• Smart Structures and Systems
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• v.3 no.2
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• pp.133-146
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• 2007

This paper addresses a new type of broad and stage-based hybrid carbon fiber reinforced polymer (HCFRP) sensor that is suitable for the sensing of infrastructures. The HCFRP sensors, a type of composite sensor, are fabricated with three types of carbon tows of different strength and moduli. For all of the specimens, the active materials are carbon tows by virtue of their electrical conductivity and piezoresistivity. The measurement principles are based on the micro- and macro-fractures of different types of carbon tows. A series of experiments are carried out to investigate the sensing performances of the HCFRP sensors. The main variables include the stack order and volume fractions of different types of carbon tows. It is shown that the change in electrical resistance is in direct proportion to the strain/load in low strain ranges. However, the fractional change in electrical resistance (${\Delta}R/R_0$) is smaller than 2% prior to the macrofractures of carbon tows. In order to improve the resistance changes, measures are taken that can enhance the values of ${\Delta}R/R_0$ by more than 2 times during low strain ranges. In high strain ranges, the electrical resistance changes markedly with strain/load in a step-wise manner due to the gradual ruptures of different types of carbon tows at different strain amplitudes. The values of ${\Delta}R/R_0$ due to the fracture of high modulus carbon tows are larger than 36%. Thus, it is demonstrated that the HCFRP sensors have a broad and stage-based sensing capability.

• Carbon letters
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• v.15 no.3
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• pp.192-197
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• 2014

A hierarchical pore structured novolac-type phenol based-activated carbon with micropores and mesopores was fabricated. Physical activation using a sacrificial silicon dioxide ($SiO_2$) template and chemical activation using potassium hydroxide (KOH) were employed to prepare these materials. The morphology of the well-developed pore structure was characterized using field-emission scanning electron microscopy. The novolac-type phenol-based activated carbon retained hierarchical pores (micropores and mesopores); it exhibited high Brunauer-Emmett-Teller specific surface areas and hierarchical pore size distributions. The hierarchical pore novolac-type phenol-based activated carbon was used as an electrode in electric double-layer capacitors, and the specific capacitance and the retained capacitance ratio were measured. The specific capacitances and the retained capacitance ratio were enhanced, depending on the $SiO_2$ concentration in the material. This result is attributed to the hierarchical pore structure of the novolac-type phenol-based activated carbon.

• Korean Journal of Materials Research
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• v.25 no.12
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• pp.678-682
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• 2015

The electrical property of polymer matrix composites with added carbon powder is studied based on the temperature dependency of the conduction mechanism. The temperature coefficient of the resistance of the polymer matrix composites below the percolation threshold (x) changed from negative to positive at 0.20 < x < 0.21; this trend decreased with increasing of the percolation threshold. The temperature dependence of the electrical property(resistivity) of the polymer matrix composites below the percolation threshold can be explained by using a tunneling conduction model that incorporates the effect of the thermal expansion of the polymer matrix composites into the tunneling gap. The temperature coefficient of the resistance of the polymer matrix composites above the percolation threshold has a positive value; its absolute value increased with increasing volume fraction of carbon powder. By assuming that the electrical conduction through the percolating paths is a thermally activated process and by incorporating the effect of thermal expansion into the volume fraction of the carbon power, the temperature dependency of the resistivity above the percolation threshold can be well explained without violating the universal law of conductivity.

• Journal of the Korea Furniture Society
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• v.22 no.1
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• pp.13-17
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• 2011

Recently, interest in indoor air quality is increasing. Especially, radon radioactivity among the indoor air is a well-known risk factor for lung cancer because of ionizing radiation in the form of ${\alpha}$-particles. This study was carried out to investigate effect of black charcoal and activated carbon for reduction of radon radiation that emitted from building materials. Black charcoal and activated carbon were used as a barrier which was against the infiltration of radon. The source of radon was gypsum board. Two types of charcoal barrier were powder- and board-type with 5 mm, 10 mm thickness respectively. The method for this determination is evaluated radon concentration in chamber. The measurements were performed with radon detector, SARAD3120. Results of this study are as following: Black charcoal and activated carbon confirmed the highly efficient barrier. Radon concentration was reduced from 72% to 85% as compared the control chamber. Radon reduction capability, however, was no difference as barrier's types. Results obtained in ventilation condition, radon concentration shows 5.93 pCi/L on average in the closed condition and shows 2.69 pCi/L in the opened condition.

