• Korean Chemical Engineering Research
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• v.50 no.1
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• pp.135-140
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• 2012

In this study, the heats of absorption of $CO_2$ with aqueous solutions of primary, secondary and tertiary amine aqueous solutions were measured in the commercial reaction calorimeter SIMULAR (HEL, UK). The heats of absorption of 30 wt% amine aqueous solutions of MEA (monoethanolamine, primary amine), EAE(2-(ethylamino)ethanol, secondary amine), and MDEA (methyldiethanolamine, tertiary amine) were measured as function of the $CO_2$ loading ratio at $40^{\circ}C$, in each case. In addition, the heats of absorption of sterically-hindered amine aqueous solutions of AMP(2-amino-2-methyl-1-propanol, primary amine), DEA(diethanolamine, secondary amine) and TEA(triethanolamine, tertiary amine) were measured to observe the steric hindrance effect. The heat of absorption is high in the following order regardless of the steric hindrance: primary amine > secondary amine > tertiary amine. The heats of absorption of amines having sterically-hindered substituents surrounding nitrogen atoms are relatively low compare to that of sterically-free amines, although the difference is very small.

• Korean Journal of Applied Biomechanics
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• v.16 no.2
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• pp.1-8
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• 2006

The purpose of this study was to evaluate normalized jerk according to shoes, slope, and velocity during walking. Eleven different test subjects used three different types of shoes (running shoes, mountain climbing boots, and elevated forefoot walking shoes) at various walking speeds(1.19, 1.25, 1.33, 1.56, 1.78, 1.9, 2, 2.11, 2.33m/sec) and gradients(0, 3, 6, 10 degrees) on a treadmill. Since there were concerns about using the elevated forefoot shoes on an incline, these shoes were not used on a gradient. Motion Analysis (Motion Analysis Corp. Santa Rosa, CA USA) was conducted with four Falcon high speed digital motion capture cameras. Utilizing the maximum smoothness theory, it was hypothesized that there would be differences in jerk according to shoe type, velocity, and slope. Furthermore, it was assumed that running shoes would have the lowest values for normalized jerk because subjects were most accustomed to wearing these shoes. The results demonstrated that elevated forefoot walking shoes had lowest value for normalized jerk at heel. In contrast, elevated forefoot walking shoes had greater normalized jerk at the center of mass at most walking speeds. For most gradients and walking speeds, hiking boots had smaller medio-lateral directional normalized jerk at ankle than running shoes. These results alluded to an inverse ratio for jerk at the heel and at the COM for all types of shoes. Furthermore, as velocity increased, medio-lateral jerk was reduced for all gradients in both hiking boots and running shoes. Due to the fragility of the ankle joint, elevated forefoot walking shoes could be recommended for walking on flat surfaces because they minimize instability at the heel. Although the elevated forefoot walking shoes have the highest levels of jerk at the COM, the structure of the pelvis and spine allows for greater compensatory movement than the ankle. This movement at the COM might even have a beneficial effect of activating the muscles in the back and abdomen more than other shoes. On inclines hiking boots would be recommended over running shoes because hiking boots demonstrated more medio-lateral stability on a gradient than running shoes. These results also demonstrate the usefulness of normalized jerk theory in analyzing the relationship between the body and shoes, walking velocity, and movement up a slope.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.10
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• pp.883-892
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• 2009

We evaluated the degradation properties of various alkanolamine absorbents (MEA, AMP, DEA, and MDEA) having different chemical structures for $CO_2$ capture. The degradation of $CO_2$ absorbent in general was known to be caused by oxygen which is in flue gas and by heat source, respectively. To analyze the effect of $CO_2$ and $O_2$ on degree of degradation, we conducted a variety of experiments at $30^{\circ}C$ and $60^{\circ}C$ (oxidative degradation) and $130^{\circ}C$ and $150^{\circ}C$ (thermal degradation), respectively. DEA showed the worst property for oxidative degradation in the presence of oxygen among the alkanolamine absorbents. In the case of thermal degradation, the degradation of absorbent was occurred for most of absorbents at $150^{\circ}C$. Among these absorbents, MEA and DEA gave the worst results. As a result, AMP which is a primary amine and having a steric hindrance showed the best result through the degradation test. But, the degradation of absorbent proceeded easily in the case of DEA which is a secondary amine and having 2 OH groups in terminal position. Consequently, we have evaluated the degree of degradation of various absorbents having different chemical structures to give the basic data for the development of alkanolamine absorbent.

