• Title/Summary/Keyword: Capacity retention

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mprovement of Estimation Method of Load Capture Ratio for Design and Evaluation of Bio-retention LID Facility (생태저류지 LID 시설의 설계 및 평가를 위한 삭감대상부하비 산정방법 개선)

  • Choi, Jeonghyeon;Lee, Okjeong;Kim, Yongseok;Kim, Sangdan
    • Journal of Korean Society on Water Environment
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    • v.34 no.6
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    • pp.569-578
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    • 2018
  • To minimize the negative alterations in hydrologic and water quality environment in urban areas due to urbanization, Low Impact Development (LID) techniques are actively applied. In Korea, LID facilities are classified as Non-point Pollution Reduction Facilities (NPRFs), and therefore they are evaluated using the performance evaluation method for NPRFs. However, while LID facilities are generally installed in small, distributed configuration and mainly work with the infiltration process, the existing NPRFs are installed on a large scale and mainly work with the reservoir process. Therefore, some limitations are expected in assessing both facilities using the same method as they differ in properties. To solve these problems, in this study, a new method for performance evaluation was proposed with focus on bio-retention LID facilities. EPA SWMM was used to reproduce the hydrologic and water quality phenomena in study area, and SWMM-LID module used to simulate TP interception performance by installing a bio-retention cell under various conditions through long-term simulations. Finally, an empirical formula for Load Capture Ratio (LCR) was derived based on storm water interception ratio in the same form as the existing method. Using the existing formula in estimating the LCR is likely to overestimate the performance of interception for non-point pollutants in the extremely low design capacity, and also underestimate it in the moderate and high design capacity.

Effect of Substituted Groups on the Retention of Monosubstituted Phenols in Reversed-Phase Liquid Chromatography (역상 액체 크로마토그래피에서 페놀 일치환체들의 머무름에 미치는 치환기들의 영향)

  • Kim, Hun Ju;Lee, In Ho;Lee, Dae Un
    • Journal of the Korean Chemical Society
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    • v.38 no.8
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    • pp.562-569
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    • 1994
  • The retention data of twenty one monosubstituted phenols in the eluent systems containing 30∼70% of methanol or acetonitrile as organic modifiers, on $ C_{18}$ and Phenyl columns were collected to investigate the effect of the substituted groups on the retention of phenols. The capacity factors of the solutes except amino phenols are greater on $ C_{18}$ than on Phenyl column. And all the solutes have shown greater capacity factors in methanol-water than that in acetonitrile-water as a mobile phase. Generally the elution order between meta and para isomers of monosubstituted phenols in consistent (p < m) regardless of the polarity of the substituted group. But the elution order between ortho and meta isomers of phenol varies with regard to the polarity of the substituted group. The retention of the monosubstituted phenols has been influenced by the interaction between the solute and unreacted silanol of columns as well as the interaction between the solute and $ C_{18}$ or phenyl group of columns. And then, the effect of unreacted silanol on the retention of the monosubstituted phenols is greater on $ C_{18}$ than on Phenyl column. And the greater hydrogen bonding acceptor basicity(${\beta}$) of the substituted group is, the greater this effect is. The relationship between the retention of the monosubstituted phenols and their parameters such as van der Waals volume(VWV) and hydrogen bonding acceptor basicity(${\beta}$) has been investigated. The good linearity has been observed in the plot log k' vs. (1.01VWV/100-1.84${\beta}$). In consequence, the retention of the monosubstituted phenols on $ C_{18}$ and Phenyl columns can be easily predicted by the parameter (1.01VWV/100-1.84${\beta}$).

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Soil Properties Affecting the Adsorption of Lead (Pb의 흡착에 영향을 미치는 토양의 특성)

  • 박상원
    • Journal of Environmental Science International
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    • v.8 no.1
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    • pp.69-74
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    • 1999
  • Soil properties which affect the retention of Pb(I) were investigated in the laboratory. It was determined, through selective removal, that organic matter and Fe-oxides are of lesser importance in influencing Pb retention than are soil clay minerals. The following trend : clays > organic matter > Fe-oxides represents the relative importance of each constituent in the adsorption of Pb by soils. The consistently greater Pb uptake by surface over subsurface samples was apparently due to differences in organic matter content, inasmuch as organic matter removal from both resulted in similar adsorption characteristics. All five soils stooled exhibited a pH-dependent trend of adsorption. The extent of Pb adsorption was least at low pH values(4~5), was maximum in the neutral pH range, and leveled off or diminished under more alkaline conditions. There was no strong correlation between Pb uptake and soil cation exchange capacity as routinely measured by the NH$_4$OAc method. A knowledge of clay mineralogy in conjunction with soil pH is suggested as being the most reliable guide to predicting Pb retention by soils.

