• Title/Summary/Keyword: Capacity Ratio

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Studies on the Chelating Agent-Impregnated Resins for the Adsorption and Separation of Metal Ions (Ⅰ). 8-Hydroxyquinoline-Impregnated Resins (금속이온 흡착 및 분리를 위한 킬레이트 시약-침윤수지에 관한 연구 (제1보). 8-Hydroxyquinoline-침윤수지)

  • Dai Woon Lee;Tack Hyuck Lee;Kwang Ha Park
    • Journal of the Korean Chemical Society
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    • v.27 no.5
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    • pp.353-360
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    • 1983
  • The adsorption behavior of 8-hydroxyquinoline (8HQ) on Amberlite XAD-4 and-7 resins was investigated by measuring its distribution coefficients under various experimental conditions, such as shaking time, pH and concentration of methanol in the medium. The application of 8HQ-impregnated-XAD resins for the absorption and separation of metal ions was studied. The maximum adsorption of 8HQ on XAD resins was observed in the 30% methanol solution having pH range from 6.0 to 9.0. The impregnation capacities of XAD resins for 8HQ were 3.81${\times}$10-2mmol, 8HQ/g, XAD-4 resins and 2.60${\times}$10-2mmol, 8HQ/g, XAD-7 resin, respectively. The 8HQ-impregnated-XAD resins were stable in pH range from 6.0 to 10.0 and the amount of 8HQ leached from XAD-4 resin by eluting with hydrochloric acid(above 5M) was negligible. The optimum pH range for the adsorption of metal ions on 8HQ-impregnated XAD resin was also 6.0 to 10.0, and the adsorption mole ratio of metal ion to 8HQ were 1 : 2 for Cu(II), Cd(II) and Ni(II), and 1 : 3 for Fe(III) at the above pH range. It was found that the absorbed metal ions on 8HQ-impregnated-XAD resins were recovered quantitatively with 5M HCl and 8HQ-impregnated-XAD-4 resin could be reusable over 5 times without decrease in its impregnation capacity.

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The Stability Evaluation Methods of Embankment on Soft Clay (연약지반 성토의 안정평가 방법)

  • Kang, Yea Mook;Lee, Dal Won;Kim, Ji Hoon;Kim, Tae Woo;Lim, Seong Hun
    • Korean Journal of Agricultural Science
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    • v.25 no.2
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    • pp.260-270
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    • 1998
  • The field tests were performed to suggest the rational method for stability evaluation of soft clay. The behavior of settlement-displacement obtained by field monitoring system was to compare and analyze the results of the observationed method, and to investigate the complex behavior of soft clay with filling height. The results of this study are summarized as follows. 1. The horizontal displacement was suddenly increased when physical properties of soft clay showed maximum values and the part of the turning point. The values of these properties were available to the fundamental data for stability evaluation. The shear deformation appeared that difference of the horizontal displacement was maximum values. 2. Although the stability of embankment by step filling showed the unstable part over the failure standard line, the embankment was confirmed stable. So the evaluation of the stability of embankment is reasonable to use the inclination of curve than failure standard line. 3. The horizontal displacement and relative settlement were increased as same ratio at improvement ground. Estimation of shear deformation using Terzaghi's modified bearing capacity should consider the relations of embankment load and undrained shear strength at nonimprovement ground, and minimum safety factor is recommended to use larger than 1.2. 4. Excess pore water pressure was increased with increasing of filling height and decreased with maintain the filling height. The embankment was unstable when filling height was exceed the evaluation standard line, and the behavior of excess pore water pressure and horizontal displacement could use as a standard of judgement of the filling velocity control because their behavior were agree with each other.

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Preparation and Characterization of Heterogeneous Anion Exchange Membrane for Recovery of Sulfate Ion from Waste Water (폐수 중 황산이온 회수를 위한 불균질 음이온교환막의 제조 및 특성)

  • Choi, Kuk-Jong;Choi, Jae-Hwan;Hwang, Eui-Hwan;Rhee, Young-Woo;Hwang, Taek-Sung
    • Polymer(Korea)
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    • v.31 no.3
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    • pp.247-254
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    • 2007
  • Heterogeneous anion exchange membranes were prepared by compression molding for the recovery of sulfate ion from waste water. The swelling ratio, transport number, and ion exchange capacity of the heterogeneous anion exchange membranes were increased and their electrical resistances were decreased as the amount of ion exchange resin content in the matrix was raised. The tensile strength of the heterogeneous anion exchange membrane was decreased with increasing the amount of ion exchange resin in the LLDPE. The tensile strength for the LDPE heterogeneous membrane containing 30 wt% anion exchange resin showed the highest value. The water content increased with increasing amount of ion exchange resin in the membrane. Moreover the highest transport number of the membrane was 0.86. The electrical resistance of LDPE matrix membrane with 50 wt% resin showed $46.5{\Omega}{\cdot}cm^2$. Current efficiency of electrodialysis for sulfate ion showed the highest value at the current density of $125 mA/cm^2$ in 0.5 mol/L sulfuric acids solution.

