• Title/Summary/Keyword: Carbon/carbon-based materials

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Active control of three-phase CNT/resin/fiber piezoelectric polymeric nanocomposite porous sandwich microbeam based on sinusoidal shear deformation theory

  • Navi, B. Rousta;Mohammadimehr, M.;Arani, A. Ghorbanpour
    • Steel and Composite Structures
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    • v.32 no.6
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    • pp.753-767
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    • 2019
  • Vibration control in mechanical equipments is an important problem where unwanted vibrations are vanish or at least diminished. In this paper, free vibration active control of the porous sandwich piezoelectric polymeric nanocomposite microbeam with microsensor and microactuater layers are investigated. The aim of this research is to reduce amplitude of vibration in micro beam based on linear quadratic regulator (LQR). Modified couple stress theory (MCST) according to sinusoidal shear deformation theory is presented. The porous sandwich microbeam is rested on elastic foundation. The core and face sheet are made of porous and three-phase carbon nanotubes/resin/fiber nanocomposite materials. The equations of motion are extracted by Hamilton's principle and then Navier's type solution are employed for solving them. The governing equations of motion are written in space state form and linear quadratic regulator (LQR) is used for active control approach. The various parameters are conducted to investigate on the frequency response function (FRF) of the sandwich microbeam for vibration active control. The results indicate that the higher length scale to the thickness, the face sheet thickness to total thickness and the considering microsensor and microactutor significantly affect LQR and uncontrolled FRF. Also, the porosity coefficient increasing, Skempton coefficient and Winkler spring constant shift the frequency response to higher frequencies. The obtained results can be useful for micro-electro-mechanical (MEMS) and nano-electro-mechanical (NEMS) systems.

2D Layered Ti3C2Tx Negative Electrode based Activated Carbon Woven Fabric for Structural Lithium Ion Battery (카본우븐패브릭 기반 2D 구조의 Ti3C2Tx 배터리음극소재)

  • Nam, Sanghee;Umrao, Sima;Oh, Saewoong;Oh, Il-Kwon
    • Composites Research
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    • v.32 no.5
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    • pp.296-300
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    • 2019
  • Two dimensional transition metal carbides and/or nitrides, known as MXenes, are a promising electrode material in energy storage due to their excellent electrical conductivity, outstanding electrochemical performance, and abundant functional groups on the surface. Use of $Ti_3C_2$ as electrode material has significantly enhanced electrochemical performance by providing more chemically active interfaces, short ion-diffusion lengths, and improved charge transport kinetics. Here, we reports the efficient method to synthesize $Ti_3C_2$ from MAX phase, and opens new avenues for developing MXene based electrode materials for Lithium-Ion batteries.

Growth Characteristics of Polyporales Mushrooms for the Mycelial Mat Formation

  • Bae, Bin;Kim, Minseek;Kim, Sinil;Ro, Hyeon-Su
    • Mycobiology
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    • v.49 no.3
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    • pp.280-284
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    • 2021
  • Mushroom strains of Polyporales from the genera Coriolus, Trametes, Pycnoporus, Ganoderma, and Formitella were explored in terms of mycelial growth characteristics for the application of mushroom mycelia as alternative sources of materials replacing fossil fuel-based materials. Among the 64 strains of Polyporales, G. lucidum LBS5496GL was selected as the best candidate because it showed fast mycelial growth with high mycelial strength in both the sawdust-based solid medium and the potato dextrose liquid plate medium. Some of the Polyporales in this study have shown good mycelial growth, however, they mostly formed mycelial mat of weak physical strength. The higher physical strength of mycelial mat by G. lucidum LBS5496GL was attributed to its thick hyphae with the diameter of 13 mm as revealed by scanning electron microscopic analysis whereas the hyphae of others exhibited less than 2 mm. Glycerol and skim milk supported the best mycelial growth of LBS5496GL as a carbon and a nitrogen source, respectively.