• Tribology and Lubricants
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• v.30 no.4
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• pp.224-233
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• 2014

We prepared polyester-polyamines to improve the effect of carbon black dispersibility for use in thermal transfer ink, and synthesized polymeric dispersing agents by two-step reactions. In the first step, we made polyester by polycondensing 1,6-hexanediol and adipic acid. The resulting polymers had carboxylic acid, which was linked with polyamine via an acid-base reaction. We then characterized the polyester-polyamine structure by NMR spectroscopy and Fourier transform infrared spectroscopy (FT-IR). We also determined the basic characterizations such as total acid numbers (TAN) (5.0-67.5 mgKOH/g), hydroxyl values (27.1-67.5 mgKOH/g), and molar masses ($M_n=1.6-8.4kg\;mol^{-1}$) for the polyester and total base numbers (TBN) (15.3-57.1 mgKOH/g), hydroxyl values (33.0-79.8 mgKOH/g), and nitrogen contents (1.02-3.48%) for the polyester-polyamine polymers. We thus prepared thermal transfer ink using carbon blacks and the polyester-polyamine dispersing agents, and evaluated the resulting mixtures for printability, adhesive force, storage stability, ink appearance, ink gloss, and processability. These mixtures showed significant dispersibility for carbon black in the ink. Thus, we concluded that the dispersibility of the polymeric materials depended on the polyamine structure and the hydrophilicity-hydrophobicity distribution of the polymeric dispersants.

• Journal of Institute of Convergence Technology
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• v.3 no.1
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• pp.45-49
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• 2013

Spherical active carbon materials have been used for the removal of pollutants in the area of food processing, water treatment, air purification, oral administration. Moreover, they are now expected to make an epoch in the areas of electronics, life science, environmental technology, and so on due to their superior physical properties. Carbon particles should be requested for the edgeless spherical shapes in order to minimize the loss due to the abrasion during the process and/or practical use, but the carbon particles manufactured from petroleum-based pitch do not meet these needs. Nowadays, thus, the spherical active carbon particles carbonized from various spherical polymer beads are studied with thermoplastic and/or thermosetting polymers. In this paper, the synthesis of spherical phenolic beads and furan beads, which are thermosetting polymers, and their carbonization techniques are examined.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2002.10a
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• pp.131-134
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• 2002

Braided carbon fiber reinforced Al matrix composites were developed and characterized. Braided carbon fiber preforms with braiding angles of $30^{\circ}$, $45^{\circ}$ and $60^{\circ}$ were manufactured by using a braiding machine. The manufactured braided carbon fibers were used as reinforcement to fabricate Al matrix composites by employing a pressure infiltration casting method. In the processing of pressure infiltration casting, important processing parameters such as melting temperature, preheating temperature of preform and applied pressure were optimized. Prediction of elastic constants on composites was performed by using the volume averaging method, which utilizes the coordinate transformation and the averaging of stiffeness and compliance constants based upon the volume of each reinforcement and matrix material. The elastic moduli of composites were evaluated by using Resonant Ultrasound Spectroscopy(RUS) method and compared with the elastic moduli obtained from static tensile test method.

• Carbon letters
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• v.18
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• pp.80-83
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• 2016

• Composites Research
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• v.34 no.5
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• pp.290-295
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• 2021

The application of lightweight structural composites to automobiles as a solution in line with global fuel economy regulations to curb global warming is recognized as a megatrend. This study was conducted to provide a technical approach that can respond to the issue of replacing parts that require conductive properties to maximize the application of thermoplastic carbon fiber reinforced plastics (CFRPs), which are advantageous in terms of repair, disposal and recycling. By utilizing the properties of the low-viscosity polymerizable oligomer matrix, it was possible to prepare a thermoplastic CFRP exhibiting excellent impregnation properties while uniformly mixing the conductive filler. Various carbon-based conductive fillers such as carbon black, carbon nanotubes, graphene nanoplatelets, graphite, and pitch-based carbon fibers were filled up to the maximum content, and electrical and thermal conductive properties of the fabricated composites were compared and studied. It was confirmed that the maximum incorporation of filler was the most important factor to control the conductive properties of the composites rather than the type or shape of the conductive carbon filler. Experimental results were observed in which it might be advantageous to apply a one-dimensional conductive carbon filler to improve electrical conductivity, whereas it might be advantageous to apply a two-dimensional conductive carbon filler to improve thermal conductivity. The results of this study can provide potential insight into the optimization of structural design for controlling the conductive properties of thermoplastic CFRPs.

• Carbon letters
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• v.5 no.1
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• pp.27-33
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• 2004

Structural changes of high modulus carbon fiber by oxidation in carbon dioxide gas using SEM, TEM, and XRD have been observed. It was shown that the originally high modulus carbon fiber is composed of highly ordered graphitic crystalline area and non-crystalline area. It was observed that the La increases during the whole oxidation process. It was shown that the oxidation of high modulus carbon fiber initiates at the non-crystalline area and at the ends of fiber. The large pores developed in fiber by direction of fiber length at high temperature ($1,100^{\circ}C$), and the small pores developed on the fiber surface at low temperature ($900^{\circ}C$). In conclusion, it is found that the oxidation of the carbon fiber was progressed through the imperfection.