• Title/Summary/Keyword: Capping Material

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Regenerative Endodontic Procedure in Korean Children and Adolescents: A Case Report (한국 소아청소년 근관치료 영역에서 재생치료, 근관치료재생술에 대한 증례보고)

  • An, So-Youn;Kim, Jin-Kyoung;Shim, Youn-Soo
    • Journal of dental hygiene science
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    • v.16 no.4
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    • pp.317-322
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    • 2016
  • Mineral trioxide aggregate (MTA) is widely used in endodontic therapy as a pulp-capping material, root or furcal perforation repair material, and for apexification and obturation of the root canal system. The purpose of this study was to formally document cases of MTA application in South Korean children and adolescents. Through this research, the practice of using MTA will be introduced and familiarized to the clinical practitioners. This study involved endodontic treatment using MTA for fractured crowns in 11- and 12-year-old. The children were followed up for 12 months until the pulp vitality was confirmed; in young permanent teeth with immature roots, the pulp is integral to the process of apexogenesis. These observational results regarding the use of MTA as an apexification material in non-vital immature permanent incisors appear to provide promising results in the search for new materials to meet existing endodontic needs.

Thermal Stable Ni-silicide Utilizing Pd Stacked Layer for nano-scale CMOSFETs (나노급 CMOSFET을 위한 Pd 적층구조를 갖는 열안정 높은 Ni-silicide)

  • Yu, Ji-Won;Zhang, Ying-Ying;Park, Kee-Young;Li, Shi-Guang;Zhong, Zhun;Jung, Soon-Yen;Yim, Kyoung-Yean;Lee, Ga-Won;Wang, Jin-Suk;Lee, Hi-Deok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.10-10
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    • 2008
  • Silicide is inevitable for CMOSFETs to reduce RC delay by reducing the sheet resistance of gate and source/drain regions. Ni-silicide is a promising material which can be used for the 65nm CMOS technologies. Ni-silicide was proposed in order to make up for the weak points of Co-silicide and Ti-silicide, such as the high consumption of silicon and the line width limitation. Low resistivity NiSi can be formed at low temperature ($\sim500^{\circ}C$) with only one-step heat treat. Ni silicide also has less dependence of sheet resistance on line width and less consumption of silicon because of low resistivity NiSi phase. However, the low thermal stability of the Ni-silicide is a major problem for the post process implementation, such as metalization or ILD(inter layer dielectric) process, that is, it is crucial to prevent both the agglomeration of mono-silicide and its transformation into $NiSi_2$. To solve the thermal immune problem of Ni-silicide, various studies, such as capping layer and inter layer, have been worked. In this paper, the Ni-silicide utilizing Pd stacked layer (Pd/Ni/TiN) was studied for highly thermal immune nano-scale CMOSFETs technology. The proposed structure was compared with NiITiN structure and showed much better thermal stability than Ni/TiN.

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Synthesis and Characterization of Y2O3 Powders by a Modified Solvothermal Process

  • Jeong, Kwang-Jin;Bae, Dong-Sik
    • Korean Journal of Materials Research
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    • v.22 no.2
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    • pp.78-81
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    • 2012
  • $Y_2O_3$ nanomaterials have been widely used in transparent ceramics and luminescent devices. Recently, many studies have focused on controlling the size and morphology of $Y_2O_3$ in order to obtain better material performance. $Y_2O_3$ powders were prepared under a modified solvothermal condition involving precipitation from metal nitrates with aqueous ammonium hydroxide. The powders were obtained at temperatures at $250^{\circ}C$ after a 6h process. The properties of the $Y_2O_3$ powders were studied as a function of the solvent ratio. The synthesis of $Y_2O_3$ crystalline particles is possible under a modified solvothermal condition in a water/ethylene glycol solution. Solvothermal processing condition parameters including the pH, reaction temperature and solvent ratio, have significant effects on the formation, phase component, morphology and particle size of yttria powders. Ethylene glycol is a versatile, widely used, inexpensive, and safe capping organic molecule for uniform nanoparticles besides as a solvent. The characterization of the synthesized Y2O3 powders were studied by XRD, SEM (FE-SEM) and TG/DSC. An X-ray diffraction analysis of the synthesized powders indicated the formation of the $Y_2O_3$ cubic structure upon calcination. The average crystalline sizes and distribution of the synthesized $Y_2O_3$ powders was less than 2 um and broad, respectively. The synthesized particles were spherical and hexagonal in shape. The morphology of the synthesized powders changed with the water and ethylene glycol ratio. The average size and shape of the synthesized particles could be controlled by adjusting the solvent ratio.

