• Title/Summary/Keyword: Canisters

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Electrochemical corrosion behavior of atmospheric-plasma-sprayed copper as a coating material for deep geological disposal canisters

  • Sung-Wook Kim;Gha-Young Kim;Young-Ho Lee;Jun-Hyuk Jang;Chung-Won Lee;Jeong-Hyun Woo;Seok Yoon
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.4032-4038
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    • 2023
  • Cu, which exhibits excellent corrosion resistance in underground environments, has been investigated as a canister material for use in the deep geological disposal of spent nuclear fuels. In this study, the technical viability of atmospheric plasma spraying for producing Cu-coated canisters was investigated. A high-purity Cu film (millimeter scale) was deposited onto a stainless-steel substrate using a plasma gun with a shroud structure. Potentiodynamic polarization studies revealed that the Cu film exhibited a sufficiently low corrosion rate in the groundwater electrolyte. In addition, no pitting corrosion was observed on the Cu film surface after accelerated corrosion studies. A prototype cylindrical Cu film was fabricated on a 1/20 scale on a stainless-steel tube to demonstrate the scalability of atmospheric plasma spraying in producing Cu-coated canisters.

Array Design of HLW Canisters considering Thermal Concentrations (암반내 열접중을 고려한 고준위 폐기물 캐니스터의 배열설계)

  • 양형식;이춘우
    • Tunnel and Underground Space
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    • v.4 no.3
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    • pp.256-260
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    • 1994
  • HLW canister array was designed by FLLSSM program, considering the thermal concentration. Rock properties were chosen as those of granite, the most possible bedrock for the repository in Korea. It was shown that repository area and excavation volumes can be determined by the pitch or distance between canisters. Pitch can be reduced to 0.6 m assuming the tolerance temperature as 200$^{\circ}C$. Thermal concentration was reduced as storage time for cooling the canister passed. After 10 years of storage the thermal problems seemed to be negligible.

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Quality Control(QC) Analysis of Ambient VOCs in Canisters Using GC/MSD Method (Canister와 GC/MSD를 이용한 대기 중 VOCs 분석시스템의 정도관리(QC))

  • Jeon, Jun-Min;Hur, Dang;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.6
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    • pp.527-538
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    • 2002
  • In this study, the performance of sampling and of analytical methodology was examined against a number of selected volatile organic compounds (VOCs) in the ambient air. The canister-based sampling method for VOCs has been a viable and widely used approach that is based on research and evaluation performed over the past several years. VOCs were determined using canisters by GCMSD analysis. A total of target analyses in this study included approximately 30 VOCs designated in TO-l4A categories including BTEX. The methodology for QC(quality control) was intensively investigated with a wide range of performance criteria such as; (1) cleanliness of canisters, (2) reproducibility of diluter, (3) instrumental detection limits of preconcentrator and GCMSD, and (4) precision and accuracy of GCMSD. For most of the compounds tested, precision was less than $\pm$5%, IDL was 0.2 ppbv, accuracy was $\pm$5%, respectively. This study demonstrated that the combination of canister sampling and GC/MSD analysis could be reliably applied to the measurements of BTEX in ppbv levels that are typically observed in/outdoor air environment.

Thermal Analysis of High Level Radioactive Waste Repository Using a Large Model

  • Park, Jeong-Hwa;Kuh, Jung-Eui;Sangki Kwon;Kang, Chul-Hyung
    • Nuclear Engineering and Technology
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    • v.32 no.3
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    • pp.244-253
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    • 2000
  • A Simple Large Model (SLM), which can be used to make thermal calculation for a deep geological repository with finite number of HLW canisters, was developed. In order to develop the SLM, a Simple Basic Model (SBM), which will be a unit of the SLM, was optimized first. The SBM was optimized to achieve the same maximum buffer temperature as that of the Detailed Basic Model (DBM) representing the real geometric aspects of the repository. In contrast to the models with the assumption of infinite number of canisters which cannot consider boundary effect, the SLM can model the real repository with finite number of canisters and thus consider the boundary effect. Thermal results from the SLM can be used to evaluate the reliability of the models, which do not consider boundary effect. This model can also be used to simulate the thermal layout design and to analyze the thermal safety of a deep geological repository as well as an underground laboratory.

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Monte Carlo simulations of criticality safety assessments of transuranic element storage in a pyroprocess facility

  • Kim, Jinhwan;Kim, Jisoo;Lim, Kyung Taek;Ahn, Seong Kyu;Park, Se Hwan;Cho, Gyuseong
    • Nuclear Engineering and Technology
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    • v.50 no.6
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    • pp.815-819
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    • 2018
  • In this study, criticality safety assessments of the potential for storing transuranic element (TRU) ingots via a pyroprocess were evaluated to determine the appropriate TRU storage design parameters, in this case the ratio of the TRU ingot height to the radius and the number of TRU ingot canisters stacked within a container. Various accident situations were modeled over a modeling period of 5 years for a cumulative inventory of TRU ingots with various water densities in submerged containers and with various pitches between the containers in the facility. Under these combinations, we calculated the threshold of TRU height and radius ratio depending on the number of canisters in a container to keep the stored TRU in a subcritical state. The ratio of the TRU ingot height to radius should not exceed 4.5, 1.1, 0.5, 0.3, and 0.2 for two, three, four, five, and six levels of stacked canisters in a container, respectively.

