• Title/Summary/Keyword: Carbon Mineralization

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Sulfur and Carbon Isotope Studies of Principal Metallic Deposits in the Metallogenic Province of the Taebaeg Mt. Region, Korea (태백산지구(太白山地區)의 금속광상(金屬鑛床)에 대(對)한 유황(硫黃) 및 탄소안정동위체(炭素安定同位體)에 관(關)한 연구(硏究))

  • Lee, Min Sung
    • Economic and Environmental Geology
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    • v.18 no.3
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    • pp.247-251
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    • 1985
  • The sulfide and carbonate mineral samples for sulfur and carbon isotope studies were collected from Sangdong, Geodo, Yeonhwa, Shinyemi and Janggun mines which are distributed in the Metallogenetic Province of the Taebaeg Mt. Region. The ${\delta}S^{34}$ values of molybdenite, pyrite, arsenopyrite, pyrrhotite, chalcopyrite, sphalerite and galena from the above mines are similar and within the range of +1.66 to +6.77‰ with the exception of chalcopyrite from Geodo mine ranging from -1.58 to 1.96‰, while the sulfide minerals are dominated by positive values between +3.05 and +5.08‰. It is suggested that the major sulfur source is genetically related to the Cretaceous granitic activity. The average ${\delta}C^{13}$ values of calcite from limestone, calcite from calcite vein in ore bodies and granite, and rhodochrosite from ore bodies are -0.60‰, -2.69‰ and -6.00‰, respectively. The data on carbon isotope compositions indicate that the calcite from limestone originated in marine environment, the rhodochrosite in hydrothermal solution, and calcite from calcite vein and granite in the mixing condition of marine and hydrothermal waters. The temperatures of mineralization by the sulfur isotopic composition coexisting pyrite-pyrrhotite from Yeonhwa No.1, sphalerite-galena from Weolam and Dong-jeom of Yeonhwa No.1 mine, sphalerite-galena and pyrite-galena from Janggun mine were $273^{\circ}C$, $460{\sim}511^{\circ}C$, $561{\sim}690^{\circ}C$, $341^{\circ}C$ and $375^{\circ}C$, respectively.

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Importance of Extracellular Enzyme Activities in Northern Peatland Biogeochemistry-Possible Coupling with Trace Gas Emission and DOC Dynamics (북구 이탄습지의 생지화학적 반응에 있어서 체외효소의 중요성-미량기체 발생량 및 용존유기탄소 동태와의 연관성에 대하여)

  • Freeman, Chris;Park, Seok-Soon;Kang, Ho-Jeong
    • Korean Journal of Ecology and Environment
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    • v.39 no.4 s.118
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    • pp.435-444
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    • 2006
  • A suite of extracellular enzyme activities involved in organic carbon decomposition were determined in three northern peatlands (a bog, a fen, and a swamp) over a 12 month period along with trace gas ($CO_2$ and $N_2O$) flux and DOC dynamics in the wetlands. The activities varied $0.008-0.066\;{\mu}mole\;g^{-1}\;min^{-1}$, $0.003-0.021\;{\mu}mole\;g^{-1}\;min^{-1}$, $0.003-0.016\;{\mu}mole\;g^{-1}\;min^{-1}$, $0.004-0.047\;{\mu}mole\;g^{-1}\;min^{-1}$, for ${\beta}-glucosidase$, cellobiohydrolase, ${\beta}-xylosidase$, and N-acetylglucosaminidase, respectively. In general, the activities were highest in the forested swamp followed by the fen and the bog. When the data from three wetlands are combined, the enzyme activities exhibited significant positive correlations with trace gas emission and available carbon. Further, the average activity of 4 enzymes explained about 20-40% of the variations of trace gas emssion and available carbon. The results indicate that enzymes related to the mineralization of organic carbon may play an important role in trace gas flux and DOC dynamics in northern peatlands.

Carbon and Nitrogen Dynamics of Wood Stakes as Affected by Soil Amendment Treatments in a Post-Fire Restoration Area (산불 훼손 복원지 내 토양개량제 처리가 Wood stakes의 탄소 및 질소 동태에 미치는 영향)

  • Park, Seong-Wan;Baek, Gyeongwon;Byeon, Hee-Seop;Kim, Yong Suk;Kim, Choonsig
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.20 no.4
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    • pp.357-365
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    • 2018
  • This study was carried out to evaluate the weight loss rates, carbon and nitrogen dynamics of wood stakes following soil amendment treatments (CLB: compound fertilizer + lime + biochar; LB: lime + biochar) in a post-fire restoration area, Ulsan Metropolitan city, southern Korea. Soil amendments in the fire-disturbed area were applied to two-times (Mar. and Jun. 2015, 2016) during the study period. Wood stakes on Mar. 2015 were buried at a top 15cm of mineral soil in two soil amendment and control treatments of Liriodendron tulipifera, Prunus yedoensis, Quercus acutissima, Pinus thunbergii plantations and an unplanted area in the post-fire restoration area. Wood stakes were collected at Oct. 2015, Mar. 2016 and Oct. 2016 to measure weight loss rates, organic carbon and nitrogen concentrations. Weight loss rates of wood stakes were not significantly affected by soil amendment treatments. However, remaining carbon of wood stakes were lowest in the control treatment (43.7%), followed by the CLB (71.3%) and the LB (71.6%) treatments. Remaining nitrogen of wood stakes was less in the control treatment (29.7%) compared with the LB treatment (52.6%). The results indicate that carbon and nitrogen mineralization of wood stakes in post-fire restoration area were delayed by soil amendment treatments.

