• 공업화학
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• 제22권5호
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• pp.495-500
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• 2011

나프타 분해 공정에서 필수적으로 발생되는 분해연료유(PFO, pyrolyzed fuel oil)에서 나프탈렌을 재결정해내고 남는 PFO 잔유물을 이용하여 $300{\sim}800^{\circ}C$에서 질소 조건에서 탄소구조체를 합성하여 보았다. PFO를 헥산이나 메탄올로 처리 후 얻은 탄소물질 프리커서를 열처리하면 $350^{\circ}C$에서는 수 십 ${\mu}m$ 크기의 flake 상의 탄소체가 만들어졌으나, $400^{\circ}C$ 이상에서는 수 ${\mu}m$로 크기가 줄며 공 모양의 탄소구조체로 변형되었다. BET와 XRD 스펙트럼에 따르면 공모양으로 합성된 메조상 탄소체는 큐빅상으로 미세 기공인 mesopore가 아직 잘 발달되지 많은 부정형 탄소임을 알려주고있다.

• 한국대기환경학회지
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• 제29권3호
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• pp.317-324
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• 2013

This research assessed the surface properties of modified activated carbons with three different acids and five different metals for ammonia gas removal. Raw bituminous coal-based activated carbon ($4{\times}8$ mesh) had low adsorption capacity of 0.72 mg $NH_3/g$ based on the analysis in the column adsorption experiment. Adsorption capacities of carbons modified with $CH_3COOH$, $H_3PO_4$, and $H_2SO_4$ increased up to 3.34, 21.00, and 35.21 mg $NH_3/g$, respectively. Those of carbons with Cu, Zn, Zr, Fe, and Sn were 9.63, 9.13, 7.09, 25.12 and 15.03 mg $NH_3/g$. Ammonia adsorption was enhanced by the presence of surface oxygen groups on carbon materials, which influenced pH of carbon surface. BET surface area of raw carbon was analyzed to be $1087m^2/g$, but it decreased by carbon surface modification. Fe-impregnated carbon showed $503.02m^2/g$ of surface area. These observations were mostly caused by chemical adsorption.

• Composites Research
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• 제35권2호
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• pp.80-85
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• 2022

본 연구에서는 항공기 방빙을 위해서 탄소계 소수성 입자인 탄소나노튜브의 코팅 횟수에 따른 테프론-폴리우레탄 탑코트의 나노입자 부착력과 표면 소수성 특성을 평가하기 위하여 실험을 진행하였다. 나노입자 부착력을 측정하기 위해서 인발접착시험을 진행하였고, 표면소수성 특성을 측정하기 위해서 정적접촉각 시험과 거칠기 평가를 진행하였다. 거칠기평가를 통하여 탄소나노튜브가 테프론-폴리우레탄 탑코트에 함침된 정도를 할 수 있었고, USB-현미경을 통하여 테프론-폴리우레탄 탑코트에 탄소나노튜브가 함침 및 분산정도를 확인하였다. 그 결과 코팅횟수가 많을수록 탄소나노튜브가 응집되고 이에 의하여 접착력이 감소한다는 것을 확인하였다. 실험결과 코팅 횟수에 따라 테프론-폴리우레탄의 소수성은 커지고 접착력은 감소하였다. 그로 인해 테프론-폴리우레탄 탑코트 와의 접착력 향상과 최적화된 소수성을 가지는 탄소나노튜브의 코팅횟수를 파악할 수 있었다.

• 한국산학기술학회논문지
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• 제22권1호
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• pp.801-807
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• 2021

전기 전자 부품을 기반으로 하는 통신장비, 컴퓨터, 이동 수단, 전산망, 군사용 장비 등 여러 산업 분야 및 사회기반시설에 있어 전자파 차폐의 필요성이 커지고 있다. 구조물의 전자파 차폐 방법은 차폐 콘크리트, 차폐 문, 차폐 창문과 같이 차폐성능을 가지고 있는 자재를 사용하여 시공하는 방법, 그리고 차폐성능이 없는 재료에 차폐 도료를 코팅하는 방법이 있다. 전자파 차폐 도료는 탄소나노튜브, 흑연, 카본 블랙, 탄소 섬유와 같은 전도성 물질을 사용하여 만들어지며, 일반적으로 사용되고 있는 수성도료에서 전자파 차폐 성능이 추가된 도료이다. 이 연구에서는 전자파 차폐 무기계 도료를 개발하기 위한 목적으로 전도성 흑연, 카본 블랙을 차폐원료로 사용한 도료의 차폐성능 및 부착성능을 평가하였다. 차폐 재료의 종류 및 사용량을 달리한 6개 배합에 대해 차폐성능과 부착강도를 평가하였다. 실험 결과, 전도성 흑연과 카본 블랙을 무게비 1:0.2로 혼합한 배합이 33.6 dB로 차폐성능이 가장 좋은 것으로 확인되었고, 부착성능은 전도성 흑연만 사용한 배합이 1.06 MPa로 가장 높은 것으로 확인되었다.

• 대한건축학회논문집:구조계
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• 제34권2호
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• pp.49-56
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• 2018

The use of highly absorptive materials in cement-based materials is increasing for internal curing purpose. However, calculation of correct absorption capacity of such materials is not easy, which leads to change in the effective water-to-cement ratio of cement paste by either absorbing or releasing water. In this study, effective absorption capacity of a highly absorptive material was found using isothermal calorimetry. Moreover, the effect of specific surface area was investigated. It was found that the method was capable of finding effective water absorption capacity of activated carbon fiber. For the activated carbon fiber used in this research, the effect of specific surface area was negligible because the high BET surface area was due to micropores less than 1nm, which does not affect the rate of hydration curve. Thus, the effective absorption capacity of such materials can be found successfully using this method.