Pressure Loss in Canisters with Conditions of Activated Carbon Particles (활성탄 입자 조건에 따른 정화통의 압력손실 특성에 관한 연구)

  • Kim, Min-Wook;Kim, Young-Soo;Park, Yong-Hwan
    • Fire Science and Engineering
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    • v.31 no.4
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    • pp.7-11
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    • 2017
  • The use of special gas masks such as PAPR is strongly required for the safe and efficient work of fire-fighters in removing fire residue and rescue activity. Special gas masks commonly use canisters with carbon activated particles. This paper analyzed the pressure distribution, velocity distribution and pressure loss characteristics in canisters using CFD simulation, and showed pressure drops are affected by inlet air velocity, canister geometry and increase dramatically especially with the decrease of particle diameters and volume fractions.

Thermal conductivity prediction model for compacted bentonites considering temperature variations

  • Yoon, Seok;Kim, Min-Jun;Park, Seunghun;Kim, Geon-Young
    • Nuclear Engineering and Technology
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    • v.53 no.10
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    • pp.3359-3366
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    • 2021
  • An engineered barrier system (EBS) for the deep geological disposal of high-level radioactive waste (HLW) is composed of a disposal canister, buffer material, gap-filling material, and backfill material. As the buffer fills the empty space between the disposal canisters and the near-field rock mass, heat energy from the canisters is released to the surrounding buffer material. It is vital that this heat energy is rapidly dissipated to the near-field rock mass, and thus the thermal conductivity of the buffer is a key parameter to consider when evaluating the safety of the overall disposal system. Therefore, to take into consideration the sizeable amount of heat being released from such canisters, this study investigated the thermal conductivity of Korean compacted bentonites and its variation within a temperature range of 25 ℃ to 80-90 ℃. As a result, thermal conductivity increased by 5-20% as the temperature increased. Furthermore, temperature had a greater effect under higher degrees of saturation and a lower impact under higher dry densities. This study also conducted a regression analysis with 147 sets of data to estimate the thermal conductivity of the compacted bentonite considering the initial dry density, water content, and variations in temperature. Furthermore, the Kriging method was adopted to establish an uncertainty metamodel of thermal conductivity to verify the regression model. The R2 value of the regression model was 0.925, and the regression model and metamodel showed similar results.

Influence of Microbial Activity on the Long-Term Alteration of Compacted Bentonite/Metal Chip Blocks

  • Lee, Seung Yeop;Lee, Jae-Kwang;Kwon, Jang-Soon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.4
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    • pp.469-477
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    • 2021
  • Safe storage of spent nuclear fuel in deep underground repositories necessitates an understanding of the long-term alteration of metal canisters and buffer materials. A small-scale laboratory alteration test was performed on metal (Cu or Fe) chips embedded in compacted bentonite blocks placed in anaerobic water for 1 year. Lactate, sulfate, and bacteria were separately added to the water to promote biochemical reactions in the system. The bentonite blocks immersed in the water were dismantled after 1 year, showing that their alteration was insignificant. However, the Cu chip exhibited some microscopic etch pits on its surface, wherein a slight sulfur component was detected. Overall, the Fe chip was more corroded than the Cu chip under the same conditions. The secondary phase of the Fe chip was locally found as carbonate materials, such as siderite (FeCO3) and calcite ((Ca, Fe)CO3). These secondary products can imply that the local carbonate occurrence on the Fe chip may be initiated and developed by an evolution (alteration) of bentonite and a diffusive provision of biogenic CO2 gas. These laboratory scale results suggest that the actual long-term alteration of metal canisters/bentonite blocks in the engineered barrier could be possible by microbial activities.

Thermal Analysis of a Horizontal Disposal System for High-level Radioactive Waste (수평 터널방식 고준위폐기물 처분시스템 주변 열 해석)

  • Choi, Heui-Joo;Kim, In-Young;Lee, Jong Youl;Kim, Hyun Ah
    • Tunnel and Underground Space
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    • v.23 no.2
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    • pp.141-149
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    • 2013
  • The thermal analysis is carried out for a geological disposal system developed for the final disposal of a ceramic high-level waste from pyroprocessing of PWR spent fuel. The horizontal disposal tunnel type is considered with the distance of 2 m between the disposal canisters and the tunnel spacing of 25 m. The temperature distributions around the disposal canisters are calculated for the horizontal tunnel based on the conceptual design. The thermal performance analysis is carried out using a FEM program, ABAQUS. The performance analysis shows that the peak temperature in a disposal system outside the disposal canister is lower than $100^{\circ}$, which meets the thermal criterion of the disposal system. According the analysis, the peak temperature for the disposal canister located boundary of the disposal system is lower by $3^{\circ}$ than that for the canister at the central area. This implies the disposal density can be improved by locating more disposal canisters along the boundary.

A Study on the Pressure Vessel containing tension material used the Prestressed Concept (프리스트레스트 개념을 적용한 긴장재가 구비된 압력용기 연구)

  • Yim, Heon-Wook
    • Journal of Convergence for Information Technology
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    • v.7 no.5
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    • pp.103-109
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    • 2017
  • A pressure vessel is a cylindrical container that accommodates a pressurized fluid. In real life, there are propane canisters and butane canisters. According to data from the Korea Gas Safety Corporation, The number of domestic gas accidents is average 33 cases of domestic gas accidents occurred per year and 20.8 for mobile butane gases. The purpose of this study was to investigate a method to prevent this kind of explosion. Common studies include forced drain through safe holes, forced separation of butane canisters, and manufacturing of high-strength steel. This paper uses a concept that reduces stress inside the cylinder using prestressed method that precede compression. In other words, install a long liner in both ends of the pressure vessel. I want to develop a safety device that acts like a gas intermediate valve.