Effects of Invasive Low Level Laser Acupuncture Therapy(LLLAT) depending on capacity at LU7+LR5 on the Hyperlipemia Rats Induced by High Fat Diet (열결(列缺).려구에 대한 용량별 He-Ne 레이저 침 조사(照射)가 고지방(高脂肪) 식이(食餌)로 유발된 고지혈증(高脂血症) 백서(白鼠)에 미치는 영향(影響))

  • Bang, Sang-Hee;Youn, Dae-Hwan;Cho, Myung-Re;Yim, Hyun-Jin;Na, Chang-Su
    • Korean Journal of Acupuncture
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    • v.23 no.1
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    • pp.1-14
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    • 2006
  • Objectives : This research was performed to investigate the effect of invasive low level laser acupuncture therapy(LLLAT) at Yolgyol+yogu(LU7+LR5) on weight gain, food intake, food efficiency, lipid metabolism and liver function in hyperlipemia rats. Methods : Experimental groups were divided into high fat diet cup(Control group), high fat diet and 15 mW/5 min LLLAT at LU7+LR5(15 mW/5 min group), 15 mW/10 min LLLAT at LU7+LR5(15 mW/10 min group), 30 mW/5 min LLLAT at LU7+LRS(30 mW/5 min group), 30 mW/10 min LLLAT at LU7+LR5(30 mW/10 min group). LLLAT was treated at the 15,30mW-5,10min once a 2day during 5 weeks. Results : Body weight was decreased significantly in 30 mW/s min group and 30 mW/10 min group compared with control group. Food intake was decreased significantly in 15 mW/5 min group and 15 mW/10 min group compared with control group. Food efficiency was decreased significantly in 30 mW/10 min group compared with control group. In the lipid metabolism, total cholesterol, HDL-cholesterol and free fatty acid were increased significantly in 15 mW/5 min group and 30 mW/10 min group compared with control group. LDL-cholesterol was increased in 30 mW/10 min group and phospholipids was decreased significantly in all experimental group compared with control group. triglyceride was not showed significant result in all experimental group. In the liver function, AST was not showed significant result in all experimental group, ALT and ALP were increased significantly in 30 mW/10 min group, ALP was decreased in 30 mW/5 min group compared with control group. Conclusions : LLLAT at LU7 and LR5 can manage hyperlipemia by controlling body weight, food intake, food efficiency ratio and lipid metabolism.

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Effect of Dietary Persimmon Peel Powder on Physico-Chemical Properties of Pork (감 껍질 분말의 급여가 돈육의 이화학적 특성에 미치는 영향)

  • Kim Young-Jik;Kim Byung-Ki
    • Food Science of Animal Resources
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    • v.25 no.1
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    • pp.39-44
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    • 2005
  • Effects of persimmon peel powder on physico-chemical properties in 60 pigs was investigated. The pigs were randomly assigned to one of the four dietary treatments: 1) Control (commercial feed) 2) T1 (commercial feed supplemented with 1% persimmon peel powder) 3) T2 (commercial feed supplemented with 3% persimmon peel powder) 4) T3 (commercial feed supplemented with 5% persimmon peel powder). In proximate composition, moisture of pork from treatment groups were decreased by addition level increased than that of control but crude fat was increased (p<0.05). Crude protein and crude ash was no significantly difference. The total cholesterol, HDL-cholesterol and triglyceride of treatment groups was higher than that of control.. LDL-cholesterol of control was higher than that of treatment groups. The WHC (water holding capacity) of control was higher than treatment groups and shear value was higher in treatments group (p<0.05). pH was not significantly different between control and treatment groups. The hardness, juiciness and flavor of sensory evaluation were improved by treatments, especially in T3 (p<0.05). The meat color of treatment group showed whiter and redder than that of control owing to higher L/sup */, a/sup */ and b/sup */ value. In fatty acids, stearic acid contents of treatment groups were higher than that of control. The unsaturated fatty acid/saturated fatty acid ratio of the control, T1 T2 and T3 were 1.78, 1.71. 1.69 and 1.66, respectively and control had higher than the treatment groups. The hardness, juiciness and flavor of sensory evaluation were improved by treatments, especially in T3 (p<0.05).