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Electrochemical Performance of M2GeO4 (M = Co, Fe and Ni) as Anode Materials with High Capacity for Lithium-Ion Batteries

  • Yuvaraj, Subramanian;Park, Myung-Soo;Kumar, Veerasubramani Ganesh;Lee, Yun Sung;Kim, Dong-Won
    • Journal of Electrochemical Science and Technology
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    • v.8 no.4
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    • pp.323-330
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    • 2017
  • $M_2GeO_4$ (M = Co, Fe and Ni) was synthesized as an anode material for lithium-ion batteries and its electrochemical characteristics were investigated. The $Fe_2GeO_4$ electrode exhibited an initial discharge capacity of $1127.8mAh\;g^{-1}$ and better capacity retention than $Co_2GeO_4$ and $Ni_2GeO_4$. A diffusion coefficient of lithium ion in the $Fe_2GeO_4$ electrode was measured to be $12.7{\times}10^{-8}cm^2s^{-1}$, which was higher than those of the other two electrodes. The electrochemical performance of the $Fe_2GeO_4$ electrode was improved by coating carbon onto the surface of $Fe_2GeO_4$ particles. The carbon-coated $Fe_2GeO_4$ electrode delivered a high initial discharge capacity of $1144.9mAh\;g^{-1}$ with good capacity retention. The enhanced cycling performance was mainly attributed to the carbon-coated layer that accommodates the volume change of the active materials and improves the electronic conductivity. Our results demonstrate that the carbon-coated $Fe_2GeO_4$ can be a promising anode material for achieving high energy density lithium-ion batteries.

Evaluation of Overburden Pressure on Soil-Water Retention Characteristics of Unsaturated Weathered Soils (상재하중의 영향을 고려한 불포화 풍화토의 함수특성 평가)

  • Park, Jai-Young;Park, Seong-Wan
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.111-118
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    • 2008
  • The purpose of this paper was to investigate the overburden effect on soil-water characteristic curve and unsaturated permeability of unsaturated weathered soils. For this, unsaturated suction and permeability tests under various overburden stress were conducted respectively. Then, the coefficient of unsaturated permeability and moisture capacity of weathered soils were estimated and compared. All these results are presented in the paper.

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Retention of Benzoic Acids in RPLC (역상액체크로마토그래피에서 벤조산류의 머무름)

  • Lee, Jae-Seok;Choi, Beom-Suk
    • Analytical Science and Technology
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    • v.13 no.3
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    • pp.269-276
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    • 2000
  • Chromatographic retention mechanism of seven benzoic acids in RPLC were investigated. Inorganic salt is pertinent for the measurement of dead time in benzoic acid. Logarthims of capacity factor (log k') and Hildebrand solubility parameter (${\delta}$) showed proportional relationship which imply the hydrophobic effect of the retention mechanism in RPLC. Enthalpies of solute transfer showed inverse proportion to temperature and organic modifier ratio of the mobile phase. It was found that the S value showed positive slope in plot of log k' vs. volume fraction of water in mobile phase. Free energy change increases with increasing organic volume fraction. The hydrophobicity index, ${\varphi}_0$(organic volume fraction) is inversely proportional to column temperature.

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Optimum Capacity of Retention Basin for Treating Nonpoint Pollutants and Its Removal Efficiency in Industrial Complex Areas (산업단지내 비점오염물질 처리를 위한 적정 저류조 용량 산정 및 처리효율)

  • Kim, Lee-Hyung;Lee, Byung-sik;Kwon, Soo-Youl
    • Journal of Wetlands Research
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    • v.7 no.3
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    • pp.75-85
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    • 2005
  • The Construction of industrial complex areas means the increase of imperviousness rate and the increase of nonpoint pollutant emissions during a rainfall. Generally the retention basin can become the alternative for removing and controling these nonpoint pollutants. Recently Ministry of Environment are trying to change the purpose of retention basins from flooding control to nonpoint pollutant control. In order to propel the stormwater management program, administration plan of stormwater management is enacted in Spring, 2005. Hereafter, in a newly developing area, the best management practices should be established to control the nonpoint pollutant. Landuses of the research area are classified to the categories of the 1st manufacturing industry, metal industry, fiber and chemical product manufacturing industry, etc. Therefore, this research was performed to understand washed-off characteristics of stormwater and to suggest the controling method of nonpoint pollutants. The optimum capacity of the retention basin can be determined by analyzing the relationships among data of rainfall, runoff, washed-off pollutants from the areas. The rainfall analysis using the data of normal year, recent 2, 5 and 10 years shows that the 80% rainfall frequency was occurred on 10mm accumulated rainfall, but which is not considered the first flush effect. However, by considering the first flush effect, the appropriate treatment capacity of rainfall can be decreased to 4-5mm accumulated rainfall. Using the criteria, the optimum capacity of retention basin is determined to $12,000m^3$ in the research area. The washed-off nonpoint pollutant loading from the areas have beeb calculated to 435ton/yr for TSS, 238ton/yr for COD, 8,518kg/yr for TKN and 1,816kg/yr for TP. The mass of 78.3ton/yr for TSS, 20.4ton/yr for BOD, 128.6ton/yr for COD, 4.6ton/yr for TKN and 980kg/yr for TP can be reduced by constructing the retention basin. The sediment accumulation rate is also calculated by $6.53kg/m^2-hr$.