Isolation of Pseudomonas putida Z104 and Degra-dation Characteristics of Benzoate and Catechol (Benzoate와 Catechol을 분해하는 Pseudomonas putida Z104의 분리 및 분해특성)

  • 김기필;김준호;김민옥;박정아;정원화;김치경
    • Korean Journal of Environmental Biology
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    • v.18 no.3
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    • pp.307-313
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    • 2000
  • Aromatic hydrocarbons are known to be recalcitrant, so that they have been concerned as pollutant chemicals. Microorganisms play a major role in the breakdown and mineralization of these compounds. However, the kinetics of the biodegradation process may be much slower than desired from environmental consideration. The biodegradation of aromatic hydrocarbons is conducted by oxidation to produce catechol as a common intermediate which is metabolized for carbon and energy sources. In this study, a bacterial isolate capable of degrading several aromatic hydrocarbons was isolated from the contaminated wastewater of Yeocheon industrial complex. On the basis of biochemical characteristics and major cellular fatty acids, the isolate was identified as Pseudomonas putida Z104. The strain Z104 can utilize benzoate and catechol as the sole carbon and energy sources via a serial degradative pathway. The strain degraded actively 0.5 mM catechol in MM2 medium at pH 7.0 and 3$0^{\circ}C$.

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Stable Isotope and Fluid Inclusion Studies of the Manjang Copper Mine, South Korea (만장동광산(萬藏銅鑛山)에 대(對)한 유체포유물(流體包有物) 및 안정동위원소분석(安定同位元素分析) 연구(硏究))

  • Kim, Kyu Han;Shin, Jeung Sook
    • Economic and Environmental Geology
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    • v.20 no.3
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    • pp.169-177
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    • 1987
  • The Manjang copper magnetite-fluorite orebodies are imbedded within the limestone beds of the Hwajonri Formation. The ore deposits are characterized by magnetite-fluorite bearing skarn orebody in the west orebody and copper sulfide veins of the central and main orebodies. This study includes fluid inclusion geothermometry, salinity analysis, stable isotope analysis, and application of phase rule to mineral associations in skarn ore. Ore minerals are closely associated with the skarn silicates such as garnet, wollastonite and epidote. Magnetite and fluorite are remarkable in the west orebody whereas chalcopyrite is dominate in the central and main orebodies where pyrite and pyrrhotite also appear as sulfide gangues. Homogenization temperature and salinity of fluid inclusions are measured ranging between $240^{\circ}C$ and $350^{\circ}C$, 6.3~12.9 wt. percent in quartz and $220^{\circ}C$ and $350^{\circ}C$, 8.5~9.9wt. percent in fluorite, respectively. This indicates that the filling temperature and salinity are higher in quartz than in fluorite with the tendency of both to be linearly decreased suggesting an attribution of meteoric water to the mineralization. $T-fo_2$ diagram in the Ca-Fe-Si system at 1 kb and $Xco_2$=0.02 shows that the mineral assemblages with decreasing temperature are andradite-hedenbergite-calcite, hedenbergite-andradite-quartz, magnetite-andradite-quartz, and magnetite-quartz-calcite, indicating that magnetite crystallizes mostly late skarn stage at lower temperature. According to the carbon and oxygen isotopic values of the host limestone and calcite in ores, the sourec of carbon might be mixture of host limestone and deep seated carbons. Sulfur isotope data imply that ore fluids be relatively homogeneous in sulfur isotopic composition, mainly derived from igneous source.

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Effect of Soil Respiration on Light Fraction-C and N Availability in Soil Applied with Organic Matter

  • Ko, Byong-Gu;Lee, Chang-Hoon;Kim, Myung-Sook;Kim, Gun-Yeob;Park, Seong-Jin;Yun, Sun-Gang
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.5
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    • pp.510-516
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    • 2016
  • Soil respiration has been recognized as a key factor of the change of organic matter and fertility due to the carbon and nitrogen mineralization. In this study, we evaluated the effect of soil respiration on the light fraction-C and inorganic N content depending on temperature in soil applied with organic matter. Soil respiration was calculated by using total $CO_2$ flux released from soil applied with $2Mg\;ha^{-1}$ of rice straw compost and rye for 8 weeks incubation at 15, 25, $35^{\circ}C$ under incubation test. After incubation test, light fraction and inorganic N content were investigated. Rye application dramatically increased soil respiration with increasing temperature. $Q_{10}$ value of rye application was 1.69, which was higher 27% than that of rice straw compost application. Light-C and $NO_3-N$ contents were negatively correlated to soil respiration. Light-C in rye application more decreased than that in rice straw compost with temperature levels. These results indicate that temperature sensitivity of soil respiration could affect soil organic mater content and N availability in soil due to carbon availability. Also, light fraction would be useful indicator to evaluate decomposition rate of organic matter in soil under a short-term test.