SiOC Anode Material Derived from Poly(phenyl carbosilane) for Lithium Ion Batteries

  • Lee, Yoon Joo;Ryu, Ji Yeon;Roh, Kwang Chul;Kim, Soo Ryong;Kwon, Woo Teck;Shin, Dong-Geun;Kim, Younghee
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.480-484
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    • 2013
  • Since SiOC was introduced as an anode material for lithium ion batteries, it has been studied with different chemical compositions and microstructures using various silicon based inorganic polymers. Poly(phenyl carbosilane) is a SiOC precursor with a high carbon supply in the form of the phenyl unit, and it has been investigated for film applications. Unlike any other siloxane-based polymers, oxygen atoms must be utilized in an oxidation process, and the amount of oxygen is controllable. In this study, SiOC anodes were prepared using poly(phenyl carbosilane) with different heat treatment conditions, and their electrochemical properties as an anode material for lithium ion batteries were studied. In detail, cyclic voltammetry and charge-discharge cycling behavior were evaluated using a half-cell. A SiOC anode which was prepared under a heat treatment condition at $1200^{\circ}C$ after an oxidation step showed stable cyclic performance with a reversible capacity of 360 mAh/g.

Evaluation of Output Performance of Flexible Thermoelectric Energy Harvester Made of Organic-Inorganic Thermoelectric Films Based on PEDOT:PSS and PVDF Matrix (PEDOT:PSS 및 PVDF 기반의 유-무기 열전 필름으로 제작된 플렉서블 열전 에너지 하베스터의 발전 성능 평가)

  • Yujin Na;Kwi-Il Park
    • Korean Journal of Materials Research
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    • v.33 no.7
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    • pp.295-301
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    • 2023
  • Thermoelectric (TE) energy harvesting, which converts available thermal resources into electrical energy, is attracting significant attention, as it facilitates wireless and self-powered electronics. Recently, as demand for portable/wearable electronic devices and sensors increases, organic-inorganic TE films with polymeric matrix are being studied to realize flexible thermoelectric energy harvesters (f-TEHs). Here, we developed flexible organic-inorganic TE films with p-type Bi0.5Sb1.5Te3 powder and polymeric matrices such as poly(3,4-eethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) and poly (vinylidene fluoride) (PVDF). The fabricated TE films with a PEDOT:PSS matrix and 1 wt% of multi-walled carbon nanotube (MWCNT) exhibited a power factor value of 3.96 µW·m-1·K-2 which is about 2.8 times higher than that of PVDF-based TE film. We also fabricated f-TEHs using both types of TE films and investigated the TE output performance. The f-TEH made of PEDOT:PSS-based TE films harvested the maximum load voltage of 3.4 mV, with a load current of 17.4 µA, and output power of 15.7 nW at a temperature difference of 25 K, whereas the f-TEH with PVDF-based TE films generated values of 0.6 mV, 3.3 µA, and 0.54 nW. This study will broaden the fields of the research on methods to improve TE efficiency and the development of flexible organic-inorganic TE films and f-TEH.

Effect of Refractories on Coating Material Properties in Evaporative Pattern Casting Process (소실모형주조용 도형재 특성에 미치는 충전재의 영향)

  • Choi, Hyun-Jin;Oh, Young-Kun;Jun, Ghi-Chan;Lee, Sung-Chun;Lee, Gyung-Whan
    • Journal of Korea Foundry Society
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    • v.17 no.6
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    • pp.569-576
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    • 1997
  • Coating materials for Evaporative Pattern Casting (EPC) process have been developed to investigate the effect of refractories on coating material properties. Three types of developed and one foreign coating materials were used. The former designated as A, B, C and the latter named S.K. The refractory of coating material A is spherical shape of zirconia, and the ones of B, C and S.K. is flake shape of mica. Strength, permeability at room and elevated temperature, anti-sand attachability and carbon residuary were evaluated at each coating materials. Permeability measurement device for elevated temperature was also designed. The zirconia type of coating material had excellent permeability, on the other hand the mica type had good strength and anti-sand attachability. It was found that the refractories were not broken during casting, so permeability indicated same trend at both room and elevated temperature. Based on results, coating material contained small size of mica which is designated as B has the best combination for cast iron.