Field Emission Characteristics of ZnO Nanowires Grown by Hydrothermal Method (수열합성법에 의해 성장된 ZnO 나노와이어의 전계방출 특성)

  • No, Im-Jun;Kim, Sung-Hyun;Shin, Paik-Kyun
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.2
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    • pp.101-105
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    • 2010
  • We fabricated FEDs(Filed emission devices) based on ZnO nanowires. The ZnO nanowires were synthesized on Au thin films by hydrothermal method at the temperature of 90[$^{\circ}C$] on hot plate. In order to form tips of the ZnO nanowire, SDS(Sodium Dodecyl Sulfate) was mixed in O.05-0.3[wt%] solution as capping material. After 2 hour growth, we obtained nanowires of chain form The high-purity nanowires showed sharp tip geometry with a wurtzite structure. The field emission properties of the ZnO nanowires were investigated in high vacuum chamber. The turn-on field for the ZnO nanowires was found to be about 4.1[V/${\mu}m$] at a current density of 0.1[${\mu}A/cm^2$].

Analytical Modeling for Reinforced Concrete Columns with Relaxed Section Details

  • Kim, Taewan;Chu, Yurim;Park, Hong-Gun
    • Architectural research
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    • v.19 no.3
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    • pp.79-87
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    • 2017
  • In earthquake engineering, dynamic analyses are usually conducted by using a nonlinear analytical model of the entire building in order to identify the performance against earthquakes. At the same time, a large number of dynamic analyses are required to consider uncertainties on analytical models and ground motions. Therefore, it is necessary for the analytical model to be adequate, that is to say, the runtime should not be too long as the entire building is modeled to be in much detail, or the nonlinear model should not yield outputs very far from the actual ones by excluding important behaviors too much. The analytical model is usually developed based on experimental results, which have been already conducted for reinforced concrete columns with relaxed details. Therefore, this study aimed at making analytical models to be able to simulate the hysteretic behavior of the columns simply and easily. The analytical model utilizes a lumped hinge model to represent nonlinear moment-rotation hysteretic behavior of RC columns, which is feasible for nonlinear dynamic analyses usually conducted in earthquake engineering and for matching the analytical model to test results. For the analytical model, elements and material models provided by OpenSees are utilized. The analytical model can define the envelope curve, pinching, and unloading stiffness deterioration, but shortcoming of this model is not to be able to consider axial force-moment interaction directly and to simulate strength deterioration after post-capping completely. However, the analytical model can still represent test results well by considering that the goal of this study is to propose a general way to represent the hysteretic behavior of RC columns with relaxed details, not to provide parameters for a refined hysteretic model that can be just applied case by case.

Stabilization of mixed heavy metals in contaminated marine sediment using steel slag (제강슬래그를 이용한 해양오염퇴적물 내 혼합 중금속 안정화)

  • Shin, Woo-Seok;Kim, Young-Kee
    • Journal of Navigation and Port Research
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    • v.38 no.3
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    • pp.269-275
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    • 2014
  • In this study, the adsorption efficiency of mixed heavy metals in aqueous solution was investigated using steel slag. Moreover, heavy-metal stabilization treatment of contaminated marine sediment was achieved using steel slag as stabilizing agents. Heavy metal adsorption was characterized using Freundlich and Langmuir equations. The equilibrium adsorption data were fitted well to the Langmuir model in steel slag. The adsorption uptake of heavy metals were higher in the order of $Pb^{2+}$ > $Cd^{2+}$ > $Cu^{2+}$ > $Zn^{2+}$ > $Ni^{2+}$. The steel slage was applied for a wet-curing duration of 150 days. From the sequential extraction results, the exchangeable, carbonate, and oxides fractions of Ni, Zn, Cu, Pb, and Cd in sediment decreased by 13.0%, 6.0%, 1.3%, 17.0%, and 50.0%, respectively.

Removal Characteristics of Mixed Heavy Metals from Aqueous Solution by Recycled Aggregate as Construction Waste (건설폐기물인 순환골재를 이용한 수용액상에서의 혼합 중금속 제거 특성)

  • Shin, Woo-Seok;Kim, Young-Kee
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.16 no.2
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    • pp.115-120
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    • 2013
  • This study examined the removal rate of mixed heavy metals from aqueous solution using recycled aggregate. The recycled aggregate is favorable for the absorbent because it contains about 95% (CaO, $SiO_2$, $Al_2O_3$ and $Fe_2O_3$), which are major ingredient of adsorbent for heavy metal. The kinetic data presented that the slow course of adsorption follows the Pseudo first and second order models. The equilibrium data were well fitted by the Langmuir model and showed the affinity order: $Cu^{2+}$ > $Pb^{2+}$ > $$Zn^{2+}{\simeq_-}Ni^{2+}$$ > $Cd^{2+}$. The results also showed that adsorption rate slightly increased with increasing pH from 6 to 10. Moreover, this trend is similar to results obtained as function of loading amount of recycled aggregate. Meanwhile, an unit adsorption rate was slightly decreased. From these results, it was concluded that the absorbents can be successfully used the removal of the heavy metals from the aqueous solutions.

