• 제목/요약/키워드: Carbon/carbon-based materials

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Copper-Based Electrochemical CO2 Reduction and C2+ Products Generation: A Review (구리 기반 전극을 활용한 전기화학적 이산화탄소 환원 및 C2+ 화합물 생성 기술)

  • Jiwon Heo;Chaewon Seong;Vishal Burungale;Pratik Mane;Moo Sung Lee;Jun-Seok Ha
    • Journal of the Microelectronics and Packaging Society
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    • v.30 no.4
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    • pp.17-31
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    • 2023
  • Amidst escalating global warming fueled by indiscriminate fossil fuel consumption, concerted efforts are underway worldwide to mitigate atmospheric carbon dioxide (CO2) levels. Electrochemical CO2 reduction technology is recognized as a promising and environmentally friendly approach to convert CO2 into valuable hydrocarbon compounds, deemed essential for achieving carbon neutrality. Copper, among the various materials used as CO2 reduction electrodes, is known as the sole metal capable of generating C2+ compounds. However, low conversion efficiency and selectivity have hindered its widespread commercialization. This review highlights diverse research endeavors to address these challenges. It explores various studies focused on utilizing copper-based electrodes for CO2 reduction, offering insights into potential solutions for advancing this crucial technology.

A Study on The Evaluation Criteria of Carbon Emission and the Development of the Evaluation Method in Apartment House (공동주택을 대상으로 한 탄소배출 평가기준 구축 및 평가방법 개발)

  • Choi, Doo-Sung;Chun, Hung-Chan
    • KIEAE Journal
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    • v.13 no.5
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    • pp.79-88
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    • 2013
  • This study creates the evaluation criteria to analyze the $CO_2$ emission quantity in the complex of apartment house among domestic buildings and proposes how to calculate the $CO_2$ emission quantity by the only simple information of apartment house. The study shows that in order to create the index of carbon emission evaluation criteria, $CO_2$ emission quantity for its input materials in these 27 apartment houses are 445,412g-$CO_2/m^2$ for apartment building, 474,322g-$CO_2/m^2$ for the basement parking lot, 483,523g-$CO_2/m^2$ for welfare facility, 729,957g-$CO_2/m^2$ for sales facility, 743,560g-$CO_2/m^2$ for other facility, 26,782g-$CO_2/m^2$ for public facility, 43,659g-$CO_2/m^2$ for landscape, 1,113g-$CO_2/m^2$ for indoor facility, 11,251g-$CO_2/m^2$ for outdoor facility and 891g-$CO_2/m^2$ for common temporary based on the average $CO_2$ emission by facility. We can also see the analysis data that in case of using the selected factors only, the rate of error is 7.51% comparing with the emission quantity by using simplified LCA method this study suggests for the whole range of apartment houses and the rate of error is average 3.24% using selective and main materials. And this it is evaluated that we can get the result which is similar to the actual $CO_2$ emission quantity with only the simple information about the apartment house.

Characteristics of Carbon Source Biosorption (유기물 생흡착 현상에 관한 기초연구)

  • Lee, Dong-Hoon;Lee, Doo-Jin;Kim, Seung-Jin;Chung, Jonwook;Bae, Wookeun
    • Journal of Korean Society on Water Environment
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    • v.22 no.1
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    • pp.23-29
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    • 2006
  • Biosorption technology was used to remove hazardous materials from wastewater, herbicide, heavy metals, and radioactive compounds, based on binding capacities of various biological materials. Biosorption process can be explained by two steps; the first step is that target contaminants is in contact with microorganisms and the second is that the adsorbed target contaminants is infiltrated with inner cell through metabolically mediated or physico-chemical pathways of uptake. Until recently, no information is available to explain the definitive mechanism of biosorption. The purpose of this study is to evaluate biosorption capabilities of organic matters using activated sludge and to investigate affecting factors upon biosorption. Over 49% of organic matter could be removed by positive biosorption reaction under anoxic condition within 10 minutes. The biosorption capacities were constant at around 50 mg-COD/mg-MLSS for all batch experiments. As starvation time increased under aerobic or anaerobic conditions, biosorption capacity increased since higher stressed microorganisms by starvation was more brisk. Starvation stress of microorganisms was higher at aerobic condition than anaerobic one. As temperature increased or easily biodegradable carbon sources were used, biosorption capacities increased. Consequently, biosorption can be estimated by biological -adsorbed capability of the bacterial cell-wall and we can achieve the cost-effective and non -residual denitrification with applying biosorption to the bio-reduction of nitrate.