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Large-scale Simulation for Optimal Design of Composite Curved Piezoelectric Actuator (복합재료 곡면형 자동기의 최적설계를 위한 대규모 수치해석 연구)

  • Chung, Soon-Wan;Hwang, In-Seong;Kim, Seung-Jo
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.04a
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    • pp.5-8
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    • 2005
  • In this paper, the electromechanical displacements of curved piezoelectric actuators composed of PZT ceramic and laminated composite materials are calculated based on high performance computing technology and the optimal configuration of composite curved actuator is examined. To accurately predict the local pre-stress in the device due to the mismatch in coefficients of thermal expansion, carbon-epoxy and glass-epoxy as well as PZT ceramic are numerically modeled by using hexahedral solid elements. Because the modeling of these thin layers increases the number of degrees of freedom, large-scale structural analyses are performed through the PEGASUS supercomputer, which is installed in our laboratory. In the first stage, the curved shape of the actuator and the internal stress in each layer are obtained by the cured curvature analysis. Subsequently, the displacement due to the piezoelectric force (which is resulted from applied voltage) is also calculated. The performance of composite curved actuator is investigated by comparing the displacements obtained by the variation of thickness and elastic modulus of laminated composite layers. In order to consider the finite deformation in the first analysis stage and include the pre-stress due to curing process in the second stage, nonlinear finite element analyses are carried out.

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Second-order Nonlinear Optical Properties of Amorphous Molecules Based on 5-(4-Diethylamino-benzylidene)-1,3-dimethyl-pyrimidine-2,4,6-trione

  • Lee, Seung-Mook;Rhee, Bum-Ku;Lee, Sang-Ho;Lee, Chul-Joo;Park, Ki-Hong
    • Journal of Photoscience
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    • v.10 no.2
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    • pp.203-208
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    • 2003
  • Two coupled molecules were successfully synthesized by condensation of amine-donor-substituted barbituric acid derivativies as nonlinear optical chromophores. A flexible spacer of the alkyl chain with different lengths of carbon chains (5 and 6 carbons) was introduced between two chromophores, which prevented crystallization and aggregation of molecules. Two coupled molecules (B-Cn-B, n=5, 6) had glass-transition temperatures on a second heating around 81 and 76$^{\circ}C$ without melting points, respectively. To explore the linear optical properties, thin-films were prepared and examined by a photometry method using Nd:YVO$_4$ CW laser. Also, microscopic and macroscopic nonlinear optical properties were measured by Hyper-Rayleigh Scattering (HRS) and the Maker Fringes method using Nd:YAG ps pulse laser, respectively. In spite of the moderate hyperpolarizabilities of coupled molecules, the second order NLO coefficient (d$\_$33/) was larger than the conventional Disperse Red 1 doped PMMA polymeric system.

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The failure analysis of patch bonded repair on Al 6061-T6 alloy structures with cracked bolt hole (볼트 균열 홀을 갖는 알루미늄 6061-T6 합금의 패치 본딩 보수/보강 부위에 대한 파괴역학적 해석에 관한 연구)

  • Yoon, Young-Ki;Kim, Guk-Gi;Park, Jong-Jun;Yoon, Hi-Seak
    • Proceedings of the KSME Conference
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    • 2000.04a
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    • pp.148-152
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    • 2000
  • The aluminum alloy 6061-T6 has been successfully used in structural applications especially the pressure vessel of the Advanced Neutron Source research reactor. And aluminum alloys, including 6061-T6, have a face-centered-cubic crystals structure. Under normal circumstances face-centered-cubic crystal structures do not exhibit cleavage fractures even at very lo9w temperatures. In aluminum-based structures, plates frequently find use as connecting links. Mechanical fasteners are often utilized in instances where ease of application, familiarity with fabrication processes, and severe dynamic loading are of concern. Plates frequently find use as connecting elements in structures built from aluminum alloys. Many structural elements employ mechanical fasteners. Twenty and twenty aluminum alloy 6061-T6 plates, representing four different bolt patterns, were mechanically deformed. And variable materials such as A1 6061-T6, Al 2024-T3, Carbon/Epoxy, Glass/Epoxy Composite and Woven fiber composite, are used as patch materials. From this experiment, it has been shown that the strength of patch-repaired specimens is different with the patch materials.

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A study on the suitability of CFRP CNT and bicycle through service design process (서비스디자인방법론을 통해 분석한 CFRP CNT와 자전거의 적합성에 관한 연구)

  • Park, Sung-Hee;Song, Sung-Il;Kang, Seung-Min
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.6
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    • pp.271-276
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    • 2018
  • Based on the service design processes, we examined the market conditions and the criteria to be considered in selecting materials and selected CFRP CNT materials in the development of bicycle design. This material was used to develop frame design among the bicycle parts. The bicycle frame, designed with CFRP CNT material through vibration attenuation testing, tensile strength testing, and stiffness test results before prototype production, shows better results than the bicycle frame manufactured with conventional CNT materials in terms of function.