• Title/Summary/Keyword: Carbon Free

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Effect of Fluorination on Electrical Behaviors of Carbon Blacks-filled HDPE Polymeric Switch

  • Seo, Min-Kang;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.30 no.6
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    • pp.1337-1340
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    • 2009
  • Electrical properties of a fluorinated carbon black (CB)-filled high-density polyethylene (HDPE) polymeric switch were investigated as a function of fluorination pressure at 0.1 ~ 0.4 MPa. From the FT-IR results, the absorption spectra of the fluorinated CB show an absorption band at 1400 ~ 1000 $cm^{-1}\;for\;{\nu}_{C-F}$ and the peak intensity increased with increasing fluorination pressure. Also, the analysis of XPS spectra of the fluorinated CB indicated that fluorine content increased with increasing fluorination pressure. Meanwhile, the surface free energy of the fluorinated CB decreased with increasing fluorination pressure. Consequently, the increase of fluorine contents of CB made a disappearance of negative temperature coefficient (NTC) behavior of the polymeric switch, which was probably due to the reduction of CB reaggregation after melting point of the HDPE, resulted from the decreasing of London dispersive component of the surface free energy for CB particles.

An analytical study on the nonlinear vibration of a double-walled carbon nanotube

  • Hajnayeb, Ali;Khadem, S.E.
    • Structural Engineering and Mechanics
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    • v.54 no.5
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    • pp.987-998
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    • 2015
  • In this paper, free vibrations of a clamped-clamped double-walled carbon nanotube (DWNT) under axial force is studied. By utilizing Euler-Bernoulli beam theory, each layer of DWNT is modeled as a beam. In this analysis, nonlinear form of interlayer van der Waals (vdW) forces and nonlinearities aroused from mid-plane stretching are also considered in the equations of motion. Further, direct application of multiple scales perturbation method is utilized to solve the obtained equations and to analyze free vibrations of the DWNT. Therefore, analytical expressions are found for vibrations of each layer. Linear and nonlinear natural frequencies of the system and vibration amplitude ratios of inner to outer layers are also obtained. Finally, the results are compared with the results obtained by Galerkin method.

Free vibration analysis of double walled carbon nanotubes embedded in an elastic medium with initial imperfection

  • Ehyaei, Javad;Daman, Mohsen
    • Advances in nano research
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    • v.5 no.2
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    • pp.179-192
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    • 2017
  • The transverse vibration of double walled carbon nanotube (DWCNT) embedded in elastic medium with an initial imperfection is considered. In this paper, Timoshenko beam theory is employed. However the nonlocal theory is used for modeling the nano scale of nanotube. In addition, the governing Equations of motion are obtained utilizing the Hamilton's principle and simply-simply boundary conditions are assumed. Furthermore, the Navier method is used for determining the natural frequencies of DWCNT. Hence, some parameters such as nonlocality, curvature amplitude, Winkler and Pasternak elastic foundations and length of the curved DWCNT are analyzed and discussed. The results show that, the curvature amplitude causes to increase natural frequency. However, nonlocal coefficient and elastic foundations have important role in vibration behavior of DWCNT with imperfection.

Validity assessment of aspect ratios based on Timoshenko-beam model: Structural design

  • Emad Ghandourah;Muzamal Hussain;Mohamed A. Khadimallah;Mashhour Alazwari;Mohamed R. Ali;Mohammed A. Hefni
    • Computers and Concrete
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    • v.31 no.1
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    • pp.1-7
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    • 2023
  • In this paper, Timoshenko-beam model is developed for the vibration of double carbon nanotubes. The resulting frequencies are gained for axial wave mode and length-to-diameter ratios. The natural frequency becomes more prominent for lower length-to-diameter ratios and diminished for higher ratios. The converse behavior is observed for axial wave mode with clamped-clamped and clamped-free boundary conditions. The frequencies of clamped-free are lower than that of clamped-clamped boundary condition. The eigen solution is obtained to extract the frequencies of double walled carbon nanotubes using Galerkin's method through axial deformation function. Computer softer MATLAB is used for formation of frequency values. The frequency data is compared with available literature and found to be in agreement.