High-Performance Ionic Polymer-Metal Composite Actuators Based on Nafion/Conducting Nanoparticulate Electrospun Webs (나피온/전도성 나노입자 전기방사 웹을 이용한 고성능 이온성 고분자-금속 복합체 구동기의 제조)

  • Jung, Yo-Han;Lee, Jang-Woo;Yoo, Young-Tai
    • Polymer(Korea)
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    • v.36 no.4
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    • pp.434-439
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    • 2012
  • To improve the performance of ionic polymer-metal composite (IPMC) actuators, Nafion films sandwiched with Nafion/conducting nanoparticulate electrospun webs were used as polymer electrolytes of IPMC. Multiwalled carbon nanotube (MWNT) and silver were the conducting nanoparticulates and the nanoparticles dispersed in a Nafion solution were electrospun. IPMCs with the Nafion/conducting nanoparticulate electrospun webs displayed improved displacements, response rates, and blocking forces. MWNT was superior to silver in terms of displacement and blocking force, and the webs without the conducting fillers also caused enhanced performances compared with the conventional IPMCs. These improvements were attributed to an elevated electrolyte flux through highly porous interlayers and capacitance induced by well dispersed conducting fillers, and low interfacial resistance between electrolyte and electrodes.

Effects of Carbon Nanotube Addition on the Mechanical Properties of Dental Glassionomer Cement (탄소나노튜브 첨가에 의한 치과용 글라스아이오노머 시멘트의 기계적 특성)

  • Kim, Dong-Ae;Kim, Han-Sem;Shin, Ueon-Sang;Lee, Hae-Hyoung
    • Korean Journal of Dental Materials
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    • v.43 no.1
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    • pp.43-50
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    • 2016
  • The aim of this study was to investigate the effect of multiwall carbon nanotube functionalized with carboxyl group (MWCNT-COOH) on the mechanical properties of dental glassionomer cement (GIC). MWCNT-COOH was prepared by the acid oxidative method. The MWCNT-COOH was incorporated into a commercial GIC powder or liquid at 0.5 wt% or 1.0 wt%. The net setting time of the cements was measured in accordance with ISO 9917 (Dental water-based cement). Specimens for compressive strength ($4mm{\varphi}{\times}6mm$), diametral tensile strength ($6mm{\varphi}{\times}4mm$) and flexure strength with modulus ($2mm{\times}2mm{\times}25mm$) were prepared by mixing with the cement liquid and kept in water bath of $(37{\pm}1)^{\circ}C$. Mechanical tests were conducted in 1 d, 7 d, and 14 days at a cross-head speed of 1 mm/min. Compressive strength of GIC mixed with 0.5 wt% MWCNT-COOH increased significantly at 7 d. However, overall mechanical properties of GIC modified with MWCNT were not significantly increased with a delayed setting time, in comparison with control cement. Overall results indicated that the MWCNT/GIC composite cements showed a limited strengthening effect for dental glassionomer cement.

Evaluation of Hydrogen Storage Performance of Nanotube Materials Using Molecular Dynamics (고체수소저장용 나노튜브 소재의 분자동역학 해석 기반 성능 평가)

  • Jinwoo Park;Hyungbum Park
    • Composites Research
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    • v.37 no.1
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    • pp.32-39
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    • 2024
  • Solid-state hydrogen storage is gaining prominence as a crucial subject in advancing the hydrogen-based economy and innovating energy storage technology. This storage method shows superior characteristics in terms of safety, storage, and operational efficiency compared to existing methods such as compression and liquefied hydrogen storage. In this study, we aim to evaluate the solid hydrogen storage performance on the nanotube surface by various structural design factors. This is accomplished through molecular dynamics simulations (MD) with the aim of uncovering the underlying ism. The simulation incorporates diverse carbon nanotubes (CNTs) - encompassing various diameters, multi-walled structures (MWNT), single-walled structures (SWNT), and boron-nitrogen nanotubes (BNNT). Analyzing the storage and effective release of hydrogen under different conditions via the radial density function (RDF) revealed that a reduction in radius and the implementation of a double-wall configuration contribute to heightened solid hydrogen storage. While the hydrogen storage capacity of boron-nitrogen nanotubes falls short of that of carbon nanotubes, they notably surpass carbon nanotubes in terms of effective hydrogen storage capacity.