• 한국분말재료학회지
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• 제28권3호
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• pp.253-258
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• 2021

There is increasing demand for the development of a new material with high strength, high stiffness, and good electrical conductivity that can be used for high-voltage direct current cables. In this study, we develop aluminum-based composites containing C₆₀ fullerenes, carbon nanotubes, or graphene using a powder metallurgical route and evaluate their strength, stiffness, coefficient of thermal expansion, and electrical conductivity. By optimizing the process conditions, a material with a tensile strength of 800 MPa, an elastic modulus of 90 GPa, and an electrical conductivity of 40% IACS is obtained, which may replace iron-core cables. Furthermore, by designing the type and volume fraction of the reinforcement, a material with a tensile strength of 380 MPa, elastic modulus of 80 GPa, and electrical conductivity of 54% IACS is obtained, which may compete with AA 6201 aluminum alloys for use in all-aluminum conductor cables.

• Tribology and Lubricants
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• 제33권1호
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• pp.15-22
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• 2017

Because the running speed of vehicles is increasing and a shorter braking distance is required, high heat-resistant brake pads are needed to satisfy the requirements of customers and car makers. In the near future, hazardous materials such as Cu, Cr, Zn, and Sb will be restricted from use in friction materials. Ceramic composites reinforced by carbon fibers are good candidates for eco-friendly friction materials. In this study, we develop ceramic composite friction materials. The friction materials are composed of carbon fibers, Si, SiC, graphite, and phenol resin and are prepared by hot forming and heat treatment at high temperatures. The density, void ratio, and compressive strength are $1.59-1.66g/cm^3$, 16.6-20, and 70-90 MPa, respectively. Friction and wear tests are performed using a pin-on-plate-type reciprocating friction tester at 25, 100, and $200^{\circ}C$. The counterpart material is a CrMoV steel extracted from a KTX brake disc. Friction coefficient, wear amount, and wear mechanism are measured and examined. We determine that the friction coefficients depend on the temperature and the fluctuation of the friction coefficients is larger at higher temperatures. The amount of wear increases with the surface temperatures of the specimens. The tribological properties of the developed composites are similar to those of a Cu-based sintered friction material. Through this study, it is confirmed that ceramic composite materials can be used as friction materials.

• Corrosion Science and Technology
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• 제19권4호
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• pp.163-173
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• 2020

Cavitation corrosion in many industrial plants has recently become a serious issue. Cavitation corrosion has generally been investigated using a vibratory method based on ASTM G32 standard, and the test can be divided into direct cavitation and indirect cavitation. Cavitation corrosion test uses the vibration frequency of the horn of 20 kHz with constant peak-to-peak displacement amplitude. In this work, the peak-to-peak amplitude was controlled from 15 ㎛ to 85 ㎛, and electrochemical measurements were obtained during indirect cavitation. The relationship between cavitation corrosion rate and electrochemical properties was discussed. Corrosion steps of carbon steel at the initial stage under cavitation condition in 3.5 % NaCl can be proposed. When the cavitation strength is relatively low, corrosion of the steel is more affected by the electrochemical process than by the mechanical process; but when the cavitation strength is relatively high, corrosion of the steel is affected more by the mechanical process than by the electrochemical process. This work confirmed that the critical ultrasonic amplitude of 0.42 %C carbon steel is 53.8 ㎛, and when the amplitude is less than 53.8 ㎛, the corrosion effect during the cavitation corrosion process is higher than the mechanical effect.

• 공업화학
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• 제7권2호
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• pp.334-340
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• 1996

석탄을 원료로 하는 탄화 시료로 분자체 특성을 지닌 탄소 흡착제를 제조하였다. 변형제를 사용하여 탄소 분자체를 만들었으며, 변형제 농도 변화에 따른 분자체 특성에 관해 연구하였다. 그리고 탄소 분자체의 성능을 측정키 위해 산소와 질소가스를 사용하였으며, Cahn microbalance(D-200)를 사용하여 탄소 흡착제의 흡착 속도를 측정하였다. 이 실험치를 흡착 속도식에 대입하여 탄소 분자체에 따른 가스의 확산도를 구하였으며, 분자체 성능에 대한 변형제 분자량과 농도의 영향을 나타내었다.

• Carbon letters
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• 제10권4호
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• pp.329-334
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• 2009

In this work, the effect of carbon nanofibers (CNFs) addition on physicochemical characteristics of CNFs-reinforced epoxy matrix nanocomposites was studied. Poly(amide imide) solutions in dimethylformamide were electrospun into webs consisting of $250{\pm}50$ nm fibers which were used to produce CNFs through stabilization and carbonization processes. As a result, the CNFs with average diameter of $200{\pm}20$ nm were obtained after carbonization process. The nanocomposites with CNFs showed an improvement of thermal stability parameters and fracture toughness factors, compared to those of the specimen without CNFs, which could be probably attributed to the higher specific surface area and larger aspect ratio of CNFs, resulting in improving the mechanical interlocking in the nanocomposites. Also, the applied external loading can effectively transfer to CNFs because strong interactions are resulted between the epoxy matrix and the CNFs.