/$TiO_2$ composite. The surface structure and elemental compositions of the composite were studied by SEM and EDX, respectively. The SEM results were presented to the characterization of porous texture on the pitch/activated carbon/$TiO_2$ composite. And EDX data was shown the presence of C, O, S, Ti and other elements. The structural properties of the composite were studied in XRD measurements. The $TiO_2$ crystal phases of the pitch/activated carbon/$TiO_2$ composite had lots of rutile-type structure which transforms from anatase-type with a little of anatase-type structure. The photocatalytic activities of the composite were evaluated using a photo-decomposition method under UV lamp. The pitch/activated carbon/$TiO_2$ composites were observed better photocatalytic activity than that of pristine $TiO_2$.

• 한국건설순환자원학회논문집
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• 제8권2호
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• pp.153-160
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• 2020

본 연구에서는 이산화탄소 포집광물을 심층혼합처리용 Soil-cement로 활용하기 위하여 최적 Soil-cement의 배합비를 도출하였으며, 이산화탄소 포집광물이 혼합된 Soil-cement의 품질특성을 평가하였다. 이산화탄소 포집광물은 슬러리 형태로 발생되며, 함수량 평가결과, 약 50%로 나타났다. 따라서, Soil-cement의 배합시 단위수량에서 이산화탄소 포집광물의 함수량을 제외하였다. 이산화탄소 포집광물 활용 Soil-cement를 현장토에 대하여 현장배합을 실시한 결과 재령 28일 기준 3.0MPa 이상을 나타냄으로써 설계 허용지지력 기준을 만족하는 것으로 나타났다. 이산화탄소 포집광물의 유해성 검증을 실시한 결과 구리(Cu)의 경우 0.055mg/L 검출되었지만 허용기준치에 만족하였으며, 이 외의 유해 물질은 용출되지 않은 것으로 분석되었다.

• 청정기술
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• 제23권4호
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• pp.364-377
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• 2017

본 연구에서는 활성탄 원료로서 국내산 무연탄의 낮은 비표면적을 향상시키기 위해 유 무연탄 혼합에 따른 화학적 활성화 및 휘발성유기화합물 흡착특성 연구를 수행하였으며, 이를 위해 원료 물성, 활성탄 제조공정별 특성, 제조 활성탄의 휘발성 유기화합물 흡착성능이 분석되었다. 실험결과, 삼성분 항목 중 높은 회분함량과 기준을 초과한 납, 비소 중금속이 국내산 원료의 단점으로 나타났다. 단점 개선을 위해 유 무연탄을 혼합하고, 전처리, 활성화, 세척, 조립 공정의 최적 조건을 도출하여 비표면적 $1,154{\sim}1,420m^2g^{-1}$의 중간세공이 발달한 소수성의 활성탄을 제조할 수 있었으며, 모든 품질규격기준을 만족하였고, 상용활성탄과 유사한 물리화학적 특성을 나타내었다. 벤젠, 자일렌, 톨루엔 흡착에 상용 성능을 위한 원료 혼합조건은 최소 $5,640kcal\;kg^{-1}$ 이상의 발열량이 필요하며, 자일렌 > 톨루엔 > 벤젠의 순서로 흡착성능이 우수한 것으로 보아 상대적으로 분자량이 크고 소수성이 강한 휘발성 유기화합물에 대하여 우수한 흡착성능을 가지는 것으로 나타났다.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2005년도 춘계학술발표대회 논문집
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• pp.261-264
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• 2005

Since the first discovery of carbon nanotube (CNT) in 1991, a window to new technological areas has been opened. One of the emerging applications of CNTs is the reinforcement of composite materials to overcome the performance limits of conventional materials. However, because of the difficulties in distributing CNTs homogeneously in metal or ceramic matrix by means of traditional composite processes, it has been doubted whether CNTs can really reinforce metals or ceramics. In this study, CNT reinforced Cu matrix nanocomposite is fabricated by a novel fabrication process named molecular level mixing process. This process produces CNT/Cu composite powders whereby the CNTs are homogeneously implanted within Cu powders. The CNT/Cu nanocomposite, consolidated by spark plasma sintering of CNT/Cu composite powders, shows to be 3 times higher strength and 2 times higher Young’s modulus than Cu matrix. This extra-ordinary strengthening effect of carbon nanotubes in metal is higher than that of any other reinforcement ever used for metal matrix composites.

• 한국표면공학회지
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• 제50권6호
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• pp.516-522
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• 2017

We report the growth of carbon nanotubes (CNT) on Invar-42 plates using coal tar pitch (CTP) by chemical vapor deposition (CVD) method. The solid phase CTP is used as an inexpensive carbon source since it produces a bunch of hydrocarbon gases such as $CH_4$ and other $C_xH_v$ by thermal decomposition over $450^{\circ}C$. The Invar-42 is a representative Ni-based ferrous alloy and can be used repetitively as a substrate for CNT growth because Ni and Fe are used as very active catalytic elements. We changed mixing ratio of carrier gases, argon and hydrogen, and temperature of growth region. It was found that the optimum gas ratio and temperature for high quality CNT growth are $Ar:H_2=400:400$ sccm and $1000^{\circ}C$, respectively. In addition, the carbon nanoball (CNB) was also obtained by just changing the mixing ratio to $Ar:H_2=100:600$ sccm. Finally, CTP can be employed as a versatile carbon source to produce various carbon-based nanomaterials, such as CNT and CNB.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 하계학술대회 논문집
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• pp.328-331
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• 2000

Carbon nanotube(CNT) was successfully grown on Ni-W alloyed substrate by applying PECVD technique(Plasma Enhanced Chemical Vapor Deposition). As a catalyst, Ni-W alloyed substrate was prepared by mechanical alloying method. In order to find the optimum growth condition, initially two different types of gas mixtures such ac $C_2$H$_2$-H$_2$and $C_2$H$_2$-MH$_3$were systematically investigated by adjusting results on the mixing ratio in temperature range of 500 to 80$0^{\circ}C$. In this work, we will report the preliminary results on the CNT processed by PECVD, which were characterized by XRD, SEM and TEM. Finally we will evalute the effect on CNT growth by changing many processing parameters, such as typical gas, mixing ratio between 2 mixture, plasma power and etc.