Characteristics of GHG Emission by Use of Equipments under Track Construction (궤도건설시 장비사용에 따른 온실가스 배출 특성)

  • Jung, Woo-Sung;Lee, Jae-Young;Kim, Jong-Su;Park, Sang-Gu;Hwang, In-Hwan;Lee, Cheol
    • Proceedings of the KSR Conference
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    • 2011.10a
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    • pp.2563-2566
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    • 2011
  • Government has presented a guideline for the calculation of carbon emission with infrastructures in 2011, which aims to manage the GHG(greenhouse gas) emission of construction sector. Generally, the main emission sources of construction works are divided into the fuel consumption of equipments and the use of materials. This study investigated the characteristics of GHG emission with the use of equipments under the construction of railroad track. Track types are classified into ballasted track and concrete track. As a result, the specific GHG emission on the construction of ballasted track at the A line was 39.53 ton $CO_{2e}/km$ and concrete track was 25.54 ton $CO_{2e}/km$. Ballasted track showed higher specific GHG emission than concrete track because of the additional construction works by the use of gravels. In future, it is necessary to study the comparison of GHG emissions with construction methods including the use of materials. Based on these results, the low carbon construction of railroad will be established continuously.

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Study on Fatigue Behavior of Carbon Fiber Reinforced Polyimide Composites (탄소섬유강화 복합적층판의 피로특성에 관한 연구)

  • 이창수;황운봉;한경섭;윤병일
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.1
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    • pp.49-60
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    • 1991
  • Fatigue behavior of carbon fiber reinforced polyimide composite materials was studied experimentally and analytically. The physical variables, such as cyclic displacements and hysteresis loop energy were observed during fatigue tests. Fatigue life of the investigated [0/90]$_{2S}$ laminates was predicted by H'||'&'||'H models which was proposed based on the fatigue modulus and resultant strain. The predicted fatigue life by H'||'&'||'H curves was reasonably close to the experimental data. Fractography study shows that fatigue failure mechanism of [0/90]$_{2S}$ laminated composite materials involves failure break, matrix tearing and fiber-matrix debonding as well as delamination of layers.

Determination of Thermal Decomposition Parameters for Ablative Composite Materials (삭마용 내열 복합재료의 열분해 반응인자 결정)

  • Kim Yun-Chul
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2005.11a
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    • pp.22-25
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    • 2005
  • The thermal degradation of carbon/phenolic composite have been studied at high temperature by using thermogravimetric (TGA). A heating .ate of 5, 10, 15, 30 and $50^{\circ}C/min$ was used for the determination of thermal decomposition parameters of composite materials at high-temperature service. It has been shown that as the heating rates is increased, the peak decomposition rates are occur at higher temperature. Based on results of thermogravimetric analysis, the pyrolysis process is analyzed and physical and mathematical models for the process are proposed. The thermal analysis also has been conducted using transient heat conduction and the in-depth temperature distribution and the density profile were evaluated along the solid rocket nozzle. As a future effort the thermal decomposition parameter determined in this investigation will be used as input to thermal and mechanical analysis when subjected to solid rocket propulsion environment.

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Effects of fiber forms on thermal anisotropy in fibrous composites (섬유강화 복합재의 열이방성에 대한 섬유 형태적 영향)

  • Sim, Hwan-Bo;Lee, Bo-Seong
    • Korean Journal of Materials Research
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    • v.5 no.2
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    • pp.215-222
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    • 1995
  • Anisotropic pitch-based C-type and hollow carbon fibers can obtain wider shear stresses during the spinning and induce higher molecular orientation than that of round along the fiber axis. These fibers reinforced unidirectional epoxy composites were prepared by hot-press moulding method and perpendicular and parallel thermal conductivities of the composites were measured by a steady-state meth od. In the case of round carbon fibers reinforced epoxy composites(H-CF/EP), thermal anisotropic factor showed nearly 50, while those of H-CF/EP and C-CF/EP showed about 130 and 118, respectively. As a result, both H-CF/EP and C-CF/EP had an excellent directional thermal conductivity to distribute heat, above 200 %.

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