GeTe Thin Film의 상 변화가 저항과 Carrier Concentration에 미치는 영향

  • Lee, Gang-Jun;Na, Hui-Do;Kim, Jong-Gi;Jeong, Jin-Hwan;Choe, Du-Jin;Son, Hyeon-Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.292-292
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    • 2011
  • TFT (Thin Film Transistor)에서 공정을 단순화 시키고, 가격을 하락시키기 위해서는 Poly-Si을 대체할 물질이 필요하다. 이 연구에서는 Chalcogenide Material의 하나인 GeTe 박막을 이용하여 TFT Channel으로 사용 가능한 물질인지 알아보기 위하여 Post-Annealing을 한 뒤, 상 변화에 따른 박막의 저항 변화, Carrier Concentration (cm-3)과 Mobility (cm2V-1s-1)의 변화를 알아보았다. Sputtering을 이용하여 증착한 GeTe 100 nm Thin Film 위에 Sputtering을 이용하여 SiO2 5 nm를 Capping Layer로 증착한 후, Post-Annealing을 200$^{\circ}C$, 300$^{\circ}C$, 400$^{\circ}C$, 500$^{\circ}C$로 온도를 변화 시키며 진행하였고, 이로 인하여 GeTe Thin Film에 외부의 영향을 최소화 하였다. 먼저 GeTe Thin Film의 Sheet Resistance를 측정한 결과는 300$^{\circ}C$ 까지 낮은 Sheet Resistance의 거동을 보이며 반면, 400$^{\circ}C$ 이상이 되면 높은 Sheet Resistance의 거동을 보인다. Hall Measurement를 통해, Carrier Concentration과 Mobility를 알아보았다. Carrier Concentration은 온도가 증가하면 1E+19에서 1E+21 까지 증가하며, Mobility는 감소하는 경향을 보인다. 500$^{\circ}C$ Post-Annealed GeTe Thin Film에서는 Resistivity가 상당히 높아 4 Point Probe (Range : 1 mohm/sq~2 Mohm/sq)로 측정이 불가능하다. XRD로 GeTe Thin Film을 분석한 결과 as-grown, 200$^{\circ}C$, 300$^{\circ}C$에서는 Cubic의 결정 구조를 보이며, Sheet Resistance가 급격히 증가한 400$^{\circ}C$, 500$^{\circ}C$에서는 Rhombohedral의 결정구조를 보인다. GeTe Thin Film은 400$^{\circ}C$ 이상의 Post-Annealing 온도에서 cubic 구조에서 Rhombohedral 구조로 상 변화가 일어난다. 위 결과를 통해, 결정 구조의 변화가 GeTe Thin Film의 저항, Carrier Concentration과 Mobility에 밀접한 영향이 미치는 것을 확인하였다.

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Adsorption characteristics of synthetic heavy metals ($Zn^{2+}$, $Ni^{2+}$, $Cd^{2+}$, $Cu^{2+}$, and $Pb^{2+}$) by bentonite (벤토나이트에 의한 혼합 중금속($Zn^{2+}$, $Ni^{2+}$, $Cd^{2+}$, $Cu^{2+}$$Pb^{2+}$) 수용액상에서의 중금속 흡착 특성)

  • Shin, Woo-Seok;Kim, Young-Kee
    • Journal of the Korea Organic Resources Recycling Association
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    • v.22 no.2
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    • pp.17-26
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    • 2014
  • In this study, the adsorption efficiency of mixed heavy metals from an aqueous solution was examined using bentonite. The physical and chemical properties of bentonite was analyzed via scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR), Further, heavy metal adsorption was characterized using Freundlich and Langmuir equations. Equilibrium adsorption data were fitted well to the Langmuir model for bentonite. The adsorption uptake of heavy metals was high and followed the order $Pb^{2+}$ > $Cu^{2+}$ > $Cd^{2+}$ > $$Zn^{2+}{\sim_=}Ni^{2+}$$. The results also showed that adsorption uptake slightly increased as increasing pH from 6 to 10. The bentonite surface was observed viay SEM and FT-IR; Si-O and Si-O-Al were found to be the main functional groups by FT-IR analysis. From these results, the adsorption mechanisms of heavy metal were not only surface adsorption and ion exchange, but also surface precipitation. Thus, bentonite could be a useful adsorbent for treating heavy metal in aqueous solution.

RESTORATION OF A FRACTURED CENTRAL INCISOR USING TOOTH FRAGMENT : CASE REPORT (상악 영구중절치의 외상환자에서 치아파절편을 이용한 치험례)

  • Choi, Eun-Young;Choi, Nam-Ki;Yang, Kyu-Ho
    • Journal of the korean academy of Pediatric Dentistry
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    • v.30 no.4
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    • pp.715-721
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    • 2003
  • Dental injuries with crown fracture occur frequently, especially in young patient Reattachment of the crown fragment has been shown to yield good esthetic results in that original tooth anatomy is restored with a material that abrades at a rate indntical to that of the adjacent tooth substance and at the same time permits continual monitoring of pulpal status through the fragment. Case 1 was complicated crown fracture with pin-point bleed ing, that was treated by direct pulp capping with calcium hydroxide and fragment reattachment. Case 2 was in trusive luxation with complicated crown fracture and was treated by pulp treatment and fragment reattachment. Case 3 was uncomplicated crown fracture, and fracture line involved slightly biologic width and treated by reattachment of the crown fragment.

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