• Survey Research
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• v.12 no.2
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• pp.113-144
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• 2011

The purposes of the present study were (1) to identify the latent classes depending on youth employees' trajectories in job satisfaction and turnover intention and (2) to test the effects of person-job fit(major fit, education level fit, skill level fit) on job satisfaction and turnover intention using Youth Panel 2001. In order to estimate latent classes of job satisfaction and turnover intention changes simultaneously and study probabilities linking latent class membership in trajectory across the two variables, we applied dual trajectory model, an extension of semi-parametric group-based approach, Results showed that four latent classes were identified for job satisfaction, which were defined, based on the trajectory patterns, as increasing group, decreasing group, medium-level group, and high-level group. And, three latent classes estimated for turnover intention were defined as low-level group, maintaining group, and rapidly decreasing group. To test the effects of person-job fit variables, we added the variables as time-dependant variables to the unconditional latent class model. The effect of education level fit and skill level fit were found significant in the groups which are low in job satisfaction and have high in turnover intention. Findings from this study suggest the need to consider trajectory heterogeneity in the study of youth employees' job satisfaction and turnover intention to capture the dynamic dimension of overlap between the two constructs.

• Proceedings of the Korean Geotechical Society Conference
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• 2008.10a
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• pp.1115-1123
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• 2008

When constructing projects such as road embankments, bridge approaches, dikes or buildings on soft, compressible soils, significant settlements may occur due to the consolidation of these soils under the superimposed loads. The compressibility of the soil skeleton of a soft clay is influenced by such factors as structure and fabric, stress path, temperature and loading rate. Although it is possible to determine appropriate relations and the corresponding material parameters in the laboratory, it is well known that sample disturbance due to stress release, temperature change and moisture content change can have a profound effect on the compressibility of a clay. The early research of Tezaghi and Casagrande has had a lasting influence on our interpretation of consolidation data. The 24 hour, incremental load, oedometer test has become, more or less, the standard procedure for determining the one-dimensional, stress-strain behavior of clays. An important notion relates to the interpretation of the data is the ore-consolidation pressure ${\sigma}_p$, which is located approximately at the break in the slope on the curve. From a practical point of view, this pressure is usually viewed as corresponding to the maximum past effective stress supported by the soil. Researchers have shown, however, that the value of ${\sigma}_p$ depends on the test procedure. furthermore, owing to sampling disturbance, the results of the laboratory consolidation test must be corrected to better capture the in-situ compressibility characteristics. The corrections apply, strictly speaking, to soils where the relation between strain and effective stress is time independent. An important assumption in Terzaghi's one-dimensional theory of consolidation is that the soil skeleton behaves elastically. On the other hand, Buisman recognized that creep deformations in settlement analysis can be important. this has led to extensions to Terzaghi's theory by various investigators, including the applicant and coworkers. The main object of this study is to suggestion the modified compression index value to predict settlements by back calculating the $C_c$ from different numerical models, which are giving best prediction settlements for multi layers including very thick soft clay.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.30 no.4
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• pp.329-334
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• 2017

The structures, which are made up with the huge number of degrees-of-freedom and the assembly of substructures, have a great complexity. In order to increase the computational efficiency, the analysis models have to be simplified. Many substructuring techniques have been developed to simplify large-scale engineering problems. The techniques are very powerful for solving nonlinear problems which require many iterative calculations. In this paper, a modal derivatives-based model order reduction method, which is able to capture the stretching-bending coupling behavior in geometrically nonlinear systems, is adopted and investigated for its performance evaluation. The quadratic terms in nonlinear beam theory, such as Green-Lagrange strains, can be explained by the modal derivatives. They can be obtained by taking the modal directional derivatives of eigenmodes and form the second order terms of modal reduction basis. The method proposed is then applied to a co-rotational finite element formulation that is well-suited for geometrically nonlinear problems. Numerical results reveal that the end-shortening effect is very important, in which a conventional modal reduction method does not work unless the full model is used. It is demonstrated that the modal derivative approach yields the best compromised result and is very promising for substructuring large-scale geometrically nonlinear problems.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.28 no.5
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• pp.553-561
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• 2015

The exponential and power law functionally graded material(FGM) theory is reformulated considering the refined shear and normal deformation theory. This theory has ability to capture the both normal deformation effect and exponential and power law function in terms of the volume fraction of the constituents for material properties through the plate thickness. Navier's method has been used to solve the governing equations for all edges simply supported plates on Pasternak elastic foundation. Numerical solutions of vibration analysis of FGM plates are presented using this theory to illustrate the effects of power law index and 3-D theory of exponential and power law function on natural frequency. The relations between 3-D and 2-D higher-order shear deformation theory are discussed by numerical results. Further, effects of (i) power law index, (ii) side-to-thickness ratio, and (iii) elastic foundation parameter on nondimensional natural frequency are studied. To validate the present solutions, the reference solutions are discussed.