Improvement of Oxidative Stability for Non-fluorinated Membranes Prepared by Substituted Styrene Monomers (스티렌 유도체를 이용한 비불소계 고분자 전해질막의 산화적 안정성 개선)

  • Moon, Seung-Hyeon;Woo, Jung-Je;Fu, Rong-Qiang;Seo, Seok-Jun;Yun, Sung-Hyun
    • Membrane Journal
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    • v.17 no.4
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    • pp.294-301
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    • 2007
  • To improve oxidative stability of non-fluorinated styrene-based polymer electrolyte membranes, copolymerized membranes were prepared using styrene derivatives such as p-methylstyrene, t-butylstyrene, and ${\alpha}-methylstyrene$ by monomer sorption method. Prepared membrane was characterized by measurement of weight gain ratio, water content, ion-exchange capacity, proton conductivity, and oxidative stability under the accelerated condition. It was found that each step of monomer sorption method including sorption, polymerization and sulfonation could be affected by the properties and the structures of styrenederivatives. Due to difficulty of polymerization, ${\alpha}$-methylstyrene was copolymerized with styrene or p-methylstyrene. Prepared membrane using ${\alpha}-methylstyrene$ and styrene showed higher performance and stability comparing to copolymerized membrane with styrene. However, copolymerized membranes with ${\alpha}-methylstyrene$ did not showed much improved oxidative stability comparing to styrene membrane due to their lower molecular weight. The t-butylstyrene membrane showed a low performance due to substituted bulky-butyl group which prevents sorption and sulfonation reaction. However, copolymerized t-butylstyrene membranes with p-methylstyrene showed good performance and much improved stability than the styrene membranes.

Effects of Aging and Soil Texture on Composting of Diesel-Contaminated Soil (디젤오염기간 및 토성이 오염토양 콤포스팅 처리에 미치는 영향)

  • Choi, Jung-Young;Namkoong, Wan;Park, Joon-Seok;Hwang, Eui-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.2
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    • pp.132-139
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    • 2002
  • This study was carried out to investigate the effects of aging and soil texture on composting of diesel-contaminated soil. The soils used for this study were silt loam and sand. Target contaminant, diesel oil, was spiked at 10,000mgTPH/kg of dry soil. Aging times of diesel-contaminated soils were 15days and 60days, respectively. Fresh diesel-contaminated soil was also investigated. Moisture content was controlled to 70% of soil field capacity. Mix ratio of soil to sludge was 1:0.3 as wet weight basis. Temperature was maintained at $20^{\circ}C$ Volatilization loss of TPH was below 2% of initial concentration. n-Alkanes lost by volatilization were mainly by the compounds of C10 to C17. Diesel in contaminated soil was mainly removed by biodegradation mechanism. First order degradation rate constant of TPH in sandy soil was ranged from 0.081 to 0.094/day, which is higher than that in silt loam(0.056-0.061/day). From fresh to 60day-aged soils, there was little difference of TPH biodegradation rate between the soils. Carbon recovery ranged from 0.61 to 0.89. TPH degradation rate was highly correlated with $CO_2$ production rate.

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Changes of Soil Properties and Evaluation of Plant Utilization According to the Application of Compost Used with Phyllite (Phyllite를 이용한 퇴비 시용에 따른 토양 특성 변화 및 작물에 대한 효용성 평가)

