• 제목/요약/키워드: Capillary method

검색결과 503건 처리시간 0.036초

Chiral Separation of Aromatic Acids by Capillary Electrophoresis Using HP $\beta$-Cyclodextrin as the Chiral Selector

  • La, Soo-Kie;Kim, Ji-Young;Kim, Jung-Han;Kim, Kyoung-Rae
    • 대한약학회:학술대회논문집
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    • 대한약학회 2002년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2
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    • pp.399.2-399.2
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    • 2002
  • Capillary electrophoretic direct chiral separation method is described for the determination of the absolute configuration of chiral aromatic acids, The enantiomeric separation was achieved by capillary electrophoresis using HP $\beta$-cyclodextrin (CD) as the chiral selector. The effect of CD concentration was investigated to optimize the chiral separation and resolution. When applied to microbial culture fluid. the present method allowed positive identification of chiral aromatic acids and their chirality as well.

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스크린메쉬윅 히트파이프에서 윅의 기공율변화에 따른 열수송한계의 이론적 고찰 (Theoretical Analysis of Heat Transportation Limitation by Porosity of Wick in Screen Mesh Wick Heat Pipe)

  • 이기우;박기호;전원표;이욱현
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.1-6
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    • 2003
  • The purpose of the present study is to investigate the capillary heat transportation limitation in heat pipe according to the change of screen mesh wick porosity. Diameter of pipe was 6 mm, and mesh numbers are 100, 150, 200 and 250 and water was selected as a working fluid. According to the change of wick porosity and mesh number, the capillary pressure, pumping pressure, liquid friction coefficient in wick, vapor friction coefficient, and capillary heat transportation limitation are analyzed by theoretical design method of a heat pipe. As some results, the capillary heat transportation limitation in screen mesh wick heat pipe is largely affected by wick porosity and mesh number.

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Development of analytical method capable of identifying the chemically or biologically oriented variants of human growth hormone by capillary electrophoresis

  • Shin, Hyoung-Goo;Hong, Sung-Tae;Son, Jae-Woon;Youn, Yu-Seok;Han, Hye-Seon;Lee, Kang-Choon
    • 대한약학회:학술대회논문집
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    • 대한약학회 2003년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2-2
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    • pp.230.3-231
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    • 2003
  • The therapeutic use of protein pharmaceuticals produced by recombinant DNA technology is increasing in recent decades. In order to investigate the quality of recombinant proteins, it is important to identify and assign the impurities produced in the process of recombination or in storage conditions. Capillary Electrophoresis is emerging technology exhibiting high sensitivity, selectivity and speed and may be most powerful tools for this application. In this study, human growth hormone (hGH) has been analyzed by various mode of capillary electrophoresis such as capillary zone electrophoresis (CZE), capillary gel electrophoresis (CGE), and capillary isoelectric focusing (cIEF) to indicate the chemically or biologically oriented variants and the degraded fragments. (omitted)

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자기보상형 유정압저어널베어링의 기본특성 (Basic Characteristics of a Self-Compensated Hydrostatic Journal Bearing)

  • 박천홍;이영준;홍성욱;이후상
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2004년도 추계학술대회 논문집
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    • pp.227-230
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    • 2004
  • A self-compensated water-hydrostatic bearing has advantages in bearing stiffness. In this paper, the mechanism is applied to hydrostatic journal bearing for achieving the high bearing stiffness. The finite element method is applied to analyze the load characteristics of the self-compensated journal bearing. From the analyzed results, it is confirmed that though the self-compensated journal bearing has higher load capacity and stiffness than conventional fixed capillary journal bearing, the merit is decreased in the case of high eccentricity, that is, a spindle system with self-compensated journal bearing must be designed to have the load capacity large enough. For improving the practicality, a rectangular type capillary is introduced and discussed. Theoretically analyzed results show that it has more advantages than the conventional annular type capillary in the practical usage. The experimental verification on the analysis method is performed, and the experimental results show good agreement with theoretical results.

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Capillary Force Lithographic Patterning of a Thermoplastic Polymer Layer for Control of Azimuthal Anchoring in Liquid Crystal Alignment

  • Kim, Hak-Rin;Shin, Min-Soo;Bae, Kwang-Soo;Kim, Jae-Hoon
    • Journal of Information Display
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    • 제9권1호
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    • pp.14-19
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    • 2008
  • We demonstrated the capillary force lithography (CFL) method for controlling the azimuthal anchoring energy of a liquid crystal (LC) alignment layer. When a thermoplastic polymer film is heated to over the glass transition temperature, the melted polymer is filled into the mold structure by the capillary action and the aspect ratio of the pattern is determined by the dewetting time of the CFL process. Here, the proposed method showed that the azimuthal anchoring energy of the LC alignment layer could be simply controlled by the surface relief patterns which were determined by the dewetting times during the CFL patterning.