Characterization of Shrinkage Reducing Type Cement Carbon Dioxide-reducible CSA Synthesis (이산화탄소 저감형 CSA합성을 통한 수축저감형 시멘트의 특성 평가)

  • Cho, Yong-Kwang;Nam, Seong-Young;Kim, Chun-Sik;Cho, Sung-Hyun;Lee, Hyoung-Woo;Ahn, Ji-Whan
    • Journal of Energy Engineering
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    • v.28 no.1
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    • pp.17-21
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    • 2019
  • Calcium sulfaluminate (CSA) was synthesized to improve the shrinkage of OPC. In this study, the setting time, the compressive strength and the length change ratio were confirmed by replacing the synthesized CSA with OPC by 10% and 13% by 16%. In the case of shrinkage-reducing type cement, formation of Ca-Al-$H_2$-based hydrate was activated. Therefore, the setting time was shortened. The compressive strength of the shrinkage - reducing type cement is comparable to that of OPC after 7 days' strength. However, shrinkage reducing type cement showed improved initial strength compared to OPC. The length change ratio was found to be improved by drying shrinkage from -0.075% to -0.047% on the 28th day.

The Cement Industry in Ethiopia

  • Mulatu, Dure;Habte, Lulit;Ahn, Ji Whan
    • Journal of Energy Engineering
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    • v.27 no.3
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    • pp.68-73
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    • 2018
  • The cement industry is one of the rapidly growing industry in Ethiopia. The average per capita cement consumption of the country has increased from 39kg to 62kg. However, this is still way below than the global average per capita consumption of 500kg. The Ethiopian government is planning to expand its cement industry by upgrading the current cement plants and also opening of new cement plants in order to meet the future demand of the country. Currently, the number of cement plants in Ethiopia has reached to 20. By the year 2025, per capita cement consumption is expected to increase to 179kg. Recently, Ethiopia has become one of Africa's largest market for the cement industry. In addition, Ethiopia has become the major exporter of cement in the Sub-Saharan African region. The Ethiopian cement industry is highly dependent on the use of imported energy sources for its production. This situation has a significant amount of impact on the high production costs of the industry. This paper will try to review the history, production, available resources, the technologies and energy use of the Ethiopian cement industry.

Applications of Sugarcane by-products to mitigate climate change in Ethiopia

  • Habte, Lulit;Mulatu, Dure;Ahn, Ji Whan
    • Journal of Energy Engineering
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    • v.27 no.3
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    • pp.36-40
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    • 2018
  • Climate change is one of the major issues in both the developed and developing world. Greenhouse gas (GHG) emission is one of the implications for climate change. It is increasing rapidly. Although the emission is much less when compared to the rest of the world, Ethiopia has also faced this global issue. The major source for GHG emission in Ethiopia is agriculture. Therefore, the agriculture sector has to be given more attention in Ethiopia. To overcome the problem, Climate-Resilient Green Economy (CRGE) strategy has been initiated. One way of executing this target is to create a sustainable and environmentally friendly pathway to use agricultural byproducts. Sugarcane is one of the major plants in Ethiopia. Its byproducts are bagasse, molasses, and press mud. Since it is a waste product, it is economical and creates a sustainable and green environment by reducing GHG emissions. Sugarcane byproducts have versatile applications like as fuel, as cement replacing material, as a mitigation for expansive soils, as biosorbent for the treatment of water and wastewater and also as a wood material. However, Ethiopia has not used this byproduct massively as it is readily available. This paper reviews the possible applications of sugarcane byproducts to mitigate climate change.

A brief review on Oyster shells origin and sedimentary evolution for the formation of limestone

  • Ramakrishna, Chilakala;Thriveni, Thenepalli;Whan, Ahn Ji
    • Journal of Energy Engineering
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    • v.27 no.3
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    • pp.48-56
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    • 2018
  • The shell waste biomineralization process has known a tremendous metamorphosis and also the nanostructure with the identification of matrix proteins in oyster shells. However, proteins are represented in minor shell components and they are the major macromolecules that control biocrystal synthesis. Aragonite and calcite were derived from molluscan shells and evaluated the source of carbonate minerals and it helps for the formation of limestone. The oyster shell wastes are large and massive. The paleoecological study of oyster beds has discovered a near-shore and thin Upper Rudeis formation with storm influence during the accumulation of oysters with highly altered by disarticulation, bioerosion, and encrustation. It is possible even in the Paleozoic mollusks provided sufficient carbonate entirely to the source of microcrystalline of limestone. The present review is to discuss paleoecologically a number of oyster shell beds accumulated and sediment to form the different types of limestone during the Middle Miocene time.