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Amorphous Lithium Lanthanum Titanate Solid Electrolyte Grown on LiCoO2 Cathode by Pulsed Laser Deposition for All-Solid-State Lithium Thin Film Microbattery (전고상 리튬 박막 전지 구현을 위해 펄스 레이저 증착법으로 LiCoO2 정극위에 성장시킨 비정질 (Li, La)TiO3고체 전해질의 특성)

  • 안준구;윤순길
    • Journal of the Korean Ceramic Society
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    • v.41 no.8
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    • pp.593-598
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    • 2004
  • To make the all-solid-state lithium thin film battery having less than 1 fm in thickness, LiCoO$_2$ thin films were deposited on Pt/TiO$_2$/SiO$_2$/Si substrate as a function of Li/Co mole ratio and the deposition temperature by Pulsed Laser Deposition (PLD). Especially, LiCoO$_2$ thin films deposited at 50$0^{\circ}C$ with target of Li/Co=1.2 mole ratio show an initial discharge capacity of 53 $\mu$Ah/cm$^2$-$\mu$m and capacity retention of 67.6%. The microstructural and electrochemical properies of (Li, La)TiO3 thin films grown on LiCoO$_2$Pt/TiO$_2$/SiO$_2$/Si structures by Pulsed Laser Deposition (PLD) were investigated at various deposition temperatures. The thin films grown at 10$0^{\circ}C$ show an initial discharge capacity of approximately 51 $\mu$Ah/cm$^2$-$\mu$m and moreover show excellent discharge capacity retention of 90% after 100 cycles. An amorphous (Li, La)TiO$_3$ solid electrolyte is possible for application to solid electrolyte for all-solid-state lithium thin film battery below 1 $\mu$m.

Effects of wearing disposable diaper with the endothermic agent on thermal responses of infant (흡열제가 첨가된 일회용 기저귀의 착용이 유아의 온열생리적 반응에 미치는 영향)

  • 성유진;이수원
    • Journal of the Korean Society of Clothing and Textiles
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    • v.23 no.4
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    • pp.499-509
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    • 1999
  • This study was carried out to investigate the effects of wearing disposable diaper with the endothermic agent on thermoregulatory response of infant. Five healthy female infants aged about 5 months were taken as a subject of this experiment. Experimental diapers were six kinds of disposable diaper constructed of nonwoven tissue, fluff pulp, super absorbent polymer, back sheet film, leg elastic, and 0g urea(A) 1g urea(B) , 2g urea(C), 3g urea (D), 4g urea(E) 5g, urea(F) respectively. Urea(98% or over purity) was used as an endothermic agent. Experiment was proceeded while infants were sleeping at 27.5$\pm$0.5$^{\circ}C$, 50$\pm$5% R.H, 0.04m/sec. Each disposable diaper's properties was tested. During the experiment rectal temperature skin temperature of 9 areas temperature inside the disposable diapers were measured, the results were as follows : 1) There was not significant difference among the diapers in absorption capacity retention capacity and rewet(p=0.05). The absorption under load was showed to A, B,

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Influence of Sputtering Conditions on Structural and Electrochemical Properties of the Si Anode Film for Lithium Secondary Batteries (리튬 이차전지에서 Si 음극박막의 스퍼터링 증착조건에 따르는 구조적, 전기화학적 특성 연구)

  • Joo, Seung-Hyun;Lee, Seong-Rae;Cho, Won-Il;Cho, Byung-Won
    • Korean Journal of Materials Research
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    • v.19 no.2
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    • pp.73-78
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    • 2009
  • This study investigated the dependence of the various sputtering conditions (Ar pressure: $2{\sim}10\;mTorr$, Power: $50{\sim}150\;W$) and thickness ($50{\sim}1200\;nm$) of Si thin film on the electrochemical properties, microstructural properties and the capacity fading of a Si thin film anode. A Si layer and a Ti buffer layer were deposited on Copper foil by RF-magnetron sputtering. At 10 mTorr, the 50 W sample showed the best capacity of 3323 mAh/g, while the 100 W sample showed the best capacity retention of 91.7%, also at 10 mTorr. The initial capacities and capacity retention in the samples apart from the 50W sample at 10 mTorr were enhanced as the Ar pressure and power increased. This was considered to be related to the change of the microstructure and the surface morphology by various sputtering conditions. In addition, thinner Si film anodes showed better cycling performance. This phenomenon is caused by the structural stress and peeling off of the Si layer by the high volume change of Si during the charge/discharge process.