2단계 모세관 리소그라피 기술을 이용한 마이크로/나노 병합구조 공정 기술 및 수학적 모델을 통한 표면 특성 분석 (Fabrication of polymer hierarchical structures by two-step temperature-directed capillary)

  • 서갑양;정훈의;이성훈;김재관
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2005년도 추계학술대회 논문집
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    • pp.272-274
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    • 2005
  • A simple method for fabricating micro/nanoscale hierarchical structures is presented using a two-step temperature-directed capillary molding technique. This lithographic method involves a sequential application of molding process in which a uniform polymer-coated surface is molded with a patterned mold by means of capillary force above the glass transition temperature of the polymer. Using this approach, multiscale hierarchical structures for biomimetic functional surfaces can be fabricated with precise control over geometrical parameters and the wettability of a solid surface can be designed in a controllable manner.

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Determination of Pd(II) and Pt(II) Metal Cyano Complexes Using Capillary Electrophoresis

  • Lee, Hue-Jin;Lee, Sang-Ho;Chung, Koo-Soon;Lee, Kwang-Woo
    • Bulletin of the Korean Chemical Society
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    • 제15권11호
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    • pp.945-949
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    • 1994
  • Mixtures of cyano complexes of palladium(II) and platinum(II) were separated by capillary electrophoresis using a fused silica capillary as a separation column and 30 mM phosphate buffer (pH 7) containing 15 wt. % acetonitrile as a running buffer. By virtue of the high ionic mobilities of the negatively charged cyano complexes of Pd(II) and Pt(II), they were separated using a cathodic injection and anodic detection scheme. The metal complexes eluted through the capillary were detected by direct UV absorption at 214 nm. A linear relationship between peak area and concentration was obtained for both ions and the detection limit was lower than $10^{-14}$ mole. The proposed method was applied to real sample, e.g., anode slime obtained from an electrolytic copper refinary, as a method for the simultaneous determination of palladium and platinum.

Estimation of Surface Forces in Micro Rough Surface Contacts

  • Kim, Doo-In;Ahn, Hyo-Sok;Choi, Dong-Hoon
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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    • pp.63-64
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    • 2002
  • In a micro-scale contact, surface forces such as capillary force and van der Waals Interaction significantly Influence the contact between asperities of rough surfaces. Little is, however, known about the variation of these surface forces as a function of chemical property of the surface (hydrophilicity), relative humidity and deformation of asperities In the real area of contact. A better understanding of these surface forces is of great necessity in order to find an optimal solution for reducing friction and adhesion of micro surfaces. We proposed an effective method to analyze capillary and van der Waals forces In nano-scale contact. In this method, Winklerian foundation model was employed to analyze the contact of rough surfaces that were obtained from atomic force microscopy (AFM) height Images. Self-mated contact of diamond-like-carbon (DLC) coatings was analyzed, as an example, by the proposed model. It was shown that the capillary force was significantly influenced by relative humidify and wet angle of the DLC surface. The deformation of asperities to a critical magnitude by external loading led to a considerable increase of both capillary and van der Waals forces.

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거친 표면간의 미세 접촉에서의 표면력 해석 (Analysis of Surface Forces in Micro Contacts between Rough Surfaces)

  • 김두인;안효석;최동훈
    • 대한기계학회논문집A
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    • 제26권10호
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    • pp.2180-2186
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    • 2002
  • In a micro-scale contact, capillary force and van der Waals interaction significantly influence the contact between asperities of rough surfaces. Little is, however, known about the variation of these surface forces as a function of chemical property of the surface (wet angle), relative humidity and deformation of asperities in the real area of contact. A better understanding of these surface forces is of great necessity in order to find a solution for reducing friction and adhesion of micro surfaces. The objective of this study is to investigate the surface forces in micro-scale rough surface contact. We proposed an effective method to analyze capillary and van der Waals forces in micro-scale contact. In this method, Winkler spring model was employed to analyze the contact of rough surfaces that were obtained from atomic force microscopy (AFM) height images. Self-mated contact of DLC(diamond like carbon) coatings was analyzed, as an example, by the proposed model. It was shown that the capillary force was significantly influenced by relative humidity and wet angle of the DLC surface. The deformation of asperities to a critical magnitude by external loading led to a considerable increase of both capillary and van der Waals forces.

Capillary Zone Electrophoresis를 이용한 음이온 동시분석에 관한 연구 (Analysis of Inorganic Acids by Capillary Zone Electrophoresis)

  • 박성우;진광호;유재훈;김동환;서배석;김영상
    • 분석과학
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    • 제11권3호
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    • pp.213-221
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    • 1998
  • Bromide, chloride, fluoride, nitrite, nitrate, sulfite, sulfate, perchlorate, chlorate 및 chlorite가 포함된 시료를 capillary zone electrophoresis(CZE)와 indirect UV detection 방법으로 분리하였다. 음이온류의 분리는 running buffer로 5 mM ammonium dichromate, 10 mM ammonium acetate, 20 mM diethylenetriamine, 10% methanol(pH 9.3)을 사용하였으며 전압은 cathode에 15 kV를 공급하였다. 또한 최초로 CZE에서 음이온의 정량이 가능하도록 각 이온들에 대한 regression과 detection limit를 결정하였고, 이 분석방법은 톨루엔을 흡입한 사람의 뇨, 부검 혈액, 폐수 및 폭약 등 시료에 적용하였으며, 음이온의 함량을 ion chromatograph(IC)와 비교 검토하였다.

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