Protective Effect of Oenanthe javanica Extract on the Carbon Tetrachloride-Induced Hepatotoxicity in Mice (미나리추출물이 사염화탄소에 의한 마우스 간손상에 미치는 영향)

  • 이상일;박용수;조수열
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.22 no.4
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    • pp.392-397
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    • 1993
  • The present work was undertaken to investigate the protective mechanism of Oenanthe iavanicu n-butanol extract on the carbon tetrachloride-induced hepatotoxicity in mice. It was observed that a striking enhancement of serum alanine aminotransferase and hepatic lipid peroxide content after carbon tetrachloride administration were markedly decreased by the presentment of Oenanthe javanica extract for 5 days. It was also observed that the hepatic aniline hydroxylase, catalase, glutathione S-transferase activity and glutathione content were not changed by the injection of Oenanthe javanica extract for 5 days. Whereas, hepatic xanthine oxidase activity was inhibited by the treatment of Oenanthe javanica extract for 5 days. After treatment with Oenanthe javanica extract, xanthine oxidase activity was decreased with dose and time-dependent manner as compared to control group. However, hepatic xanthine oxidase activity was not affected by the addition of Oenanthe javanica extract in vitro. These results suggest that the inhibition of hepatic xanthine oxidase activity by the injection of Oenanthe javanica extract is believed to be a possible protective mechanism for the carbon tetrachloride-indured hepatotoxicity in mice.

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Thermomechanical Properties of Carbon Fibres and Graphite Powder Reinforced Asbestos Free Brake Pad Composite Material

  • Thiyagarajan, P.;Mathur, R.B.;Dhami, T.L.
    • Carbon letters
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    • v.4 no.3
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    • pp.117-120
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    • 2003
  • Asbestos is being replaced throughout the world among friction materials because of its carcinogenic nature. This has raised an important issue of heat dissipation in the non-asbestos brake pad materials being developed for automobiles etc. It has been found that two of the components i.e. carbon fibres as reinforcement and graphite powder as friction modifier, in the brake pad material, can playa vital role in this direction. The study reports the influence of these modifications on the thermal properties like coefficient of thermal expansion (CTE) and thermal conductivity along with the mechanical properties of nonasbestos brake pad composite samples developed in the laboratory.

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Effect of Silicon Infiltration on the Mechanical Properties of 2D Cross-ply Carbon-Carbon Composites

  • Dhakate, S.R.;Aoki, T.;Ogasawara, T.
    • Carbon letters
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    • v.5 no.3
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    • pp.108-112
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    • 2004
  • Effect of silicon infiltration on the bend and tensile strength of 2D cross-ply carbon-carbon composites are studied. It is observed that bend strength higher than tensile strength in both types of composite is due to the different mode of fracture and loading direction. After silicon infiltrations bend and tensile strength suddenly decreases of carbon-carbon composites. This is due to the fact that, after silicon infiltration, silicon in the immediate vicinity of carbon forms the strong bond between carbon and silicon by formation silicon carbide and un-reacted silicon as free silicon. Therefore, these composites consist of three components carbon, silicon carbide and silicon. Due to mismatch between these three components secondary cracks developed and these cracks propagate from $90^{\circ}$ oriented plies to $0^{\circ}$ oriented plies by damaging the fibers (i.e., in-situ fiber damages). Hence, secondary cracks and in-situ fiber damages are responsible for degradation of mechanical properties of carbon-carbon composites after silicon infiltration which is revealed by microstructure investigation study by scanning electron microscope.

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Study on control of carbon dioxide in subway car (지하철 객실의 이산화탄소 제어방안 연구)

  • Cho, Young-Min;Kwon, Soon-Bark;Park, Duck-Shin;Park, Jae-Hyung;Lee, Ju-Yeol
    • Proceedings of the KSR Conference
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    • 2010.06a
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    • pp.2195-2201
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    • 2010
  • High concentration of carbon dioxide in subway cabin may cause various adverse effects on the passengers. Because carbon dioxide is produced by breathing of passengers, carbon dioxide concentration at rush-hours is extremely high. In most cases, the ventilation is not that easy for subway cars due to the high concentration of dust in tunnels. In this study, more practical way to control carbon dioxide in subway car was suggested. The decrease of carbon dioxide concentration was observed when the system was applied to a real subway car. The regenerative method for maintenance-free carbon dioxide control system was also suggested.

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Synthesis of Vertically Aligned SiNW/Carbon Core-shell Nanostructures

  • Kim, Jun-Hui;Kim, Min-Su;Kim, Dong-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.488.2-488.2
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    • 2014
  • Carbon-based materials such as carbon nanotubes and graphene have emerged as promising building blocks in applications for nanoelectronics and energy devices due to electrical property, ease of processability, and relatively inert electrochemistry. In recent years, there has been considerable interest in core-shell nanomaterials, in which inorganic nanowires are surrounded by inorganic or organic layers. Especially, carbon encapsulated semiconductor nanowires have been actively investigated by researchers in lithium ion batteries. We report a method to synthesize silicon nanowire (SiNW) core/carbon shell structures by chemical vapor deposition (CVD), using methane (CH4) as a precursor at growth temperature of $1000{\sim}1100^{\circ}C$. Unlike carbon-based materials synthesized via conventional routes, this method is of advantage of metal-catalyst free growth. We characterized these materials with FE-SEM, FE-TEM, and Raman spectroscopy. This would allow us to use these materials for applications ranging from optoelectronics to energy devices such as solar cells and lithium ion batteries.

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