  • Park, Young-Hee;Chang, Ki-Woon;Hong, Jei-Gu
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.2
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    • pp.92-99
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    • 2002
  • The study was conducted to investigate the changes of soil properties and evaluation of plant utilization according to the application of compost used with phyllite. At this experiment, the plant cultivation test(lettuce and radish plant) was carried out to know about physico-chemical properties of compost, humus degradarion and stabilization degree, and some effects among rhe treatments were best at 20Mg/ha in PSPC 10(Phyllite, Saw dust, Pig manure Compost) plots and ar 10Mg/ha in PSPC 20 treatments, respectively. The EC value was high in the compost. Therefore the EC was appeared more than 2ds/m at the applied 40Mg/ha with compost. And in case of lettuce, Avail.-$P_2O_5$ and EC were more increased than in the radish plots, highly. In contrast, in case of radish, Toral-N, Total-C, and EC contents were decreased after plant cultivation. That is, it could know that radish was fond of absorprion of nitrogen. Also, BD values of soil physical properties were decreased according to increasing of phyllite addition ratio, however water holding capacity(WHC) was increased. The plant test had not been darnaged through the application of compost used with phyllite in soil and there had not been worse on changing of soil physico-chemical properties. Consequently, phyllite composts have been thought on agricultural utilized possibility.

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Water Balance Analysis of Pumped-Storage Reservoir during Non-Irrigation Period for Recurrent Irrigation Water Management (순환형 농업용수관리를 위한 농업용 저수지의 비관개기 양수저류 추정)

  • Bang, Na-Kyoung;Nam, Won-Ho;Shin, Ji-Hyeon;Kim, Han-Joong;Kang, Ku;Baek, Seung-Chool;Lee, Kwang-Ya
    • Journal of The Korean Society of Agricultural Engineers
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    • v.62 no.4
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    • pp.1-12
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    • 2020
  • The extreme 2017 spring drought affected a large portion of South Korea in the Southern Gyeonggi-do and Chungcheongnam-do districts. This drought event was one of the climatologically driest spring seasons over the 1961-2016 period of record. It was characterized by exceptionally low reservoir water levels, with the average water level being 36% lower over most of western South Korea. In this study, we consider drought response methods to alleviate the shortage of agricultural water in times of drought. It could be to store water from a stream into a reservoir. There is a cyclical method for reusing water supplied from a reservoir into streams through drainage. We intended to present a decision-making plan for water supply based on the calculation of the quantity of water supply and leakage. We compared the rainfall-runoff equation with the TANK model, which is a long-term run-off model. Estimations of reservoir inflow during non-irrigation seasons applied to the Madun, Daesa, and Pungjeon reservoirs. We applied the run-off flow to the last 30 years of rainfall data to estimate reservoir storage. We calculated the available water in the river during the non-irrigation season. The daily average inflow from 2003 to 2018 was calculated from October to April. Simulation results show that an average of 67,000 tons of water is obtained during the non-irrigation season. The report shows that about 53,000 tons of water are available except during the winter season from December to February. The Madun Reservoir began in early October with a 10 percent storage rate. In the starting ratio, a simulated rate of 4 K, 6 K, and 8 K tons is predicted to be 44%, 50%, and 60%. We can estimate the amount of water needed and the timing of water pump operations during the non-irrigation season that focuses on fresh water reservoirs and improve decision making for efficient water supplies.

Comparison of the Total Phenolic and Flavonoid Contents and Antioxidant Activities of Four Kinds of Sand Dune Plants Living in Taean, Korea (태안에서 서식하는 사구식물 4종의 폴리페놀, 플라보노이드 함량과 항산화 활성 비교)

  • Kim, Soon-seok;Cha, Hyeon-cheol
    • Korean Journal of Plant Resources
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    • v.30 no.1
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    • pp.8-16
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    • 2017
  • This study attempted to investigate the antioxidant properties of four different species of sand dune plants (Calystegia soldanella, Messerschmidia sibirica, Vitex rotundifolia and Rosa rugosa). In order to validate the antioxidant activity of these plants, we first determined the total amount of flavonoid versus phenolic contents (TFC/TPC) and extracted crude flavonoids for measuring antioxidant activities that were determined by DPPH, ABTS and FRAP assays with radical scavenging effects. We found that highest amounts of TPC were detected in R. rugose with values of 110.20 mg/g (leaves) and 65.71 mg/g (stems), while the highest amounts of TFC in V. rotundifolia with values of 38.07 mg/g (leaves) and 6.55 mg/g (stems). We further examined how closely related the amounts of TFC/TPC in antioxidant activities and found that R. rugose has the highest activities of radical scavenging with values of $63.4{\mu}g/ml$ and $51.2{\mu}g/ml$ determined by DPPH and ABTS assays compared with the value of $21.2{\mu}g/ml$ by FRAP assay. It is of note that there is a statistically significant correlation between the resulting antioxidant activities and the total ratio of TFC and TPC, suggesting that the different amounts of TFC/TPC may directly contribute to the various antioxidant activities.