• 공업화학
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• 제18권1호
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• pp.64-70
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• 2007

분산성이 우수한 carbon-slurry 연료의 제조와 특성 분석을 하였다. Carbon-slurry 연료는 액체연료(Jet A-1)와 탄소 입자 그리고 적당한 첨가제를 혼합하여 얻었다. Carbon-slurry 연료의 분산성은 교반 온도, 탄소 입자의 특성 그리고 첨가제의 양과 종류 등에 따라서 달라진다. 특히 첨가제의 종류가 slurry 연료의 안정성에 가장 중요하였다. 다양한 음이온성, 양이온성, 비이온성 형태의 첨가제를 사용하여 carbon-slurry 연료의 분산성을 분석하였고, 이 결과 나트륨 염의 형태를 가진 음이온성 첨가제를 사용하였을 경우 carbon-slurry 연료의 분산성이 가장 우수하였음을 확인하였다. Carbon-slurry 연료의 분산성은 빛이 투과되는 광도 값을 측정하여 분석하였다.

• 한국지반환경공학회 논문집
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• 제25권8호
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• pp.13-19
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• 2024

본 연구에서는 풍화토 비탈면에서 발생하는 세굴 및 표층 붕괴 면의 표층 보강을 목적으로 탄소섬유와 친환경고화재(E.S.B.)를 혼합하여 일축 압축강도 시험을 수행하였다. E.S.B.와 탄소섬유의 최적 배합비를 결정하기 위해 E.S.B.는 10%, 20%, 30%의 조건을 설정하였고, 탄소섬유는 0.3%, 0.6%, 0.9%, 1.2%로 설정하였다. 또한, 건조밀도 및 재령 기간에 따른 일축 압축강도 변화를 분석하기 위해 최대건조단위 중량의 85%, 95%를 적용하고 재령 기간 3일, 7일, 28일로 설정하였다. 비탈면 표층 보강을 위한 기준 강도는 ACI 230.1R-09(2009)에서 7일 기준 4MPa, 28일 기준 6MPa로 제안하고 있다. 압축시험 결과 E.S.B. 보강토의 일축 압축강도는 다짐도 95%인 경우 E.S.B. 혼합비율 10% 이상에서 기준 강도를 충족하는 것을 알 수 있다. 또한, 친환경고화재(E.S.B.) 보강토에 탄소섬유를 혼합한 결과 일축 압축강도에 의한 항복점 이후 탄소섬유를 혼합한 조건에서 연성 형태의 파괴 형상이 나타나 항복 이후 발생하는 전도에 대하여 보완할 수 있으며, 탄소섬유 0.6% 혼합비율에서 최대강도를 발현하는 것으로 분석되었다. 탄소섬유 보강토는 탄소섬유를 혼합하지 않은 조건과 비교하여 일축 압축강도가 약 54~70%의 강도증가율이 나타났다.

• 한국유기농업학회지
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• 제11권4호
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• pp.93-102
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• 2003

This research was made to determine the optimum mixing ratio cattle manure and food waste investigating the effect that gets the growth and reproductive efficiency of earthworm and productivity of earthworm casts at processing process when handled cattle manure and food waste by vermicomposting, in order to establish the treatment system of organic wastes by vermicomposting. Survival ratio of earthworm was highest in the mixing ratio 80~100% : 20~0% of cattle manure and food Waste, and the increasing ratio was highest in cattle manure 100%, and the number of young worms, the weight of young worms and the productivity of earthworm casts in plots more than the mixing ratio 60% of cattle manure were significantly higher than in the other treatment plots(p<0.05). Total nitrogen and carbon contents in earthworm cast were decreased when rearing time of earthworm was increased. Carbon and nitrogen rate(C/N) of earthworm cast in plots more than the mixing ratio 80% of cattle manure was significantly higher than in the other treatment plots(p<0.05). pH in earthworm cast was higher than that in residual matter. The contents of electrolytic conductivity in the higher mixing ratio of food waste were significantly higher than those in the other treatment plots(p<0.05).

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2020년도 봄 학술논문 발표대회
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• pp.126-127
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• 2020

Recently, as interest in environmental issues increases, minimizing carbon dioxide generated during cement manufacturing is a problem to be solved. In order to solve such a problem, it is required to use an industrial by-product of recycled aggregate, blast furnace slag, and circulating fluidized bed boiler fly ash to replace it on the basis of geopolymer(=cementless). This study examines the characteristics of eco-friendly artificial stone according to the mixing ratio of geopolymer-based recycled aggregate. As a result of the experiment, when the addition rate of the alkali stimulant was 15% and the mixing ratio of the circulating aggregate was 70%, the flexural strength and compressive strength were the highest. Density and water absorption decreased as density of circulating aggregates increased and water absorption increased. However, when the mixing ratio of the circulating aggregate exceeded 70%, the flexural strength and compressive strength decreased. Therefore, in order to obtain strengths meeting the KS standards, the mixing ratio of recycled aggregate was set to 70%, and artificial stone was manufactured using industrial by-products.