• Journal of the Korean Applied Science and Technology
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• v.36 no.1
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• pp.200-207
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• 2019

In this study, flexible supercapacitor based on the all solid state electrolyte with PVA (polyvinyl alcohol)-$H_3PO_4$, ionic liquid as a BMIMBF4 (1-buthyl-3-methylimidazolium tetrafluoroborate) and reduced graphene oxide/conductive polymer composite was fabricated and characterized electrochemical properties with function of its flexibility. In order to measure and compare that electrochemical performances (including cyclic voltammetry(CV), electrochemical impedance spectroscopy(EIS) and galvanostatic charge/discharge,after 0~100th bending test) of prepared flexible supercapacitor based on reduced graphene oxide/conducting polymer composite and all solid state electrolyte, we have conducted press machine with constant pressure ( 0.01/cm2) for $100^{th}$ bending test. As a result, specific capacitance of the flexible supercapacitor was 43.9 F/g which value decreased to 42.0 and 40.1 F/g after 50 and $100^{th}$ bending test, respectively. This result exhibited that decreased electrochemical property of the flexible supercapacitor effected on physical stress on the electrode after repeated bending test. In addition, we have measured that electrode surface morphology by SEM to prove its decreased electrochemical property of the flexible supercapacitor after prolonged bending test.

• Journal of the Korea Institute of Building Construction
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• v.22 no.6
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• pp.651-662
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• 2022

The electrochemical impedance spectroscopy(EIS) method was used to evaluate the concrete deterioration process related to chloride-induced steel corrosion with various corrosion levels(initiation, rust propagation and acceleration periods). The impressed current technique, with four total current levels of 0C, 13C, 65C and 130C, was used to accelerate steel corrosion in concrete cylinder samples with w/c ratio of 0.4, 0.5, and 0.6, immersed in a 0.5M NaCl solution. A series of EIS measurements was performed to monitor concrete deterioration during the accelerated corrosion test in this study. Some critical parameters of the equivalent circuit were obtained through the EIS analysis. It was observed that the charge transfer resistance(R_c) dropped sharply as the impressed current increased from 0C to 13C, indicating a value of approximately 10kΩcm². However, the sensitivity of R_c significantly decreased when the impressed current was further increased from 13C to 130C after corrosion of steel had been initiated. Meanwhile, the double-layer capacitance value(C_dl) linearly increased from 50×10^-6μF/cm² to 250×10^-6μF/cm² as the impressed current in creased from 0C to 130C. The results in this study showed that monitoring C_dl is an effective measurement parameter for evaluating the progress of internal concrete damages(de-bonding between steel and concrete, micro-cracks, and surface-breaking cracks) induced by steel corrosion. The findings of this study provide a fundamental basis for developing an embedded sensor and signal interpretation method for monitoring concrete deterioration due to steel corrosion at various corrosion levels.

• Journal of the Korean Vacuum Society
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• v.16 no.5
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• pp.330-337
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• 2007

Influence of glass dielectric property (dielectric constant K, dielectric loss) on the external electrode fluorescent lamps of the dielectric barrier discharge has been investigated with 4-different glasses. Conventional borosilicate glass tubes with $K=5.6{\sim}5.9$ and tan ${\delta}=5.0{\times}10^{-3}{\sim}6.0{\times}10^{-3}$ and aluminosilicate glass tubes with high K=6.6 and low tan ${\delta}=1{\times}10^{-4}$ and soda-lime glass tribes with K=7.7 and tan ${\delta}=1.37{\times}10^{-2}$ have been compared. The high value of dielectric constant K makes the capacitance of external electrode fluorescent lamps intensity and enhances the discharge efficiency. The dielectric loss of tan ${\delta}$ shows the factor of power consumption in the external electrode to induce heats and to be weak in pinhole stability. The aluminosilicate glass tubes of high K and low tan ${\delta}$ have been enhanced by $14{\sim}18%$ in luminance and efficiency in comparison with the conventional borosilicate glass tubes and the aluminosilicate external electrode fluorescent lamps are strong against the pinhole formation. Soda-lime glass tubes with high K and high tan ${\delta}$ are a little favorable in luminance and efficiency and they are very weak in pinhole occurrence.