• Journal of Korea Water Resources Association
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• v.53 no.11
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• pp.973-983
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• 2020

Recently, SAR (Synthetic Aperture Radar) is being highlighted as a solution to the coarse spatial resolution of remote sensing data in water resources research field. Spatial resolution up to 10 m of SAR backscattering coefficient has facilitated more elaborate analyses of the spatial distribution of soil moisture, compared to existing satellite-based coarse resolution (>10 km) soil moisture data. It is essential, however, to multilaterally analyze how various hydrological and environmental factors affect the backscattering coefficient, to utilize the data. In this study, soil moisture estimated by WCM (Water Cloud Model) and linear regression is compared with in-situ soil moisture data at 5 soil moisture observatories in the Korean peninsula. WCM shows suitable estimates for observing instant changes in soil moisture. However, it needs to be adjusted in terms of errors. Soil moisture estimated from linear regression shows a stable error range, but it cannot capture instant changes. The result also shows that the effect of soil moisture on backscattering coefficients differs greatly by land cover, distribution of vegetation, and water content of vegetation, hence that there're still limitations to apply preexisting models directly. Therefore, it is crucial to analyze variable effects from different environments and establish suitable soil moisture model, to apply SAR to water resources fields in Korea.

• Korean Chemical Engineering Research
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• v.45 no.3
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• pp.258-263
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• 2007

Ammonia water was investigated as a new absorbent of the chemical absorption process for the removal of $CO_2$ in flue gas. The suitable range of ammonia water concentration and $CO_2$ loading ($mol\;CO_2/mol\;NH_3$) were decided in the point of view of $CO_2$ absorption capacity and $NH_4HCO_3$ precipitation. The absorption capacity of $CO_2$ and the precipitation of $NH_4HCO_3$ in liquid phase were calculated by the Pitzer model for electrolyte solution. The $CO_2$ absorption capacity of the ammonia water over $5\;molNH_3/kgH_2O$ was higher than that of conventional amine absorbent. The $CO_2$ loadings where precipitation occurred were decided at various absorbent concentrations. Theses values were higher than 0.5 in the concentration range of $5-14\;molNH_3/kgH_2O$ at 293, 313 K. The absorber for the removal of $CO_2$ in flue gas could be operated without $NH_4HCO_3$ precipitation by using high concentration of ammonia water below these $CO_2$ loading values. The optimum temperature of the ammonia water absorbent for removal of $CO_2$ in flue gas was 297-312 K depending on the concentration of ammonia water.

• Ecology and Resilient Infrastructure
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• v.2 no.3
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• pp.216-223
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• 2015

The conservation project to protect an endangered fish, Gobiobotia naktongensis was executed against declining the gene diversity of the fish after the construction of Youngju Dam in a sand-bed stream (Naeseongcheon Stream). We tried to move the populations of G. naktongensis from submerged planned sites to alternative habitats, bred artificially and augmented the juveniles to optimal habitat, and monitored the results of the restoration implementation. No entity of G. naktongensis was confirmed at the planned submerged sites despite attempting to capture more than 8 times and eventually the movement to alternative habitat could not be implemented. About 40 individuals of G. naktongensis were captured in the Naeseongcheon Stream and a total of 5,000 individuals were artificially spawned up. The population of juvenile inherited the genetic diversity from the brood stock. The bred juveniles were discharged at the selected optimal site that had a habit condition what was similar to their natural habitat. The micro-dispersion around the discharging area was found at the early stages of the augmentation. The re-capturing rate of discharged juveniles was reduced as time passed. The discharged juveniles seemed to adapt to the natural environment of Naeseongcheon Stream. The observation of their high abdominal distension and excrement demonstrated that the juveniles fed successfully in the discharging area. Therefore, securement of genetic homogeneity and enhancement of restoration population of G. naktongensis in upstream and downstream of Youngju Dam site from the artificial seed producing seemed to be primarily successful and long-term monitoring and analysis of the effect was expected to be necessary.